Radiello Cod.165 Rev. 2 - 31 July 2006
MATERIAL SAFETY DATA SHEET
radiello? chemiadsorbing cartridge cod. 165
1. Product and company identification page 2
2. Composition. Information on ingredients page 2
3. Health hazard identification page 2
4. First Aid Measures page 3
5. Fire Fighting Measures page 3
6. Accidental Release Measures page 4
7. Handling and Storage page 4
8. Exposure Control. Personal protection page 5
9. Physical and Chemical properties page 6
10. Stability and Reactivity page 6
11. Toxicological information page 7
12. Ecological information page 8
13. Disposal Considerations page 8
14. Transport Information page 8
15. Regulatory Information page 8
16. Other Information page 9
Centro di Ricerche Ambientali/Padova
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Radiello Cod.165 Rev. 2 - 31 July 2006
1. Product and company identification
radiello? chemiadsorbing cartridge cod.
1.1 Product Information
165
Sampling Substrate for environmental
1.1.1 Use
assays of aldehydes
Adsorbing cartridge code 165
1.1.2 Trade Name
Fondazione Salvatore Maugeri
1.2 Company Identification
Fondazione Salvatore Maugeri
1.2.1 Name of supplier
Centro di Ricerche Ambientali/Padova
Address
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Telephone number
1.3 Emergency contact number
Tel. 0382 24444
National Toxicology Center
2. Composition. Information on ingredients
The sampling device is made by a stainless steel micronet electro tapered filled with the adsorbing
made by the following substances identified under the rule 2001/59 recognized in Italy with the
force of law since14/06/2002:
Cas# % Symbol R Frases
Ingredients
FLORISIL LB 1343-88-0
Sigma - Aldrich cod 20281 >98 not required not required
2,4 DINITROPHENYLHYDRAZINE 119-26-6
Sigma - Aldrich cod 42210 <2 Xn, F R 1, R11, R22
3. Health hazard identification
The product is not classified as hazardous according to directive 1999/45 and Law N. 65 of 14/03/03
(Hazardous Products) because the 2,4 DINITROPHENYLHYDRAZINE concentration is not over the
value of the 25% to be classified R 22 "harmful if swallowed" and moreover the lower
concentration in the blended and special preparation mode (homogeneous disperse on inert
material) and packaging (800mg single pack each) allowed this products to be not classified as R 1
"Dry material is an explosive" e R 11 "Easily flammable".
Health risk: None Environment risk: None Chemical-Physical damage: None
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4. First Aid Measures
In case of or if any symptom is present call a doctor
4.1 General Indications
showing this MSDS
Do not administer any substances by mouth to an unconscious
person.
4.2 First aid procedures in the case of:
Should be not expected effects come from products
4.2.1 Inhalation
vapor inhalation. Nevertheless, in case of breathing
symptoms (cough, dispnea), remove to fresh air. Put the
person in semi-sited position and if not breathing gives
the artificial respiration. If breathing is difficult give
oxygen.
In case of skin contact, flush with copious amounts of
4.2.2 Contact with the skin
water for at least 15 minutes. Remove contaminated
clothing and shoes. Call a doctor.
In case of contact with eye, flush with copious amounts
4.2.3 Contact with the eyes
of water for at least 15 minutes. Assure adequate
flushing by separating the eyelids with finger. Call a
doctor.
If swallowed, wash out mouth with water provided
4.2.4 Ingestion
person is conscious. Call a doctor.
5. Fire fighting measures
The product is not flammable. Nevertheless, in case of fire in an indoor ambient (e.g.: Warehouse)
follow the rules below:
Send away the people. Allontanare i non addetti ai
5.1 General indications
lavori. Stay on the upperwind side. Doesn't come indoor
without appropriate safety apparatus specify at point 5.5
Water spry, Carbon Dioxide, Appropriate foam, dry
5.2 Entinguishing media
chemical powder.
5.3 Entinguishing media that must Not known
not be used
Emits toxic fumes under fire conditions (e.g.: CO ?br>
5.4 Exposure risks in the case of fire
NOx). Refer to point 11.2. for symptoms.
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Wear self-contained breathing apparatus and protective
5.5 Fire fighting equipment
clothing to prevent contact with skin and eyes.
6. Accidental release measures
It is suggested to handle the product with safety gloves.
6.1 Personal precautions
Avoid skin and eyes contact.
Due to the handled product quantity and safety
6.2 Environmental precautions
packaging mode is not recognized the possibility to
create environment pollution and damage. Don't spread
the product on environment.
6.3 Cleaning-up methods
In case of spread, avoid raising dust. Sweep up, place in
6.3.1 Decontamination
a bag and hold for waste disposal. Ventilate area and
wash spill site after material pickup is complete.
Eliminate the polluted aqueous solution, under the local
6.3.2 Elimination
safety rules.
7. Handling and storage
7.1 Handling
Ensure a proper ventilation. No any other requirement.
7.1.1 Technical measures
Avoid contact with the eyes, skin and clothing. Avoiding
7.1.2 Precautionary measures
breathing dust. Avoid prolonged or repeated exposure.
Don't smoke. Keep out from ignition source.
.
7.2 Storage
Take all the safety measure to avoid accidental outdoor
7.1.1 Technical measures
product spread in case of breaking.
Keep container closet with the original label or in
7.1.2 Storage conditions
appropriate storage container in a fresh, dry ambient.
Keep away from flame.
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8. Exposure control. Personal protection
Follow the In Force Safety rules and the supplier
8.1 General hygiene measures
company recommendation as described in point 7.1.
Ensure good ventilation. Wash thoroughly after
handling.
Not applicable.
8.2 Olfactive perception threshold
Not known
8.3 Professional Exposure
Limits
Metahemoglobine
8.4 Exposure Bio marker
8.4 Personal protection measures
Not needed.
8.5.1 Respiratory protection
Safety Glass
8.5.2 Eye protection
Chemical Safety Gloves.
8.5.3 Hand protection
Adeguate protective lab coat.
8.5.4 Skin protection
9. Physical and chemical Properties
Solid powder
9.1 Physical State
Yellow
9.2 Color
Not detectable
9.3 Odor
Not applicable
9.4 pH
Not applicable
9.5 Boiling point
Not applicable
9.6 Melting point
Not inflammable
9.7 Flash point
Not inflammable
9.8 Flammability
Not inflammable
9.9 Auto-ignition
Not known
9.10 Explosive properties
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Not known
9.11 Combustion properties
Not applicable
9.12 Vapor pressure
Not applicable
9.13 Relative density
Not applicable
9.14 Solubility in water
Not applicable
9.15 Solubility in organic solvents
Not applicable
9.16 Partition coefficient
n-octanol/water
Not applicable
9.17 Vapor density
Not applicable
9.18 Miscibility
Not applicable
9.19 Evaporation rate
Not applicable
9.20 Conductivity
Not applicable
9.21 Viscosity
10. Stability and reactivity
Stable product, Avoid oxidizing and warming source
10.1 Conditions to avoid
Strong oxidizing agents
10.2 Materials to avoid
Hazardous Decomposition products are: Carbon
10.3 Hazardous decomposaition
Monoxide, Carbon dioxide, Nitrogen Oxides.
products
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11.Toxicological information
The only component of the product with Oral DL50 on rat
11.1 Toxicological data
below 2000 mg/Kg is due to the
2,4DINITROPHENYLHYDRAZINE, Toxicological
data reported willbe related to this substance.
DL50 oral rat 500 mg/Kg
11.2 Acute Toxicity
DL50 intraperitoneal mouse 450 mg/Kg
Rabbit eyes, 500mg 24 h, mild irritation effect
11.2.1 Skin contact
Absorption into the body leads to the formation of
Sign and Symptoms of Exposure
methemoglobin which in sufficent concentration causes
cyanosis. Onset may be delayed 2 to 4 hours or longer.
Skin Contact: May cause skin irritation
Route of Exposure
Skin Absorption: May be harmful is absorbed through
the skin.
Eye Contact: May cause eye irritation.
Inhalation: Material may be irritating to mucous
membranes and upper respiratory tract. May be Harful if
inhaled.
Ingestion: Harmful if swallowed.
Rat :
11.3 Chronic Exposure
50 mg/L, Cell type: Liver,
Unscheduled DNA synthesis
Mouse
1900 UMOL/Kg intraperitoneal, DNA damage
ZPOS: Histidine reversion (Ames).
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12. Ecological information
No data reported
12.1 Mobility
N.D.
12.2 Life time and degradability
N.D.
12.3 Bioaccumulation power
N.D.
12.4 Water Toxicity
Don't spread the product in ambient or part of it.
12.5 Observation
13. Disposal considerations
Contact a licensed professional waste disposal service to dispose of this material. After the use, the
product should be dispose as per as other laboratory products. Observe all federal, state, and local
environmental regulations.
14. Transport information
No special International rules is requires for the transport
14.1 General information
of this product.
Not dangerous.
14.2 Road and rail transport
(ADR/RID)
Not dangerous.
14.3 Marine transport
(IMDG/IMO)
Not dangerous.
14.4 Air transport (ICAQ/IATA)
15. Regulatory Information
Not required
15.1 Labeling
None
15.2 Hazard symbols
None
15.3 Risk phrases
None
15.4 Caution suggestions
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16. Other information
Ingredients Symbol R phrases
FLORISIL LB
Sigma - Aldrich cod 20281 none not required
2,4DINITROPHENYLHYDRAZINE
Sigma - Aldrich cod 42210 Xn, F R 1: Explosive when dry
R11: Highly Flammable.
R22: Harmful if swallowed.
Advice to users
The information is this material safety data sheet is based on our current knowledge and on Italian and
European Community regulations. The product must not be used for any purposes other than those specified
in section 1, in the absence of written instructions on its handling. It is the user's responsibility to take all
measures necessary to conform with local and national regulations.
The information in this data sheet complies with Directive CEE 1999/45 (assimilated in Italy by Law No. 65
of 14/03/03) and with Directive CEE 2001/58 (assimilated in Italy by Ministerial Decree 7/9/2002). The set
of regulations mentioned is simply intended to help the user comply with his or her obligations during the
use of this product
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