Conforms to ANSI Z400.5-2004 Standard (United States, Canada, Mexico, Brazil).
Material Safety Data Sheet
ROYCO 46, 46TF
1. Product and company identification
Product name : ROYCO 46, 46TF
Material uses : Lubricant.
Supplier/Manufacturer : Chemtura Canada Co. / Cie
700 Third Line
Oakville, ONT
Canada L6J 5A3
Tel: (905) 827-9087
Fax: (905) 827-2862
MSDS # : AC1087
MILSPEC# : Mil-L-46000;Mil-L-46150
Validation date : 07/30/2007
MSDS authored by: : Atrion Regulatory Services, Inc.
In case of emergency : CHEMTREC: 800-424-9300 (United States)
CANUTEC (613) 996-6666 (Canada)
2. Hazards identification
Physical state : Liquid.
Odor : Mild.
Hazard status : This material is classified hazardous under OSHA regulations in the United States, the
WHMIS Controlled Product Regulation in Canada, the NOM-018-STPS-2000 in Mexico
and Brazil NBR 14725:2001.
Emergency overview : WARNING!
CAUSES EYE AND SKIN IRRITATION. MAY BE HARMFUL IF SWALLOWED.
Harmful if swallowed. Severely irritating to eyes. Irritating to skin. Do not ingest. Do not
get in eyes. Avoid breathing vapor or mist. Avoid contact with skin and clothing. Wash
thoroughly after handling.
Routes of entry : Skin contact. Eye contact. Ingestion.
Potential acute health effects
Inhalation : No known significant effects or critical hazards.
Ingestion : May be harmful if swallowed.
Skin : Irritating to skin.
Eyes : Severely irritating to eyes. Risk of serious damage to eyes.
Potential chronic health effects
Chronic effects : No known significant effects or critical hazards.
Carcinogenicity : No known significant effects or critical hazards.
Mutagenicity : No known significant effects or critical hazards.
Teratogenicity : No known significant effects or critical hazards.
Developmental effects : No known significant effects or critical hazards.
Fertility effects : No known significant effects or critical hazards.
Over-exposure signs/symptoms
Inhalation : No specific data.
Ingestion : No specific data.
Skin : Adverse symptoms may include the following:
irritation
redness
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2. Hazards identification
Eyes : Adverse symptoms may include the following:
pain or irritation
watering
redness
Medical conditions : Pre-existing digestive disorders may be aggravated by over-exposure to this product.
aggravated by over-
exposure
See toxicological information (section 11)
3. Composition/information on ingredients
United States
Name CAS number %
Phosphonic Acid, Bis(1-Methylethyl) Ester 1809-20-7 1-5
Canada
Name CAS number %
Phosphonic Acid, Bis(1-Methylethyl) Ester 1809-20-7 1-5
Mexico
Classification
Name UN number IDLH H F R Special CAS number %
Phosphonic Acid, Bis(1-Methylethyl) Ester Not regulated. - 1 2 0 1809-20-7 1-5
Brazil
Name CAS number %
Phosphonic Acid, Bis(1-Methylethyl) Ester 1809-20-7 1-5
There are no ingredients present which, within the current knowledge of the supplier and in the concentrations
applicable, are classified as hazardous to health or the environment and hence require reporting in this section.
4. First aid measures
Eye contact : Check for and remove any contact lenses. In case of contact, immediately flush eyes
with plenty of water for at least 20 minutes. Get medical attention if irritation occurs.
Skin contact : Wash with soap and water. Get medical attention if irritation occurs.
Inhalation : If inhaled, remove to fresh air. If not breathing, give artificial respiration. Get medical
attention if symptoms appear.
Ingestion : Do not induce vomiting. Never give anything by mouth to an unconscious person. Get
medical attention if symptoms appear.
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. It may
be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Notes to physician : No specific treatment. Treat symptomatically. Contact poison treatment specialist
immediately if large quantities have been ingested or inhaled.
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5. Fire-fighting measures
Flammability of the product : In a fire or if heated, a pressure increase will occur and the container may burst.
Extinguishing media
Suitable : Use an extinguishing agent suitable for the surrounding fire.
Not suitable : None known.
Special exposure hazards : Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training.
Hazardous combustion : The final products of combustion are carbon oxides and water. Nitrogen, sulfur and
metal oxides may also be produced in some cases.
products
Special protective : Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.
equipment for fire-fighters
6. Accidental release measures
Personal precautions : No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Avoid breathing vapor or mist.
Provide adequate ventilation. Wear appropriate respirator when ventilation is
inadequate. Put on appropriate personal protective equipment (see section 8).
Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
Methods for cleaning up : Stop leak if without risk. Move containers from spill area. Approach release from
upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash
spillages into an effluent treatment plant or proceed as follows. Contain and collect
spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or
diatomaceous earth and place in container for disposal according to local regulations
(see section 13). Dispose of via a licensed waste disposal contractor. Contaminated
absorbent material may pose the same hazard as the spilled product. Note: see section
1 for emergency contact information and section 13 for waste disposal.
7. Handling and storage
Handling : Put on appropriate personal protective equipment (see section 8). Eating, drinking and
smoking should be prohibited in areas where this material is handled, stored and
processed. Workers should wash hands and face before eating, drinking and smoking.
Do not breathe vapor or mist. Do not ingest. Avoid contact with eyes, skin and clothing.
Keep in the original container or an approved alternative made from a compatible
material, kept tightly closed when not in use. Empty containers retain product residue
and can be hazardous. Do not reuse container.
Storage : Store in accordance with local regulations. Store in original container protected from
direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials
(see section 10) and food and drink. Keep container tightly closed and sealed until ready
for use. Containers that have been opened must be carefully resealed and kept upright
to prevent leakage. Do not store in unlabeled containers. Use appropriate containment
to avoid environmental contamination.
8. Exposure controls/personal protection
Consult local authorities for acceptable exposure limits.
Recommended monitoring : If this product contains ingredients with exposure limits, personal, workplace atmosphere
or biological monitoring may be required to determine the effectiveness of the ventilation
procedures
or other control measures and/or the necessity to use respiratory protective equipment.
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Engineering measures : No special ventilation requirements. Good general ventilation should be sufficient to
control worker exposure to airborne contaminants. If this product contains ingredients
with exposure limits, use process enclosures, local exhaust ventilation or other
engineering controls to keep worker exposure below any recommended or statutory
limits.
Personal protection
Eye protection : Safety glasses with side shields.
Skin protection/Body : Not applicable.
Respiratory protection : Not applicable.
Hand protection : Natural rubber (latex).
HMIS Code/Personal :B
protective equipment
Personal protection in case : Safety glasses, goggles or face shield. Impervious gloves. Full suit. Boots. Wear
MSHA/NIOSH-approved self-contained breathing apparatus or equivalent and full
of a large spill
protective gear.
Hygiene measures : Wash hands, forearms and face thoroughly after handling compounds and before
eating, smoking and using the lavatory and at the end of the day. Follow good industrial
hygiene practice.
Environmental exposure : Emissions from ventilation or work process equipment should be checked to ensure they
comply with the requirements of environmental protection legislation. In some cases,
controls
fume scrubbers, filters or engineering modifications to the process equipment will be
necessary to reduce emissions to acceptable levels.
9. Physical and chemical properties
Physical state : Liquid.
Color : Beige.
Odor : Mild.
Specific gravity : 0.92
Flash point : Open cup: >145癈 (293癋) (Cleveland.).
10 . Stability and reactivity
Stability and reactivity : The product is stable.
Conditions of instability : None known.
Incompatibility with various : Reactive or incompatible with the following materials: oxidizing materials.
substances
Hazardous decomposition : Under normal conditions of storage and use, hazardous decomposition products should
not be produced.
products
Hazardous polymerization : Will not occur.
Conditions of reactivity : None known.
11 . Toxicological information
Toxicity data
Product/ingredient name Test / Route Species Result
Phosphonic Acid, Bis(1-Methylethyl) Ester LD50 Dermal Rabbit 5700 mg/kg
LD50 Oral Rat 1700 mg/kg
Acute Effects
Eyes : Severely irritating to eyes. Risk of serious damage to eyes.
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Skin : Irritating to skin.
: No known significant effects or critical hazards.
Inhalation
: May be harmful if swallowed.
Ingestion
Potential chronic health : Carcinogenic effects: Not applicable.
Mutagenic effects: Not applicable.
effects
Teratogenic effects: Not applicable.
12 . Ecological information
Environmental effects : No known significant effects or critical hazards.
Other adverse effects : No known significant effects or critical hazards.
13 . Disposal considerations
Waste disposal : The generation of waste should be avoided or minimized wherever possible. Dispose of
surplus and non-recyclable products via a licensed waste disposal contractor. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any regional
local authority requirements. Avoid dispersal of spilled material and runoff and contact
with soil, waterways, drains and sewers.
Disposal should be in accordance with applicable regional, national and local laws and regulations.
Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
for additional handling information and protection of employees.
14 . Transport information
NAERG : Not applicable.
Regulatory information
UN/ IMDG/ IATA DOT/ TDG : Not regulated.
15 . Regulatory information
United States
HCS Classification : Irritating material
U.S. Federal regulations : TSCA 8(b) inventory: All components listed.
SARA 302/304/311/312 extremely hazardous substances: No products were found.
SARA 302/304 emergency planning and notification: No products were found.
SARA 302/304/311/312 hazardous chemicals: No products were found.
SARA 311/312 MSDS distribution - chemical inventory - hazard identification: No
products were found.
Clean Water Act (CWA) 307: No products were found.
Clean Water Act (CWA) 311: No products were found.
Clean Air Act (CAA) 112 accidental release prevention: No products were found.
Clean Air Act (CAA) 112 regulated flammable substances: No products were found.
Clean Air Act (CAA) 112 regulated toxic substances: No products were found.
State regulations : Connecticut Carcinogen Reporting: None of the components are listed.
Connecticut Hazardous Material Survey: None of the components are listed.
Florida substances: None of the components are listed.
Illinois Chemical Safety Act: None of the components are listed.
Illinois Toxic Substances Disclosure to Employee Act: None of the components are
listed.
Louisiana Reporting: None of the components are listed.
Louisiana Spill: None of the components are listed.
Massachusetts Spill: None of the components are listed.
Massachusetts Substances: None of the components are listed.
Michigan Critical Material: None of the components are listed.
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Minnesota Hazardous Substances: None of the components are listed.
New Jersey Hazardous Substances: None of the components are listed.
New Jersey Spill: None of the components are listed.
New Jersey Toxic Catastrophe Prevention Act: None of the components are listed.
New York Acutely Hazardous Substances: None of the components are listed.
New York Toxic Chemical Release Reporting: None of the components are listed.
Pennsylvania RTK Hazardous Substances: None of the components are listed.
Rhode Island Hazardous Substances: None of the components are listed.
California Prop. 65 : No products were found.
Canada
WHMIS (Canada) : Class D-2B: Material causing other toxic effects (Toxic).
Canadian lists : CEPA DSL: All components listed.
Canada inventory : Canada inventory: All components are listed or exempted.
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations
and the MSDS contains all the information required by the Controlled Products Regulations.
Mexico
HAZARD RATINGS
Classification :
4- Extreme
1 Flammability 3- Serious
2- Moderate
Health 1 0 Reactivity 1- Slight
Special 0- Minimal
This product, (and its ingredients) is (are) listed on national inventories, or is (are)
exempted from being listed, in Australia (AICS), in Europe (EINECS/ELINCS), in Korea
(TCCL), in Japan (METI), in the Philippines (RA6969).
The Restriction of : In compliance.
Hazardous Substances in
Electrical and Electronic
Equipment (ROHS)
Directive (2002/95/EC)
16 . Other information
Label requirements : CAUSES EYE AND SKIN IRRITATION. MAY BE HARMFUL IF SWALLOWED.
Hazardous Material : HAZARD RATINGS
Information System (U.S.A.) 4- Extreme
1 3- Serious
Health
2- Moderate
1 1- Slight
Flammability
0- Minimal
0
Physical hazards
B
Personal protection See section 8 for more detailed information
on personal protection.
The customer is responsible for determining the PPE code for this material.
National Fire Protection :
Association (U.S.A.)
Flammability
1
1 0
Health Instability
Special
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References : ANSI Z400.1, MSDS Standard, 2004. - Manufacturer's Material Safety Data Sheet. -
29CFR Part1910.1200 OSHA MSDS Requirements. - 49CFR Table List of Hazardous
Materials, UN#, Proper Shipping Names, PG. - Canada Gazette Part II, Vol. 122, No. 2.
Registration SOR/88-64, 31 December 1987. Hazardous Products Act "Ingredient
Disclosure List" - Canadian Transport of Dangerous Goods, Regulations and Schedules,
Clear Language version 2005. - Official Mexican Standards NOM-018-STPS-2000 and
NOM-004-SCT2-1994. Brazil NBR 14725:2001.
Responsible name : Mr. Max Naggar
: 07/30/2007
Date of issue
Date of previous issue : 03/31/2006
Version : 5
ANDEROL, ROYCO, PQ, and AOSyn are registered trademarks of Anderol, Inc., a Chemtura Company.
Notice to reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above named
supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the
information contained herein. Final determination of suitability of any material is the sole responsibility of the
user. All materials may present unknown hazards and should be used with caution. Although certain hazards are
described herein, we cannot guarantee that these are the only hazards that exist.
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