Sheet No. 53 Revision Date: 08 February 2006
MATERIAL SAFETY DATA SHEET
HMIS: NFPA:
Health- 1 Flammability- 0 Reactivity- 0 Pers. Health- 1 Flammability- 0 Reactivity- 0 Special
Protection- N Hazard- N
WHMIS: D 2 B
Section 1: Product and Company Identification
Product: Nilodew Dumpster Deodorizer Synonyms:
NILODOR, INC.
10966 INDUSTRIAL PARKWAY NW
BOLIVAR, OHIO 44612, USA
Non-Emergency: 24 hr Emergency Spill Information:
US 800-443-4321 Chem-Tel, Inc.
US, Canada: 800-255-3924. International:
International 010-330-874-1017
1-813-248-0584
Section 2. Hazards Identification
EMERGENCY OVERVIEW
Appearance/Odor: Gray-brown granules
Classified as hazardous by the criteria of NOHSC.
WARNING
Flammability : Not classified as flammable
Health Hazards Listed : R 49: May cause cancer if inhaled (only if dry/dusty, see below)
Ecological Hazards Listed : None known
Potential Health Effects: See section 11 for more information.
Likely Routes of Exposure: Respiration
Eye: Direct exposure can irritate
Skin: Prolonged or repeated exposure can irritate
Ingestion: Not expected to be a problem
Inhalation: See below
Medical Conditions Aggravated By Exposure:
Allergies to fragrances; respiratory problems
Target Organs: Lungs, see below
This product may contain known or suspected carcinogens as listed by OSHA, IARC, or NTP; see Section 11
This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200).
Potential Environmental Effects: (See section 12 for more information.)
None known
Section 3. Composition/Information on Ingredients
WHMIS
Component CAS# % by Weight Controlled
Silica: Quartz 14808-60-7 3-7 Y
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Silica: Cristobalite 14464-46-1 1-5 Y
Silica, Fused 60676-86-0 40 - 60 Y
Cinnamaldehyde 104-55-2 0.1 - 1.0 Y
Methyl Salicylate 119-36-8 0.1 - 1.0 Y
Section 4. First Aid Measures
Flush eyes with copious amounts of clean water, holding lids open. If irritation
Eye Contact:
persists, consult a physician.
Skin Contact: Wash with soap and water.
Inhalation: Remove to fresh air.
Ingestion: Give water or milk to drink if conscious.
Inhalation of fragrance is not expected to be a problem. Inhaled or Respirable Quartz
Note to Physicians:
and Cristobalite have been associated with cancer.
Section 5. Fire Fighting Measures
Suitable Extinguishing Media: Foam, carbon dioxide, dry chemical
Unsuitable Extinguishing Media: Fragrance portion could float on surface of water and continue burning
Products of Combustion: Oxides of carbon and nitrogen.
Due to crystalline silica, self-contained breathing apparatus is
Protection of Firefighters:
recommended
Section 6. Accidental Release Measures
Keep away from skin and eyes. If product appears dry or dusty, wear dust mask
Personal Precautions:
or respirator.
Environmental Precautions: Keep out of surface waters and sanitary sewers.
Methods for Containment: No special requirements. Liquid portion is adsorbed on mineral carrier.
Methods for Clean-Up: Sweep up or shovel up for disposal.
After granular powder has been swept or shoveled up, area of spill may be
Other Information:
mopped with soap and water.
Section 7. Handling and Storage
HANDLING
Keep away from skin and eyes. If product is dry or dusty, wear dust mask or respirator.
STORAGE
Original container at ambient temperatures (below 60癈/140癋)
Section 8. Exposure Controls/Personal Protection
EXPOSURE GUIDELINES
COMPONENT: TWA: LD-50
Silica: Quartz TLV 10 mg/cu m Not determined
Silica: Cristobalite TLV 10 mg/cu m Not determined
Silica, Fused TLV 6 mg/cu m 3160 mg/kg
Cinnamaldehyde None established 2220 mg/kg
Methyl Salicylate None established 887 mg/kg
Engineering Controls: Normal Ventilation
Eye/Face Protection: Protective goggles recommended if handling large quantities
Skin Protection: Rubber or other protective gloves recommended if handling large quantities
Respiratory Protection: Dust mask or respirator recommended, especially if product appears dry or dusty.
General Hygiene Considerations: Keep out of food and beverages
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Section 9. Physical and Chemical Properties
Color: Gray to brown Odor: Spicy
Physical State: Granular Solid Odor Treshhold:
pH: Not applicable Freezing Point: Not applicable
Evaporation Rate: Not applicable Boiling Point: Not applicable
Flash Point: Not applicable Flammability(solid,gas): Not considered flammable.
Upper Flammability Limit: Not determined Lower Flammabilty Limit: Not determined
Specific Gravity: Not determined. Bulk density greater
Vapor Pressure: Less than 1 Torr at 20癈
than 0.75 g/mL
Vapor Density: Not determined Auto-ignition Temperature: Not determined
Volatile Organic Compound (VOC),%weight: Solubility (water): Insoluble
Less than 20%, all fragrance Percent Volatile: Less than 35% including water
Section 10. Stability and Reactivity
Stability: Stable
Conditions to Avoid: None known
Incompatable Materials: None known
Hazardous Decomposition Products: None known
Possibility of Hazardous Reactions: Extremely improbable
Section 11. Toxicology Information
ACCUTE EFFECTS
Not determined for mixture. Weighted average more than 6 grams per kilogram,
Oral LD50:
acute.
Not considered toxic by skin contact. Weighted average more than 5 grams per
Dermal LD50:
kilogram, acute.
Not considered acutely toxic by inhalation. Weighted average more than 4
Inhalation:
milligrams per Liter.
Eye Irritation: Direct contact with fine particles can irritate eyes
Skin Irritation: Prolonged or repeated contact can irritate skin
Sensitization: None known
CHRONIC EFFECTS
Quartz and Cristobalite are IARC Class 1 Carcinogens if inhaled, NTP Class A,
known carcinogens if "Respirable" and "Known to the State of California to Cause
Carcinogenicity:
Cancer" if "Respirable". "Respirable" is generally considered to include particle
size.
Mutagenicity: None known
Reproductive Effects: None known
Developmental Effects: None known
Section 12. Ecological Information
Ecotoxicity: None known
Persistence/Degradability: None known.
Bioaccumulation/Accumulation: Mineral carrier is persistent. Fragrance is biodegradable.
Mobility in Enviroment: None known
Section 13. Disposal Considerations
Disposal: Mineral carrier is not mobile.
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Section 14. Transportation Information
US DOT (ground)
Proper Shipping Description: Dispose according to Federal, State or Provincial, and Local regulations
CANADA TDG (ground)
Proper Shipping Description: Not a Hazardous Material
ICAO (air)
Proper Shipping Description: Not a Dangerous Good
IMDG (water)
Proper Shipping Description: Not a Dangerous Good
Section 15. Regulatory Information
Global Inventories
TSCA: United States Included
DSL: Canada Included
ECL: Korea Not-Known
PICCS: Philippines Not-Known
ENCS: Japan Not-Known
AICS: Australia Included
IECS: China Not-Known
EINECS: European Union Included
SARA 313 Information : Does not contain reportable concentrations of any SARA 313 Substances
California Safe Drinking Water and Toxic Enforcement Act pf 1986 :(Proposition 65)
"Respirable" Quartz and Cristobalite are listed under Proposition 65 as known carcinogens.
WHMIS: Canadian Workplace Hazardous Material Information System
D2B
Section 16. Other Information
Legends:
NFPA, HMIS:
0=Minimal Hazard, 1=Slight Hazard, 2=Moderate Hazard, 3=Severe Hazard, 4=Extreme Hazard
Prepared By: Technical Dept.
While we believe that the data contained herein are factual and the opinions expressed are those of qualified
experts regarding the results of tests conducted, the data are not to be taken as warranty or representation for
which we assume legal responsibility. The information is offered solely for your consideration, investigation
and verification. Any use of these data and information must be determined by the user to be in accordance with
federal, state and local laws.
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