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MSDS Material Safety Data Sheet
CAS

137-09-7 6132-04-3 68-04-2

File Name: 137-09-7_6132-04-3_68-04-2.asp

                                                                                                             MSDS
MATERIAL SAFETY DATA SHEET
P.O. Box 329 - 802 Washington Avenue Chestertown, MD 21620 - USA
TELEPHONE # FOR INFORMATION 410 778-3100
24 HOUR EMERGENCY NUMBER (CHEM-TEL): USA, Canada, Puerto Rico 800-255-3924;
Outside North American Continent 813-248-0585 (call Collect)

1. Product Identification Manufactured By: LaMotte Company
Product Code: 3976 802 Washington Avenue
Product Description: Dissolved Oxygen Tablets Chestertown, MD 21620



2. Composition/Information On Ingredients
Hazard CAS#/Name
TLV
% PEL
137-09-7 0.1 N/E N/E
Yes
2,4 Diaminophenol Dihydrochloride

Yes 6132-04-3 25 N/E N/E
Sodium Citrate




All other ingredients are proprietary, NJTSRN 80100291-5036p


(No proprietary ingredients are toxic or highly hazardous)


*Ingredients not listed by name are proprietary to LaMotte Co, registered under the state of New Jersey (U.S.A.) trade secret
protection law, assigned the NJ Trade Secret Registry # 80100291-5036p and may be disclosed only in a medical emergency.




1
Product Code: 3976 Product Description: Dissolved Oxygen Tablets


3. Hazards Overview
Primary Route Of Entry: Skin Ingestion
May stain skin. Harmful if swallowed.




HMIS Hazard
Scale: 4 = Extreme, 3 = High, 2 = Moderate, 1= Slight, 0 = Least
Health: 1 Flammability: 0 Reactivity: 0


Carcinogenicity: Yes: NTP


Other Health Related Comments:
NTP - 2,4 Diaminophenol Dihydrochloride is suspected of causing cancer in humans. RTECS class: tumorigen; mutagen. See Toxicity,
Section 11.


4. First Aid Measures
Eye Contact: Immediately flush eye with water for several minutes. Consult physician if irritation develops.
Skin Contact: Flush thoroughly with water. Wash skin with soap and water.

Ingestion: If more than a few tablets have been swallowed induce vomiting. Consult physician.

Inhalation: N/A

5. Fire Fighting Measures

Flash Point (Method Used): LEL: N/A UEL: N/A
N/A

Not a fire hazard
Extinguishing Media:
N/A
Special Fire Fighting Procedures:

N/A
Unusual Fire & Explosion Hazard:




6. Accidental Release Measures
Sweep up spilled tablets. <100 tablets can usually be discarded to trash, or dissolve in a beaker of water and wash down
drain with more water. Wash hands after contact with tablets.




2
Product Code: 3976 Product Description: Dissolved Oxygen Tablets


7. Handling & Storage
Store in cool, dry place away from heat and moisture. Keep out of reach of young children.




8. Exposure Controls/Personal Protection
Ventilation
Normal




Protection When Handling
Gloves Eye Protection Lab Coat




Avoid handling tablets. Wash after handling.
Work/Hygenic Practices:




9. Physical & Chemical Properties

Gray Tablet N/A
Appearance: Vapor Density:
Soluble N/A
Solubility In Water: Vapor Pressure:
None N/A
Odor: Boiling Point:
8 (2 tablets in 4.8mL water) Unknown
pH: Melting Point:



10. Stability & Reactivity
Yes
Stable:
Heat, moisture
Conditions To Avoid:
N/A
Incompatibility (Materials To Avoid):
N/A
Hazardous Decomposition Products:




3
Product Code: 3976 Product Description: Dissolved Oxygen Tablets


11. Toxicological Information
Oral rat LD50: 240 mg/kg for 2,4 Diaminophenol Dihydrochloride("Amidol"). It is used in hair dyes & chemical tests. Pure Amidol toxic if
swallowed; may cause allergy(skin) w/ repeated contact. However, each 100 mg tablet contains only 1 milligram of it).


Skin
Target Organs:




12. Ecological Information
Information Not Yet Available




13. Disposal Considerations
Small quantities may be discarded to trash or dissolved in water and flushed to drain with water, if local regulations
permit. Dispose according to federal, state, and local regulations.




QRLabel53
14. Transportation Information
Not Regulated For Transport


15. Regulatory Information
Chemical Inventory Status
USA Europe --- Canada ---
TSCA EC
Hazard Ingredient DSL NDSL Australia Japan

Yes 137-09-7 Yes Yes Yes No Yes Yes
2,4 Diaminophenol Dihydrochloride

Yes 68-04-2 Yes Yes Yes No Yes Yes
Sodium Citrate anhydrous

Federal, State, & International Regulations
--- SARA 302 --- --------- SARA 313 ---------
RCRA TSCA
Listed
Ingredient RQ TPQ Chemical Category CERCLA 261.33 8(D)
137-09-7 No No No No No No No
2,4 Diaminophenol Dihydrochloride

68-04-2 No No No No No No No
Sodium Citrate anhydrous




4
Product Code: 3976 Product Description: Dissolved Oxygen Tablets



--- SARA 311/312 --- -------- Australia -------
Hazchem Poison This MSDS Is
Hazard Categories
WHMIS Compliant
Acute Chronic Fire Pressure Reactivity Code Schedule
Ingredient
137-09-7 Yes Yes No No No 2R None Allocated
2,4 Diaminophenol Dihydrochloride

68-04-2 No No No No No None Allocated None Allocated
Sodium Citrate anhydrous

Yes No No No No None Allocated None Allocated Yes
product 3976
as a whole

16. Other Information
Australia: This product is not classified as a hazardous substance according to the criteria of ASCC based on a risk assessment according to
ASCC/NOHSC criteria


Prepared By: IP, Regulatory Affairs Department
Revised: 11/29/2007




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