STAY CLEAN LIQUID SOLDERING FLUX
MATERIAL SAFETY DATA SHEET 01/11/00
MSDS PROVIDED BY:
STOODY INDUSTRIAL AND WELDING SUPPLY, INC.
3316 National Ave., San Diego, Ca. 92113
Phone: (619) 234-6750
MILITARY EMERGENCY RESPONSE NUMBER 1-800-851-8061
Prepared to U.S. OSHA, CMA, ANSI and Canadian WHMIS Standards
(REPRODUCED SIWS)
PART I What is the material and what do I need to know in an emergency?
1. PRODUCT IDENTIFICATION
STAY CLEAN LIQUID SOLDERING FLUX
TRADE NAME (AS LABELED):
CHEMICAL NAME/CLASS: Zinc Chloride/Ammonium Chloride Solution
SYNONYMS: Not Applicable
PRODUCT USE: Metal-Working Operations
DOCUMENT NUMBER: 0099
SUPPLIER/MANUFACTURER'S NAME: J.W. HARRIS CO., INC. & HARRIS WELCO
DIVISION/ J.W. HARRIS CO.
ADDRESS: 1051 York Rd.
Kings Mountain, NC 28086
EMERGENCY PHONE: CHEMTREC: 1-800-424-9300
BUSINESS PHONE: 704-739-6421
DATE OF PREPARATION: September 10, 1998
2. COMPOSITION and INFORMATION ON INGREDIENTS
CHEMICAL NAME CAS # % w/w EXPOSURE LIMITS IN AIR
ACGIH OSHA
TLV STEL PEL STEL IDLH OTHER
3 3 3 3 3 3
mg/m mg/m mg/m mg/m mg/m mg/m
2 (vacated NIOSH REL:
Zinc Chloride 7646-85-7 < 30 1 2 1 60
1989 PEL) TWA = 1
(exposure limits are for
STEL = 2
Zinc Chloride fume)
Carcinogen: EPA-D
5-
Ammonium Chloride 12125-02-9 25 10 20 10 20 (vacated NE NIOSH REL:
(vacated TWA = 10
1989 PEL)
(exposure limits are for
1989 STEL = 20
Ammonium Chloride
PEL)
fume)
Hydrochloric Acid 7647-01-0 <5 NE 7.5 C NE 7.5 C 76 NIOSH REL: 7 C
DFG MAK: 7
Carcinogen: IARC-3
Methanol 67-56-1 <5 262 (skin) 328 260 325 7980 NIOSH REL:
(vacated TWA = 260 (skin)
1989 PEL) STEL = 325
DFG MAK:
TWA = 260 (skin)
Water 7732-18-5 Balance NE NE NE NE NE NE
NE = Not Established. C = Ceiling Limit. See Section 16 for Definitions of Terms Used.
NOTE(1): All WHMIS required information is included. It is located in appropriate sections based on the ANSI Z400.1-1993 format.
SIWS PROVIDES MSDS AS A COURTISY. TO ENSURE ACCURATE AND CURRENT DATA, OBTAIN AND USE ONLY MSDS FROM MANUFACTURER. PAGE 1 OF 9
STAY CLEAN LIQUID SOLDERING FLUX
MATERIAL SAFETY DATA SHEET
3. HAZARD IDENTIFICATION
EMERGENCY OVERVIEW: This product is a clear, colorless liquid, possessing a slight, sweet odor. This material is
acidic and can irritate and burn the skin, eyes, and any other contaminated tissue. This product is not flammable nor
reactive under normal circumstances; however, it may generate flammable hydrogen gas upon contact with metals.
Emergency responders must wear the proper personal protective equipment suitable for the situation to which they are
responding.
SYMPTOMS OF OVER-EXPOSURE BY ROUTE OF EXPOSURE: The most
significant routes of over-exposure for this product are by contact with skin, eye HAZARDOUS MATERIAL INFORMATION SYSTEM
contact, or inhalation of mists or sprays generated by this product. The
symptoms of overexposure to this product, by route of entry, are as follows:
HEALTH (BLUE) 3
INHALATION: If vapors, mists, or sprays of this product are inhaled, they can
irritate and burn the nose, throat, and respiratory system. Symptoms of
inhalation over-exposure may include sore throat, choking, coughing, and
difficulty breathing. Prolonged or repeated over-exposure may cause burns and
ulcers to the nose and throat, dental erosion, bronchitis, and stomach pains. It (RED) 0
FLAMMABILITY
has been reported that a worker developed asthmatic symptoms after
performing soldering work with a flux containing Ammonium and Zinc Chlorides
(components of this product). It has been reported that inhalation of Methanol
(a component of this product) vapors in high concentrations can cause REACTIVITY (YELLOW) 0
blindness. Severe inhalation overexposure may cause pulmonary edema (a
life-threatening accumulation of fluid in the lungs) or pneumonitis. Symptoms of
pulmonary edema (e.g., shortness of breath, chest pains) can be delayed for
D
PROTECTIVE EQUIPMENT
several hours after exposure. Severe inhalation of vapors or fumes (as may
occur if individuals are exposed in poorly-ventilated areas, such as confined
spaces) may be harmful. EYES HANDS BODY
RESPIRATORY
CONTACT WITH SKIN or EYES: Depending on the duration and
concentration of over-exposure, skin contact with this product can irritate and SEE SECTION 8 SEE SECTION 8
burn the skin. Repeated or prolonged over-exposure to this product may
result in dermatitis (red, dry, itchy skin) and ulceration. Depending on the
For routine applications.
duration and concentration of over-exposure, eye contact with this product can
irritate and burn the eyes. Eye over-exposure can cause pain, tearing, and See Section 16 for Definition of Ratings
redness. Severe eye over-exposure may cause blindness.
SKIN ABSORPTION: Methanol (a component of this product) is readily absorbed through the skin. Because Methanol is a minor
component of this product, skin absorption is not anticipated to be a significant route of over-exposure.
INGESTION: Ingestion is not anticipated to be a likely route of occupational exposure for this product. If this product is swallowed, it
can irritate and burn the mouth, throat, and other tissues of the digestive system. Symptoms can include headache, drowsiness,
confusion, nausea, vomiting, burning sensation in the esophagus and stomach, abdominal pain, bloody diarrhea, convulsions, high
blood pressure, and coma. Ingestion of Methanol (a component of this product) can cause blindness though due to the relatively low
concentration of Methanol in the product, this is not anticipated to be a significant hazard). Severe ingestion over-exposure may be
fatal.
INJECTION: Though not anticipated to be a likely route of occupational exposure for this product, injection of this product (via
punctures or lacerations by a contaminated object) may cause local reddening, tissue swelling, and discomfort in addition to the
wound.
HEALTH EFFECTS OR RISKS FROM OVER-EXPOSURE: An Explanation in Lay Terms. Symptoms associated with over-
exposure to this product are as follows:
ACUTE: Symptoms of inhalation over-exposure may include sore throat, choking, coughing, difficulty breathing. Lung damage may
occur after severe inhalation exposures. Depending on the duration and concentration of over-exposure, skin or eye contact with
this product can irritate and burn contaminated tissue. Ingestion overexposure may be harmful or fatal.
CHRONIC: Prolonged or repeated inhalation over-exposure may cause burns and ulcers to the nose and throat, dental erosion,
bronchitis, and stomach pains. Repeated or prolonged over-exposure to this product may result in dermatitis (red, dry, itchy skin)
and ulceration. Refer to Section 11 (Toxicology Information) for additional data.
TARGET ORGANS: Skin, eyes, respiratory system, central nervous system.
SIWS PROVIDES MSDS AS A COURTISY. TO ENSURE ACCURATE AND CURRENT DATA, OBTAIN AND USE ONLY MSDS FROM MANUFACTURER. PAGE 2 OF 9
STAY CLEAN LIQUID SOLDERING FLUX
MATERIAL SAFETY DATA SHEET
PART II What should I do if a hazardous situation occurs?
4. FIRST-AID MEASURES
SKIN EXPOSURE: If this product irritates the skin, begin decontamination with running water. Minimum flushing is for 15 minutes.
Do not interrupt flushing. Victim must seek medical attention if any adverse reaction occurs.
EYE EXPOSURE: If this product enters the eyes, open victim's eyes while under gently running water. Use sufficient force to open
eyelids. Have victim "roll" eyes. Minimum flushing is for 15 minutes. Do not interrupt flushing. Victim must seek immediate medical
attention.
INHALATION: If vapors, mists or sprays of this product are inhaled, remove victim to fresh air. If necessary, use artificial respiration
to support vital functions. Victim must seek medical attention if any adverse reaction occurs.
INGESTION: If this product is swallowed, CALL PHYSICIAN OR POISON CONTROL CENTER FOR MOST CURRENT
INFORMATION. If professional advice is not available, do not induce vomiting. Victim should drink large quantities of water. If milk
is available, victim should drink it after drinking water. Never induce vomiting or give diluents (milk or water) to someone who is
unconscious, having convulsions, or unable to swallow.
Victims of chemical exposure must be taken for medical attention. Rescuers should be taken for medical attention if necessary.
Take copy of label and MSDS to health professional with victim.
5. FIRE-FIGHTING MEASURES
FLASH POINT: Not flammable.
NFPA RATING
AUTOIGNITION TEMPERATURE: Not applicable.
FLAMMABLE LIMITS (in air by volume, %): Lower (LEL): Not applicable. FLAMMABILITY
Upper (UEL): Not applicable
FIRE EXTINGUISHING MATERIALS: This material is not flammable. Use 0
extinguishing media appropriate for surrounding fire.
0
3
Water Spray: YES (for cooling) Carbon Dioxide: YES HEALTH REACTIVITY
Halon: YES Foam: YES
Dry Chemical: YES Other: Any "ABC" Class.
UNUSUAL FIRE AND EXPLOSION HAZARDS: This product is acidic and presents
a contact hazard to firefighters. During a fire, irritating and toxic gases (e.g., carbon OTHER
monoxide, carbon dioxide, hydrogen chloride, nitrogen and zinc oxides, and
See Section 16 for
ammonia)
Definition of Ratings
may be generated.
Explosion Sensitivity to Mechanical Impact: Not sensitive.
Explosion Sensitivity to Static Discharge: Not sensitive.
SPECIAL FIRE-FIGHTING PROCEDURES: Incipient fire responders should wear eye protection. Structural firefighters must wear
Self-Contained Breathing Apparatus and full protective equipment. Chemical resistant clothing (e.g., chemical splash suit) may be
necessary. Move containers from fire area if it can be done without risk to personnel. If possible, prevent runoff water from
entering storm drains, bodies of water, or other environmentally sensitive areas.
6. ACCIDENTAL RELEASE MEASURES
SPILL AND LEAK RESPONSE: Uncontrolled releases should be responded to by trained personnel using pre-planned procedures.
Proper protective equipment should be used. In case of a spill, clear the affected area, protect people, and respond with trained
personnel.
In the event of an incidental release of this product, personnel should wear gloves, safety glasses (or goggles), and face shield
during clean up. In the event of a non-incidental release, minimum Personal Protective Equipment should be Level B: triple-gloves
(rubber gloves and nitrile gloves over latex gloves), chemical resistant suit and boots, hard-hat, and Self-Contained
Breathing Apparatus. Absorb spilled liquid with polypads or other suitable absorbing material. Neutralize area with sodium
bicarbonate or other agent suitable for acids. Test area with litmus paper to insure neutralization is complete. Decontaminate the
area thoroughly. Place all spill residue in a suitable container and seal Dispose of in accordance with applicable U.S. Federal, State,
or local procedures and appropriate Canadian standards (see Section 13, Disposal Considerations).
SIWS PROVIDES MSDS AS A COURTISY. TO ENSURE ACCURATE AND CURRENT DATA, OBTAIN AND USE ONLY MSDS FROM MANUFACTURER. PAGE 3 OF 9
STAY CLEAN LIQUID SOLDERING FLUX
MATERIAL SAFETY DATA SHEET
PART III How can I prevent hazardous situations from occurring
7. HANDLING and STORAGE
WORK PRACTICES AND HYGIENE PRACTICES: As with all chemicals, avoid getting this product ON YOU or IN YOU. Wash
thoroughly after handling this product. Do not eat or drink while handling this material. Avoid generating splashes or sprays of this
product. Remove contaminated clothing immediately.
STORAGE AND HANDLING PRACTICES: All employees who handle this material should be trained to handle it safely. Empty
containers may contain residual liquid; therefore, empty containers should be handled with care.
Store this product in a cool, dry location, away from direct sunlight, sources of intense heat, or where freezing is possible. Store away
from incompatible chemicals (see Section 10, Stability and Reactivity). Material should be stored in secondary containers or in a
diked area, as appropriate. Storage and use areas should be covered with impervious materials. Keep container tightly closed
when not in use. Inspect all incoming containers before storage to ensure they are properly labeled and not damaged.
PROTECTIVE PRACTICES DURING MAINTENANCE OF CONTAMINATED EQUIPMENT: Follow practices indicated in Section 6
(Accidental Release Measures). Make certain that application equipment is locked and tagged-out safely. Collect all rinsates and
dispose of according to applicable U.S. Federal, State, or local procedures and appropriate Canadian standards.
8. EXPOSURE CONTROLS - PERSONAL PROTECTION
VENTILATION AND ENGINEERING CONTROLS: Use with adequate ventilation to ensure exposure levels are maintained below
the limits provided in Section 2 (Composition and Information on Ingredients). Exhaust directly to the outside, taking necessary
precautions for environmental protection. Prudent practice is to ensure eyewash/safety shower stations are available near areas
where this product is used.
RESPIRATORY PROTECTION: Maintain airborne contaminant concentrations below guidelines listed in Section 2 (Composition
and Information on Ingredients) if applicable. If respiratory protection is needed, use only protection authorized in the U.S. Federal
OSHA Standard (29 CFR 1910.134), applicable U.S. State regulations, or the appropriate standards of Canada and its Provinces.
Use supplied air respiration protection if oxygen levels are below 19.5% or are unknown. The following NIOSH respiratory selection
guidelines are available for Zinc Chloride Fume:
CONCENTRATION RESPIRATORY PROTECTION
UP TO 10 mg/m3: Dust, mist, and fume respirator or Supplied-Air Respirator (SAR).
3
UP TO 25 mg/m : Powered air-purifying respirator with dust, mist, and fume filter(s) or SAR operated in a continuous-flow
mode.
3
UP TO 50 mg/m : Full-facepiece respirator with high-efficiency particulate filter(s), powered air-purifying respirator with
tight-fitting facepiece and high-efficiency particulate filter(s), full-facepiece Self-Contained Breathing
Apparatus (SCBA), or full-facepiece SAR.
EMERGENCY OR PLANNED ENTRY INTO UNKNOWN CONCENTRATIONS OR IDLH CONDITIONS: Positive pressure, full-
facepiece SCBA or positive pressure, full-facepiece SAR with an auxiliary positive pressure SCBA.
ESCAPE: Full-facepiece respirator with high-efficiency particulate filter(s) or escape-type SCBA.
EYE PROTECTION: Safety glasses or goggles. Faceshields may be needed if operations generate splashes or sprays.
HAND PROTECTION: Wear neoprene or rubber gloves for routine industrial use.
BODY PROTECTION: None needed for normal circumstances of use. Use body protection appropriate for task (i.e., apron,
coveralls, chemically-resistant boots).
9. PHYSICAL and CHEMICAL PROPERTIES
RELATIVE VAPOR DENSITY (air = 1): 4.0 EVAPORATION RATE (nBuAc = 1): > 1
SPECIFIC GRAVITY (water = 1): 0.9 FREEZING/MELTING POINT: Not established.
SOLUBILITY IN WATER: Slightly soluble. BOILING POINT: Not established.
VAPOR PRESSURE: Not established. pH: Not applicable.
ODOR THRESHOLD: Not established.
COEFFICIENT OF OIL/WATER DISTRIBUTION (PARTITION COEFFICIENT): Not established.
APPEARANCE AND COLOR: This product is a clear, colorless liquid with a slight, sweet odor.
HOW TO DETECT THIS SUBSTANCE (warning properties): Litmus paper will turn red upon contact with this product. The odor
may also act as a distinguishing characteristic of this product.
SIWS PROVIDES MSDS AS A COURTISY. TO ENSURE ACCURATE AND CURRENT DATA, OBTAIN AND USE ONLY MSDS FROM MANUFACTURER. PAGE 4 OF 9
STAY CLEAN LIQUID SOLDERING FLUX
MATERIAL SAFETY DATA SHEET
10. STABILITY and REACTIVITY
STABILITY: Stable.
DECOMPOSITION PRODUCTS: Carbon monoxide, carbon dioxide, hydrogen chloride, nitrogen and zinc oxides, and ammonia.
MATERIALS WITH WHICH SUBSTANCE IS INCOMPATIBLE: Strong oxidizers, acids, alkalis and their carbonates, hydrogen
cyanide, interhalogens, ammonium nitrate, potassium chlorate, lead and silver salts.
HAZARDOUS POLYMERIZATION: Will not occur.
CONDITIONS TO AVOID: Extreme temperatures, incompatible materials.
PART IV Is there any other useful information about this material?
11. TOXICOLOGICAL INFORMATION
TOXICITY DATA: Human toxicological data are available for the components of this product, as listed below. Other data for
animals are available but are not presented in this Material Safety Data Sheet.
HYDROCHLORIC ACID: METHANOL (continued): METHANOL (continued):
LCLo (inhalation, human) = 1300 ppm/ 30 TDLo (oral, man) = 3429 mg/kg; eye effects TCLo (inhalation, human) = 300 ppm; eye,
central nervous system, pulmonary effects
minutes LDLo (oral, human) = 428 mg; central nervous
LCLo (inhalation, human) = 3000 ppm/ 5 system, pulmonary effects ZINC CHLORIDE:
minutes LDLo (oral, human) = 143 mg/kg; eye, DNA Inhibition System (human, lymphocyte) =
LDLo (unreported, man) = 81 mg/kg pulmonary, gastrointestinal effects 0.360 mmol/L
TDLo (oral, woman) = 4000 mg/kg; eye, 3
METHANOL: TCLo (inhalation, man) = 4800 mg/m / 30
pulmonary, gastrointestinal effects
DNA Inhibition System (lymphocyte, human) minutes; pulmonary effects
3
TCLo (inhalation, human) = 86000 mg/m ; eye, 3
300 mmol/L TCLo (inhalation, human) = 4800 mg/m / 3
pulmonary effects
LDLo (oral, man) = 6422 mg/kg; central hours
nervous system, pulmonary,
gastrointestinal effects
SUSPECTED CANCER AGENT: Hydrochloric Acid (a component of this product) is on the following list:
IARC Group 3, Not Classifiable as to Carcinogenicity to Humans
Zinc Chloride (a component of this product) is on the following list:
EPA-D, Not Classifiable as to Human Carcinogenicity.
The other components of this product are not found on the following lists: FEDERAL OSHA Z LIST, NTP, IARC, and
CAL/OSHA, and therefore are not considered to be, nor suspected to be, cancer-causing agents by these agencies.
IRRITANCY OF PRODUCT: This product can severely irritate and burn contaminated tissue.
SENSITIZATION TO THE PRODUCT: It has been reported that a worker developed asthmatic symptoms after performing
soldering work with a flux containing Ammonium and Zinc Chlorides (components of this product).
REPRODUCTIVE TOXICITY INFORMATION: Listed below is information concerning the effects of this product on the
human reproductive system.
Mutagenicity: This product is not reported to produce mutagenic effects in humans. Human mutation data are available
for Methanol and Zinc Chloride (components of this product); these data were obtained during clinical studies on specific
human tissues exposed to high doses of these compounds. Animal mutation data are available for Ammonium Chloride
and Hydrochloric Acid (components of this product); these data were obtained during clinical studies on specific animal
tissues exposed to high doses of these compounds.
Embryotoxicity: This product is not reported to produce embryotoxic effects in humans.
Teratogenicity: This product is not reported to cause teratogenic effects in humans. Clinical studies on test animals
exposed to relatively high doses of Methanol and Zinc Chloride (components of this product) indicate teratogenic effects.
Reproductive Toxicity: This product is not reported to cause adverse reproductive effects in humans. Clinical studies on
test animals exposed to relatively high doses of Hydrochloric Acid, Methanol, and Zinc Chloride (components of this
product) indicate adverse reproductive effects.
A mutagen is a chemical which causes permanent changes to genetic material (DNA) such that the changes will propagate
through generational lines. An embryotoxin is a chemical which causes damage to a developing embryo (i.e. within the first eight
weeks of pregnancy in humans), but the damage does not propagate across generational lines. A teratogen is a chemical which
causes damage to a developing fetus, but the damage does not propagate across generational lines. A reproductive toxin is
any substance which interferes in any way with the reproductive process.
SIWS PROVIDES MSDS AS A COURTISY. TO ENSURE ACCURATE AND CURRENT DATA, OBTAIN AND USE ONLY MSDS FROM MANUFACTURER. PAGE 5 OF 9
STAY CLEAN LIQUID SOLDERING FLUX
MATERIAL SAFETY DATA SHEET
11. TOXICOLOGICAL INFORMATION (Continued)
ACGIH BIOLOGICAL EXPOSURE INDICES: Currently, there is a ACGIH Biological Exposure Index (BEI) associated with
Methanol (a component of this product).
CHEMICAL DETERMINANT SAMPLING TIME BEI
METHANOL
?Methanol in urine ?End of shift ?15 mg/L
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Dermatitis, other skin disorders, and respiratory conditions may
be aggravated by over-exposure to this product.
RECOMMENDATIONS TO PHYSICIANS: Treat symptoms and eliminate overexposure. Provide oxygen, if necessary.
Pulmonary function tests, chest X-rays, and nervous system evaluations may prove useful. Consultation with an
ophthalmologist is recommended if eye exposure leads to tissue damage.
12. ECOLOGICAL INFORMATION
ALL WORK PRACTICES MUST BE AIMED AT ELIMINATING ENVIRONMENTAL CONTAMINATION.
ENVIRONMENTAL STABILITY: The components of this product will decompose under normal environmental conditions.
Additional environmental data are available as follows:
HYDROCHLORIC ACID: Water solubility: 56.5 g/ 100 cc (60?C); 82.3 g/ 100 cc (0?C).
METHANOL: Log Kow = -0.77. Water Solubility = Miscible. BOD (g/g) = 0.76-1.12 standard dilution/sewage seed. Methanol occurs naturally as a plant
volatile and during microbial degradation of biological wastes. When released on land or water, it is apt to volatilize and biodegrade. The estimated half-
life in water is 5.3 hours to 2.6 days. Methanol is highly mobile in soil. The Bioconcentration Factor for Methanol is 2.0.
65
ZINC CHLORIDE: Water solubility: 432 g/ 100 mL (25?C), 614 g/ 100 mL (100?C). Zinc can persist indefinitely as a cation. Radioactive zinc ( Zn) has
been found to concentrate in plants and milk. Acute Hazard Level Threshold: For vegetables and other crops - 750 ppm (Zn)
EFFECT OF MATERIAL ON PLANTS or ANIMALS: This product can be harmful to plant and animal life. Specific data on
test animals are available, but are not presented in this Material Safety Data Sheet.
EFFECT OF CHEMICAL ON AQUATIC LIFE: Large releases of this product may be harmful or fatal to exposed aquatic
life. Additional aquatic toxicity data are available as follows:
HYDROCHLORIC ACID: HYDROCHLORIC ACID (continued): ZINC CHLORIDE:
LC (Lepomis macrochirus, bluegill sunfish) =
LC100 (trout) = 10 mg/L/ 24 hours Acute Hazard Level Threshold: For fish - 0.1
LC50 (shrimp) = 100-330 ppm/ 48 hours(salt 3.6 mg/L/ 48 hours ppm (Zn)
LC50 (Lepomis macrochirus/bluegill sunfish)
water) Odorless zinc poisoning causes inflamed
LC50 (starfish) = 100-300 mg/L/ 48 hours = pH 3.0-3.5/ 96 hours gills in fish.
TLm (sunfish) = 96 hours/ pH 3.6/ 20癈
LC50 (cockle) = 330-1000 mg/L/ 48 hours Laboratory studies of Atlantic salmon,
TLm (Gambusia affinis, mosquito fish) = 282 rainbow trout, carp, and goldfish have
TLm (goldfish) = 96 hours/ pH 4/ 20?C
ppm/ 96 hours/ fresh water shown avoidance reactions by these fish
TLm (stickleback) = 96 hours/ pH 4.6/ 20?C
LC50 (Carassium auratus, goldfish) = 178 to zinc in water.
METHANOL: 65
mg/L (1-2 hour survival time) Radioactive zinc ( Zn) has been found to
LC50 (Pimephales promelas, fathead
LC50 (shore crab) = 240 mg/L/ 48 hours concentrate in aquatic life.
minnow) = 29.4 mg/L/ 96 hours
13. DISPOSAL CONSIDERATIONS
PREPARING WASTES FOR DISPOSAL: Waste disposal must be in accordance with appropriate U.S. Federal, State, and
local regulations or with regulations of Canada and its Provinces. This product, if unaltered by use, may be disposed of by
treatment at a permitted facility or as advised by your local hazardous waste regulatory authority.
U.S. EPA WASTE NUMBER: D002 (Characteristic/Corrosivity), applicable to wastes consisting only of this product.
14. TRANSPORTATION INFORMATION
THIS MATERIAL IS HAZARDOUS (Per 49 CFR 172.101) BY THE U.S. DEPARTMENT OF TRANSPORTATION.
PROPER SHIPPING NAME: Corrosive liquids, n.o.s. (Zinc Chloride, Hydrochloric Acid)
HAZARD CLASS NUMBER and DESCRIPTION: 8 (Corrosive)
UN IDENTIFICATION NUMBER: UN 1760
PACKING GROUP: III
DOT LABEL(S) REQUIRED: CORROSIVE
NOTE: Consumer commodity shipments of this product 1 gallon or less in volume may be renamed "Consumer Commodity"
and reclassed as ORM-D material. Refer to 49 CFR 173.154(c) for additional information.
NORTH AMERICAN EMERGENCY RESPONSE GUIDEBOOK NUMBER (1996): 154
MARINE POLLUTANT: The components of this product are not designated by the Department of Transportation to be
Marine Pollutants (49 CFR 172.101, Appendix B).TRANSPORT CANADA TRANSPORTATION OF DANGEROUS GOODS
REGULATIONS: THIS MATERIAL IS CONSIDERED AS DANGEROUS GOODS. Use the above information for the
preparation of Canadian shipments.
SIWS PROVIDES MSDS AS A COURTISY. TO ENSURE ACCURATE AND CURRENT DATA, OBTAIN AND USE ONLY MSDS FROM MANUFACTURER. PAGE 6 OF 9
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MATERIAL SAFETY DATA SHEET
15. REGULATORY INFORMATION
ADDITIONAL U.S. REGULATIONS:
U.S. SARA REPORTING REQUIREMENTS: The components of this product are subject to the reporting requirements of
Sections 302, 304, and 313 of Title III of the Superfund Amendments and Reauthorization Act, as follows:
CHEMICAL NAME SARA 302 SARA 304 SARA 313
(40 CFR 355, Appendix A) (40 CFR Table 302.4) (40 CFR 372.65)
Ammonium Chloride No Yes No
Hydrochloric Acid No Yes Yes
Methanol No Yes Yes
Yes (as Zinc Compound)
Zinc Chloride No Yes
U.S. SARA THRESHOLD PLANNING QUANTITY: Not applicable.
U.S. CERCLA REPORTABLE QUANTITY (RQ): Ammonium Chloride = 5000 lb.; Hydrochloric Acid = 5000 lb.; Methanol =
5000 lb.; Zinc Chloride = 1000 lb.
U.S. TSCA INVENTORY STATUS: The components of this product are listed on the TSCA Inventory.
OTHER U.S. FEDERAL REGULATIONS: Not applicable.
U.S. STATE REGULATORY INFORMATION: The components of this product are covered under specific State regulations,
as denoted below:
Alaska - Designated Toxic and Hazardous Minnesota - List of Hazardous Substances: Pennsylvania - Hazardous Substance List:
Substances: Ammonium Chloride Fume, Ammonium Chloride, Hydrochloric Acid, Ammonium Chloride, Hydrochloric Acid,
Hydrochloric Acid, Methanol, Zinc Chloride Methanol, Zinc Chloride Fume. Methanol, Zinc Chloride.
Fume. Michigan-Critical Materials Register: Zinc Rhode Island - Hazardous Substance List:
California - Permissible Exposure Limits for Compounds. Ammonium Chloride Fume, Hydrochloric
Chemical Contaminants: Ammonium Missouri - Employer Information/Toxic Acid, Methanol, Zinc Chloride Fume.
Chloride, Hydrochloric Acid, Methanol, Zinc Substance List: Ammonium Chloride, Texas - Hazardous Substance List:
Chloride Fume. Hydrochloric Acid, Methanol, Zinc Chloride. Hydrochloric Acid, Methanol, Zinc Chloride
Florida - Substance List: Ammonium Chloride, New Jersey - Right to Know Hazardous Fume.
Hydrochloric Acid, Methanol, Zinc Chloride Substance List: Ammonium Chloride, West Virginia - Hazardous Substance List:
Fume. Hydrochloric Acid, Methanol, Zinc Chloride. Hydrochloric Acid, Methanol, Zinc Chloride
Illinois - Toxic Substance List: Ammonium North Dakota - List of Hazardous Chemicals, Fume.
Chloride Vapor, Hydrochloric Acid, Methanol, Reportable Quantities: Ammonium Wisconsin - Toxic and Hazardous
Zinc Chloride Fume. Chloride, Hydrochloric Acid, Methanol, Zinc Substances: Hydrochloric Acid, Methanol,
Kansas - Section 302/313 List: Hydrochloric Chloride. Zinc Chloride Fume.
Acid, Methanol.
Massachusetts - Substance List: Ammonium
Chloride, Hydrochloric Acid, Methanol, Zinc
Chloride Fume.
CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT (PROPOSITION 65): No component of this
product is on the California Proposition 65 Lists.
ANSI LABELING (Z129.1): DANGER! CORROSIVE. MAY BE HARMFUL OR FATAL IF INHALED OR SWALLOWED.
CAUSES SKIN OR EYE BURNS. Do not taste or swallow. Do not get on skin or in eyes. Avoid breathing vapors or mist.
Keep container closed. Use only with adequate ventilation. Wash thoroughly after handling. Wear gloves, goggles, face-
shields, suitable body protection, and NIOSH/MSHA-approved respiratory protection, as appropriate. FIRST-AID: In case of
contact, immediately flush skin or eyes with plenty of water for at least 15 minutes while removing contaminated clothing and
shoes. If inhaled, remove to fresh air. If ingested, do not induce vomiting. Get medical attention. IN CASE OF FIRE: Use
water fog, dry chemical, CO2, or "alcohol" foam. IN CASE OF SPILL: Absorb spill with polypads or other suitable absorbent
materials. Neutralize with agent suitable for acids. Place residue in suitable container and seal. Consult Material Safety
Data Sheet for additional information.
ADDITIONAL CANADIAN REGULATIONS:
CANADIAN DSL/NDSL INVENTORY STATUS: The components of this product are on the DSL/NDSL Lists.
OTHER CANADIAN REGULATIONS: Not applicable.
CANADIAN ENVIRONMENTAL PROTECTION ACT (CEPA) PRIORITIES SUBSTANCES LISTS: The components of this
product are not on the CEPA Priorities Substances Lists
SIWS PROVIDES MSDS AS A COURTISY. TO ENSURE ACCURATE AND CURRENT DATA, OBTAIN AND USE ONLY MSDS FROM MANUFACTURER. PAGE 7 OF 9
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MATERIAL SAFETY DATA SHEET
15. REGULATORY INFORMATION (Continued)
CANADIAN WHMIS SYMBOLS:
D1B: Poisonous and Infectious Materials/ Immediate and Serious Toxic Effects. E: Corrosive Material.
.
16. OTHER INFORMATION
PREPARED BY: CHEMICAL SAFETY ASSOCIATES, Inc.
9163 Chesapeake Drive, San Diego, CA 92123-1002
619/565-0302
This Material Safety Data Sheet is offered pursuant to OSHA's Hazard Communication Standard (29 CFR 1910.1200). Other government regulations
must be reviewed for applicability to this product. The information contained herein relates only to the specific product. If the product is combined with
other materials, all component properties must be considered. To the best of the J.W. Harris Company, Inc.'s knowledge, the information and
recommendations contained in this publication are reliable and accurate as the date of issue. However, accuracy, suitability, or completeness are not
guaranteed, and no warranty, guarantee, or representation, expressed or implied, is made by J.W. Harris Co., Inc. as to the absolute correctness or
sufficiency of any representation contained in this and other publications; J.W. Harris Co., Inc. assumes no responsibility in connection therewith; nor
can it be assumed that all acceptable safety measures may not be required under particular or exceptional conditions or circumstances. Data may be
changed from time to time. Be sure to consult the latest edition.
DEFINITIONS OF TERMS
A large number of abbreviations and acronyms appear on a MSDS. Some of these which are commonly used include the following:
CAS #: This is the Chemical Abstract Service Number which uniquely identifies each constituent. It is used as a unique identifier for the chemical.
EXPOSURE LIMITS IN AIR: 1 (materials that require substantial pre-heating before burning); 2
(combustible liquid or solids; liquids with a flash point of 38-93癈 [100-200?F]);
ACGIH - American Conference of Governmental Industrial Hygienists, a 3 (Class IB and IC flammable liquids with flash points below 38?C [100?F]); 4
professional association which establishes exposure limits. TLV - Threshold
(Class IA flammable liquids with flash points below 23?C [73?F] and boiling
Limit Value - an airborne concentration of a substance which represents
points below 38?C [100?F]. Reactivity Hazard: 0 (normally stable); 1 (material
conditions under which it is generally believed that nearly all workers may be
that can become unstable at elevated temperatures or which can react slightly
repeatedly exposed without adverse effect. The duration must be considered,
with water); 2 (materials that are unstable but do not detonate or which can
including the 8-hour Time Weighted Average (TWA), the 15-minute Short
react violently with water); 3 (materials that can detonate when initiated or
Term Exposure Limit, and the instantaneous Ceiling Level (C). Skin
which can react explosively with water); 4 (materials that can detonate at
absorption effects must also be considered.
normal temperatures or pressures). PPE Rating D: Hand, eye, face, and
OSHA - U.S. Occupational Safety and Health Administration.
body protection is required for routine chemical use.
PEL - Permissible Exposure Limit - This exposure value means exactly the
same as a TLV, except that it is enforceable by OSHA. The OSHA
NATIONAL FIRE PROTECTION ASSOCIATION: Health Hazard: 0 (material
Permissible Exposure Limits are based in the 1989 PELs and the June, 1993
that on exposure under fire conditions would offer no hazard beyond that of
Air Contaminants Rule (Federal Register: 58: 35338-35351 and 58: 40191).
ordinary combustible materials); 1 (materials that on exposure under fire
Both the current PELs and the vacated PELs are indicated. The phrase,
conditions could cause irritation or minor residual injury); 2 (materials that on
"Vacated 1989 PEL," is placed next to the PEL which was vacated by Court
intense or continued exposure under fire conditions could cause temporary
Order. IDLH - Immediately Dangerous to Life and Health - This level
incapacitation or possible residual injury); 3 (materials that can on short
represents a concentration from which one can escape within 30-minutes
exposure could cause serious temporary or residual injury); 4 (materials that
without suffering escape-preventing or permanent injury. The DFG - MAK is
under very short exposure causes death or major residual injury).
the Republic of Germany's Maximum Exposure Level, similar to the U.S. PEL.
Flammability Hazard and Reactivity Hazard: Refer to definitions for
NIOSH is the National Institute of Occupational Safety and Health, which is
"Hazardous Materials Identification System".
the research arm of the U.S. Occupational Safety and Health Administration
(OSHA). NIOSH issues exposure guidelines called Recommended Exposure
Levels (RELs). When no exposure guidelines are established, an entry of NE
FLAMMABILITY LIMITS IN AIR:
is made for reference.
Much of the information related to fire and explosion is derived from the
HAZARD RATINGS: National Fire Protection Association (NFPA). Flash Point - Minimum
HAZARDOUS MATERIALS IDENTIFICATION SYSTEM: This rating system temperature at which a liquid gives off sufficient vapors to form an ignitable
was developed by the National Paint and Coating Association and has been mixture with air. Autoignition Temperature: The minimum temperature
adopted by industry to identify the degree of chemical hazards. Health required to initiate combustion in air with no other source of ignition. LEL - the
Hazard: 0 (minimal acute or chronic exposure hazard); 1 (slight acute or lowest percent of vapor in air, by volume, that will explode or ignite in the
chronic exposure hazard); 2 (moderate acute or significant chronic exposure presence of an ignition source. UEL - the highest percent of vapor in air, by
hazard); 3 (severe acute exposure hazard; onetime overexposure can result in volume, that will explode or ignite in the presence of an ignition source.
permanent injury and may be fatal); 4 (extreme acute exposure hazard;
TOXICOLOGICAL INFORMATION:
onetime overexposure can be fatal). Flammability Hazard: 0 (minimal hazard);
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MATERIAL SAFETY DATA SHEET
Human and Animal Toxicology: Possible health hazards as derived from
human data, animal studies, or from the results of studies with similar
compounds are presented. Definitions of some terms used in this section are:
LD50 - Lethal Dose (solids & liquids) which kills 50% of the exposed animals;
LC50 - Lethal Concentration (gases) which kills 50% of the exposed animals;
ppm concentration expressed in parts of material per million parts of air or
3
water; mg/m concentration expressed in weight of substance per volume of
air; mg/kg quantity of material, by weight, administered to a test subject,
based on their body weight in kg. Other measures of toxicity include TDLo,
the lowest dose to cause a symptom and TCLo the lowest concentration to
cause a symptom; TDo, LDLo, and LDo, or TC, TCo, LCLo, and LCo, the
lowest dose (or concentration) to cause lethal or toxic effects. Cancer
Information: The sources are: IARC - the International Agency for Research
on Cancer; NTP - the National Toxicology Program, RTECS - the Registry of
Toxic Effects of Chemical Substances, OSHA and CAL/OSHA. IARC and
NTP rate chemicals on a scale of decreasing potential to cause human cancer
with rankings from 1 to 4. Subrankings (2A, 2B, etc.) are also used. Other
Information: BEI - ACGIH Biological Exposure Indices, represent the levels
of determinants which are most likely to be observed in specimens collected
from a healthy worker who has been exposed to chemicals to the same extent
as a worker with inhalation exposure to the TLV. Ecological Information:
EC is the effect concentration in water. BCF = Bioconcentration Factor, which
is used to determine if a substance will concentrate in lifeforms which
consume contaminated plant or animal matter. TLm = median threshold limit;
Coefficient of Oil/Water Distribution is represented by log Kow or log Koc and
is used to assess a substance's behavior in the environment.
REGULATORY INFORMATION:
This section explains the impact of various laws and regulations on the
material. U.S.: EPA is the U.S. Environmental Protection Agency. DOT is the
U.S. Department of Transportation. SARA is the Superfund Amendments and
Reauthorization Act. TSCA is the U.S. Toxic Substance Control Act.
CERCLA (or Superfund) refers to the Comprehensive Environmental
Response, Compensation, and Liability Act. Labeling is per the American
National Standards Institute (ANSI Z129.1). CANADA: CEPA is the
Canadian Environmental Protection Act. WHMIS is the Canadian Workplace
Hazardous Materials Information System. TC is Transport Canada.
DSL/NDSL are the Canadian Domestic/Non-Domestic Substance.
SIWS PROVIDES MSDS AS A COURTISY. TO ENSURE ACCURATE AND CURRENT DATA, OBTAIN AND USE ONLY MSDS FROM MANUFACTURER. PAGE 9 OF 9
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