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81335-47-9 10-25-0 1336-21-6 081335-37-7

File Name: 81335-47-9_10-25-0_1336-21-6_081335-37-7.asp

AMBRANDS
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Atlanta, GA 30339

MATERIAL SAFETY DATA SHEET CAS NO. 81335-47-9
DATE: 1/1/01
EMERGENCY TELEPHONE: 800-265-0761 Rev: 10-25-05

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PRODUCT TRADE NAME: IMAGE(r) CONSUMER CONCENTRATE (3.3%)
IDENTIFICATION SYNONYMS: Ammonium salt of
2-[4,5-dihydro-4-methyl-4-(1-methylethyl)-5-oxo-
1H-imidazol-2-yl]-3-quinoline carboxylic acid;
Ammonium Salt; Imazaquin.
CHEMICAL FAMILY: Imidazolinone
MOLECULAR FORMULA: C<17>H<16>N<3>O<3>.NH<4>
MOLECULAR WEIGHT: 328.370
USAGE: Herbicide
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WARNING CAUTION! Keep out of reach of children.
STATEMENTS Avoid contact with eyes and skin.
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INGREDIENTS COMPONENT CAS. NO. % PEL/TLV
Ammonium Hydroxide 1336-21-6 1.50 None Established
Imazaquin 081335-37-7 3.38 5 mg/m>3<
Technical
Inerts 95.12

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REFERENCE: Ammonium Hydroxide None
Imazaquin Technical American Cyanamid 1988
Inerts
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PHYSICAL APPEARANCE AND Dark brown liquid
PROPERTIES ODOR:
BOILING POINT: Not available
VAPOR PRESSURE: Not available

DENSITY: 1.015 g/mL
VAPOR DENSITY: Not available
% VOLATILITY (BY 97%
VOL.):
PH: 7.03
EVAPORATION RATE: Not available
SOLUBILITY IN Miscible
WATER:
VISCOSITY: 2.9 CP
FREEZING POINT: Not available

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FIRE AND FLASH POINT: >215F
EXPLOSION DECOMPOSITION TEMP:Not available
HAZARD
INFORMATION FIRE EXTINGUISHING MEDIA:
This material will not burn or burns with difficulty. Use
an extinguishing agent suitable for surrounding fires.
FIRE CONTROL TACTICS:
Wear self-contained, positive pressure breathing apparatus
and full fire fighting protective clothing.
Keep unnecessary people away. Use as little water as
possible. Dike area of fire to prevent material run-off.
Use spray or fog - solid stream may cause spreading.
Do not decontaminate personnel or equipment, or handle
broken packages or containers without protective equipment
as specified in the Exposure Control Section.
Decontaminate emergency personnel with soap and water
before leaving the fire area.
Avoid breathing dusts, vapors and fumes from burning
materials. Control run-off water - if water enters a
drainage system, advise the authorities downstream.
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NFPA HAZARD
RATING NFPA Rating Not Assigned
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REACTIVITY DATA STABILITY Temperatures > 100F
CONDITIONS TO AVOID:
INCOMPATIBLE Oxidizing agents
MATERIALS:
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HEALTH HAZARD TOXICITY DATA AND
INFORMATION EFFECTS OF OVEREXPOSURE:
ACUTE TOXICITY DATA:
There is no toxicity data on this formulation. Information
presented below represents data from a similar formulated
material.
The acute oral LD<50> in rats for the combined sexes was
shown to be > 5000 mg/kg b.w., indicating that the
material is relatively non-toxic by ingestion in single
doses.
The acute dermal LD<50> in rabbits for the combined sexes
was > 5000 mg/kg b.w., indicating that the product is
relatively non-toxic by dermal contact in single doses.
The product is mildly irritating to the skin of rabbits.
Liquid splashed into the eyes may produce local
irritation.



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CHRONIC TOXICITY DATA:
There is no chronic toxicity data available for this
product. Imazaquin is not listed as a carcinogen by IARC.,
OSHA or NTP.
EMERGENCY AND FIRST AID PROCEDURES:
: Drink two glasses of water. Induce
vomiting by touching back of throat with fingers.
: Flush eyes with copious amounts of water.
Get medical attention if irritation occurs.
: Wash skin with soap and water. Get medical
attention if irritation persists.
: If exposure is excessive, remove to fresh
air.
NOTES TO PHYSICIAN:
There is no specific antidote for exposure to this
material. Treatment of overexposure should be directed at
the control of symptoms and the clinical condition.
Toxicology studies have shown the material to be of very
low acute toxicity.
MEDICAL CONDITION AGGRAVATED BY OVEREXPOSURE:
A knowledge of the available toxicology information and of
the physical and chemical properties of the material
suggests that overexposure is unlikely to aggravate
existing medical conditions.
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EXPOSURE During the formulation of this product, wear rubber
CONTROL METHODS gloves, goggles, and protective clothing while handling.
Wash thoroughly with soap and water after handling.
Ventilation is not required under normal use conditions.
For end-users refer to product label for PPE/clothing if
appropriate.
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SPILL OR LEAK Wear appropriate clothing and personal protective
PROCEDURES equipment (See "Exposure Control".)
Keep away from drains, surface and ground water, and soil.
Dike spill area to prevent spill from spreading. Absorb
the spilled material with an inert absorbent such as
granular clay or sawdust. Shovel or sweep the absorbed
spill into covered containers for proper disposal. (See
"Waste Disposal".)
Rinse the spill area and any tools or implements several
times with soapy water. Contain and absorb this rinsate
with inert absorbents and place into the same covered




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container as the spilled material.
Spills to the soil can be shoveled directly into covered
containers for disposal. If the spill occurred to a body
of water, immediately notify the appropriate authorities
downstream of the spill so that they can decide what if
any further action is needed.
Depending on local spill reporting requirements and the
amount released to the environment, it may be necessary to
notify the regulatory authorities.

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WASTE DISPOSAL: To avoid disposal, all attempts should be made to use this
product completely, in accordance with its registered use. If
this is not possible, handle with care and dispose in a safe
manner. Empty containers or liners may retain some product
residues. DO NOT REUSE. Rinse the container or liner as
needed for disposal. Render it unusable by crushing or
puncturing. Dispose of the container and any rinsate in a
safe manner. Follow all applicable community, national or
regional regulations regarding waste management methods.
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SPECIAL HANDLING AND STORAGE:
PRECAUTIONS Do not store below 32F.
If the product becomes crystalline, store at room
temperature to thaw. Shake well before using.
Do not contaminate water, food, or feed by storage or
disposal. Store in a secure, dry, well-ventilated
separate room, building or covered area.
Not for use or storage in or around the home.
Keep away from sources of ignition and protect from
exposure to fire and heat.
Segregate from oxidizers and incompatible materials listed
in the Reactivity Data Section.




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ADDITIONAL REGULATORY INFORMATION
SARA Title III Data
Section 311 and 312 Hazard Categories
Immediate Health Hazard - Y Reactive Hazard - N
Delayed Health Hazard -N Sudden Pressure - N
Release Hazard
Fire Hazard -N
Section 302 Extremely Hazardous Substances - None
Section 313 Toxic Chemicals - None
CERCLA Reportable Quantity
IMAGE CONSUMER CONCENTRATE (3.3%) - This product has a CERCLA RQ of
1,000,000 pounds (118,000 gal) based on sodium phosphate dibasic. The
RQ for pure sodium phosphate dibasic is 5,000 pounds.
This product does not have an EHS (extremely hazardous substance) RQ.
RCRA Hazardous Waste Code(s) And Statement(s)
IMAGE CONSUMER CONCENTRATE (3.3%) - None.
This product does not have any listed hazardous waste codes. It is
the responsibility of the waste generator to determine at the time
of disposal whether any characteristic hazardous waste codes apply.
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APPENDIX
The information and statements herein are believed to be reliable but are
not to be construed as a warranty or representation for which we assume
legal responsibility. Users should undertake sufficient verification and
testing to determine the suitability for their own particular purpose of any
information or products referred to herein. NO WARRANTY OF FITNESS FOR A
PARTICULAR PURPOSE IS MADE.
_______________________________________________________________________________
SOURCE AND DATE INFORMATION DATE: 1/1/01
_______________________________________________________________________________

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