MSDS Material Safety Data Sheet

1336-21-6 7664-41-7

File Name: 1336-21-6_7664-41-7.asp

                                      Material Safety Data Sheet
Revision Issued: JUL 27, 2001 Supercedes: MAY 31, 2001 First Issued: AUG 31, 1996
Section I - Product and Company Identification
Product Name: Aqua Ammonia 31
PotashCorp MSDS No:
1101 Skokie Blvd., Northbrook, IL 60062
Phone (800) 241-6908* (847) 849-4200 Flammability

Suite 500, 122 - 1st Avenue South
Saskatoon, Saskatchawan Canada S7K 7G3
3 Reactivity
Phone (800) 667-0403 from Canada* (800) 667-3930 from USA
Emergencies (800) 424-9300 (CHEMTREC)
Web Site Specific Hazard
Health Emergencies, Contact Your Local Poison Center N F PA CODE
Aqua Ammonia/
Aqueous Ammonia,
NH4OH / H20 Industrial
Ammoniacal Liquid
Common Name: ___________________ Formula: _______________ Synonym: ________________________ Use: ___________________

Section II - Composition/Information On Ingredients

Exposure Limits
% by
Chemical Name(s) CAS No. Weight
mg/m3 mg/m3 mg/m3 mg/m3
ppm ppm ppm ppm
Aqua Ammonia / 1336-21-6 25(1) 25(1) 35(1) 18-30(1)
Ammonium Hydroxide

Section III - Hazard Identification
Inhalation of 500 PPM Ammonia considered immediately dangerous to life and health
Potential Acute Health Effects:
Eyes and Skin: EYES: Liquid: Intensely irritating; in extreme, corneal ulceration or blindness.
SKIN: Liquid: Corrosive burns or blister formation. Gas: Irritates moist skin.
Ammonia vapors are highly irritating to throat at approximately 400 PPM. Causes edema, dyspnoea,
bronchospasm, chest pain, pink frothy sputum. Inhalation of 500 PPM Ammonia considered immediately
dangerous to life and health (OSHA).
As with other corrosive alkalis: Severe burning of gullet, stomach, mouth, and throat. Possible death
from shock or asphyxia. Human lethal dose not established: Any amount can be dangerous.
Potential Chronic
No other potential chronic health effects known.
Health Effects:
No No No
Lists: IARC Monograph: __________ NTP: __________ OSHA: __________

Section IV - First Aid Measures
Immediately flood with large amounts of water for at least 15 minutes. Seek prompt medical attention.
Quickly remove contaminated clothing Immediately wash area with large amounts of water for at least 15
minutes. Seek prompt medical attention. Wash clothing before re-use.
Ingestion: Do not induce vomiting. Encourage victim to drink large amounts of water, substituting as available, diluted
vinegar or citrus juices. Seek prompt medical attention.
Inhalation: Use respiratory protection as necessary and remove to fresh air at once. If breathing stops, give artificial
respiration. Seek prompt medical attention.

Section V - Fire Fighting Measures
None 651篊 (1204篎)(Based on Ammonia)
Flash Point: ____________________________ Autoignition Temperature: ____________________________
Lower: 16% Upper: 25%
(Based on Ammonia) (Based on Ammonia)
Lower Explosive Limit: ____________________________ Upper Explosive Limit: ____________________________

(Based on ammonia). Ammonia increases the fire hazard from other combustible materials, includ-
Unusual Fire and
ing oil. Flammable limits are broadened by increasing temperature. Ammonia vapor in the range of
Explosion Hazards:
16-25% in air can explode on contact with ignition sources.
Extinguishing Media: Fire extinguishing agents recommended: Water spray
Fire extinguishing agents to avoid: CO2 may react violently
Special Firefighting Wear full protective clothing. Stop flow of gas before extinguishing fire. Use water spray to keep
Procedures and
fire-exposed containers cool.
Product Name: Aqua Ammonia Page 2 of 4

Section VI - Accidental Release Measures
Remain upwind of spill or leak. Evacuate immediate areas and wear appropriate protective equipment
Small Spill:
depending on the concentration of ammonia in immediate area.
In unknown concentrations SCBA must be worn. Keep ignition sources away.
Large Spill:
If spill could potentially enter any waterway, including intermittent dry creeks, contact the local authorities.
Release Notes:
If in the U.S., contact the US COAST GUARD NATIONAL RESPONSE CENTER toll free number
800-424-8802. In case of accident or road spill notify: CHEMTREC IN USA at 800-424-9300; CANUTEC
in Canada at 613-996-6666 CHEMTREC in other countries at (International code)+1-703-527-3887.
See Section XIII for disposal information and Section XV for regulatory requirements. Large and
small spills may have a broad definition depending on the user's handling system. Therefore, the spill
category must be defined at the point of release by technically qualified personnel.

Section VII - Handling and Storage
Provide ventilation sufficient to maintain exposure below TWA/TLV/PEL (based on ammonia).
Handling: Avoid all contact of liquid with the body. Minimize gas contact. Good maintenance to prevent leaks. Keep
away from heat and open flames. Use good process control.
Storage: Preferably stored outside, otherwise in cool, dry well-ventilated non-combustible location, away from all
possible sources of ignition and oxidizers. Protect containers from heat, corrosion.
Storage and physical damage ?in locating storage areas, consideration should be given to health and fire
hazards, population density, and proximity of water supplies. Also, closed containers should be provided
with safety relief valves, as necessary.

Section VIII - Exposure Controls/ Personal Protection
Provide ventilation sufficient to maintain exposure below TWA/TLV/PEL (based on ammonia).
Personal Protection:
Wear hard hat, chemical safety goggles, full-face shield if eyes are not covered by respiratory
device. Do not wear contact lenses
Eye Protection:
Protective Clothing: Wear rubber apron, impervious protective clothing and rubber boots for routine product use.
Specialized handling ?alkali-resistant gloves. For leak or spill or other emergency, use full protective
Respiratory Use an approved NIOSH ammonia respirator. (Special: refers to a specific cartridge or canister for
Protection: NH3 gas.) Up to 100 PPM chemical cartridge respirator, special, supplied-air respirator, or self-con-
tained breathing apparatus. 100 to 300 PPM, chemical cartridge respirator, special with full-face
piece. Supplied air respirator (gas mask, special supplied-air respirator, or self-contained breathing
apparatus) required for exposure of 300 ppm or greater. Latter two types should have full-face
Other Protective Provide safety shower and eye wash facility at sites of handling and storage.
Clothing or Equipment:

Section IX - Physical and Chemical Properties
Appearance/Color/Odor: This material at normal conditions is a clear liquid with a strong pungent ammonia odor.
-77篊 36篊
Melting Point/Range: Boiling Point:
100% Not Available
Solubility in Water:. Boiling Point/Range:
Specific Gravity: (H20 = 1): 0.897 (28-30%) at 60?F 2, 159 mmHg at 25篊
Vapor Pressure (mmHg):
Vapor Density: (Air = 1): (NH3 Gas) 0.596 (60?F, 15.6?C) 35.05
Molecular Weight:
Not Applicable (at 20?C) 100%
Bulk Density: %Volatiles:
11.6 in a 1.0 normal solution;4.75 @ 25篊 Not Applicable
pH: Evaporation Rate:
Not applicable
Product Name: Aqua Ammonia Page 3 of 4

Section X - Stability and Reactivity
This product is stable under normal ambient conditions of temperature and pressure
Will not occur
Conditions to Avoid: Heating increases vapor pressure. Ammonia gas may be released when aqua ammonia is heated.
Materials to Avoid Oxidizing materials, strong acids, halogens; avoid use of non-ferrous metals. Boron, chlorites,
(Incompatibilities): chromium trioxide, dimethyl sulfate, ethylene oxide, gold, mercury, nitrogen tetroxide, oleum, phos-
Hazardous Gaseous ammonia on heating. Normal combustion products of ammonia vapor are nitrogen (*N2)
Decomposition and water. Oxides of nitrogen may be produced under certain conditions.

Section XI - Toxicological Information
Significant Routes
Eyes, Digestive Tract, Respiratory Tract, Skin
of Exposure:
Acute Oral LD50 (rat): 350 mg/kg.
Toxicity to Animals:
Acute Toxicity, Other routes LDL0 (rabbit) : 5 mg total NH3/kg.
Special Remarks
on Toxicity Bacterial Genetic Toxicity In-Vitro: Negative
to Animals:
No effects known.
Other Effects
on Humans:
Special Remarks
Human lethal dose not established: Any amount can be dangerous.
on Chronic Effects
on Humans:
Special Remarks
No other effects known.
on Other Effects
on Humans:

Section XII - Ecological Information
Ecotoxicity: Acute Toxicity to Fish: 24-h LC50: 20 -25 mg total NH3/L. Acute Toxicity to Daphnia: 48-h TLm: 16 mg
total NH3/L. Toxicity to Aquatic Plants: Decline in phytoplankton population. Slightly toxic to aquatic
organisms as defined by USEPA.
Environmental No known environmental fate.
No known toxicity.
No known degradation.

Section XIII - Disposal Considerations
Disposal of ammonium hydroxide may be subject to federal, state and local regulations.
Product Disposal:
General Users of the product should review their operations in terms of applicable laws and regulations,
Comments: then consult with appropriate regulatory agencies before discharging or disposing of waste
material of the product.
Product Name: Aqua Ammonia Page 4 of 4

Section XIV - Transportation Information
USDOT TDG - Canada
for solutions with more than 10% for solutions with more than 10%
but not more than 35% but not more than 35%
Ammonia Solutions Ammonia Solutions
Proper Shipping Name:
8 8, (9.2)
Hazard Class:
UN2672 UN2672
Identification Number:
Packing Group (Technical Name): III III
Corrosive Corrosive
Labeling/ Placarding:
Authorized Packaging:
Trucks: DOT 51, MC 306,307, 312,330,331, 407, 412
If product exceeds the CERCLA Reportable Quantity, the notation "RQ" shall be added before
or after the basic shopping description
European Transportation:

Section XV - Regulatory Information
SARA Hazard This product has been reviewed according to the EPA Hazard Categories promulgated under Section 311
Category: and 312 of the Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered,
under applicable definitions, to meet the following categories:
Yes Yes Yes No
Fire: ______ Pressure Generating: ______ Reactivity: ______ Acute: ______ Chronic: ______
40 CFR Part 355 - Extremely Hazardous Substances: None
40 CFR Part 370 - Hazardous Chemical Reporting: Applicable
All intentional ingredients listed on the TSCA inventory.
This product contains the following substances subject to the reporting requirements of Title III (EPCRA) of
the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372:
SARA (1986) Reporting
Percent by CERCLA RQ
Chemical CAS No.
Weight 311 312 313
Ammonium Hydroxide 1336-21-6 Yes
37.0 - 61.7 Yes see
see Note (1) Yes
1000 lbs. (100%
(see Note (1)) (as NH4OH) Note (2)
2700 lbs (18% wt.
Solution As NH3)
1620 lbs. (30% wt.
Solution As NH3 )
Note: (1) CERCLA reports Aqua Ammonia as Ammonium Hydroxide (CAS 1336-21-6)
(2) Reported as Aqueous Ammonia (CAS 7664-41-7) 18 - 30% (for SARA reporting)
If this product contains components subject to substances designated as CERCLA Reportable
CERCLA/Superfund, Quantity (RQ) Substances, it will be designated in the above table with the RQ value in pounds.
40 CFR Parts 117,302:
If there is a release of RQ Substance to the environment, notification to the National Response
Center, Washington D.C. (1-800-424-8802) is required.
This product is WHMIS controlled. Class D1b,E
WHMIS Hazard Symbol and Classification:
This product does contain ingredient(s) on this list.
Ingredient Disclosure List:
All intentional ingredients are listed on the DSL
Environmental Protection:
(Domestic Substance List).

Section XVI - Other Information
3 1 0
NFPA Hazard Rating: Health _________ Fire _________ Reactivity _________ Special Hazards __________________

0 = Insignificant 1 = Slight 2 = Moderate 3 = High 4 = Extreme

All, New Format
Section(s) changed since last revision:

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