3M MATERIAL SAFETY DATA SHEET 3M(TM) BATHROOM & SHOWER CLEANER CONCENTRATE (Product No. 51, Twist 'n
Fill(tm) System) 11/07/2005
Material Safety Data Sheet
Copyright, 2005, 3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly
utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is
obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit
thereon.
SECTION 1: PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: 3M(TM) BATHROOM & SHOWER CLEANER CONCENTRATE (Product No. 51,
Twist 'n Fill(tm) System)
MANUFACTURER: 3M
DIVISION: Commercial Care Division
ADDRESS: 3M Center
St. Paul, MN 55144-1000
EMERGENCY PHONE: 1-800-364-3577 or (651) 737-6501 (24 hours)
Issue Date: 11/07/2005
Supercedes Date: 02/12/2003
Document Group: 09-5351-3
Product Use:
Specific Use: For daily cleaning of surfaces such as ceramic, tile, stainless steel, fixtures, floors and
more.
SECTION 2: INGREDIENTS
Ingredient C.A.S. No. % by Wt
WATER 7732-18-5 60 - 90
ALCOHOLS, C8-18 68551-07-5 10 - 30
HYDROCHLORIC ACID 7647-01-0 7 - 13
ETHOXYLATED C9-11 ALCOHOLS 68439-46-3 3- 7
POLYOXYETHYLENE TALLOW AMINE 61791-26-2 1- 5
SECTION 3: HAZARDS IDENTIFICATION
3.1 EMERGENCY OVERVIEW
Specific Physical Form: Liquid
Odor, Color, Grade: Clear, yellow liquid with pungent odor of hydrochloric acid
General Physical Form: Liquid
Immediate health, physical, and environmental hazards: May cause chemical eye burns. May cause chemical skin burns. May
cause chemical gastrointestinal burns. May cause target organ effects.
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3M MATERIAL SAFETY DATA SHEET 3M(TM) BATHROOM & SHOWER CLEANER CONCENTRATE (Product No. 51, Twist 'n
Fill(tm) System) 11/07/2005
3.2 POTENTIAL HEALTH EFFECTS
Eye Contact:
Corrosive (Eye Burns): Signs/symptoms may include cloudy appearance of the cornea, chemical burns, severe pain, tearing,
ulcerations, significantly impaired vision or complete loss of vision.
Skin Contact:
Corrosive (Skin Burns): Signs/symptoms may include localized redness, swelling, itching, intense pain, blistering, ulceration, and
tissue destruction.
Inhalation:
Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and
throat pain.
Prolonged or repeated exposure may cause:
Respiratory Effects: Signs/symptoms may include cough, shortness of breath, chest tightness, wheezing, increased heart rate,
bluish colored skin (cyanosis), sputum production, changes in lung function tests, and/or respiratory failure.
May be absorbed following inhalation and cause target organ effects.
Ingestion:
Gastrointestinal Corrosion: Signs/symptoms may include severe mouth, throat and abdominal pain; nausea; vomiting; and diarrhea;
blood in the feces and/or vomitus may also be seen.
May be absorbed following ingestion and cause target organ effects.
Target Organ Effects:
Prolonged or repeated exposure may cause:
Hard Tissue Effects: Signs/symptoms may include color changes in the teeth and nails; changes in development of bone,
teeth or nails; weakening of the bones; and/or hair loss.
3.3 POTENTIAL ENVIRONMENTAL EFFECTS
A 3M Product Environmental Data Sheet (PED) is available.
A conservative assessment indicates this product presents a low environmental risk. Components released to the environment through
use and disposal are expected to have insignificant environmental impacts.
SECTION 4: FIRST AID MEASURES
4.1 FIRST AID PROCEDURES
The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are
followed.
Eye Contact: Immediately flush eyes with large amounts of water for at least 15 minutes. Get immediate medical attention.
Skin Contact: Remove contaminated clothing and shoes. Immediately flush skin with large amounts of water for at least 15 minutes.
Get immediate medical attention. Wash contaminated clothing and clean shoes before reuse.
Inhalation: Remove person to fresh air. If signs/symptoms develop, get medical attention.
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3M MATERIAL SAFETY DATA SHEET 3M(TM) BATHROOM & SHOWER CLEANER CONCENTRATE (Product No. 51, Twist 'n
Fill(tm) System) 11/07/2005
If Swallowed: Do not induce vomiting. Give victim two glasses of water. Never give anything by mouth to an unconscious person.
Get immediate medical attention.
SECTION 5: FIRE FIGHTING MEASURES
5.1 FLAMMABLE PROPERTIES
Not Applicable
Autoignition temperature
Not Applicable
Flash Point
Not Applicable
Flammable Limits - LEL
Not Applicable
Flammable Limits - UEL
Not Applicable
OSHA Flammability Classification:
5.2 EXTINGUISHING MEDIA
Material will not burn.
5.3 PROTECTION OF FIRE FIGHTERS
Special Fire Fighting Procedures: Wear full protective equipment (Bunker Gear) and a self-contained breathing apparatus
(SCBA).
Unusual Fire and Explosion Hazards: Not applicable.
SECTION 6: ACCIDENTAL RELEASE MEASURES
Accidental Release Measures: Refer to other sections of this MSDS for information regarding physical and health hazards,
respiratory protection, ventilation, and personal protective equipment. Call 3M-HELPS line (1-800-364-3577) for more information
on handling and managing the spill. Evacuate unprotected and untrained personnel from hazard area. The spill should be cleaned up
by qualified personnel. Ventilate the area with fresh air. Contain spill. For larger spills, cover drains and build dikes to prevent entry
into sewer systems or bodies of water. Avoid contact with incompatible materials listed in the Reactivity Data Section. For large
spills, if necessary, get assistance from professional spill clean up team. For small spills, carefully cover the spill with soda ash
(sodium carbonate) or sodium bicarbonate. Work from around the perimeter inward. Avoid splashing. Add enough water to ease
mixing and stir. Continue stirring and adding water and neutralizing agent until the reaction stops. Let cool before collecting. Or use a
commercially available 'Acid spill' clean-up kit. Follow the kit directions exactly, as specified. Working from around the edges of the
spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent
until it appears dry. Remember, adding an absorbent material does not remove a toxic, corrosivity or flammability hazard. Collect as
much of the spilled material as possible. Clean up residue with a dilute solution (approximately 1 to 5%) of soda ash (sodium
carbonate) or baking soda (sodium bicarbonate) in water. Place in a metal container approved for use in transportation by appropriate
authorities. The container must be lined with polyethylene plastic or contain a plastic drum liner made of polyethylene. Cover, but do
not seal for 48 hours. Dispose of collected material as soon as possible.
In the event of a release of this material, the user should determine if the release qualifies as reportable according to
local, state, and federal regulations.
SECTION 7: HANDLING AND STORAGE
7.1 HANDLING
Keep out of the reach of children. This product is not intended to be used without prior dilution as specified on the product label.
Avoid breathing of vapors, mists or spray. Avoid skin contact. Avoid eye contact. Do not eat, drink or smoke when using this
product. Wash exposed areas thoroughly with soap and water. Keep away from aluminum and zinc. Avoid contact with oxidizing
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3M MATERIAL SAFETY DATA SHEET 3M(TM) BATHROOM & SHOWER CLEANER CONCENTRATE (Product No. 51, Twist 'n
Fill(tm) System) 11/07/2005
agents. Do not mix with bleach or ammonia products.
7.2 STORAGE
Keep container in well-ventilated area. Store away from oxidizing agents. Store away from strong bases.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1 ENGINEERING CONTROLS
Use in a well-ventilated area.
NOTE: When used as directed and diluted and dispensed with a TWIST 'n FILL(TM) Chemical Dispenser, special ventilation is not
required.
8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE)
8.2.1 Eye/Face Protection
Avoid eye contact.
NOTE: When used as directed and diluted and dispensed with a TWIST 'n FILL(TM) Chemical Dispenser, eye contact with the
concentrate is not expected to occur.
If the product is not used with the Twist 'n Fill system or if there is an accidental release, the following eye protection is
recommended: Full Face Shield, Indirect Vented Goggles
8.2.2 Skin Protection
Avoid skin contact.
NOTE: When used as directed and diluted and dispensed with a TWIST 'n FILL(TM) Chemical Dispenser, skin contact with the
concentrate is not expected to occur.
If the product is not used with the Twist 'n Fill system or if there is an accidental release, select and use gloves and/or protective
clothing to prevent skin contact based on the results of an exposure assessment. Consult with your glove and/or protective clothing
manufacturer for selection of appropriate compatible materials. Gloves made from the following material is recommended: Butyl
Rubber, Neoprene. The following protective clothing material(s) are recommended: Apron - Neoprene.
8.2.3 Respiratory Protection
Avoid breathing of vapors, mists or spray.
NOTE: When used as directed and diluted and dispensed with a TWIST 'n FILL(TM) Chemical Dispenser, respiratory protection is
not required.
If the product is not used with the Twist 'n Fill system or if there is an accidental release, select one of the following NIOSH approved
respirators based on airborne concentration of contaminants and in accordance with OSHA regulations: Fullface air-purifying
respirator with organic vapor/acid gas cartridges. Consult the current 3M Respiratory Selection Guide for additional information or
call 1-800-243-4630 for 3M technical assistance.
8.2.4 Prevention of Swallowing
Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water.
8.3 EXPOSURE GUIDELINES
Ingredient Authority Type Limit Additional Information
HYDROCHLORIC ACID ACGIH CEIL 2 ppm Table A4
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3M MATERIAL SAFETY DATA SHEET 3M(TM) BATHROOM & SHOWER CLEANER CONCENTRATE (Product No. 51, Twist 'n
Fill(tm) System) 11/07/2005
HYDROCHLORIC ACID OSHA CEIL 5 ppm Table Z-1
SOURCE OF EXPOSURE LIMIT DATA:
ACGIH: American Conference of Governmental Industrial Hygienists
CMRG: Chemical Manufacturer Recommended Guideline
OSHA: Occupational Safety and Health Administration
AIHA: American Industrial Hygiene Association Workplace Environmental Exposure Level (WEEL)
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
Liquid
Specific Physical Form:
Clear, yellow liquid with pungent odor of hydrochloric acid
Odor, Color, Grade:
Liquid
General Physical Form:
Not Applicable
Autoignition temperature
Not Applicable
Flash Point
Not Applicable
Flammable Limits - LEL
Not Applicable
Flammable Limits - UEL
> 200 篎
Boiling point
No Data Available
Density
No Data Available
Vapor Density
< 27 psia [@ 131 篎]
Vapor Pressure
Not Applicable
Vapor Pressure
1 [Ref Std: WATER=1]
Specific Gravity
<1
pH
Not Applicable
Melting point
Not Applicable
Solubility In Water
Complete
Solubility in Water
Not Applicable
Average particle size
Not Applicable
Bulk density
Not Applicable
Evaporation rate
Not Applicable
Evaporation rate
Not Applicable
Molecular weight
0.05 % weight - 0.15 % weight
Volatile Organic Compounds
Not Applicable
Kow - Oct/Water partition coef
67 - 100 %
Percent volatile
Not Applicable
Percent volatile
Not Applicable
Softening point
1.68 g/l - 5.04 g/l
VOC Less H2O & Exempt Solvents
< 100 centipoise
Viscosity
SECTION 10: STABILITY AND REACTIVITY
Stability: Stable.
Materials and Conditions to Avoid: Strong bases Additional Information: Do not mix with bleach or ammonia products.
Not Applicable
Hazardous Polymerization: Hazardous polymerization will not occur.
Other Stability: Not Applicable
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3M MATERIAL SAFETY DATA SHEET 3M(TM) BATHROOM & SHOWER CLEANER CONCENTRATE (Product No. 51, Twist 'n
Fill(tm) System) 11/07/2005
Other Hazardous Polymerization: Not Applicable
Hazardous Decomposition: Under recommended usage conditions, hazardous decomposition products are not expected. Hazardous
decomposition products may occur as a result of oxidation, heating, or reaction with another material.
SECTION 11: TOXICOLOGICAL INFORMATION
Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its
components.
SECTION 12: ECOLOGICAL INFORMATION
ECOTOXICOLOGICAL INFORMATION
A 3M Product Environmental Data Sheet (PED) is available.
CHEMICAL FATE INFORMATION
A 3M Product Environmental Data Sheet (PED) is available.
SECTION 13: DISPOSAL CONSIDERATIONS
Waste Disposal Method: Dispose of waste product in a permitted hazardous waste facility.
Incinerate in a permitted hazardous waste incinerator in the presence of a combustible material. As a disposal alternative, dispose of
waste product in a permitted hazardous waste facility.
EPA Hazardous Waste Number (RCRA): D002 (Corrosive)
Since regulations vary, consult applicable regulations or authorities before disposal.
SECTION 14:TRANSPORT INFORMATION
ID Number UPC ID Number UPC
70-0709-8531-5 00-48011-26321-7 70-0709-8532-3 00-48011-26320-0
70-0710-0730-9 00-48011-26320-0 70-0710-0947-9 00-48011-26321-7
Please contact the emergency numbers listed on the first page of the MSDS for Transportation Information for this
material.
SECTION 15: REGULATORY INFORMATION
US FEDERAL REGULATIONS
311/312 Hazard Categories:
Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - Yes
Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA):
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3M MATERIAL SAFETY DATA SHEET 3M(TM) BATHROOM & SHOWER CLEANER CONCENTRATE (Product No. 51, Twist 'n
Fill(tm) System) 11/07/2005
Ingredient C.A.S. No % by Wt
HYDROCHLORIC ACID 7647-01-0 7 - 13
STATE REGULATIONS
CHEMICAL INVENTORIES
The components of this product are in compliance with the chemical notification requirements of TSCA.
All applicable chemical ingredients in this material are listed on the European Inventory of Existing Chemical Substances (EINECS),
or are exempt polymers whose monomers are listed on EINECS.
The components of this material are in compliance with the new chemical notification requirements for the Korean Existing
Chemicals Inventory.
The components of this product are listed on the Australian Inventory of Chemical Substances.
The components of this product are listed on Japan's Chemical Substance Control Law List (also known as the Existing and New
Chemical Substances List.)
All the components of this product are listed on China's Inventory of Chemical Substances.
The components of this product are in compliance with notification requirements in the Philippines.
The components of this product are listed on the Canadian Domestic Substances List.
INTERNATIONAL REGULATIONS
This MSDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.
SECTION 16: OTHER INFORMATION
NFPA Hazard Classification
Health: 3 Flammability: 0 Reactivity: 0 Special Hazards: None
Corrosive: Yes
National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are
presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the
inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to
be generated in significant quantities.
HMIS Hazard Classification
Health: 3 Flammability: 0 Reactivity: 0 Protection: X - See PPE section.
Hazardous Material Identification System (HMIS? hazard ratings are designed to inform employees of chemical hazards in the workplace. These
ratings are based on the inherent properties of the material under expected conditions of normal use and are not intended for use in emergency
situations. HMIS?ratings are to be used with a fully implemented HMIS?program. HMIS?is a registered mark of the National Paint and Coatings
Association (NPCA).
Revision Changes:
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3M MATERIAL SAFETY DATA SHEET 3M(TM) BATHROOM & SHOWER CLEANER CONCENTRATE (Product No. 51, Twist 'n
Fill(tm) System) 11/07/2005
Section 1: Product use information was modified.
Section 16: NFPA hazard classification heading was modified.
Section 16: HMIS hazard classification heading was modified.
Copyright was modified.
Section 8: Exposure guidelines data source legend was modified.
Section 3: Potential effects from inhalation information was modified.
Section 3: Potential effects from ingestion information was modified.
Section 5: Fire fighting procedures information was modified.
Section 6: Release measures information was modified.
Section 7: Handling information was modified.
Section 7: Storage information was modified.
Section 8: Engineering controls information was modified.
Section 8: Eye/face protection phrase was modified.
Section 8: Skin protection phrase was modified.
Section 8: Respiratory protection information was modified.
Section 13: Waste disposal method information was modified.
Section 15: 311/312 hazard categories heading was modified.
Section 4: First aid for inhalation - termination of exposure - was modified.
Section 4: First aid for inhalation - medical assistance - was modified.
Section 4: First aid for ingestion (swallowing) - decontamination - was modified.
Section 10: Hazardous polymerization heading was modified.
Section 2: Ingredient table was modified.
Section 16: HMIS explanation was modified.
Section 16: NFPA explanation was modified.
Section 15: Inventories information was modified.
Section 15: EPCRA 313 text was modified.
Section 12: Ecotoxicological information heading was modified.
Section 12: Chemical fate information heading was modified.
Section 8: Exposure guidelines ingredient information was modified.
Sections 3 and 9: Odor, color, grade information was modified.
Section 9: Property description for optional properties was modified.
Section 9: Specific gravity information was modified.
Section 9: Melting point information was modified.
Section 16: NFPA hazard classification for special hazards was modified.
Section 10: Hazardous decompostion heading was modified.
Section 8: Eye/face protection comment was added.
Section 8: Skin protection comment was added.
Section 8: Respiratory protection comment was added.
Section 3: Potential environmental effects comment was added.
Section 3: Potential environmental effects heading was added.
Section 7: Storage comment was added.
Section 3: Other potential health effects heading was added.
Section 3: Immediate ingestion hazard(s) was added.
Section 3: Potential environmental effects information was added.
Section 10: Other hazardous polymerization information was added.
Section 10: Other stability physical property was added.
Section 10: Other hazardous polymerization heading was added.
Section 10: Other stability heading was added.
Section 10: Materials and conditions to avoid physical property was added.
Section 3: Immediate other hazard(s) was added.
Section 3: Other health effects information was added.
Section 9: Vapor pressure text was added.
Section 9: Solubility in water value was added.
Section 2: Ingredient phrase was added.
Section 12: Ecotoxicological phrase was added.
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3M MATERIAL SAFETY DATA SHEET 3M(TM) BATHROOM & SHOWER CLEANER CONCENTRATE (Product No. 51, Twist 'n
Fill(tm) System) 11/07/2005
Section 12: Chemical Fate phrase was added.
Section 8: Eye/face protection information was deleted.
Section 8: Skin protection - recommended gloves information was deleted.
Section 8: Respiratory protection - recommended respirators information was deleted.
Section 8: Eye/face protection text was deleted.
Section 8: Skin protection - recommended gloves text was deleted.
Section 8: Skin protection - protective clothing recommendations was deleted.
Section 8: Respiratory protection - recommended respirators was deleted.
Section 8: Skin protection - protective clothing information was deleted.
Section 8: Respiratory protection - recommended respirators guide was deleted.
Section 8: Skin protection - protective clothing text was deleted.
Section 8: Respiratory protection - recommended respirators punctuation was deleted.
Section 8: Eye/face protection information - punctuation - was deleted.
Section 8: Skin protection - protective clothing - punctuation was deleted.
Section 8: Skin protection - recommended gloves - punctuation was deleted.
DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M
MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY
OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of
use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely
within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a
particular purpose and suitable for user's method of use or application.
3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may
have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy.
In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M.
3M MSDSs are available at www.3M.com
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