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1318-93-0 1310-73-2 3332-27-2 7681-52-9 137-16-6

File Name: 1318-93-0_1310-73-2_3332-27-2_7681-52-9_137-16.asp

                               PRODUCT SAFETY DATA SHEET
Print date: 10 Feb 2009
Print date: 02 Jan 2007


1. PRODUCT AND COMPANY IDENTIFICATION


Item Number / Product code: 59631-34062

Product name:
LYSOL?BRAND DISINFECTANT TOILET BOWL
CLEANER PLUS BLEACH (LIQUID) - CANADIAN

Validation / Revision Date: 22 August 2006
10 February 2009

DrugIdentifier:
EPA Identification Number 02271559
EPA Reg. Number: 777-83

Formula Number: 492-053B (362087)

UPC Number and Size: 59631-34062 (710 ml.)

Product Description: Toilet bowl cleaner w/ bleach. (<5% Chlorine Bleach)

Reckitt Benckiser (Canada) Inc.
Reckitt Benckiser, Inc.
Manufacturer:
2 Wickman Road Unit 2
1680 Tech Avenue,
Mississauga, Ontario L4W 5S9 CANADA
Toronto, Ontario M8Z 5M5 CANADA
Emergency telephone number: 800-888-0192 (Canada)



Transportation Emergencies: 1-800-424-9300 (U.S. & Canada) CHEMTREC
Outside the U.S. and Canada (North America), call: 703-527-3887

2. COMPOSITION / INFORMATION ON INGREDIENTS

Product components: Contains less than (<) 5% Bleach.




Product code: 59631-34062 Page 1 of 8
Product name: LYSOL?BRAND DISINFECTANT
TOILET BOWL CLEANER PLUS BLEACH
(LIQUID) - CANADIAN
Components: Wt % ACGIH: OSHA:
0-1 None None
MONTMORILLONITE
1318-93-0
1-5 Ceiling: 2 mg/m?@10 TWA (PEL): 2 mg/m?@10
SOD HYDROXIDE 25% MEMBRAN
1310-73-2
5-10 None None
MYRISTAMINE OXIDE 30%
3332-27-2
15-20 None None
SODIUM HYPOCHLORITE 13%
7681-52-9
0-1 None None
SODIUM LAUROYL SARCOSINAT
137-16-6




3. HAZARDS IDENTIFICATION

EMERGENCY OVERVIEW
WARNING: EYE AND SKIN IRRITANT.
Harmful if swallowed
DO NOT get in eyes, on skin or on clothing.
For sensitive skin or prolonged use, wear appropriate skin protection (rubber gloves).
Odors may irritate.
Use only in well ventilated areas.
Avoid prolonged breathing of vapors.


Not recommended for use by persons with heart conditions or chronic respiratory problems such as asthma, emphysema
or obstructive lung disease.

KEEP OUT OF REACH OF CHILDREN




4. FIRST AID MEASURES

Inhalation: Move to fresh air.

Skin contact: Wash off immediately with soap and plenty of water.
If skin irritation occurs or persists, call a physician.

Eye contact: In case of eye contact, hold eyes open and IMMEDIATELY rinse eyes thoroughly with plenty of
water. Remove any contact lenses and continue rinsing for at least 15 minutes. Get
IMMEDIATE medical attention!

Ingestion: If swallowed, rinse mouth and drink a glass of water. Call a physician or Poison Control Center
IMMEDIATELY!
Never give anything by mouth to an unconscious person.

Notes to physician: Contains Bleach and Sodium Hydroxide.
Contains surfactants.

Aggravated Medical Conditions: No information available.

5. FIRE-FIGHTING MEASURES

Flash point: CLOSED CUP: Higher than 93.3?C (>200?F). [Tagliabue].

Flammability Limits in Air:

Product code: 59631-34062 Page 2 of 8
Product name: LYSOL?BRAND DISINFECTANT
TOILET BOWL CLEANER PLUS BLEACH
(LIQUID) - CANADIAN
Lower: No information available.
Upper: No information available.

Autoignition temperature: No information available.

Suitable extinguishing media: As suitable for surrounding fire.

Extinguishing media which must not No information available.
be used for safety reasons:

Specific hazards: Contains bleach and sodium hydroxide.
Contains surfactants.

Unusual hazards: Acid and heat accelerate decomposition. Decomposition products
may include chlorine gas.

Special protective equipment for firefighters: As in any fire, wear self-contained breathing apparatus, pressure-
demand, MSHA / NIOSH (approved or equivalent) and full
protective gear.

Specific methods: Standard procedure for chemical fires.



NFPA: Health: 2 Flammability: 0 Instability: 0

HMIS: Health: 2 Flammability: 0 Reactivity: 0
Key: Personal Protection Index = D.
(Also see Sections 3 & 8)

6. ACCIDENTAL RELEASE MEASURES

Personal precautions: Ensure adequate ventilation.

Environmental precautions: Do not allow material to contaminate ground water system.

Methods for cleaning up: When performing the required clean-up operation, wear the appropriate personal protective
equipment such as impervious gloves and eye protection.

Small spills: Dilute with water and mop up, or absorb with an inert material and place in an
appropriate waste disposal container.

Large spills: Contain and collect for later disposal according to local, provincial, state or federal
regulations.

7. HANDLING AND STORAGE

Handling: WARNING: EYE AND SKIN IRRITANT!
Do not get in eyes, on skin or on clothing.
Odors may irritate.
Use with adequate ventilation.
Avoid prolonged breathing of vapor.
Harmful if swallowed.

Safe handling advice: Read and follow product label instructions.
Not recommended for use by persons with heart conditions or chronic respiratory problems
such as asthma, emphysema or obstructive lung disease.




Product code: 59631-34062 Page 3 of 8
Product name: LYSOL?BRAND DISINFECTANT
TOILET BOWL CLEANER PLUS BLEACH
(LIQUID) - CANADIAN
Storage: Store containers in an upright position in a cool, dry area, inaccessable to small children and
pets.
Do not reuse container.
Discard empty container in household trash.
KEEP OUT OF REACH OF CHILDREN

It is a violation of federal law to use this product in a manner inconsistent with its labeling

Incompatible products: This product should not be used on or placed on toilet bowl lids, vanities, sinks, bathtubs,
cabinets, counter tops, rugs, etc.
DO NOT mix with household chemicals, such as products containing ammonia, other toilet
bowl cleaners, other acidic cleaners or other Lysol?products as hazardous gases may be
released.


8. EXPOSURE CONTROLS / PERSONAL PROTECTION


Engineering measures For occupational exposures, ensure adequate ventilation.
to reduce exposure:

Personal Protective Equipment
Respiratory protection: None required under normal use conditions.

Hand protection: Wear impervious gloves where the potential for contact with the liquid is possible.

Skin and body protection: Usual safety precautions while handling the product will provide adequate protection against
injury or irritation. Follow product label instructions.

Eye protection: Safety glasses.

Hygiene measures: Avoid contact with skin, eyes and clothing.




9. PHYSICAL AND CHEMICAL PROPERTIES

Physical state: Viscous liquid.
Appearance: Opaque
Colour: Royal blue.
Odour: Apple.
pH: 12.7 - 13.2.
pH of the liquid "as is" @ 25?C (77?F)
Strongly alkaline.
Flash point: Greater than 93?C (>200?F)
Specific gravity: 1.05 - 1.07
Vapour pressure: Not determined.
Solubility: Completely soluble.

Explosion limits:
- upper: No data available.
- lower: No data available.

10. STABILITY AND REACTIVITY

Stability: Stable under recommended storage conditions.

Polymerization: Hazardous polymerisation does not occur.




Product code: 59631-34062 Page 4 of 8
Product name: LYSOL?BRAND DISINFECTANT
TOILET BOWL CLEANER PLUS BLEACH
(LIQUID) - CANADIAN
Hazardous decomposition products: Oxides of carbon and unknown organic compounds.
May generate chlorine or oxygen.

Materials to avoid: Do not mix with other household chemicals.

Conditions to avoid: Store away from excessive heat and moisture.

11. TOXICOLOGICAL INFORMATION
Acute toxicity

Component Information:


Product Information
LC50/inhalation/4h/rat = No information available.
LD50/dermal/rabbit = No information available.
LD50/oral/rat = No information available.

Local effects
Skin irritation: Skin irritant.

Eye irritation: Eye irritant.

Inhalation Avoid breathing vapors.
Odors may irritate.
Use only in a well ventilated area.

Ingestion Harmful if swallowed.
See Section 4 for First Aid instructions.

Sensitization Not expected to be a skin sensitiser.

Chronic toxicity: No information available.

Specific effects
Carcinogenic effects: Not listed as carcinogenic by OSHA, NTP or IARC.

Mutagenic effects: No information available.

Reproductive toxicity: No information available.

Target organ effects: No information available.

Information is based on data on the components and the toxicology of similar products.

12. ECOLOGICAL INFORMATION

Product Information

Aquatic toxicity: Because of pH change (Higher / Alkaline) when in water, bulk quantity spills present the
possibility of danger to aquatic life.

Component Information:

Other information:

Ozone depletion potential; ODP; (R-11 = 1) = No information available.
Global warming potential (GWP) = No information available.




Product code: 59631-34062 Page 5 of 8
Product name: LYSOL?BRAND DISINFECTANT
TOILET BOWL CLEANER PLUS BLEACH
(LIQUID) - CANADIAN
Additional ecological information: Bulk quantities, if spilled, would be toxic to fish, birds and
mammals. Control and clean up all exterior spills and
prevent liquid from entering any streams, rivers, lakes and
all other bodies of water.

13. DISPOSAL CONSIDERATIONS

Waste from residues / unused Dispose of in accordance with local regulations.
products:

Contaminated packaging: Do not re-use empty containers.
Dispose of empty container in household trash.

Waste Disposal: Wearing appropriate personal protective equipment, collect and store in an appropriate
container for disposal according to local, state, provincial and federal regulations.

14. TRANSPORT INFORMATION

UN / Id No: UN 3266

DOT:
Classification: UN 3266 - Corrosive Liquid, Basic, Inorganic N.O.S. (Sodium Hypochlorite, Sodium
Hydroxide), Class 8, PG II.
Re-Classed as Consumer Commodity ORM-D.
Proper shipping name: Consumer Commodity
U.S. DOT - Hazard Class: Not applicable.
Subsidiary risk: Not applicable.
Packing Group: Not applicable.
DOT RQ (lbs): Not applicable.
ERG No: ERG 171
- (154 as UN 3266)

TDG (Canada):
Classification: UN3266, Corrosive Liquid, Basic, Inorganic N.O.S. (Sodium Hypochlorite, Sodium Hydroxide),
Class 8, Packing Group II.
Re-Classed as Consumer Commodity - LTD QTY.
Proper shipping name: Consumer Commodity / LTD. QTY.
Status: Not applicable.
Packing Group: Not applicable.
WHMIS hazard class: E Corrosive material

IMDG / IMO
Classification: UN 3266, Corrosive Liquid, Basic, Inorganic, N.O.S. (Sodium Hypochlorite, Sodium
Hydroxide), Class 8, PG II, Limited Quantity.
Proper shipping name: Corrosive Liquid, Basic, Inorganic, N.O.S. (Sodium Hypochlorite, Sodium Hydroxide)
Class: 8
Subsidiary Risk: Not applicable.
Packing group: III
IMDG page: See DG List.
Marine pollutant: Not applicable.
EMS: F-A / S-B
MFAG: See Guide.
Maximum quantity: See DG List.

ADR / RID
Classification: Not applicable.
Proper shipping name: Not applicable.
Class: Not applicable.
Subsidiary risk: Not applicable.
Packing Group: Not applicable.
ADR/RID-labels: Not applicable

Product code: 59631-34062 Page 6 of 8
Product name: LYSOL?BRAND DISINFECTANT
TOILET BOWL CLEANER PLUS BLEACH
(LIQUID) - CANADIAN
Hazard Identification Number: Not applicable.
CEFIC Tremcard No: Not applicable.

ICAO / IATA:
Classification: UN 3266, Corrosive Liquid, Basic, Inorganic, N.O.S. (Sodium Hypochlorite, Sodium
Hydroxide), Class 8, PG II, Limited Quantity.
Proper shipping name: Corrosive Liquid, Basic, Inorganic, N.O.S. (Sodium Hypochlorite, Sodium Hydroxide)
Class: 8
Subsidiary Risk: Not applicable
Packing Group: II
Maximum quantity See DG List.

15. REGULATORY INFORMATION


Components: PICCS: TSCA: DSL: NDSL: ENCS: CHINA: AICS: EINECS-No
MONTMORILLONITE Present Present 215-288-5
SOD HYDROXIDE 25% MEMBRAN Present Present 215-185-5
MYRISTAMINE OXIDE 30% Present Present 222-059-3
SODIUM HYPOCHLORITE 13% Present Present 231-668-3
SODIUM LAUROYL SARCOSINAT Present Present 205-281-5




U.S. Regulations:

Components: MONTMORILLONITE - 1318-93-0
NJRTK: Not Listed.
California Proposition 65 - None.
CERCLA/SARA 313: None
Components: SOD HYDROXIDE 25% MEMBRAN - 1310-73-2
NJRTK: Not Listed.
California Proposition 65 - None.
CERCLA/SARA 313: None
Components: MYRISTAMINE OXIDE 30% - 3332-27-2
NJRTK: Not Listed.
California Proposition 65 - None.
CERCLA/SARA 313: None
Components: SODIUM HYPOCHLORITE 13% - 7681-52-9
NJRTK: Not Listed.
California Proposition 65 - None.
CERCLA/SARA 313: None
Components: SODIUM LAUROYL SARCOSINAT - 137-16-6
NJRTK: Not Listed.
California Proposition 65 - None.
CERCLA/SARA 313: None

Canada
WHMIS hazard class: E Corrosive material

16. OTHER INFORMATION




Product code: 59631-34062 Page 7 of 8
Product name: LYSOL?BRAND DISINFECTANT
TOILET BOWL CLEANER PLUS BLEACH
(LIQUID) - CANADIAN
National Fire HMIS (U.S.A.): Health Hazard 2
Protection Fire Hazard 0
Association (U.S.A.): Reactivity 0
Personal Protection D




Reason for revision: This is a new formulation of an existing product.

Additional advice: This product should only be used as directed on the label and for the purpose intended.

Regulatory Department
Prepared by: Reckitt Benckiser (U.S.) Inc.
Product Safety Department
1 Philips Parkway
Montvale, New Jersey 07646-1810 USA.
Phone: 201-573-6391
FAX: 201-476-7770.

Disclaimer: To the best of our knowledge, the information contained herein is accurate. However, neither
the above named supplier nor any of its subsidiaries assumes any liability whatsoever for the
accuracy or completeness of the information contained herein. Final determination of
suitability of any material is the sole responsibility of the user. All materials may present
unknown hazards and should be used with caution. Although certain hazards are described
herein, we cannot guarantee that these are the only hazards that exist.




Product code: 59631-34062 Page 8 of 8
Product name: LYSOL?BRAND DISINFECTANT
TOILET BOWL CLEANER PLUS BLEACH
(LIQUID) - CANADIAN

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