CHRISTRIO
Manufacturer of Beauty Products
1950 Compton Ave. Ste. 103
Corona, CA. 92881
Phone: (951) 808 ?4730 Fax: (951) 808 ?4734
MATERIAL SAFETY DATA SHEET
Section I: Product and Company Identification
Product name: Deluxe Acrylic Monomer
Chemical Name: N/A
CHRISTRIO CORP.
Manufacturer:
Family Name: Monomer 1950 Compton Ave. #103
Corona, CA. 92881
Product Use: Liquid Emergency Phone #: 800 535- 5053
International Phone #: 1-352-323-3500
Information Contact: (951) 808 ?4730
Section II: Product composition/Ingredients
Limits
Exposure Carcinogen
ACGIH
Chemical Identity CAS# INCI Name %
IARC/NTP/
OSHA
TWA/ST
TWA/STEL OSHA
EL
Ethyl
Ethyl Methacrylate 97-63-2 N/E N/E Not Listed 83
Methacrylate
Hydroxyethyl
Hydroxyethyl Methacrylate 868-77-9 N/E N/E Not Listed 8
Methacrylate
Triethylene Glycol
Triethylene Glycol
109-16-0 N/E N/E Not Listed 6
Dimethacrylate
Dimethacrylate Esters Esters
Dimethyl p
Dimethyl p Toluidine 99-97-8 N/E N/E Not Listed 2
Toluidine
Benzophenone-12 25973-55-1 N/E N/E Not Listed .7
Benzophenone-12
2-Hydroxy-4-n-
2-Hydroxy-4-n-
1843-05-6 N/E N/E Not Listed .3
octoxybenzopheno
octoxybenzophenone ne
Hazard symbols: Xi, F, N Risk Phrases: R11, R36/38, R51/53, R65, R67 Safety Phrases: S7/9,
S16, S33, S36/37, S46
N/E ?None Established
N/R ?Not Reviewed
ND/A ?No Data Available
N/A ?Not Available
Section III: Hazard Identification
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EMERGENCY OVERVIEW
Flammable liquid and vapor!
Aspiration hazard if swallowed.
Can enter lungs and cause damage.
May cause eye, skin or respiratory tract irritation.
Dangerous for the environment.
Protential Health Effects, Sign and Symptoms of Exposure:
Primary Route of Entry Inhalation, skin contact, eye contact.
Eye Exposure causes eye irritation. Symptoms include stinging, tearing,
redness and swelling.
Skin Can cause skin irritation. Prolonged or repeated contact may dry skin.
Symptoms may include redness, burning, drying, cracking, and skin
burns.
Ingestion Causes gastrointestinal irritation with nausea, vomiting and diarrhea.
Aspiration of material into lungs may cause chemical pneumonitis
which may be fatal. May cause agitation, delirium, convulsions and
muscle spasms.
Inhalation Inhalation of high concentrations may cause central nervous system
effects characterized by nausea, headache, dizziness, unconsciousness
and coma. Causes respiratory tract irritation. Aspiration may lead to
pulmonary edema. Vapors may cause dizziness or suffocation.
Sub-Chronic effects Prolonged or repeated skin contact may cause dermatitis. Effects may
be delayed. Chronic exposure may cause thyroid damage with thyroid
enlargement, a decrease in metabolic rate, the symptoms of
hypothyroidism and reduction in the protein-bound fraction of the
serum iodine and in the thyroxine content of the thyroid gland. May
cause skin rashes, occasionally an exfoilative dermatitis occurs and
may prove fatal.
NOTE: Refer to Section 11, Toxicological Information for details.
Section IV: First Aid Measure
First Aid for Eye If symptoms develop, move individual away from exposure and into
fresh air. Flush eyes gently for 15 minutes with water while holding
eyelids apart. If symptoms persist or there is any visual difficulty, seek
medical attention.
First Aid for Skin Remove contaminated clothing and wash exposed area with soap and
water. If symptoms persist, seek medical attention.
First Aid for Inhalation Remove to fresh air. If breathing is difficult, administer oxygen. If
symptoms persist, seek medical attention.
First Aid for Ingestion Do NOT induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Possible aspiration hazard. Get medical
attention immediately.
Section V: Fire fighting Measures
Flash Point Flammable Limit Auto-ignition Temperature
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(篎/篊) (Vol %) (Vol %)
TAG CLOSED 40癋/4.44? 400ppm ND/A
Method:
Extinguishing Media: Foam, dry chemical, cold water spray
Fire Fighting Instructions: Cool fire exposed containers with water, remove away from building.
Use self-contained breathing apparatus to fight fire.
Unusual Hazards: When exposed to heat and flame, material is a fire explosion hazard.
It may produce toxic products CO, Carbon Dioxide and oxides of
nitrogen.
Section VI: Accident Release Measures
Spill or Release Procedure: Eliminate all sources of heat and ignition. Use absorbent material for
spills and dike it, wash spilled material into retaining containers.
Place containers in well ventilated area. Consult an expert on disposal
of recovered material and ensure conformity to local disposal
regulations. Keep unnecessary and unprotected personnel from
entering. Contain and recover liquid when possible. Use non-sparking
tools and equipment. Collect liquid in an appropriate container or
absorb with inert materials (e.g. vermiculite, dry sand, earth) and
place in a chemical waste container. Do not use combustible
materials such as sawdust. Do not flush in sewer! US Regulations
(CERCLA) require reporting spills and releases to soil, water and air
in excess of reportable quantities. The toll free number for the US
Coast Guard National Response Center is (800)424-8802. EU
Regulations require the consultation of directive 98/24/EC. If a leak
or spill has not ignited, use water spray to disperse the vapors, to
protect personnel attempting to stop leak and to flush spills away
from exposures.
Section VII: Handling and Storage
Handling: Wash thoroughly after handling. Ground and bond containers when
transferring material. Use spark-proof tools and explosion proof
equipment. Avoid contact with eyes, skin and clothing. Empty
containers retain product residue and can be dangerous. Keep
containers tightly closed. Avoid contact with heat, sparks and flames.
Do not pressurize, cut, weld, braze, solder, drill, grind or expose empty
containers to heat sparks or open flame. Use only with adequate
ventilation. Avoid breathing vapor.
Storage: Keep away from heat, sparks and flame. Store in well ventilated area.
Store @ 70 + 15癋, allow some air space above liquid level. Keep
containers closed while not in use.
Explosion Hazard: Vapors are heavier than air and may travel along the ground or may be
moved by ventilation and ignited by pilot lights, other flames, sparks,
heaters, smoking or other ignition sources at locations distant from
material handling point. Never use welding or cutting torch on or neat
drum (even empty) because product (even just residue) can ignite
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explosively.
Section VIII: Exposure Controls/Personal Protective Equipment
Engineering Control Facilities storing or ultilizing this material should be equipped with an
eye facility and safety shower. Use process enclosures local exhaust
ventilation, or other engineering controls to control airborne levels
below recommended exposure limits. Use explosion-proof ventilation
equipment.
IDLH for: CAS# 142-82-5: 750 ppm (NIOSH)
CAS# 141-78-6: 10% lower explosive limit
CAS#: 67-63-0: 10% lower explosive limit
Personal Protective Equipment
General To identify additional Personal Protective Equipment (PPE)
requirements, it is recommended that a hazard assessment in
accordance with the OSHA PPE Standard (29CFR1910.132), or
European Standard EN166 be conducted before using this product .
Provide eye wash stations and safety showers. Wear impervious
clothing to prevent ANY contact with this product, such as gloves,
apron, boots, or whole body suit. Nitrile rubber is better than PVC.
Eye/Face Protection Use impermeable clothing to prevent ANY contact with this product,
such as gloves, apron, boots, or whole body suit. Nitrile rubber is better
than PVC.
Skin Protection Wear resistant gloves. To prevent repeated or prolonged skin contact,
wear impervious clothing and boots.
Respirator Protection A NIOSH/MSHA approved air purifying respirator with an organic
vapor cartridge or canister may be permissible under certain limited
circumstances where airborne concentrations are expected to exceed
exposure limits. Protection provided by nuisance level organic vapor
dust masks can be used; however the use of the respirator is limited.
Follow OSHA respirator regulations found in 29 CFR 1910.134 or
European Standard EN 149.
Section XI: Physical and Chemical Properties
Odor & Odor Special %
Appearance pH Viscosity
Threshold Gravity Volatile
Clear liquid N/A (H2O=1):0.98 N/A 99+
Fruity Ester Odor
Decomposition Octanol/Water Vapor Vapor Evaporation Ignition Solubility
Boiling
Point/ Temperature Partitioning Pressure Density Rate in Water
Freezing (20C)
Coefficient
Point Log Po/w
N/A N/A N/A (Air=1):1 N/A N/A Insoluble
170?77篊)
Flash Point Flammable Limit Auto-ignition Temperature
(篎/篊) (vol%) (vol%)
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TAG CLOSED 40癋/4.44? 400ppm ND/A
Section X: Stability and Reactivity
Stability: Stable Incompatibility (Materials to Avoid):
Avoid oxidizing agents, acids & bases (heat).
Hazardous Decomposition Products: Heated Hazardous Polymerization: Will not occur.
material produce NO2, CO2, CO.
Condition to Avoid: Heat, flame, ignition sources.
Section XI: Toxicological Information
Acute Oral Acute Dermal Acute Inhalation Irritation-Skin Irritation-Eye
Toxicity Toxicity Toxicity
Inhalation, rat: LC50
Oral, rat: LD50 Skin, rabbit: LD50 CAS#142-82-5= 103
Mild Mild
CAS#141-78-6 = 5620 mg/kg CAS#141-78-6= >20 mg/kg gm/m3/4H
CAS#67-63-0 = 5045 mg/kg CAS#67-63-0= 12800 mg/kg CAS#141-78-6= 200 gm/m3
Sensitization Mutagenicity Sub-chronic Toxicity
CAS#: 141-78-6 = Hamster fibroblast 9g/L
ND/A ND/A
sex chromosome Loss/Non-disjunction:
S. Cerevisiae 24400ppm
RTECS#: CAS#142-82-5, MI7700000
CAS#141-78-6, AH5425000
CAS#67-63-0, unlisted
Section XII: Ecological Information
Acute
Acute Toxicity to
Toxici
Acute Toxicity Fish Toxicity to Sewage
Bioconcentration
ty to
Invertebrate Bacteria
Algae
CAS#142-82-5= Goldfish: LC50 = 4.0 mg/L/24H
N/DA N/DA N/DA N/DA
CAS#141-78-6= Flathead minnow: LC50= 230mg/L/96H
CAS#67-63-0= Flathead minnow: LC50= 1000 mg/L/96H
Chemical Fate Information
Biodegradability The substance is toxic to aquatic organisms. In the food chain
important to humans, bioaccumulation takes place, specifically in
fish. No other information available.
Chemical Oxygen Demand ND/A
To the best of our knowledge, the ecotoxocological and chemical fate properties have not been thoroughly investigated.
Do not allow to enter drinking water supplies, wastewater, or soil.
Section XIII: Disposable Concentrations
Dispose of diking materials and absorbent in compliance with State, Local, and Federal regulations. Residual vapors
may explode on ignition; do not cut, drill, or weld on or near the container. Mix with compatible chemical which is less
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flammable and incinerate. Whatever cannot be saved for recovery or recycling should be handled as hazardous waste
and sent to a RCRA approved waste
facility. Processing, use or contamination of this product may change the waste management options. State and local
disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in
accordance with federal, state and local requirements. For EU Member States, please refer to any relevant Community
provisions relating to waste. In their absence, it is useful to remind the user that national or regional provisions may be
in force.
Section XIV: Transport Information
DOT/UN
Shipping Name: UN1993, Flammable liquids, n.o.s., (heptane, ethyl
acetate), 3, PGII
Identification Number: UN1993
Marine Pollutant: T8, T31
Special Provisions: None
Emergency Response Guidebook (ERG) #: 128
IATA (DGR)
Proper Shipping Name: UN1993, Flammable liquids, n.o.s., (heptane, ethyl
acetate), 3, PGII
Class or Division: 3
UN or ID Number: UN1993
Packaging Instructions:
Emergency Response Guidance (ICAO) #:
IMO (IMDG):
Proper Shipping Name: UN1993, Flammable liquids, n.o.s., (heptane, ethyl
acetate), 3, PGII
Class of Division: 3.2
UN or ID Number: UN1993
Special Provision & Storage/Segregation: None
Emergency Schedule (EmS)#: N/A
Other Information: Flash point > Flash point = 4.44篊
Section XV: Regulatory Informatio
US Federal Regulations:
US Federal Regulations:
Clean Air act: This product contains the following Hazardous Air Pollutant ( HAP's):
HAP/ODS ?None
Clean Water Act: The following ingredients are listed as hazardous pollutants under the
Priority Pollutant List CWA: None
FDA: Food Packaging This product has not been cleared by the FDA for use in food packaging
Status and/or other applications and indirect food packaging additive.
Occupational Safety and This product is considered to be hazardous under the OSHA Hazard
Health Act Communication Standard. It's hazards are:
?Immediate (acute) health hazard
?Chronic (delayed) health hazard
?Fire hazard
RCRA This product contains the following chemicals considered to be
hazardous waste under RCRA (40 CFR 261).Ethyl Acetate CAS # 141-
78-6 RCRA Code: U112
This product contains the following chemicals regulated under Section
SARA Title III: Section
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304 as extremely hazardous chemicals for emergency release
302 (TPQ)
notification ("CERCLA" List ):
?Ethyl Acetate CAS #141-78-6 RQ (Lbs) 5000
SARA Title III: Section This product contains no chemicals regulated under Sec. 302 as extremely
302(RQ) hazardous substances.
SARA Title III: This product is considered to be hazardous under OSHA Hazard
Section 311-312 Communication Standard and is regulated under Section 311-312 (40 CFR
370). Is hazard are:
?Immediate (acute) health hazard
?Chronic (delayed) health hazard
?Fire hazard
SARA Title III: Section This product contains the following chemicals which are subject to the
313 reporting requirements of Section 313 of Title III of the Superfund
Amendments and Reauthorization Act of 1986 and 40 CFR part 372:
Isopropyl Alcohol CAS #67-63-0.
TSCA Section 8 (b): This product contains chemical listed on the TSCA inventory or otherwise
Inventory complies with TSCA pre-manufacture notification requirements.
TSCA Significant New TSCA premanufacture notification requirements.
None of the chemicals in this material have a SNUR under TSCA.
Use Rule
State Regulations:
CA Right-to-Know law: Ethyl Acetate CAS # 141-78-6; Heptane CAS #142-82-5: Isopropyl Alcohol CAS #
67-63-0.
CA No Significant Risk Rule:
MA Right-to-Know Law: Ethyl Acetate CAS # 141-78-6; Heptane CAS # 142-82-5; Isopropyl Alcohol CAS
# 67-63-0.
NJ Right-to-Know Law: Ethyl Acetate CAS # 141-78-6; Heptane CAS # 142-82-5; Isopropyl Alcohol CAS
# 67-63-0.
PA Right-to-Know Law: Ethyl Acetate CAS # 141-78-6; Heptane CAS # 142-82-5; Isopropyl Alcohol CAS
# 67-63-0.
FL Right-to-Know Law: Ethyl Acetate CAS # 141-78-6; Heptane CAS # 142-82-5; Isopropyl Alcohol CAS
# 67-63-0.
MN Right-to-Know Law: Ethyl Acetate CAS # 141-78-6; Heptane CAS # 142-82-5; Isopropyl Alcohol CAS
# 67-63-0.
International Regulations:
CDSL: Canadian Inventory Heptane CAS# 142-82-5 is on the DSL List. WHMIS = B2, D2B.
Ethyl acetate CAS #141-78-6 is on the DSL list. WHMIS = B2, D2B.
(on Canadian Transitional List)
Isopropyl alcohol CAS #67-63-0 is on the DSL list. WHMIS = B2, D2B.
Tolnaftate CAS# 2398-96-1 is on the DSL List. WHMIS = N/DA
EINECS: European Inventory: Isopropyl Alcohol CAS # 67-63-0.
Antifungal Solution:
?HAZARD SYMBOLS: Xi: Irritant, F: Highly Flammable, N: Dangerous
for Environment
?RISK PHRASES: R11: highly flammable, R36/38: Irritating to eyes and
skin, R51/53: toxic to aquatic organisms, may cause long-term adverse
effects in the aquatic environment, R65: Harmful, may cause lung
damage if swallowed, R67: Vapors may cause drowsiness and dizziness.
?SAFETY PHRASES: S7/9: keep container tightly closed and in a well-
ventilated place, S16: keep away from sources of ignition- no smoking,
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S33: Take precautionary measures against static discharges, S36/37:
Wear suitable protective clothing and gloves, S46: If swallowed seek
medical advice immediately and show this container or label.
Section XVI: Other Information
Hazard Rating System
NFPA: Health 2/ Flammability 3/ Reactivity 0
HMIS: Health 2/ Flammability 3/ Reactivity 0
Revised: Sept. 30th, 2008
Revised Sections since Last Version Section 2-16 contents and format update throughout.
The information presented herein was obtained from sources considered to be liable. However, this
information is provided without any warranty, expressed or implied, regarding its correctness or
suitability for consumers intended to use and/or application. For this and other reasons, we assume
no responsibility and expressly disclaim liability for loss, damage or expense arising out of any way
connected with handling, storage, use or disposal of the product. This MSDS was prepared
expressly for this product. Use the materials only directed. If the product is used as a component of
other product, the information contained within the MSDS may not be applicable. If one could
have any concerns with or problems understanding this MSDS form, please direct all questions to
INFOTRAC, Chemical Emergency Resources System at (800) 535-5053.
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