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MSDS Material Safety Data Sheet
CAS

1336-21-6 111-46-6 616-45-5 7732-18-5

File Name: 1336-21-6_111-46-6_616-45-5_7732-18.asp

                                             Material Safety Data Sheet

1. PRODUCT AND COMPANY IDENTIFICATION



FastINK (TM) Inkjet Fabric Ink - Magenta
Revision date: 06/11/2004

U.S. Graphic Arts, Inc., dba U.S. Screen Printing Institute
Supplier
1901 E. 5th Street
Tempe, Arizona 85281 United States of America

For non-emergency information contact: 480-929-0640
Emergency telephone number

Spill Emergency 480-929-0640
Health Emergency 480-929-0640
Chemtrec 800-424-9300

2. COMPOSITION/INFORMATION ON INGREDIENTS


Component CAS-No. Concentration


Acrylic polymer(s) Not Hazardous 1.0 - 10.0%

Individual residual monomers Not Required <100.0PPM

Aqua ammonia 1336-21-6 <=0.2%

Magenta Pigment Not Hazardous 5.0 - 10.0%

Anionic surfactant Trade Secret 1.0 - 5.0%

Diethylene glycol 111-46-6 10.0 - 15.0%

Pyrrolidone 616-45-5 5.0 - 10.0%

Water 7732-18-5 60.0 - 70.0%


3. HAZARDS IDENTIFICATION
Emergency Overview
Appearance

Form Translucent liquid
Color Magenta


WARNING!
Hazard Summary
INHALATION OF VAPOR OR MIST CAN CAUSE HEADACHE,
NAUSEA AND IRRITATION OF THE NOSE, THROAT AND LUNGS.
CAUSES SEVERE EYE IRRITATION.
PROLONGED OR REPEATED OVEREXPOSURE TO DIETHYLENE
GLYCOL CAN CAUSE KIDNEY AND LIVER EFFECTS.
Potential Health Effects

Inhalation
Primary Routes of Entry:
Eye contact
Skin contact
Eyes: Direct contact with material can cause the following:
severe irritation
tearing
reddening
Skin: Material can cause the following:
Skin irritation
Prolonged or repeated overexposure to the solvent(s) in this material can cause the following:
defatting and drying of the skin which can lead to irritation and dermatitis
Ingestion: Material is possibly harmful if swallowed.
Material can cause the following:
abdominal pain
vomiting
nausea
dizziness
diarrhea
gastrointestinal irritation
Inhalation: Inhalation of solvent vapor or mist can cause the following:
irritation of nose, throat, and lungs
headache
nausea
Chronic Exposure: Prolonged or repeated overexposure to diethylene glycol can cause kidney and liver effects.


4. FIRST AID MEASURES
Inhalation: Move to fresh air. Give artificial respiration if breathing has stopped. If breathing is difficult, give
oxygen. Consult a physician.
Skin contact: Remove contaminated clothing. Wash affected skin areas thoroughly with soap and water.
Consult a physician if irritation persists. Wash contaminated clothing before reuse. Do not take clothing home to
be laundered.
Eye contact: IMMEDIATELY flush eyes with a large amount of water for at least 15 minutes. Get prompt medical
attention.
Ingestion: Drink 1 or 2 glasses of water. Never give anything by mouth to an unconscious person. Consult a
physician. If vomiting occurs spontaneously, keep airway clear.


5. FIRE-FIGHTING MEASURES


Noncombustible
Flash point
not applicable
Lower explosion limit
not applicable
Upper explosion limit
Combustion generates toxic fumes of the following:, nitrogen oxides
Thermal decomposition
(NOx), Carbon oxides, sulfur oxides
Use the following extinguishing media when fighting fires involving this
Suitable extinguishing
material:
media:
polar solvent (alcohol) foam
water spray
dry chemical
carbon dioxide (CO2)
Specific hazards during fire fighting: Material can splatter above 100C/212F. Dried product can burn.
Special protective equipment for fire-fighters: Wear self-contained breathing apparatus and protective suit.
Further information: Remain upwind.
Avoid breathing smoke.
Use water spray to cool unopened containers.


6. ACCIDENTAL RELEASE MEASURES
Personal precautions
Appropriate protective equipment must be worn when handling a spill of this material. See SECTION 8, Exposure
Controls/Personal Protection, for recommendations.
If exposed to material during clean-up operations, see SECTION 4, First Aid Measures, for actions to follow.

Methods for cleaning up
Keep spectators away.
Floor may be slippery; use care to avoid falling.
Avoid breathing vapor.
Ventilate the area.
Contain spills immediately with inert materials (e.g., sand, earth).
Transfer liquids and solid diking material to separate suitable containers for recovery or disposal.
CAUTION: Keep spills and cleaning runoff out of municipal sewers and open bodies of water.


7. HANDLING AND STORAGE
Handling
Keep from freezing - product stability may be affected. Avoid contact with skin, eyes and clothing. Wash
thoroughly after handling. Store in a cool, dry, well ventilated place. Keep container closed when not in use.
Storage
Storage temperature:40 - 60 癈(104 - 140 癋)
Other data: NOTE: Formaldehyde will be generated under acidic conditions. Maintain adequate ventilation
under these conditions to prevent exposure to formaldehyde above the recommended ceiling of 0.3 ppm.
Further information:
Monomer vapors can be evolved when material is heated during processing operations. See SECTION 8, for
types of ventilation required.
Improper disposal or re-use of this container may be dangerous and illegal. Refer to applicable local, state and
federal regulations.
Dispose empty container in a sanitary landfill or by incineration as allowed by state and local authorities.


8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Exposure limit(s)
Exposure limits are listed below, if they exist.

Component Regulation Type of listing Value
Aqua ammonia U.S. Screen TWA 25 ppm
U.S. Screen STEL 35 ppm
ACGIH TWA 17 mg/m3 25 ppm
ACGIH STEL 24 mg/m3 35 ppm
OSHA_TRANS PEL 35 mg/m3 50 ppm


Component Regulation Type of listing Value
Diethylene glycol U.S. Screen TWA 84 mg/m3
Eye protection: Use chemical splash goggles (ANSI Z87.1 or approved equivalent). Eye protection worn must
be compatible with respiratory protection system employed.
Hand protection: Chemical-resistant gloves should be worn whenever this material is handled. The glove(s)
listed below may provide protection against permeation. (Gloves of other chemically resistant materials may not
provide adequate protection): Neoprene gloves Gloves should be removed and replaced immediately if there is
any indication of degradation or chemical breakthrough. Rinse and remove gloves immediately after use. Wash
hands with soap and water.
Skin and body protection: Use chemically resistant apron or other impervious clothing to avoid prolonged or
repeated skin contact.
Respiratory protection: A respiratory protection program meeting OSHA 1910.134 and ANSI Z88.2
requirements or equivalent must be followed whenever workplace conditions warrant a respirator's use. None
required if airborne concentrations are maintained below the exposure limit listed in Exposure Limit Information.
Up to 10 times the exposure limit: Wear a properly fitted NIOSH approved (or equivalent) half-mask, air-purifying
respirator. Up to 1000 ppm organic vapor: Wear a properly fitted NIOSH approved (or equivalent) full-facepiece,
air-purifying respirator, OR full-facepiece, airline respirator in the pressure demand mode. Above 1000 ppm
organic vapor or Unknown: Wear a properly fitted NIOSH approved (or equivalent) self-contained breathing
appartus in the pressure demand mode, OR full-facepiece, airline respirator in the pressure demand mode with
emergency escape provision. Air-purifying respirators should be equipped with NIOSH approved (or equivalent)
organic vapor cartridges and R95 or P95 filters.
Protective measures: Facilities storing or utilizing this material should be equipped with an eyewash facility and
a safety shower.
Engineering measures: Use local exhaust ventilation with a minimum capture velocity of 100 ft/min. (0.5
m/sec.) at the point of vapor evolution. Refer to the current edition of Industrial Ventilation: A Manual of
Recommended Practice published by the American Conference of Governmental Industrial Hygienists for
information on the design, installation, use, and maintenance of exhaust systems.


9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance

Translucent liquid
Form
Magenta
Colour
7.5 - 9.5
pH
100 癈 (212 癋) Water
Boiling point/range
0 癈 (32 癋) Water
Melting point/range
Noncombustible
Flash point
not applicable
Lower explosion limit
not applicable
Upper explosion limit
17.0 mmHgat20 癈 (68 癋) Water
Vapour pressure
<1.0water
Relative vapour density
Dilutable
Water solubility
0.95 - 1.05
Relative density
2.5 - 4.0 mPa.s
Viscosity, dynamic
<1Water
Evaporation rate
85 - 94 %
Percent volatility
NOTE: The physical data presented above are typical values and should not be construed as a specification.
10. STABILITY AND REACTIVITY


This material is considered stable.
Hazardous reactions
However, avoid temperatures above 177C/350F, the onset of polymer
decomposition. Thermal decomposition is dependent on time and
temperature.

Avoid contact with acids, alkalies and strong oxidizing agents.
Materials to avoid

Thermal decomposition may yield acrylic monomers.,
Hazardous
decomposition products
Product will not undergo polymerization.
polymerization


11. TOXICOLOGICAL INFORMATION
No toxicity data are available for this material.
The information shown in SECTION 3, Hazards Identification, is based on toxicity profiles of similar materials or
on the solvents present in this material.
Component:Aqua ammonia

LD50rat 350 mg/kg
Acute oral toxicity
Component:Aqua ammonia

LDLohuman 43 mg/kg
Acute oral toxicity
Component:2,2'-oxybisethanol diethylene glycol

LD50rat 10,000 mg/kg
Acute oral toxicity
Component:2,2'-oxybisethanol diethylene glycol

LD50rabbit 10,000 mg/kg
Acute dermal toxicity

12. ECOLOGICAL INFORMATION
There is no data available for this product.
2,2'-oxybisethanol diethylene glycol
Ecotoxicity effects

LC50
Toxicity to fish
>100 mg/l
EC50Daphnia magna
Toxicity to aquatic
100 mg/l
invertebrates

13. DISPOSAL CONSIDERATIONS
Disposal
Disposal:
Incinerate liquid and contaminated solids in accordance with local, state, and federal regulations.
Waste Classification: When a decision is made to discard this material as supplied, it does not meet RCRA's
characteristic definition of ignitability, corrosivity, or reactivity, and is not listed in 40 CFR 261.33. The toxicity
characteristic (TC), however, has not been evaluated by the Toxicity Characteristic Leaching Procedure (TCLP).


14. TRANSPORT INFORMATION

DOT
Not regulated for transport
IMO/IMDG
Not regulated (Not dangerous for transport)
Transportation classifications may vary by container volume and may be influenced by regional or country
variations in regulations


15. REGULATORY INFORMATION
Workplace Classification
This product is considered hazardous under the OSHA Hazard Communication Standard (29 CFR 1910.1200).
This product is a'controlled product' under the Canadian Workplace Hazardous Materials Information System
(WHMIS).
SARA TITLE III:Section 311/312 Categorizations (40CFR370):Chronic Health Hazard
Acute Health Hazard
SARA TITLE III:Section 313 Information (40CFR372)
This product does not contain a chemical which is listed in Section 313 at or above de minimis concentrations.
CERCLAInformation(40CFR302.4)
Releases of this material to air, land, or water are not reportable to the National Response Center under the
Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) or to state and local
emergency planning committees under the Superfund Amendments and Reauthorization Act (SARA) Title III
Section 304.
US. Toxic Substances Control Act (TSCA) All components of this product are in compliance with the
inventory listing requirements of the U.S. Toxic Substances Control Act (TSCA) Chemical Substance Inventory.
Pennsylvania
Any material listed as "Not Hazardous" in the CAS REG NO. column of SECTION 2, Composition/Information On
Ingredients, of this MSDS is a trade secret under the provisions of the Pennsylvania Worker and Community
Right-to-Know Act.
California (Proposition 65)
This product contains trace levels of a component or components known to the state of California to cause
cancer:

Components: Formaldehyde 50-00-0
Ethyl acrylate 140-88-5


16. OTHER INFORMATION
Hazard Rating

Health Fire Reactivity
2* 1 0
HMIS
Legend

ACGIH American Conference of Governmental Industrial Hygienists
BAc Butyl acetate
OSHA Occupational Safety and Health Administration
PEL Permissible Exposure Limit
STEL Short Term Exposure Limit (STEL):
TLV Threshold Limit Value
TWA Time Weighted Average (TWA):
| Bar denotes a revision from prior MSDS.
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief
at the date of its publication. The information given is designed only as a guidance for safe handling, use,
processing, storage, transportation, disposal and release and is not to be considered a warranty or quality
specification. The information relates only to the specific material designated and may not be valid for such
material used in combination with any other materials or in any process, unless specified in the text. Version:1.0

Print Date: 06/11/2004

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