MATERIAL SAFETY DATA SHEET
SECTION 1 - PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: Sheila Shine (Liquid)
GENERAL USE: Polishing agent, Cleaner. Do not use on Floors and Bathtubs. May pose slipping
hazard.
PRODUCT DESCRIPTION: Clear liquid, wintergreen odor. USA and Canada
DATE PREPARED: July 26, 2007
MANUFACTURER'S NAME
Page 1 of 4
May 22, 2007
Sheila Shine, Inc. SUPERSEDES:
ADDRESS (NUMBER, STREET, P.O. BOX) TELEPHONE NUMBER FOR INFORMATION
1201 NW 1st Ave. (305) 379-1881
(CITY, STATE AND ZIP CODE) COUNTRY EMERGENCY TELEPHONE NUMBER
Miami, FL 33136 USA ChemTel Inc. 1- (800) 255-3924 Intl. + 01 (813) 248-0585
DISTRIBUTOR'S NAME
Same
ADDRESS (NUMBER, STREET, P.O. BOX) TELEPHONE NUMBER FOR INFORMATION
(CITY, STATE AND ZIP CODE) COUNTRY EMERGENCY TELEPHONE NUMBER
SECTION 2 - HAZARDOUS INGREDIENTS
OSHA PEL ACGIH TWA
% SARA RQ
HAZARDOUS COMPONENTS CAS # TITLE III LBS
(by weight) PPM MG/M3 PPM MG/M3
Perchloroethylene (a,b,c,d,e,f,g) 127-18-4 10 -30 100 200 25 Yes 100
Severely solvent refined light paraffinic petroleum oil 64741-89-5 30 - 60 5 (oil mist)
Xylene (mixed) (a,b,c) 1330-20-7 7 - 13 100 435 100 Yes 1000
Heavy paraffinic petroleum oil (h) 64741-88-4 10 - 30 5 (mist) 5 (mist)
Ethylbenzene (a,c,d) 100-41-4 1-5 100 435 125 545 Yes 1000
Methyl salicylate 119-36-8 < 0.1 not established
(a,c) See Section 15
(b) Indicates that the Resource Conservation and Recovery Act (RCRA) has determined the waste for this chemical is listed as hazardous and must be handled
according to regulations in 40 CFR 260-281.
(d) Indicates substance appears on National Toxicology Program (NTP) list of carcinogens, International Agency for Research on Cancer (IARC) list of
carcinogens or is regulated by the Occupational Safety and Health Administration (OSHA) as a possible carcinogen.
(e) Indicates listing in Table Z - 2, 29 CFR 1910.1000, value shown is 8-hour Time Weighted Average. See table for acceptable ceiling concentration limits and
acceptable maximum peak above the acceptable ceiling concentration.
(f) California Prop 65, Safe Drinking Water and Toxic Enforcement Act of 1986, chemicals known to the state to cause cancer or reproductive toxicity. A
person in the course of doing business must warn others who may consume, come into contact with, or otherwise be exposed to this chemical.
(g) Product is listed or defined as a marine pollutant in IMDG Code or 49 CFR 172.101 Appendix B, List of Marine Pollutants and must be classified as an
Environmentally Hazardous Substance, Class 9, in addition to any other defined hazards for this product.
(h) IARC has determined that residual fuels are possibly carcinogenic to humans. Handling procedures and safety precautions in the MSDS should be followed
to minimize employee's exposure.
SECTION 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Danger! May be fatal if swallowed, inhaled or absorbed through the skin. Affects liver, kidneys, central nervous system and gastrointestinal
tract. Causes severe eye irritation. Causes irritation to skin and respiratory tract. Environmental hazard. Flammable, harmful. Hazard
Symbols - Xn, N. Risk Phrases - R40, 51/53
POTENTIAL HEALTH EFFECTS
INHALATION: High concentrations are irritating to the respiratory tract; may cause headache, dizziness, nausea, vomiting or even death in
confined or poorly ventilated areas. The primary effect of inhalation is narcosis.
SKIN: Brief contact may cause slight irritation; prolonged contact may cause moderate irritation or dermatitis. This problem may be
accentuated by liquid becoming trapped against the skin by contaminated clothing and shoes.
EYES: High vapor concentration or contact may cause irritation, discomfort or pain. May cause slight transient corneal injury.
INGESTION: Swallowing of this material may result in irritation of the mouth and GI tract. Vomiting and subsequent aspiration into the lungs
may lead to chemical pneumonia and pulmonary edema which is a potentially fatal condition.
CARCINOGENICITY Yes Yes No
NTP? IARC MONOGRAPHS? OSHA REGULATED?
This is or contains a component (perchloroethylene) that has been reported to be carcinogenic based on its IARC, OSHA, ACGIH, NTP, or
EPA classification. IARC Rating: 2A; NTP Rating: Clear evidence.
MATERIAL SAFETY DATA SHEET
PRODUCT NAME: Sheila Shine (Liquid)
Page 2 of 4
July 26, 2007
SECTION 4 - FIRST AID MEASURES
INHALATION: Remove affected person to fresh air; provide oxygen if breathing is difficult; if affected person is not breathing, administer CPR
and seek emergency medical attention.
SKIN: Remove contaminated clothing; wash affected area with soap and water; launder contaminated clothing before reuse; if irritation
persists, seek medical attention.
EYES: Check for and remove contact lenses. Flush eyes with clear running water for 15 minutes while holding eyelids open; if irritation
persists, seek medical attention.
INGESTION: If conscious drink large amounts of water; DO NOT induce vomiting. Take affected person immediately to a hospital; do not
give anything by mouth to unconscious person.
SECTION 5 - FIRE FIGHTING MEASURES
FLAMMABLE LIMITS LEL: Not determined UEL: Not determined
FLASH POINT (METHOD USED)
AUTOIGNITION TEMPERATURE: NFPA CLASS:
Not determined
132.8?F (56?C) TOC IC
GENERAL HAZARDS: Product is flammable and vapors concentrated in a confined or poorly ventilated area can be ignited upon contact with
a high energy spark, flame or high intensity source of heat such as welding spark. Products of combustion include compounds of carbon,
chlorine, hydrogen and oxygen, including carbon monoxide and phosgene. Toxic gases will form upon combustion.
EXTINGUISHING MEDIA
Carbon dioxide, water fog, dry chemical, chemical foam. Do not use solid stream of water since stream will scatter and spread fire
FIRE FIGHTING PROCEDURES
Fire fighters should wear NIOSH / MSHA approved, self - contained breathing apparatus for possible exposure to hydrogen chloride and
phosgene. Fine water spray can be used to keep fire - exposed containers cool.
UNUSUAL FIRE AND EXPLOSION HAZARDS
Vapors concentrated in a confined or poorly ventilated area can be ignited upon contact with a high energy spark, flame or high intensity
source of heat such as welding spark.
HAZARDOUS COMBUSTION PRODUCTS
In case of a fire, phosgene, chlorides, oxides of carbon, hydrocarbons, fumes or vapors, and toxic smoke may be produced.
SECTION 6 - ACCIDENTAL RELEASE MEASURES
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: CAUTION - FLAMMABLE. Evacuate and ventilate area; confine
and absorb into absorbent; place material into approved containers for disposal; for spills in excess of allowable quantities (RQ) notify the
National Response Center (800) 424 - 8802; refer to CERCLA 40 CFR 302 and SARA Title III, Section 313 40 CFR 372 for detailed
instructions concerning reporting requirements. Do not discharge into lakes, ponds, streams or public waters.
SECTION 7 - HANDLING AND STORAGE
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE: Keep container closed when not in use; protect containers from abuse;
protect from extreme temperatures. CAUTION - FLAMMABLE - keep away from all sources of ignition. "Empty" containers may contain
residue which may form explosive vapors. Do not weld or cut near empty container that has not been professionally reconditioned. Use non-
sparking tools when opening and closing containers. Maintain well ventilated work areas to minimize exposure when handling this material.
Do not use on Floors. May pose slipping hazard.
SECTION 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
ENGINEERING CONTROLS
The use of local exhaust ventilation is recommended to control emissions near the source. Provide mechanical ventilation of confined spaces.
Use explosion-proof ventilation equipment.
PERSONAL PROTECTION:
RESPIRATORY PROTECTION: None required while threshold limits are kept below maximum allowable concentrations; if TWA exceeds
limits, NIOSH approved respirator must be worn. Refer to 29 CFR 1910.134 or European Standard EN 149 for complete regulations. DO
NOT enter low - lying areas without self - contained breathing apparatus where vapors may be present. Inhalation could be fatal.
PROTECTIVE GLOVES: Neoprene, butyl or nitrile rubber gloves with cuffs.
EYE PROTECTION: Chemical splash goggles. Refer to 29 CFR 1910.133 or European Standard EN166.
OTHER PROTECTIVE CLOTHING OR EQUIPMENT: Safety eyewash station nearby.
WORK / HYGIENIC PRACTICES: Practice safe workplace habits. Minimize body contact with this, as well as all chemicals in general.
MATERIAL SAFETY DATA SHEET
PRODUCT NAME: Sheila Shine (Liquid)
Page 3 of 4
July 26, 2007
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
VAPOR PRESSURE VAPOR DENSITY (AIR = 1)
10 mm Hg @ 20?C >1
SPECIFIC GRAVITY (WATER = 1) EVAPORATION RATE (n-Butyl Acetate = 1)
0.964 <1
SOLUBILITY IN WATER FREEZING POINT
Negligible Not determined
pH APPEARANCE AND ODOR
Not applicable Clear liquid, wintergreen odor
BOILING POINT PHYSICAL STATE
234?F (112?C) Liquid
VISCOSITY VOLATILE ORGANIC COMPOUNDS (Total VOC's)
Like that of water 8.03 pounds / gallon (957 grams / liter)
SECTION 10 - STABILITY AND REACTIVITY
CONDITIONS TO AVOID: Extreme temperatures, open flames.
STABILITY UNSTABLE:
STABLE: X
INCOMPATIBILITY (MATERIALS TO AVOID): Strong oxidizers, strong acids.
HAZARDOUS DECOMPOSITION OR BYPRODUCTS: Decomposition will not occur if handled and stored properly. In case of a fire, oxides
of carbon, hydrocarbons, fumes or vapors, and smoke may be produced.
CONDITIONS TO AVOID: None
HAZARDOUS POLYMERIZATION MAY OCCUR:
WILL NOT OCCUR: X
SECTION 11 - TOXICOLOGICAL INFORMATION
LD50 of Ingredient LC50 of Ingredient
Hazardous Ingredients CAS # EINECS # (Specify Species and Route) (Specify Species)
2629 mg / kg 34,200 mg / m3
Perchloroethylene (a,b,c,d,e,f,g) 127-18-4 204-825-9
Oral - rat Inhalation - rat
> 5 gm / kg Not established
Severely solvent refined light paraffinic petroleum oil 64741-89-5 265-091-3
Oral - rat
4300 mg / kg 5000 ppm / 4H
Xylene (mixed) (a,b,c) 1330-20-7 215-535-7
Oral - rat Inhalation - rat
> 5000 mg / kg > 3.9 mg / liter
Heavy paraffinic petroleum oil (h) 64741-88-4 265-090-8
Oral - rat Inhalation - rat
3500 mg / kg 4000 ppm/4H(LCLo)
Ethylbenzene (a,c,d) 100-41-4 202-849-4
Oral - rat Inhalation - rat
887 mg / kg Not established
Methyl salicylate 119-36-8 204-317-7
Oral - rat
SECTION 12 - ECOLOGICAL INFORMATION
No data are available on the adverse effects of this material on the environment. Neither COD nor BOD data are available. Based on the
chemical composition of this product it is assumed that the mixture can be treated in an acclimatized biological waste treatment plant system
in limited quantities. However, such treatment should be evaluated and approved for each specific biological system. One of the ingredients
in this mixture (perchloroethylene) is classified as a Marine Pollutant.
SECTION 13 - DISPOSAL CONSIDERATIONS
WASTE DISPOSAL METHOD: Dispose of in accordance with local, state, and federal regulations. This product may produce hazardous
vapors in a closed disposal container creating a dangerous environment. Refer to 40 CFR 260 - 299 for complete waste disposal regulations.
Consult your local, state, or federal agency before disposing of any chemicals. Do not flush to sanitary sewer or waterway.
SECTION 14 - TRANSPORT INFORMATION
PROPER SHIPPING NAME: Flammable liquids, toxic, n.o.s. (Petroleum distillates, Perchloroethylene)
DOT HAZARD CLASS / Pack Group: 3 (6.1) / III IATA HAZARD CLASS / Pack Group: 3 (6.1) / III
REFERENCE: 49 CFR 173.150, .203, .242 IMDG HAZARD CLASS: 3 (6.1) / III
UN / NA IDENTIFICATION NUMBER: UN 1992 RID/ADR Dangerous Goods Code: 3 (6.1) / III
LABEL: FLAMMABLE, TOXIC UN TDG Class / Pack Group: 3 (6.1) / III
HAZARD SYMBOLS: F, T Hazard Identification Number (HIN): 36
Note: Transportation information provided is for reference only. Customer is urged to consult 49 CFR 100 - 177, IMDG, IATA, EC, United
Nations TDG, and WHMIS (Canada) TDG information manuals for detailed regulations and exceptions covering specific container sizes,
packaging materials and methods of shipping.
MATERIAL SAFETY DATA SHEET
PRODUCT NAME: Sheila Shine (Liquid)
Page 4 of 4
July 26, 2007
SECTION 15 - REGULATORY INFORMATION
TSCA (Toxic Substance Control Act)
All components of this product are listed on the U.S. Toxic Substances Control Act Chemical Inventory (TSCA Inventory) or are exempted
from listing because a Low Volume Exemption has been granted in accordance with 40 CFR 723.50.
SARA TITLE III (Superfund Amendments and Reauthorization Act)
311/312 Hazard Categories
Immediate health, fire hazard
313 Reportable Ingredients:
(a) Indicates a toxic chemical subject to annual reporting requirements of Section 313 of the Emergency Planning and Community Right-To-
Know Act of 1986 and of 40 CFR 372.
CERCLA (Comprehensive Response Compensation and Liability Act)
(c) The Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) has notification requirements for releases or
spills to the environment of the Reportable Quantity (RQ for this mixture = 400 lbs) or greater amounts, according to 40 CFR 302.
California Prop 65, Safe Drinking Water and Toxic Enforcement Act of 1986
There is a reportable chemical present (perchloroethylene) known to the state of California to cause cancer or reproductive toxicity.
CPR (Canadian Controlled Products Regulations)
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all
the information required by the Controlled Products Regulations. WHMIS Classification: B3, D1B, D2A, D2B
IDL (Canadian Ingredient Disclosure List)
Components of this product identified by CAS number and listed on the Canadian Ingredient Disclosure List are shown in Section 2.
DSL / NDSL (Canadian Domestic Substances List / Non-Domestic Substances List)
Components of this product identified by CAS number are listed on the DSL or NDSL, or are otherwise in compliance with the New
Substances Notification (NSN) regulations. Only ingredients classified as "hazardous" are listed in Section 2 unless otherwise indicated.
EINECS (European Inventory of Existing Commercial Chemical Substances)
Components of this product identified by CAS numbers are on the European Inventory of Existing Commercial Chemical Substances.
EC Risk Phrases SYMBOL(S) REQUIRED EC Safety Phrases
FOR LABEL
R40 Limited evidence of a carcinogenic effect. S2 Keep out of the reach of children.
R51/53 Toxic to aquatic organisms, may cause long- S23 Do not breathe vapour.
term adverse effects in the aquatic environment. Harmful Environment S36/37 Wear suitable protective clothing and
gloves.
Hazard
S61 Avoid release to the environment. Refer to
special instructions / safety data sheets.
SECTION 16 - OTHER INFORMATION
Specific toxicity tests have not been conducted on this product. Our hazard evaluation is based on Information from similar products, the
ingredients, technical literature, and/or professional experience.
HMIS HAZARD RATINGS * = Chronic Health Hazard 2 = MODERATE
HEALTH 2
0 = INSIGNIFICANT 3 = HIGH
FLAMMABILITY 3
1 = SLIGHT 4 = EXTREME
PHYSICAL HAZARD 0
PERSONAL PROTECTIVE EQUIPMENT Safety Glasses, Gloves
B
REVISION SUMMARY:
This MSDS has been revised in the following sections: No changes noted
MSDS Prepared by: Comprehensive Data Base, Inc.
P.O. Box 395
Intercession City, FL 33848 USA
(863) 644 - 3298 www.compdatabase.com or www.msds.cc
The information contained herein is believed to be accurate but is not warranted to be so. Data and calculations are based on information furnished by the
manufacturer of the product and manufacturers of the components of the product. Users are advised to confirm in advance of need that information is current,
applicable and suited to the circumstances of use. Vendor assumes no responsibility for injury to vendee or third persons proximately caused by the material if
reasonable safety procedures are not adhered to as stipulated in the data sheet. Furthermore, vendor assumes no responsibility for injury caused by abnormal use
of this material even if reasonable safety procedures are followed. Any questions regarding this product should be directed to the manufacturer of the product as
described in Section 1.
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