Material Safety Data Sheet
Product name : Titebond Liquid Hide Glue
1. Product and company identification
CAS # : mixture
Address : Franklin International
2020 Bruck Street
Columbus OH 43207
Contact person : Franklin Technical Services
Telephone : (800) 877-4583
Emergency phone: : Franklin Security
(614) 445-1300
Reference number : 1103
: 5012
Product code
Date of revision : 4/29/2010.
Print date : 4/29/2010.
Chemtrec (24 Hour) : (800) 424 - 9300
Chemtrec International : (703) 527 - 3887
Chemical family : Adhesive.
Product use : Hide Glue
: Protein Dispersion
Product type
2. Hazards identification
Physical state : Liquid.
Odor : Characteristic. [Slight]
OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
Emergency overview : WARNING!
CAUSES EYE IRRITATION. MAY BE HARMFUL IF SWALLOWED. MAY CAUSE
RESPIRATORY TRACT AND SKIN IRRITATION. MAY CAUSE TARGET ORGAN
DAMAGE.
May be harmful if swallowed. Irritating to eyes. Slightly irritating to the skin and
respiratory system. Do not ingest. Avoid breathing vapor or mist. Avoid contact with
eyes, skin and clothing. May cause target organ damage. Use only with adequate
ventilation. Keep container tightly closed and sealed until ready for use. Wash
thoroughly after handling.
Routes of entry : Eye contact. Ingestion.
Potential acute health effects
Inhalation : Slightly irritating to the respiratory system. Exposure to decomposition products may
cause a health hazard. Serious effects may be delayed following exposure.
Ingestion : Harmful if swallowed.
Skin : Slightly irritating to the skin.
Eyes : Irritating to eyes.
Potential chronic health effects
Chronic effects : May cause target organ damage.
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2. Hazards identification
Carcinogenicity : No known significant effects or critical hazards.
Mutagenicity : No known significant effects or critical hazards.
Teratogenicity : No known significant effects or critical hazards.
Developmental effects : No known significant effects or critical hazards.
Fertility effects : No known significant effects or critical hazards.
Target organs : May cause damage to the following organs: upper respiratory tract, skin, eyes.
Contains material which may cause damage to the following organs: gastrointestinal
tract.
Over-exposure signs/symptoms
Inhalation : Adverse symptoms may include the following:
respiratory tract irritation
coughing
Ingestion : No specific data.
Skin : Adverse symptoms may include the following:
irritation
redness
Eyes : Adverse symptoms may include the following:
pain or irritation
watering
redness
Medical conditions : Pre-existing disorders involving any target organs mentioned in this MSDS as being at
risk may be aggravated by over-exposure to this product.
aggravated by over-
exposure
See toxicological information (section 11)
3. Composition/information on ingredients
United States
Name CAS number %
ammonium thiocyanate 1762-95-4 1-5
cyanoguanidine 461-58-5 1-5
Canada
Name CAS number %
ammonium thiocyanate 1762-95-4 1-5
Mexico Classification
Name CAS number UN number % IDLH H F R Special
ammonium thiocyanate 1762-95-4 Not 1-5 - 2 1 0
available.
cyanoguanidine 461-58-5 Not 1-5 - 2 0 0
available.
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in
this section.
4. First aid measures
Eye contact : Check for and remove any contact lenses. Immediately flush eyes with plenty of water
for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical
attention immediately.
Skin contact : In case of contact, immediately flush skin with plenty of water for at least 15 minutes
while removing contaminated clothing and shoes. Wash clothing before reuse. Clean
shoes thoroughly before reuse. Get medical attention immediately.
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4. First aid measures
Inhalation : Move exposed person to fresh air. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel.
Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention
immediately.
Ingestion : Wash out mouth with water. Do not induce vomiting unless directed to do so by medical
personnel. Never give anything by mouth to an unconscious person. Get medical
attention immediately.
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. It may
be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Notes to physician : In case of inhalation of decomposition products in a fire, symptoms may be delayed.
The exposed person may need to be kept under medical surveillance for 48 hours.
5. Fire-fighting measures
Flammability of the product : In a fire or if heated, a pressure increase will occur and the container may burst.
Extinguishing media
Suitable : Use an extinguishing agent suitable for the surrounding fire.
Not suitable : None known.
Special exposure hazards : Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training.
Special protective : Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.
equipment for fire-fighters
6. Accidental release measures
Personal precautions : No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Avoid breathing vapor or mist.
Provide adequate ventilation. Wear appropriate respirator when ventilation is
inadequate. Put on appropriate personal protective equipment (see section 8).
Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
Small spill : Stop leak if without risk. Move containers from spill area. Dispose of via a licensed
waste disposal contractor. Absorb with an inert material.
Large spill : Stop leak if without risk. Move containers from spill area. Approach release from
upwind. Prevent entry into sewers, water courses, basements or confined areas.
Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth,
vermiculite or diatomaceous earth and place in container for disposal according to local
regulations (see section 13). Dispose of via a licensed waste disposal contractor.
Contaminated absorbent material may pose the same hazard as the spilled product.
Note: see section 1 for emergency contact information and section 13 for waste
disposal.
7. Handling and storage
Handling : Put on appropriate personal protective equipment (see section 8). Eating, drinking and
smoking should be prohibited in areas where this material is handled, stored and
processed. Workers should wash hands and face before eating, drinking and smoking.
Do not ingest. Avoid contact with eyes, skin and clothing. Avoid breathing vapor or mist.
Use only with adequate ventilation. Wear appropriate respirator when ventilation is
inadequate. Keep in the original container or an approved alternative made from a
compatible material, kept tightly closed when not in use. Empty containers retain
product residue and can be hazardous. Do not reuse container.
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7. Handling and storage
Storage : Store in accordance with local regulations. Store in original container protected from
direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials
(see section 10) and food and drink. Keep container tightly closed and sealed until ready
for use. Containers that have been opened must be carefully resealed and kept upright
to prevent leakage. Do not store in unlabeled containers. Use appropriate containment
to avoid environmental contamination.
8. Exposure controls/personal protection
Canada
Occupational exposure limits TWA (8 hours) STEL (15 mins) Ceiling
Ingredient List name ppm mg/m?Other ppm mg/m?Other ppm mg/m?Other Notations
No exposure limit value known.
Consult local authorities for acceptable exposure limits.
Recommended monitoring : If this product contains ingredients with exposure limits, personal, workplace atmosphere
or biological monitoring may be required to determine the effectiveness of the ventilation
procedures
or other control measures and/or the necessity to use respiratory protective equipment.
Engineering measures : Use only with adequate ventilation. If user operations generate dust, fumes, gas, vapor
or mist, use process enclosures, local exhaust ventilation or other engineering controls
to keep worker exposure to airborne contaminants below any recommended or statutory
limits.
Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period. Appropriate
techniques should be used to remove potentially contaminated clothing. Wash
contaminated clothing before reusing. Ensure that eyewash stations and safety showers
are close to the workstation location.
Personal protection
Respiratory : Use a properly fitted, air-purifying or air-fed respirator complying with an approved
standard if a risk assessment indicates this is necessary. Respirator selection must be
based on known or anticipated exposure levels, the hazards of the product and the safe
working limits of the selected respirator.
Hands : Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary.
Eyes : Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists or
dusts.
Skin : Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before handling
this product.
Environmental exposure : Emissions from ventilation or work process equipment should be checked to ensure they
comply with the requirements of environmental protection legislation.
controls
9. Physical and chemical properties
Physical state : Liquid.
Flash point : Closed cup: >93.3癈 (>199.9癋) [Setaflash.]
Color : Amber.
Odor : Characteristic. [Slight]
pH : 6.5
Boiling/condensation point : 100癈 (212癋)
Relative density : 1.15
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9. Physical and chemical properties
Volatility : 48% (w/w)
VOC (less water, less : 0 g/l
exempt solvents)
Solubility : Soluble in the following materials: cold water and hot water.
10 . Stability and reactivity
Chemical stability : The product is stable.
Possibility of hazardous : Under normal conditions of storage and use, hazardous reactions will not occur.
reactions
Hazardous polymerization : Under normal conditions of storage and use, hazardous polymerization will not occur.
Conditions to avoid : No specific data.
Materials to avoid : No specific data.
Incompatibility : Reactive or incompatible with the following materials: acids and alkalis.
ammonium thiocyanate: Reactive or incompatible with the following materials: reducing
materials and metals.
Hazardous decomposition : Under normal conditions of storage and use, hazardous decomposition products should
not be produced.
products
11 . Toxicological information
United States
Acute toxicity
Product/ingredient name Result Species Dose Exposure
ammonium thiocyanate LD50 Oral Rat 750 mg/kg -
cyanoguanidine LD Oral Rat >500 mg/kg -
LD50 Oral Rat >20000 mg/kg -
LDLo Unreported Rat 600 mg/kg -
Chronic toxicity
No known significant effects or critical hazards.
Irritation/Corrosion
No known significant effects or critical hazards.
Sensitizer
No known significant effects or critical hazards.
Carcinogenicity
No known significant effects or critical hazards.
Mutagenicity
No known significant effects or critical hazards.
Teratogenicity
No known significant effects or critical hazards.
Reproductive toxicity
No known significant effects or critical hazards.
Canada
Acute toxicity
Product/ingredient name Result Species Dose Exposure
ammonium thiocyanate LD50 Oral Rat 750 mg/kg -
Chronic toxicity
No known significant effects or critical hazards.
Irritation/Corrosion
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11 . Toxicological information
No known significant effects or critical hazards.
Sensitizer
No known significant effects or critical hazards.
Carcinogenicity
No known significant effects or critical hazards.
Mutagenicity
No known significant effects or critical hazards.
Teratogenicity
No known significant effects or critical hazards.
Reproductive toxicity
No known significant effects or critical hazards.
Mexico
Acute toxicity
Product/ingredient name Result Species Dose Exposure
ammonium thiocyanate LD50 Oral Rat 750 mg/kg -
cyanoguanidine LD Oral Rat >500 mg/kg -
LD50 Oral Rat >20000 mg/kg -
LDLo Unreported Rat 600 mg/kg -
Chronic toxicity
No known significant effects or critical hazards.
Irritation/Corrosion
No known significant effects or critical hazards.
Sensitizer
No known significant effects or critical hazards.
Carcinogenicity
No known significant effects or critical hazards.
Mutagenicity
No known significant effects or critical hazards.
Teratogenicity
No known significant effects or critical hazards.
Reproductive toxicity
No known significant effects or critical hazards.
12 . Ecological information
Environmental effects : No known significant effects or critical hazards.
United States
Aquatic ecotoxicity
No known significant effects or critical hazards.
Biodegradability
No known significant effects or critical hazards.
Canada
Aquatic ecotoxicity
No known significant effects or critical hazards.
Biodegradability
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12 . Ecological information
No known significant effects or critical hazards.
Mexico
Aquatic ecotoxicity
No known significant effects or critical hazards.
Biodegradability
No known significant effects or critical hazards.
Other adverse effects : No known significant effects or critical hazards.
13 . Disposal considerations
Waste disposal : The generation of waste should be avoided or minimized wherever possible. Empty
containers or liners may retain some product residues. This material and its container
must be disposed of in a safe way. Dispose of surplus and non-recyclable products via
a licensed waste disposal contractor. Disposal of this product, solutions and any by-
products should at all times comply with the requirements of environmental protection
and waste disposal legislation and any regional local authority requirements. Avoid
dispersal of spilled material and runoff and contact with soil, waterways, drains and
sewers.
Disposal should be in accordance with applicable regional, national and local laws and regulations.
Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
for additional handling information and protection of employees.
14 . Transport information
Regulatory UN number Proper shipping Classes PG* Label Additional
information name information
DOT Classification Not - - - -
regulated.
TDG Classification Not - - - -
regulated.
Mexico Not - - - -
regulated.
Classification
ADR/RID Class Not - - - -
regulated.
IMDG Class Not - - - -
regulated.
IATA-DGR Class Not - - - -
regulated.
PG* : Packing group
15 . Regulatory information
United States
HCS Classification : Irritating material
Target organ effects
U.S. Federal regulations : United States inventory (TSCA 8b): All components are listed or exempted.
SARA 302/304/311/312 extremely hazardous substances: No products were found.
SARA 302/304 emergency planning and notification: No products were found.
SARA 302/304/311/312 hazardous chemicals: ammonium thiocyanate
SARA 311/312 MSDS distribution - chemical inventory - hazard identification:
ammonium thiocyanate: Immediate (acute) health hazard
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15 . Regulatory information
DEA List I Chemicals : Not listed
(Precursor Chemicals)
DEA List II Chemicals : Not listed
(Essential Chemicals)
SARA 313
Product name CAS number Concentration
Form R - Reporting : ammonium thiocyanate 1762-95-4 1-5
requirements
Supplier notification : ammonium thiocyanate 1762-95-4 1-5
SARA 313 notifications must not be detached from the MSDS and any copying and redistribution of the MSDS shall
include copying and redistribution of the notice attached to copies of the MSDS subsequently redistributed.
State regulations : Massachusetts Spill: None of the components are listed.
Massachusetts Substances: The following components are listed: AMMONIUM
THIOCYANATE
New Jersey Hazardous Substances: The following components are listed:
AMMONIUM THIOCYANATE
New Jersey Spill: None of the components are listed.
New Jersey Toxic Catastrophe Prevention Act: None of the components are listed.
Pennsylvania RTK Hazardous Substances: The following components are listed:
THIOCYANIC ACID, AMMONIUM SALT
Canada
WHMIS (Canada) : Class D-1B: Material causing immediate and serious toxic effects (Toxic).
Class D-2B: Material causing other toxic effects (Toxic).
Canadian lists : CEPA Toxic substances: None of the components are listed.
Canadian ARET: None of the components are listed.
Canadian NPRI: The following components are listed: Ammonia (total)
Alberta Designated Substances: None of the components are listed.
Ontario Designated Substances: None of the components are listed.
Quebec Designated Substances: None of the components are listed.
Canada inventory : All components are listed or exempted.
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations
and the MSDS contains all the information required by the Controlled Products Regulations.
Mexico
Classification :
1 Flammability
Health 2 0 Reactivity
Special
International regulations
International lists : Australia inventory (AICS): All components are listed or exempted.
China inventory (IECSC): All components are listed or exempted.
Japan inventory: Not determined.
Korea inventory: All components are listed or exempted.
New Zealand Inventory of Chemicals (NZIoC): All components are listed or exempted.
Philippines inventory (PICCS): All components are listed or exempted.
Chemical Weapons : Not listed
Convention List Schedule I
Chemicals
Chemical Weapons : Not listed
Convention List Schedule
II Chemicals
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15 . Regulatory information
Chemical Weapons : Not listed
Convention List Schedule
III Chemicals
16 . Other information
Label requirements : CAUSES EYE IRRITATION. MAY BE HARMFUL IF SWALLOWED. MAY CAUSE
RESPIRATORY TRACT AND SKIN IRRITATION. MAY CAUSE TARGET ORGAN
DAMAGE.
Hazardous Material :
Information System (U.S.A.)
* 1
Health
1
Flammability
0
Physical hazards
Caution: HMIS?ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks Although HMIS?ratings are not required on MSDSs under 29 CFR
1910.1200, the preparer may choose to provide them. HMIS?ratings are to be used with a fully implemented
HMIS?program. HMIS?is a registered mark of the National Paint & Coatings Association (NPCA). HMIS?br>
materials may be purchased exclusively from J. J. Keller (800) 327-6868.
The customer is responsible for determining the PPE code for this material.
Date of printing : 4/29/2010.
: 4/29/2010.
Date of issue
Date of previous issue : 4/29/2009.
Version :1
Indicates information that has changed from previously issued version.
Notice to reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above-named
supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the
information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present
unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot
guarantee that these are the only hazards that exist.
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