MATERIAL SAFETY DATA SHEET
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1. Product and Company Identification
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Product Name ACE Toilet Bowl Cleaner
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Mixture
CAS #
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Toilet bowl cleaner
Product use
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Iron Out dba Summit Brands
Manufacturer
7201 Engle Road
Fort Wayne, IN 46804-5875 US
Phone: 260-483-2519
Emergency Phone: 1-800-424-9300 (CHEMTREC)
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LEGEND Health * 3
0
HMIS/NFPA
Flammability 0
Severe 4
3 0
Serious 3
Physical Hazard 0
Moderate 2
Slight 1 Personal Protection
B
Minimal 0
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2. Hazards Identification
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DANGER -- CORROSIVE
Emergency overview
Causes chemical burns to eyes and skin.
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Potential short term health effects
Eye, Skin contact, Inhalation, Ingestion.
Routes of exposure
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Causes chemical burns. May cause blindness.
Eyes
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Causes chemical burns.
Skin
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May cause respiratory tract irritation.
Inhalation
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Harmful if swallowed. May cause chemical burns to mouth, throat and stomach.
Ingestion
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Eyes. Respiratory system. Skin.
Target organs
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Prolonged or repeated exposure to dilutions can cause drying, defatting and dermatitis.
Chronic effects
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The product causes burns of eyes, skin and mucous membranes.
Signs and symptoms
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3. Composition / Information on Ingredients
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Ingredient(s) CAS # Percent
Hydrogen chloride 7647-01-0 7 - 13
Ethoxylated aliphatic amines 61791-26-2 1-5
Methyl salicylate 119-36-8 0 - 0.1
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4. First Aid Measures
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First aid procedures
Immediately flush with cool water. Remove contact lenses, if applicable, and continue
Eye contact
flushing for 15 minutes. Obtain medical attention immediately.
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Immediately flush with water. Wash with soap and water. Obtain medical attention if
Skin contact
irritation persists.
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If symptoms develop move victim to fresh air. If symptoms persist, obtain medical
Inhalation
attention.
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Do not induce vomiting. If vomiting occurs naturally, have victim lean forward to reduce
Ingestion
risk of aspiration. Never give anything by mouth if victim is unconscious, or is
convulsing. Obtain medical attention.
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Symptoms may be delayed.
Notes to physician
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If you feel unwell, seek medical advice (show the label where possible). Ensure that
General advice
medical personnel are aware of the material(s) involved, and take precautions to protect
themselves. Show this safety data sheet to the doctor in attendance. Avoid contact with
eyes and skin. Keep out of reach of children.
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5. Fire Fighting Measures
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Not flammable by WHMIS/OSHA criteria.
Flammable properties
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Extinguishing media
Treat for surrounding material.
Suitable extinguishing media
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Unsuitable extinguishing media Not available
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Protection of firefighters
Not available
Specific hazards arising from
the chemical
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Firefighters should wear full protective clothing including self contained breathing
Protective equipment for
apparatus.
firefighters
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May include and are not limited to: Oxides of carbon. Oxides of nitrogen. Ammonia.
Hazardous combustion products
Hydrogen chloride.
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Explosion data
Not available
Sensitivity to mechanical
impact
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Not available
Sensitivity to static discharge
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6. Accidental Release Measures
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Keep unnecessary personnel away. Do not touch or walk through spilled material. Do
Personal precautions
not touch damaged containers or spilled material unless wearing appropriate protective
clothing. Keep people away from and upwind of spill/leak.
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Stop leak if you can do so without risk. Prevent entry into waterways, sewers,
Methods for containment
basements or confined areas.
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Before attempting clean up, refer to hazard data given above. Small spills may be
Methods for cleaning up
absorbed with non-reactive absorbent and placed in suitable, covered, labelled
containers. Prevent large spills from entering sewers or waterways. Contact emergency
services and supplier for advice. Never return spills in original containers for re-use.
Large Spills: Wet down with water and dike for later disposal. After removal flush
contaminated area thoroughly with water.
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7. Handling and Storage
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Use good industrial hygiene practices in handling this material. Do not get this material
Handling
in your eyes, on your skin, or on your clothing.
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Keep out of the reach of children.Store in a closed container away from incompatible
Storage
materials.
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8. Exposure Controls / Personal Protection
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Exposure limits
Ingredient(s) Exposure Limits
Ethoxylated aliphatic amines ACGIH-TLV
Not established
OSHA-PEL
Not established
Hydrogen chloride ACGIH-TLV
Ceiling: 2 ppm
OSHA-PEL
Ceiling: 5 ppm
Methyl salicylate ACGIH-TLV
Not established
OSHA-PEL
Not established
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General ventilation normally adequate.
Engineering controls
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Personal protective equipment
Wear chemical goggles.
Eye / face protection
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Rubber gloves. Confirm with a reputable supplier first.
Hand protection
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As required by employer code.
Skin and body protection
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Where exposure guideline levels may be exceeded, use an approved NIOSH respirator.
Respiratory protection
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General hygiene considerations Handle in accordance with good industrial hygiene and safety practice. When using do
not eat or drink. Wash hands before breaks and immediately after handling the product.
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9. Physical and Chemical Properties
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Clear.
Appearance
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Blue
Color
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Liquid
Form
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Wintergreen
Odor
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Not available
Odor threshold
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Liquid
Physical state
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<1
pH
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Not available
Melting point
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Not available
Freezing point
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Not available
Boiling point
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Not available
Flash point
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Not available
Pour point
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Not available
Evaporation rate
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Not available
Flammability limits in air, lower, %
by volume
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Not available
Flammability limits in air, upper, %
by volume
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Not available
Vapor pressure
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Not available
Vapor density
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1.04
Specific gravity
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Not available
Octanol/water coefficient
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Not available
Auto-ignition temperature
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100 - 220 cPs
Viscosity
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Not available
Percent volatile
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10. Stability and Reactivity
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Stable under recommended storage conditions.
Chemical stability
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Do not mix with other chemicals.
Conditions to avoid
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Bases. Reducing agents.
Incompatible materials
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Hazardous decomposition products May include and are not limited to: Oxides of carbon. Oxides of nitrogen. Ammonia.
Hydrogen chloride.
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Hazardous polymerization does not occur.
Possibility of hazardous reactions
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11. Toxicological Information
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Component analysis - LC50
Ingredient(s) LC50
Ethoxylated aliphatic amines Not available
Hydrogen chloride 935 ppm mouse; 3124 mg/l/4h rat
Methyl salicylate Not available
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Component analysis - Oral LD50
Ingredient(s) LD50
Ethoxylated aliphatic amines 620 mg/kg rat
Hydrogen chloride 900 mg/kg rabbit; 700 mg/kg rat
Methyl salicylate 887 mg/kg rat; 1110 mg/kg mouse; 2100 mg/kg dog; 1300 mg/kg
rabbit; 700 mg/kg guinea pig
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Effects of acute exposure
Causes chemical burns. May cause blindness.
Eye
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Causes chemical burns.
Skin
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May cause respiratory tract irritation.
Inhalation
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Harmful if swallowed. May cause chemical burns to mouth, throat and stomach.
Ingestion
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Non-hazardous by WHMIS/OSHA criteria.
Sensitization
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Non-hazardous by WHMIS/OSHA criteria.
Chronic effects
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Non-hazardous by WHMIS/OSHA criteria.
Carcinogenicity
ACGIH - Threshold Limit Values - Carcinogens
Hydrogen chloride 7647-01-0 A4 - Not Classifiable as a Human Carcinogen
IARC - Group 3 (Not Classifiable)
Hydrogen chloride 7647-01-0 Monograph 54 [1992]
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Non-hazardous by WHMIS/OSHA criteria.
Mutagenicity
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Non-hazardous by WHMIS/OSHA criteria.
Reproductive effects
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Contains a potential teratogen per Canadian WHMIS criteria.
Teratogenicity
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Not available
Synergistic Materials
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12. Ecological Information
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See below
Ecotoxicity
Ecotoxicity - Freshwater Fish Species Data
Hydrogen chloride 7647-01-0 96 Hr LC50 Gambusia affinis: 282 mg/L [static]
Ecotoxicity - Microtox Data
Methyl salicylate 119-36-8 1 Hr EC50 Bacillus subtilis: 989 mg/L; 16 Hr EC50 Pseudomonas putida: 380 mg/L
Ecotoxicity - Water Flea Data
Methyl salicylate 119-36-8 24 Hr EC50 Daphnia magna: 50 mg/L
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Not available
Environmental effects
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Not available
Aquatic toxicity
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Not available
Persistence / degradability
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Not available
Bioaccumulation / accumulation
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Not available
Partition coefficient
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Not available
Mobility in environmental media
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Not available
Chemical fate information
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Not available
Other adverse effects
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13. Disposal Considerations
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Not available
Waste codes
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Review federal, state/provincial, and local government requirements prior to disposal.
Disposal instructions
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Not available
Waste from residues / unused
products
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Not available
Contaminated packaging
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14. Transport Information
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U.S. Department of Transportation (DOT)
Basic shipping requirements:
Corrosive liquids, n.o.s. (HYDROGEN CHLORIDE)
Proper shipping name
8
Hazard class
UN1760
UN number
III
Packing group
Additional information:
IB3, T7, TP1, TP28
Special provisions
154
Packaging exceptions
154
ERG number
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Transportation of Dangerous Goods (TDG - Canada)
Basic shipping requirements:
Corrosive liquid, n.o.s. (HYDROGEN CHLORIDE)
Proper shipping name
8
Hazard class
1760
UN number
III
Packing group
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15. Regulatory Information
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This product has been classified in accordance with the hazard criteria of the Controlled
Canadian federal regulations
Products Regulations and the MSDS contains all the information required by the
Controlled Products Regulations.
Canada - WHMIS - Ingredient Disclosure List
Hydrogen chloride 7647-01-0 1%
Methyl salicylate 119-36-8 0.1 %
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This product is a "Hazardous Chemical" as defined by the OSHA Hazard
US Federal regulations
Communication Standard, 29 CFR 1910.1200.
All components are on the U.S. EPA TSCA Inventory List.
U.S. - CERCLA/SARA - Hazardous Substances and their Reportable Quantities
Hydrogen chloride 7647-01-0 5000 Lb final RQ; 2270 kg final RQ
U.S. - CERCLA/SARA - Section 302 Extremely Hazardous Substances EPCRA RQs
Hydrogen chloride 7647-01-0 5000 Lb EPCRA RQ (gas only)
U.S. - CERCLA/SARA - Section 302 Extremely Hazardous Substances TPQs
Hydrogen chloride 7647-01-0 500 Lb TPQ (gas only)
U.S. - CERCLA/SARA - Section 313 - Emission Reporting
Hydrogen chloride 7647-01-0 1.0 % de minimis concentration (acid aerosols including mists, vapors, gas, fog, and other
airborne forms of any particle size)
U.S. - CWA (Clean Water Act) - Hazardous Substances
Hydrogen chloride 7647-01-0 Present
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Occupational Safety and Health Administration (OSHA)
Yes
29 CFR 1910.1200 hazardous
chemical
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CERCLA (Superfund) reportable quantity
Hydrogen chloride: 5000.0000
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Superfund Amendments and Reauthorization Act of 1986 (SARA)
Immediate Hazard - Yes
Hazard categories
Delayed Hazard - Yes
Fire Hazard - No
Pressure Hazard - No
Reactivity Hazard - No
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No
Section 302 extremely
hazardous substance
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Section 311 hazardous chemical Yes
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Not available
Clean Air Act (CAA)
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Not available
Clean Water Act (CWA)
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Controlled
WHMIS status
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Class D - Division 2A, Class E - Corrosive Material
WHMIS classification
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WHMIS labeling
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This product does not contain a chemical known to the State of California to cause
State regulations
cancer, birth defects or other reproductive harm.
U.S. - California - 8 CCR Section 339 - Director's List of Hazardous Substances
Hydrogen chloride 7647-01-0 Present
U.S. - Illinois - Toxic Air Contaminants
Hydrogen chloride 7647-01-0 Present (aerosol)
U.S. - Louisiana - Reportable Quantity List for Pollutants
Hydrogen chloride 7647-01-0 5000 Lb RQ (applies to unauthorized emissions based on total mass emitted into or onto
all media within any consecutive 24-hour period); 1000 lb RQ (applies to unauthorized
emissions based on total mass emitted into the atmosphere)
U.S. - Massachusetts - Right To Know List
Hydrogen chloride 7647-01-0 Extraordinarily hazardous
U.S. - Minnesota - Hazardous Substance List
Hydrogen chloride 7647-01-0 Present
U.S. - New Jersey - Right to Know Hazardous Substance List
Hydrogen chloride 7647-01-0 sn 1012
U.S. - New York - Reporting of Releases Part 597 - List of Hazardous Substances
Hydrogen chloride 7647-01-0 5000 Lb RQ (air); 100 lb RQ (land/water)
U.S. - North Carolina - Control of Toxic Air Pollutants
Hydrogen chloride 7647-01-0 0.7 mg/m3 (acute irritants)
U.S. - Ohio - Extremely Hazardous Substances - Threshold Quantities
Hydrogen chloride 7647-01-0 500 Lb TQ (gas only)
U.S. - Pennsylvania - RTK (Right to Know) List
Hydrogen chloride 7647-01-0 Environmental hazard
Methyl salicylate 119-36-8 Present
U.S. - Rhode Island - Hazardous Substance List
Hydrogen chloride 7647-01-0 Toxic; Flammable
Methyl salicylate 119-36-8 Flammable
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Inventory name
Country(s) or region Inventory name On inventory (yes/no)*
Canada Domestic Substances List (DSL) Yes
Canada Non-Domestic Substances List (NDSL) No
United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory Yes
A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)
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16. Other Information
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Information contained herein was obtained from sources considered technically accurate
Disclaimer
and reliable. While every effort has been made to ensure full disclosure of product
hazards, in some cases data is not available and is so stated. Since conditions of actual
product use are beyond control of the supplier, it is assumed that users of this material
have been fully trained according to the requirements of all applicable legislation and
regulatory instruments. No warranty, expressed or implied, is made and supplier will not
be liable for any losses, injuries or consequential damages which may result from the
use of or reliance on any information contained in this document.
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28-Sep-2009
Issue date
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15-Sep-2009
Effective date
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15-Sep-2012
Expiry date
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Dell Tech Laboratories Ltd. (519) 858-5021
Prepared by
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For an updated MSDS, please contact the supplier/manufacturer listed on the first
Other information
page of the document.
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