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MSDS Material Safety Data Sheet
CAS

7732-18-5 1336-21-6 7664-41-7

File Name: 7732-18-5_1336-21-6_7664-41.asp

Material Safety Data Sheet



0.1% Ammonium Hydroxide in Water (v/v) (472)
Version 1 Revision Date 05/30/2008 Print Date 05/30/2008

SECTION 1. PRODUCT AND COMPANY IDENTIFICATION

Product name : 0.1% Ammonium Hydroxide in Water (v/v) (472)
MSDS Number : 000000012982
Product Use Description : Laboratory chemicals


Company : Honeywell International Inc.
1953 South Harvey Street
Muskegon, MI 49442

For more information call : 1-800-368-0050
(Monday-Friday, 9:00am-5:00pm)

In case of emergency call : Medical: 1-800-498-5701
: Transportation: 1-800-424-9300 or 703-527-3887
: (24 hours/day, 7 days/week)



SECTION 2. HAZARDS IDENTIFICATION
Emergency Overview

Form : liquid, clear

Color : colourless

Odor : ammoniacal

Hazard Summary : May be harmful if inhaled. May be harmful if swallowed. May
irritate eyes. May cause respiratory tract irritation. May cause
irritation of the gastrointestinal tract. May irritate skin. Do not
swallow. Avoid breathing vapors, mist or gas. Avoid contact
with skin, eyes and clothing.


Potential Health Effects

Skin : May irritate skin.

Eyes : May irritate eyes.

Ingestion : May be harmful if swallowed.
May cause irritation of the gastrointestinal tract.

Inhalation : May be harmful if inhaled.
May cause

Chronic Exposure : None known.



Page 1 /9
Material Safety Data Sheet



0.1% Ammonium Hydroxide in Water (v/v) (472)
Version 1 Revision Date 05/30/2008 Print Date 05/30/2008


Carcinogenicity

No component of this product present at levels greater than or equal to 0.1% is identified as a known or
anticipated carcinogen by NTP, IARC, or OSHA.


SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Component CAS-No. Weight %

Water 7732-18-5 >99.00
Ammonium hydroxide 1336-21-6 <1.00


SECTION 4. FIRST AID MEASURES

Inhalation : Remove to fresh air. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen. Use oxygen as required,
provided a qualified operator is present. Call a physician.

Skin contact : Wash off immediately with plenty of water for at least 15
minutes. Take off contaminated clothing and shoes immediately.
Wash contaminated clothing before re-use. Call a physician if
irritation develops or persists.

Eye contact : Rinse immediately with plenty of water, also under the eyelids,
for at least 15 minutes. Call a physician if irritation develops or
persists.

Ingestion : Do not induce vomiting without medical advice. Never give
anything by mouth to an unconscious person. Call a physician.


Notes to physician

Treatment : Treat symptomatically.



SECTION 5. FIRE-FIGHTING MEASURES

Flash point : not applicable

Lower explosion limit : not applicable

Upper explosion limit : not applicable

Suitable extinguishing : Use extinguishing measures that are appropriate to local
media circumstances and the surrounding environment.

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Material Safety Data Sheet



0.1% Ammonium Hydroxide in Water (v/v) (472)
Version 1 Revision Date 05/30/2008 Print Date 05/30/2008

Water spray
Foam
Carbon dioxide (CO2)
Dry chemical

Specific hazards during fire : The product is not flammable.
fighting In case of fire hazardous decomposition products may be
produced such as:
Ammonia
nitrogen oxides (NOx)

Special protective : In the event of fire and/or explosion do not breathe fumes.
equipment for fire-fighters Wear self-contained breathing apparatus and protective suit.
No unprotected exposed skin areas.



SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions : Immediately evacuate personnel to safe areas.
Keep people away from and upwind of spill/leak.
Wear personal protective equipment. Unprotected persons
must be kept away.
Ensure adequate ventilation.
Do not swallow.
Avoid breathing vapors, mist or gas.
Avoid contact with skin, eyes and clothing.

Environmental precautions : Prevent further leakage or spillage if safe to do so.
Discharge into the environment must be avoided.
Do not flush into surface water or sanitary sewer system.
Prevent product from entering drains.

Methods for cleaning up : Ventilate the area.
Contain and collect spillage with non-combustible absorbent
materials, e.g. sand, earth, vermiculite, diatomaceous earth and
place in container for disposal according to local regulations
(see section 13).



SECTION 7. HANDLING AND STORAGE
Handling

Handling : Handle with care.
Wear personal protective equipment.
Use only in well-ventilated areas.
Keep container tightly closed.
Containers which are opened must be carefully resealed and
kept upright to prevent leakage.
Do not swallow.


Page 3 /9
Material Safety Data Sheet



0.1% Ammonium Hydroxide in Water (v/v) (472)
Version 1 Revision Date 05/30/2008 Print Date 05/30/2008

Avoid breathing vapors, mist or gas.
Avoid contact with skin, eyes and clothing.

Advice on protection against : Normal measures for preventive fire protection.
fire and explosion

Storage
Requirements for storage : Keep containers tightly closed in a dry, cool and well-ventilated
areas and containers place.
Containers which are opened must be carefully resealed and
kept upright to prevent leakage.
Keep away from heat and sources of ignition.
Keep away from direct sunlight.
Store away from incompatible substances.



SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Protective measures : Ensure that eyewash stations and safety showers are close to
the workstation location.
Do not swallow.
Avoid contact with skin, eyes and clothing.
Avoid breathing vapors, mist or gas.

Engineering measures : Use with local exhaust ventilation.
Prevent vapor buildup by providing adequate ventilation during
and after use.

Eye protection : Wear as appropriate:
Safety glasses with side-shields
Goggles
If splashes are likely to occur, wear:
Goggles or face shield, giving complete protection to eyes

Hand protection : Protective gloves
Gloves must be inspected prior to use.
Replace when worn.

Skin and body protection : Wear as appropriate:
Rubber or plastic apron
Rubber or plastic boots
If splashes are likely to occur, wear:
Protective suit

Respiratory protection : When workers are facing concentrations above the exposure
limit they must use appropriate certified respirators.
For rescue and maintenance work in storage tanks use
self-contained breathing apparatus.
Use NIOSH approved respiratory protection.

Page 4 /9
Material Safety Data Sheet



0.1% Ammonium Hydroxide in Water (v/v) (472)
Version 1 Revision Date 05/30/2008 Print Date 05/30/2008


Hygiene measures : Handle in accordance with good industrial hygiene and safety
practice.
When using do not eat, drink or smoke.
Wash hands before breaks and at the end of workday.
Keep working clothes separately.
Remove and wash contaminated clothing before re-use.
Do not swallow.
Avoid breathing vapors, mist or gas.
Avoid contact with skin, eyes and clothing.

Exposure Guidelines

Ammonia 7664-41-7 ACGIH TWA 25 ppm

ACGIH STEL 35 ppm

NIOSH REL 25 ppm 18 mg/m3

NIOSH STEL 35 ppm 27 mg/m3

US CA OEL TWA PEL 25 ppm 18 mg/m3

US CA OEL STEL 35 ppm 27 mg/m3

OSHA Z1 PEL 50 ppm 35 mg/m3

OSHA Z1A STEL 35 ppm 27 mg/m3



SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Form : liquid, clear

Color : colourless

Odor : ammoniacal

pH : 10.9

Melting point/range : not determined

Boiling point/boiling range : not determined

Vapor pressure : not determined

Relative vapour density : not determined

Density : 0.9979 g/cm3
at 20 癈 (68 癋)

Page 5 /9
Material Safety Data Sheet



0.1% Ammonium Hydroxide in Water (v/v) (472)
Version 1 Revision Date 05/30/2008 Print Date 05/30/2008

Water solubility : completely soluble



SECTION 10. STABILITY AND REACTIVITY

Conditions to avoid : Heat, flames and sparks.
Keep away from direct sunlight.

Materials to avoid : Halogens
Nitromethane
Acids
Bases
Metals
Metal halides
Dimethyl sulfate
Silver nitrate
Propylene oxide

Hazardous decomposition : In case of fire hazardous decomposition products may be
products produced such as:
Ammonia
nitrogen oxides (NOx)

Hazardous reactions : Hazardous polymerisation does not occur.
Stable under normal conditions.



SECTION 11. TOXICOLOGICAL INFORMATION

Acute oral toxicity Component: 1336-21-6 Ammonium hydroxide
(Component) LD50 rat
Dose: 350 mg/kg

Acute inhalation toxicity Component: 1336-21-6 Ammonium hydroxide
(Component) LC50 rat
Dose: 5.1 mg/l
Exposure time: 1 h



SECTION 12. ECOLOGICAL INFORMATION



Toxicity to fish : Component: 1336-21-6 Ammonium hydroxide
(Component) LC50
Species: Oncorhynchus mykiss (rainbow trout)
Dose: > 0.1 mg/l
Exposure time: 96 h


Page 6 /9
Material Safety Data Sheet



0.1% Ammonium Hydroxide in Water (v/v) (472)
Version 1 Revision Date 05/30/2008 Print Date 05/30/2008

Toxicity to fish : Component: 1336-21-6 Ammonium hydroxide
(Component) LC50
Species: Bluegill sunfish
Dose: > 0.2 mg/l
Exposure time: 96 h

Toxicity to fish : Component: 1336-21-6 Ammonium hydroxide
(Component) LC50
Species: Fathead minnow
Dose: > 0.7 mg/l
Exposure time: 96 h

Toxicity to fish : Component: 1336-21-6 Ammonium hydroxide
(Component) LC50
Species: Cyprinus carpio (Carp)
Dose: 1.1 mg/l
Exposure time: 96 h

Toxicity to daphnia and : Component: 1336-21-6 Ammonium hydroxide
other aquatic invertebrates. LC50
(Component) Species: Daphnia
Dose: 25.4 mg/l
Exposure time: 48 h



SECTION 13. DISPOSAL CONSIDERATIONS

Waste Information: Observe all Federal, State, and Local Environmental regulations.


SECTION 14. TRANSPORT INFORMATION

Not dangerous goods
DOT

Not dangerous goods
TDG

Not dangerous goods
IATA

Not dangerous goods
IMDG


SECTION 15. REGULATORY INFORMATION

Inventories

EU. EINECS : On the inventory, or in compliance with the inventory

US. Toxic Substances : On TSCA Inventory
Control Act


Page 7 /9
Material Safety Data Sheet



0.1% Ammonium Hydroxide in Water (v/v) (472)
Version 1 Revision Date 05/30/2008 Print Date 05/30/2008

Australia. Industrial : On the inventory, or in compliance with the inventory
Chemical (Notification and
Assessment) Act

Canada. Canadian : All components of this product are on the Canadian DSL list.
Environmental Protection
Act (CEPA). Domestic
Substances List (DSL).
(Can. Gaz. Part II, Vol. 133)

Japan. Kashin-Hou Law List : On the inventory, or in compliance with the inventory

Korea. Toxic Chemical : On the inventory, or in compliance with the inventory
Control Law (TCCL) List

Philippines. The Toxic : On the inventory, or in compliance with the inventory
Substances and Hazardous
and Nuclear Waste Control
Act

China. Inventory of Existing : On the inventory, or in compliance with the inventory
Chemical Substances


National regulatory information


: Ammonium hydroxide 1336-21-6
SARA 313 Components

: Acute Health Hazard
SARA 311/312 Hazards

: 100000 lbs
CERCLA Reportable
Quantity

: This product does not contain any chemicals known to State of
California Prop. 65
California to cause cancer, birth, or any other reproductive
defects.




: Ammonium hydroxide 1336-21-6
Massachusetts RTK

: Water 7732-18-5
New Jersey RTK
: Ammonium hydroxide 1336-21-6

: Water 7732-18-5
Pennsylvania RTK
: Ammonium hydroxide 1336-21-6

Page 8 /9
Material Safety Data Sheet



0.1% Ammonium Hydroxide in Water (v/v) (472)
Version 1 Revision Date 05/30/2008 Print Date 05/30/2008


: Not Rated
WHMIS Classification




SECTION 16. OTHER INFORMATION

HMIS III NFPA
Health Hazard :2 2
Flammability :0 0
Physical Hazard :0
Instability : 0




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