Print Date: 12/13/05
ACC# 93765
Revision Date: 10/2/2008
Version: 1
Material Safety Data Sheet
Mark-It Tissue Marking Dye-Orange
Section 1 - Chemical Product and Company Identification
MSDS Name:
Mark-It Tissue Marking Dye-Orange
Catalog Numbers:
5000O
Synonyms:
None Known.
Company Identification:
Richard Allan Scientific
4481 Campus Drive
Kalamazoo, MI 49008
Company Phone Number:
800-522-7270
Emergency Phone Number:
800-424-9300
CHEMTREC Phone Number, US:
(800) 424-9300
CHEMTREC Phone Number, Europe:
(202) 483-7616
Section 2 - Composition, Information on Ingredients
EINECS/
CAS# Chemical Name: Hazard Risk Phrases
Percent ELINCS
Symbols
7732-18-5 Water 50-55 231-791-2
1336-21-6 Ammonium hydroxide 0.6 215-647-6
2682-20-4 Proclin 300 <0.1 220-239-6
Section 3 - Hazards Identification
EMERGENCY OVERVIEW
Appearance: Orange liquid
Caution! May cause eye, skin, and respiratory tract irritation. The toxicological
properties of this material have not been fully investigated.
Target Organs: No data found
Potential Health Effects
Eye:
May cause eye irritation.
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Print Date: 12/13/05
ACC# 93765
Revision Date: 10/2/2008
Version: 1
Material Safety Data Sheet
Mark-It Tissue Marking Dye-Orange
Skin:
May cause skin irritation.
Ingestion:
May cause irritation of the digestive tract. The toxicological properties of this substance have not been
fully investigated. May cause nausea and vomiting.
Inhalation:
May cause respiratory tract irritation.
Chronic:
No information found.
Section 4 - First Aid Measures
Eyes:
In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical aid.
Skin:
In case of contact, flush skin with plenty of water. Remove contaminated clothing and shoes. Get medical
aid if irritation develops and persists. Wash clothing before reuse.
Ingestion:
If swallowed, do not induce vomiting unless directed to do so by medical personnel. Never give anything
by mouth to an unconscious person. Get medical aid.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give
oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
Section 5 - Fire Fighting Measures
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or
equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by
thermal decomposition or combustion.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or appropriate foam.
Autoignition Temperature:
Not available
Explosion Limits:
Lower: Not available Upper: Not available
Flash Point:
Not available
NFPA Rating:
(estimated) Health: 1; Flammability: 0; Instability: 0
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Print Date: 12/13/05
ACC# 93765
Revision Date: 10/2/2008
Version: 1
Material Safety Data Sheet
Mark-It Tissue Marking Dye-Orange
Section 6 - Accidental Release Measures
General Information:
Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Avoid
runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, observing
precautions in the Protective Equipment section. Provide ventilation.
Section 7 - Handling and Storage
Handling:
Wash thoroughly after handling. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing.
Keep container tightly closed. Avoid ingestion and inhalation.
Storage:
Store in a tightly closed container. Store at 15?30癈.
Section 8 - Exposure Controls, Personal Protection
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower.
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits
Chemical Name: ACGIH NIOSH OSHA
None listed None listed None listed
Water
None listed None listed None listed
Ammonium hydroxide
None listed None listed None listed
Proclin 300
None listed None listed None listed
D&c orange no. 17
OSHA Vacated PELs
Personal Protective Equipment
Eyes:
Wear chemical splash goggles.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or
European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.
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Print Date: 12/13/05
ACC# 93765
Revision Date: 10/2/2008
Version: 1
Material Safety Data Sheet
Mark-It Tissue Marking Dye-Orange
Section 9 - Physical and Chemical Properties
Physical State: Liquid
Color: Orange
Odor: Ammonia-like
pH: No information found
Vapor Pressure: No information found
Vapor Density: No information found
Evaporation Rate: No information found
Viscosity: No information found
Boiling Point: No information found
Freezing/Melting Point: No information found
Decomposition Temperature: No information found
Solubility in water: No information found
Specific Gravity/Density: No information found
Molecular Formula: Solution
Molecular Weight: No information found
Section 10 - Stability and Reactivity
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Excess heat
Incompatibilities with Other Materials
Strong oxidizing agents
Hazardous Decomposition Products
Carbon monoxide, carbon dioxide, nitrogen oxides (NOx) and ammonia (NH3)
Hazardous Polymerization
Will not occur.
Section 11 - Toxicological Information
RTECS:
CAS# 7732-18-5: ZC0110000
CAS# 1336-21-6: BQ9625000
CAS# 2682-20-4: NX8157080
CAS# 3468-63-1: QL3854000
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Print Date: 12/13/05
ACC# 93765
Revision Date: 10/2/2008
Version: 1
Material Safety Data Sheet
Mark-It Tissue Marking Dye-Orange
LD50/LC50:
CAS# 7732-18-5:
Oral, rat: LD50 = >90 mL/kg.
CAS# 1336-21-6:
Draize test, rabbit, eye: 250 ug Severe
Draize test, rabbit, eye: 44 ug Severe
Oral, rat: LD50 = 350 mg/kg.
CAS# 2682-20-4:
No information found
CAS# 3468-63-1:
No information found
Carcinogenicity:
CAS# 7732-18-5: Not listed as a carcinogen by ACGIH, IARC, NTP, or CA Prop 65.
CAS# 1336-21-6: Not listed as a carcinogen by ACGIH, IARC, NTP, or CA Prop 65.
CAS# 2682-20-4: Not listed as a carcinogen by ACGIH, IARC, NTP, or CA Prop 65.
CAS# 3468-63-1
ACGIH: Not listed
California: carcinogen, initial date 7/1/90
NTP: Not listed
IARC: Not listed
Epidemiology:
No information found
Teratogenicity:
No information found
Reproductive:
No information found
Mutagenicity:
No information found
Neurotoxicity:
No information found
Other:
The toxicological properties have not been fully investigated.
Section 12 - Ecological Information
No information found
Section 13 - Disposal Considerations
Chemical waste generators must determine whether a discarded chemical is classified as a hazardous
waste. US EPA guidelines for the classification determination are listed in 40 CFR Part 261.3. Additionally,
waste generators must consult state and local hazardous waste regulations to ensure complete and
accurate classification.
RCRA P Series Wastes
None of the components are on this list.
RCRA U Series Wastes
None of the components are on this list.
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Print Date: 12/13/05
ACC# 93765
Revision Date: 10/2/2008
Version: 1
Material Safety Data Sheet
Mark-It Tissue Marking Dye-Orange
Section 14 - Transport Information
US DOT Canadian TDG
Proper Shipping Not Regulated Not Regulated
Name:
Hazard Class:
UN Number:
Packing Group:
USA RQ: CAS# 1336-21-6: 1000 lb final RQ; 454 kg final RQ
Section 15 - Regulatory Information
US Federal
TSCA
CAS# 7732-18-5 is listed on the TSCA Inventory.
CAS# 1336-21-6 is listed on the TSCA Inventory.
CAS# 2682-20-4 is listed on the TSCA Inventory.
CAS# 3468-63-1 is listed on the TSCA Inventory.
Health and Safety Reporting List
None of the components are on this list.
Chemical Test Rules
None of the components are on this list.
TSCA Section 12b
CAS# 2682-20-4: Section 5
TSCA Significant New Use Rule (SNUR)
None of the components are on this list.
CERCLA Hazardous Substances and corresponding RQs
CAS# 1336-21-6: 1000 lb final RQ; 454 kg final RQ
SARA Section 302 Extremely Hazardous Substances
None of the components are on this list.
SARA Hazard Categories
CAS# 1336-21-6: immediate, delayed.
SARA Section 313
None of the components are on this list.
Clean Air Act - Hazardous Air Pollutants (HAPs)
None of the components are on this list.
Clean Air Act - Class 1 Ozone Depletors
None of the components are on this list.
Clean Air Act - Class 2 Ozone Depletors
None of the components are on this list.
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Print Date: 12/13/05
ACC# 93765
Revision Date: 10/2/2008
Version: 1
Material Safety Data Sheet
Mark-It Tissue Marking Dye-Orange
Clean Water Act - Hazardous Substances
CAS# 1336-21-6 is listed as a Hazardous Substance under the CWA.
Clean Water Act - Priority Pollutants
None of the components are on this list.
Clean Water Act - Toxic Pollutants
None of the components are on this list.
OSHA - Highly Hazardous
None of the components are on this list.
OSHA - Specifically Regulated Chemicals
None of the components are on this list.
US State
State Right to Know
Ammonium hydroxide can be found on the following state Right-to-Know lists: California, New Jersey,
Pennsylvania, Massachusetts.
No information found
California Prop 65
WARNING: This product contains D&c orange no. 17, a chemical known to the State of California to cause
cancer.
California No Significant Risk Level
None of the components are on this list.
None of the components are on this list.
None of the components are on this list.
None of the components are on this list.
European/International Regulations
European Labelling in Accordance with EC Directives:
Hazard Symbols: None listed
Risk Phrases: None listed
Safety Phrases: S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
No information found
United Kingdom Occupational Exposure Limits
No information found
United Kingdom Maximum Exposure Limits
No information found
Canadian DSL/NDSL
CAS# 7732-18-5 is listed on Canada's DSL List.
CAS# 1336-21-6 is listed on Canada's DSL List.
CAS# 2682-20-4 is listed on Canada's DSL List.
CAS# 3468-63-1 is listed on Canada's DSL List.
Canadian WHMIS Classifications
No information found
This product has been classified in accordance with the hazard criteria of the Controlled Products
Regulations and the MSDS contains all of the information required by those regulations.
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Print Date: 12/13/05
ACC# 93765
Revision Date: 10/2/2008
Version: 1
Material Safety Data Sheet
Mark-It Tissue Marking Dye-Orange
Canadian Ingredient Disclosure List
CAS# 1336-21-6 is listed on the Canadian Ingredient Disclosure List.
Section 16 - Other Information
Color information has been
MSDS Creation Date: December 12, 2005
Revision Date: October 2, 2008
This MSDS is intended for review and guidance in the receipt, storage, handling, use and disposal of product purchased
from us, and for no other purpose. Use this product only as directed and in accordance with applicable instructions and
warnings provided with the product. Please consult your institution's policies regarding use of this product. If you have
obtained this MSDS other than in connection with the supply of this product from us, this MSDS should be consulted for
general information only, and should not be relied upon for any purpose. As with the use of all hazardous materials, you
should in all instances follow the guidance of the MSDS provided or available with the specific product purchased.
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