United States Office of Solid Waste EPA 550-B-01-003
Environmental Protection and Emergency Response October 2001
Agency (5104) www.epa.gov/ceppo
LIST OF LISTS
Consolidated List of Chemicals
Subject to the
Emergency Planning and
Community Right-To-Know Act
(EPCRA) and Section 112(r) of
the Clean Air Act
EPCRA Section 302 Extremely Hazardous Substances
CERCLA Hazardous Substances
EPCRA Section 313 Toxic Chemicals
CAA 112(r) Regulated Chemicals For Accidental Release
Prevention
Chemical Emergency Preparedness and Prevention Office Printed on recycled paper
TABLE OF CONTENTS
Page
Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . i
List of Lists -- Consolidated List of Chemicals (by CAS #) Subject to the Emergency Planning and
Community Right-to-Know Act (EPCRA) and Section 112(r) of the Clean Air Act . . . . . . . . . 1
Appendix A: Alphabetical Listing of Consolidated List . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . A-1
Appendix B: Radionuclides Listed Under CERCLA . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . B-1
Appendix C: RCRA Waste Streams and Unlisted Hazardous Wastes . . . . . . . . . . . . . . . . . . . . . . . . . C-1
LIST OF LISTS
Consolidated List of Chemicals Subject to the Emergency Planning and
Community Right-to-Know Act (EPCRA) and Section 112(r) of the Clean Air Act
This consolidated chemical list includes chemicals subject to reporting requirements under the
Emergency Planning and Community Right-to-Know Act (EPCRA), also known as Title III of the
Superfund Amendments and Reauthorization Act of 1986 (SARA)1, and chemicals listed under section
112(r) of the Clean Air Act (CAA). This consolidated list has been prepared to help firms handling
chemicals determine whether they need to submit reports under sections 302, 304, or 313 of EPCRA and,
for a specific chemical, what reports may need to be submitted. It will also help firms determine whether
they will be subject to accident prevention regulations under CAA section 112(r). Separate lists are also
provided of Resource Conservation and Recovery Act (RCRA) waste streams and unlisted hazardous
wastes, and of radionuclides reportable under the Comprehensive Environmental Response,
Compensation, and Liability Act of 1980 (CERCLA). These lists should be used as a reference tool, not
as a definitive source of compliance information. Compliance information for EPCRA is published in
the Code of Federal Regulations (CFR), 40 CFR Parts 302, 355, and 372. Compliance information for
CAA section 112(r) is published in 40 CFR Part 68. This document is also available in a searchable
database format at http://www.epa.gov/ceppo/ap-otgu.htm.
The chemicals on the consolidated list are ordered both by the Chemical Abstracts Service (CAS)
registry number and alphabetically. For the list ordered by CAS number, categories of chemicals which
generally do not have CAS registry numbers, but which are cited under CERCLA, are placed at the front
of the list. EPCRA section 313 categories are placed at the end of the list with their 313 category code.
The lists include chemicals referenced under five federal statutory provisions, discussed below.
More than one chemical name may be listed for one CAS number because the same chemical may appear
on different lists under different names. For example, for CAS number 8001-35-2, the names toxaphene
(from the section 313 list), camphechlor (from the section 302 list), and camphene, octachloro- (from the
CERCLA list) all appear on this consolidated list. The chemical names on the consolidated lists
generally are those names used in the regulatory programs developed under EPCRA, CERCLA, and CAA
section 112(r), but each chemical may have other synonyms that do not appear on these lists.
(1) EPCRA Section 302 Extremely Hazardous Substances (EHSs)
The presence of EHSs in quantities at or above the Threshold Planning Quantity (TPQ) requires
certain emergency planning activities to be conducted. The extremely hazardous substances and their
TPQs are listed in 40 CFR Part 355, Appendices A and B. For section 302 EHSs, Local Emergency
Planning Committees (LEPCs) must develop emergency response plans and facilities must notify the
State Emergency Response Commission (SERC) and LEPC if they receive or produce the substance on
site at or above the EHS's TPQ. Additionally if the TPQ is met, facilities with a listed EHS are subject
to the reporting requirements of EPCRA section 311 (provide material safety data sheet or a list of
covered chemicals to the SERC, LEPC, and local fire department) and section 312 (submit inventory
1
This consolidated list does not include all chemicals subject to the reporting requirements in EPCRA
sections 311 and 312. These hazardous chemicals, for which material safety data sheets (MSDS) must be developed
under the Hazard Communication Standard (29 CFR 1910.1200), are identified by broad criteria, rather than by
enumeration. There are over 500,000 products that satisfy the criteria. See 40 CFR Part 370 for more information.
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form - Tier I or Tier II). The minimum threshold for section 311-312 reporting for EHS substances is
500 pounds or the TPQ, whichever is less.
TPQ. The consolidated list presents the TPQ (in pounds) for section 302 chemicals in the
column following the CAS number. For chemicals that are solids, there may be two TPQs given (e.g.,
500/10,000). In these cases, the lower quantity applies for solids in powder form with particle size less
than 100 microns, or if the substance is in solution or in molten form. Otherwise, the 10,000 pound TPQ
applies.
EHS RQ. Releases of reportable quantities (RQ) of EHSs are subject to state and local reporting
under section 304 of EPCRA. EPA has promulgated a rule (61 FR 20473, May 7, 1996) that adjusted
RQs for EHSs without CERCLA RQs to levels equal to their TPQs. The EHS RQ column lists these
adjusted RQs for EHSs not listed under CERCLA and the CERCLA RQs for those EHSs that are
CERCLA hazardous substances (see the next section for a discussion of CERCLA Rqs).
Note that ammonium hydroxide is not covered under section 302; the EHS RQ is based on
anhydrous ammonia. Ammonium hydroxide (which is also known as aqueous ammonia) is subject to
CERCLA, with its own RQ.
(2) CERCLA Hazardous Substances
Releases of CERCLA hazardous substances, in quantities equal to or greater than their reportable
quantity (RQ), are subject to reporting to the National Response Center under CERCLA. Such releases
are also subject to state and local reporting under section 304 of EPCRA. CERCLA hazardous
substances, and their reportable quantities, are listed in 40 CFR Part 302, Table 302.4. Radionuclides
listed under CERCLA are provided in a separate list, with RQs in Curies.
RQ. The CERCLA RQ column in the consolidated list shows the RQs (in pounds) for chemicals
that are CERCLA hazardous substances. Carbamate wastes under RCRA that have been added to the
CERCLA list with statutory one-pound RQs are indicated by an asterisk ("*") following the RQ.
Metals. For metals listed under CERCLA (antimony, arsenic, beryllium, cadmium, chromium,
copper, lead, nickel, selenium, silver, thallium, and zinc), no reporting of releases of the solid form is
required if the mean diameter of the pieces of the solid metal released is greater than 100 micrometers
(0.004 inches). The RQs shown on the consolidated list apply to smaller particles.
Note that the consolidated list does not include all CERCLA regulatory synonyms. See 40 CFR
Part 302, Table 302.4 for a complete list.
There have been a few additions and deletions to Table 302.4 since this document was last
updated (November 1998). Hazardous wastes K174 and K175 have been added to this list. Removed
from Table 302.4 are caprolactam (CAS 105-60-2), 2,4,6-tribromophenol (CAS 118-79-6), and K140
floor sweepings, off-specification products and spent filtermedia from the production of 2,4,6-
tribromophenol.
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(3) CAA Section 112(r) List of Substances for Accidental Release Prevention
Under the accident prevention provisions of section 112(r) of the CAA, EPA developed a list of
77 toxic substances and 63 flammable substances. Threshold quantities (TQs) were established for these
substances. The list and TQs identify processes subject to accident prevention regulations. The list of
substances and TQs and the requirements for risk management programs for accidental release
prevention are found in 40 CFR Part 68. This consolidated list includes both the common name for each
listed chemical under section 112(r) and the chemical name, if different from the common name, as
separate listings.
The CAA section 112(r) list includes several substances in solution that are covered only in
concentrations above a specified level. These substances include ammonia (concentration 20% or
greater) (CAS number 7664-41-7); hydrochloric acid (37% or greater) (7647-01-0); hydrogen
fluoride/hydrofluoric acid (50% or greater) (7664-39-3); and nitric acid (80% or greater) (7697-37-2).
Hydrogen chloride (anhydrous) and ammonia (anhydrous) are listed, in addition to the solutions of these
substances, with different TQs. Only the anhydrous form of sulfur dioxide (7446-09-5) is covered.
These substances are presented on the consolidated list with the concentration limit or specified form
(e.g., anhydrous), as they are listed under CAA section 112(r). Flammable fuels used as a fuel or held for
sale as a fuel at a retail facility are not subject to the rule.
TQ. The CAA section 112(r) TQ column in the consolidated list shows the TQs (in pounds) for
chemicals listed for accidental release prevention. The TQ applies to the quantity of substance in a
process, not at the facility as a whole.
(4) EPCRA Section 313 Toxic Chemicals
Emissions, transfers, and waste management data for chemicals listed under section 313 must be
reported annually as part of the community right-to-know provisions of EPCRA (40 CFR Part 372).
Section 313. The notation "313" in the column for section 313 indicates that the chemical is
subject to reporting under section 313 and section 6607 of the Pollution Prevention Act under the name
listed. In cases where a chemical is listed under section 313 with a second name in parentheses or
brackets, the second name is included on this consolidated list with an "X" in the section 313 column.
An "X" in this column also may indicate that the same chemical with the same CAS number appears on
another list with a different chemical name. Since the last updating of the list in November 1998, a
number of reporting thresholds have changed. These include reporting thresholds for 18 chemicals that
meet the EPCRA section 313 criteria for persistence and bioaccumulation, as well as lead and lead
compounds (except lead contained in stainless steel, brass, and bronze alloys). Chemicals that have had
reporting thresholds changed are marked with a " ^ " symbol on the list. The revised thresholds are listed
at the end of this section.
Diisocyanates, Dioxins and Dioxin-like Compounds, and PACs. In the November 30, 1994,
expansion of the section 313 list, 20 specific chemicals were added as members of the diisocyanate
category, and 19 specific chemicals were added as members of the polycyclic aromatic compounds
(PAC) category. In October 1999, EPA added a category of dioxin and dioxin-like compounds that
includes 17 specific chemicals. These chemicals are included in the CAS order listing on this
consolidated list. The symbol "#" following the "313" notation in the section 313 column identifies
diisocyanates, the symbol "!" identifies the dioxin and dioxin-like compounds, and the symbol "+"
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identifies PACs, as noted in the Summary of Codes. Chemicals belonging to these categories are
reportable under section 313 by category, rather than by individual chemical name.
Ammonium Salts. The EPCRA section listing for ammonia includes the following qualifier
"includes anhydrous ammonia and aqueous ammonia from water dissociable ammonium salts and other
sources; 10 percent of total aqueous ammonia is reportable under this listing". The qualifier for
ammonia means that anhydrous forms of ammonia are 100% reportable and aqueous forms are limited to
10% of total aqueous ammonia. Therefore, when determining threshold and releases and other waste
management quantities all anhydrous ammonia is included but only 10% of total aqueous ammonia is
included. Any evaporation of ammonia from aqueous ammonia solutions is considered anhydrous
ammonia and should be included in threshold determinations and release and other waste management
calculations.
In this document ammonium salts are not specifically identified as being reportable EPCRA
section 313 chemicals. However, water dissociable ammonia salts, such as ammonium chloride, are
reportable if they are placed in water. When ammonium salts are placed in water, reportable aqueous
ammonia is manufactured. As indicated in the ammonia qualifier, all aqueous ammonia solutions from
water dissociable ammonium salts are covered by the ammonia listing. For example, ammonium chloride
is a water dissociable ammonium salt and reportable aqueous ammonia will be manufactured when it is
placed in water.
Unlike other ammonium salts, ammonium hydroxide is specifically identified as being a
reportable EPCRA section 313 chemical. This is because the chemical ammonium hydroxide (NH4OH)
is a misnomer. It is a common name used to describe a solution of ammonia in water (i.e., aqueous
ammonia), typically a concentrated solution of 28 to 30 percent ammonia. EPA has consistently
responded to questions regarding the reportability of these purported ammonium hydroxide solutions
under the EPCRA Section 313 ammonia listing by stating that these are 28 to 30 percent solutions of
ammonia in water and that the solutions are reportable under the EPCRA Section 313 ammonia listing.
For a more detailed discussion, see page 34175 of the Federal Register final rule of June 30, 1995 (60 FR
34172). (See also EPA's EPCRA section 313, Guidance for Reporting Aqueous Ammonia, EPA 745-R-
00-005, www.epa.gov/TRI)
Additions. Added to the list of toxic chemicals subject to reporting under EPCRA section 313
are seven chemicals and two chemical compound categories. These are:
Chemicals
CAS
1) benzo(g,h,i)perylene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 191242
2) benzo(j,k)fluorine (as a member of the PACs category) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 206440
3) 3-methylcholanthrene (as a member of the PACs category) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 56495
4) octachlorostyrene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 29082744
5) pentachlorobenzene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 608935
6) tetrabromobisphenol A . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 79947
7) vandium (except when contained in an alloy) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7440622
Chemical Categories
Category Code
1) vandium compounds . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . N770
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2) dioxin and dioxin like compounds (Manufacturing; and the processing or
otherwise use of dioxin and dioxin like compounds if the dioxin and dioxin-like
compounds are present as contaminants in a chemical and if they were created
during the manufacturing of that chemical) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . N150
Stayed Chemicals. There are three EPRCA section 313 chemicals that are listed in the CFR but
for which the Agency has issued an administrative stay that excludes them from reporting until the stays
are lifted. These chemicals, identified by "313s" in the Sec. 313 table column, are methyl mercaptan
(CAS number 74-93-1), hydrogen sulfide (CAS number 7783-06-4), and 2,2-dibromo-3-
nitrilopropionamide (CAS number 10222-01-2). Check the TRI website (www.epa.gov/triexplorer) for
updated regulatory information.
TRI Thresholds. Reporting under EPCRA section 313 is triggered by the quantity of a chemical
that is manufactured, processed, or otherwise used during the calendar year. For most TRI chemicals, the
thresholds are 25,000 pounds manufactured or processed or 10,000 pound otherwise used. EPA has
recently lowered the reporting thresholds for certain chemicals and chemical categories that meet the
criteria for persistence and bioaccumulation. The following list provides the thresholds for these
chemicals( in pounds unless otherwise noted):
Chemical Name or Category CAS Number Threshold (lbs)
Aldrin 309-00-2 100
Benzo(g,h,i)perylene 191-24-2 10
Chlordane 57-74-9 10
Dioxin and dioxin-like compound category (manufacturing; and NA 0.1 gram
processing or otherwise use of dioxin and dioxin-like compounds if they
are present as contaminants in a chemical and if they were created during
the manufacture of that chemical)
Heptachlor 76-44-8 10
Hexachlorobenzene 118-74-1 10
Isodrin 465-73-6 10
Lead and lead compounds except lead contained in stainless steel, brass, NA 100
and bronze alloys (applies to reporting for 2001(due July 2002) and later)
Methoxychlor 72-43-5 100
Octachlorostyrene 29082-74-4 10
Pendimethalin 40487-42-1 100
Pentachlorobenzene 608-93-5 10
Polycyclic aromatic compounds category NA 100
Polychlorinated biphenyls (PCBs) 1336-36-3 10
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