SAFETY DATA SHEET
Based on Directive 2001/58/EC of the Commission of the European Communities
Li in 0.5M HCl IRMM-615
1. Identification of the substance/preparation and of the company/undertaking
1.1 Identification of the substance or preparation:
Product name: IRMM-615
none
Synonyms:
N.A. IRMM-615
CAS No. : Reference number :
N.A. N.D.
EC index No. : NFPA code :
N.A. N.A.
EINECS No. : Molecular weight :
N.A. N.A.
RTECS No. : Formula :
1.2 Use of the substance or the preparation:
Certified reference material for laboratory use only
1.3 Company/undertaking identification:
Institute for Reference Materials and Measurements
Retieseweg
B-2440 Geel
Tel. : +32 14 57 12 11
Fax : +32 14 58 42 73
1.4 Telephone number for emergency:
+32 70 245 245
Antigifcentrum
p/a Militair Hospitaal Koningin Astrid, Bruynstraat 1, B-1120 Brussel
2. Composition/information on ingredients
Hazardous ingredients CAS No. Conc. in Hazard Risks
% symbol
EINECS/ELINCS No. (R-phrases)
hydrochloric acid 7647-01-0 2 C 34-37 (1)
231-595-7
(1) For R-phrases in full: see heading 16
IsotopeS
3.850(14) 10-6 mol (6Li) g-1 (solution)
6
amount fraction Li: 95.632 6(84)%
3. Hazards identification
- No hazard classification in accordance with directives 67/548/EEC and/or
1999/45/EC
4. First aid measures
4.1 Eye contact:
- Consult a doctor/medical service if irritation persists
- Rinse immediately with water
4.2 Skin contact:
- Consult a doctor/medical service if irritation persists
- Rinse with water
4.3 After inhalation:
- Consult a doctor/medical service if breathing problems develop
- Unconscious: maintain adequate airway and respiration
- Remove the victim into fresh air
4.4 After ingestion:
- Consult a doctor/medical service if you feel unwell
- Never give water to an unconscious person
Printing date : 01-2007 1/8
Compiled by : Brandweerinformatiecentrum voor Gevaarlijke Stoffen vzw (BIG)
Technische Schoolstraat 43 A, B-2440 Geel
+32 14 58 45 47 http://www.big.be E-mail: info@big.be
MSDS established : 03-04-2001 Revision date : 06-06-2006
Reference number : BIG\34859GB Revision number : 002
Reason for revision : 8
Li in 0.5M HCl IRMM-615
5. Fire-fighting measures
5.1 Suitable extinguishing media:
- Non combustible
- Fire extinguishing media: not applicable
5.2 Unsuitable extinguishing media:
- No data available
5.3 Special exposure hazards:
- On heating: formation of small quantities of chlorine, hydrogen chloride
5.4 Instructions:
- No specific firefighting instructions required
5.5 Special protective equipment for firefighters:
- Protective clothing for exposure to chemicals
6. Accidental release measures
6.1 Personal protection/precautions:
See heading 8.2/8.3/13
6.2 Environmental precautions:
- Contain leaking substance
6.3 Methods for cleaning up:
- Take up liquid spill with absorbent paper
- Clean contaminated surfaces with an excess of water
- Wash clothing and equipment after handling
7. Handling and storage
7.1 Handling:
- Observe normal hygiene standards
- Clean contaminated clothing
7.2 Storage:
- Keep container tightly closed
- Meet the legal requirements
- Keep away from: heat sources
: N.D.
Storage temperature 癈
: N.D.
Quantity limits kg
: N.D.
Storage life days
Materials for packaging :
- suitable : quartz
- to avoid : no data available
7.3 Specific uses:
- See information supplied by the manufacturer
Printing date : 01-2007 2/8
Li in 0.5M HCl IRMM-615
8. Exposure controls/Personal protection
8.1 Exposure limit values:
hydrochloric acid
mg/m3 -
TLV-TWA : ppm
mg/m3 -
TLV-STEL : ppm
mg/m3 2
TLV-Ceiling : ppm
mg/m3
:2 1
WEL-LTEL ppm
mg/m3
:8 5
WEL-STEL ppm
mg/m3
: 3.0 2
MAK ppm
mg/m3
:8
MAC-TGG 8 h
mg/m3
: 15
MAC-TGG 15 min.
mg/m3
MAC-Ceiling :
mg/m3
VME-8 h : ppm
mg/m3
VLE-15 min. : ppm
mg/m3 5
GWBB-8 h :8 ppm
mg/m3 10
GWK-15 min. : 15 ppm
mg/m3
Momentary value : ppm
mg/m3 5
EC :8 ppm
mg/m3 10
EC-STEL : 15 ppm
Sampling methods:
- Hydrogen Chloride (Acids, inorganic) NIOSH 7903
- Hydrogen Chloride OSHA ID 174SG
8.2 Exposure controls:
8.2.1 Occupational exposure controls:
- Measure the concentration in the air regularly
- Work under local exhaust/ventilation
Environmental exposure controls: see heading 13
8.2.2
8.3 Personal protection:
8.3.1 respiratory protection:
- Not required for normal conditions of use
8.3.2 hand protection:
- No data available
Suitable materials: No data available
- Breakthrough time: N.D.
8.3.3 eye protection:
- No data available
8.3.4 skin protection:
- No data available
Suitable materials: No data available
Printing date : 01-2007 3/8
Li in 0.5M HCl IRMM-615
9. Physical and chemical properties
9.1 General information:
Appearance (at 20癈) : Liquid
Odour : N.D.
Colour : Colourless
9.2 Important health, safety and environmental information:
pH value : N.D.
Boiling point/boiling range : N.D. 癈
Flashpoint : N.A. 癈
Explosion limits : N.A. vol% ( 癈)
Vapour pressure (at 20癈) : N.D. hPa
Vapour pressure (at 50癈) : N.D. hPa
Relative density (at 20癈) : N.D.
Water solubility : N.D.
Soluble in : No data available
Relative vapour density : N.D.
Viscosity : N.D. Pa.s
Partition coefficient n-octanol/water : N.D.
Evaporation rate
ratio to butyl acetate : N.D.
ratio to ether : N.D.
9.3 Other information:
Melting point/melting range : N.D. 癈
Auto-ignition point : N.A. 癈
g/m3
Saturation concentration : N.D.
10. Stability and reactivity
10.1 Conditions to avoid/reactivity:
- No data available
10.2 Materials to avoid:
- Keep away from: heat sources
10.3 Hazardous decomposition products:
- On heating: formation of small quantities of chlorine, hydrogen chloride
11. Toxicological information
11.1 Acute toxicity:
: N.D.
LD50 oral rat mg/kg
: N.D.
LD50 dermal rat mg/kg
: N.D.
LD50 dermal rabbit mg/kg
: N.D.
LC50 inhalation rat mg/l/4 h
: N.D.
LC50 inhalation rat ppm/4 h
11.2 Chronic toxicity:
hydrochloric acid
: not listed
EC carc. cat.
: not listed
EC muta. cat.
: not listed
EC repr. cat.
Printing date : 01-2007 4/8
Li in 0.5M HCl IRMM-615
A4
Carcinogenicity (TLV) :
not listed
Carcinogenicity (MAC) :
not listed
Carcinogenicity (VME) :
not listed
Carcinogenicity (GWBB) :
: not listed
Carcinogenicity (MAK)
: not listed
Mutagenicity (MAK)
:C
Teratogenicity (MAK)
:3
IARC classification
ingestion, inhalation, eyes and skin
11.3 Routes of exposure:
11.4 Acute effects/symptoms:
AFTER EYE CONTACT
- Slight irritation
11.5 Chronic effects:
- Not listed in carcinogenicity class (IARC,EC,TLV,MAK)
- Not listed in mutagenicity class (EC,MAK)
- Not classified as toxic to reproduction (EC)
12. Ecological information
12.1 Ecotoxicity:
- No data available
12.2 Mobility:
- Volatile organic compounds (VOC): N.A.%
- Maximum concentration in drinking water: 250 mg/l (chloride) (Directive
98/83/EC)
For other physicochemical properties see heading 9
12.3 Persistence and degradability:
- biodegradation BOD5 N.A.
: % ThOD
- water :
- soil N.D.
: T ? days
12.4 Bioaccumulative potential:
- log Pow : N.D.
- BCF : N.D.
12.5 Other adverse effects:
- WGK : N.D.
- Effect on the ozone layer : Not dangerous for the ozone layer
(1999/45/EC)
- Greenhouse effect : no data available
- Effect on waste water purification : no data available
13. Disposal considerations
13.1 Provisions relating to waste:
- Waste material code (75/442/EEC, Council Decision 2001/118/EC, O.J. L47 of
16/2/2001): 16 05 09 (discarded chemicals other than those mentioned in 16
05 06, 16 05 07 or 16 05 08
Printing date : 01-2007 5/8
Li in 0.5M HCl IRMM-615
13.2 Disposal methods:
- Remove for physico-chemical/biological treatment
- Recycle/reuse
13.3 Packaging/Container:
- Waste material code packaging (75/442/EEC, Council Decision 2001/118/EC,
O.J. L47 of 16/2/2001): 20 01 99 (other fractions not otherwise specified)
14. Transport information
14.1 Classification of the substance in compliance with UN Recommendations
:-
UN number
CLASS :
SUB RISKS :
PACKING :
PROPER SHIPPING NAME :
14.2 ADR (transport by road)
: NOT SUBJECT
CLASS
PACKING :
CLASSIFICATION CODE :
DANGER LABEL TANKS :
DANGER LABEL PACKAGES :
14.3 RID (transport by rail)
: NOT SUBJECT
CLASS
PACKING :
CLASSIFICATION CODE :
DANGER LABEL TANKS :
DANGER LABEL PACKAGES :
14.4 ADNR (transport by inland waterways)
: NOT SUBJECT
CLASS
PACKING :
CLASSIFICATION CODE :
DANGER LABEL TANKS :
DANGER LABEL PACKAGES :
14.5 IMDG (maritime transport)
: NOT SUBJECT
CLASS
SUB RISKS :
PACKING :
MFAG :
EMS :
MARINE POLLUTANT :
14.6 ICAO (air transport)
: NOT SUBJECT
CLASS
SUB RISKS :
PACKING :
PACKING INSTRUCTIONS PASSENGER AIRCRAFT :
PACKING INSTRUCTIONS CARGO AIRCRAFT :
: not restricted for any mode of
14.7 Special precautions in connection with
international transport
transport
Printing date : 01-2007 6/8
Li in 0.5M HCl IRMM-615
15. Regulatory information
Classification according to directives 67/548/EEC and/or 1999/45/EC
NOT APPLICABLE
16. Other information
The information provided on this MSDS is correct to the best of our knowledge, information and belief
at the date of its publication. The information given is designed only as a guidance for safe
handling, use, processing, storage, transportation, disposal and release and is not to be considered
as a warranty or quality specification. The information relates only to the specific material
designated and may not be valid for such material used in combination with any other material or in
any process, unless specified in the text.
= NOT APPLICABLE
N.A.
= NOT DETERMINED
N.D.
= INTERNAL CLASSIFICATION (NFPA)
(*)
Exposure limits:
: Threshold Limit Value - ACGIH USA
TLV
: Workplace Exposure Limits - United Kingdom
WEL
: Maximale Arbeitsplatzkonzentrationen - Germany
MAK
: Maximale aanvaarde concentratie - The Netherlands
MAC
: Valeurs limites de Moyenne d'Exposition - France
VME
: Valeurs limites d'Exposition ?court terme - France
VLE
GWBB : Grenswaarde beroepsmatige blootstelling - Belgium
: Grenswaarde kortstondige blootstelling - Belgium
GWK
: Indicative occupational exposure limit values - directive 2000/39/EC
EC
Inhalable fraction = T: Total dust = E: Einatembarer Aerosolanteil
I :
Respirable fraction = A: Alveoleng鋘giger Aerosolanteil/Alveolar dust
R :
Ceiling limit
C :
Chronic toxicity:
: List of the carcinogenic substances and processes - The Netherlands
K
Full text of any R-phrases referred to under heading 2:
R34 : Causes burns
R37 : Irritating to respiratory system
Printing date : 01-2007 7/8
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