SAFETY DATA SHEET
Loctite Corporation 319 Rear View Mirror Bonder
Environmental Health & Safety Affairs 0150319 14.00 IE EA 14.04.2003 MSDS_IE
Health & Regulatory Affairs - Europe
This safety data sheet has been prepared in accordance with the requirements of EC Directives
1999/45/EC and 2001/58/EC and provides information relating to the safe handling and use of
the product.
1. PRODUCT AND COMPANY INFORMATION
0150319
Product Code
319 Rear View Mirror Bonder
Trade Name
Henkel Loctite Adhesives Ltd.
Manufacturer/Supplier
Watchmead,
Address
Welwyn Garden City,
Herts., AL7IJB.
UK
01 707 358800
Phone Number
01 707 358900
Fax Number
+353-1-4599301/+353-87-2629625/+353-1-4046444
Emergency Phone Number
2. COMPOSITION / INFORMATION ON INGREDIENTS
Anaerobic adhesive.
Nature
Hazardous Components in Product for EC
Component Name CAS / EINEC Concentration R Phrases Classification
Hydroxypropyl Methacrylate 27813-02-1 248- 20.00 - 40.00 R36, R43 Xi
666-3
1-Acetyl-2-phenylhydrazine 114-83-0 204- 0.10 - 1.00 R68/22, R21, R43 Xn
055-3
Cumene Hydroperoxide 80% 80-15-9 201- 0.10 - 1.00 R7, R21/22, R23, O, T, N
254-7 R34, R48/20/22,
R51/53
Acrylic acid 79-10-7 201-177- 1.00 - 5.00 R10, R20/21/22, C, N
9 R35, R50
3. HAZARD IDENTIFICATION
Irritating to respiratory system and skin. Risk of serious damage to eyes. May cause sensitisation
by skin contact.
4. FIRST AID MEASURES
First Aid - Inhalation
Should not be a problem as product is of low volatility. However, if feeling unwell remove patient
to fresh air.
First Aid - Skin
Wash with plenty of soap and water. If irritation persists, seek medical advice.
First Aid - Eyes
Flush eyes with plenty of water for at least 15 minutes. If irritation persists seek medical
attention.
First Aid - Ingestion
Rinse mouth with water then give plenty of water to drink. Do not induce vomiting.
5. FIRE FIGHTING MEASURES
Non flammable product (flash point is greater than 100癈 (CC)). Trace amounts of toxic fumes
may be released on incineration and the use of breathing apparatus is recommended. If product
is involved in fire extinguish with dry powder, foam or carbon dioxide.
6. ACCIDENTAL RELEASE MEASURES
Ventilate area.
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MSDS_IE
SAFETY DATA SHEET
Loctite Corporation 319 Rear View Mirror Bonder
Environmental Health & Safety Affairs 0150319 14.00 IE EA 14.04.2003 MSDS_IE
Health & Regulatory Affairs - Europe
6. ACCIDENTAL RELEASE MEASURES
For small spills wipe up with paper towel and place in container for disposal.
For large spills absorb onto inert absorbent material and place in sealed container for disposal.
7. HANDLING AND STORAGE
Handling
Avoid contact with skin and eyes. Prolonged or repeated skin contact should be avoided.
Gloves and safety glasses should be worn.
Storage
Store in original containers at 8癈-21癈 and do not return residual materials to containers as
contamination may reduce the shelf life of the bulk product.
Keep container tightly sealed.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Occupational exposure limits
HSA (2002).C.O.P.: OEL 10 ppm,(30 mg/m3) 8h TWA
Acrylic acid
HSA (2002).C.O.P.: OEL 20 ppm,(60 mg/m3) 15 min
exposure limit.
ACGIH: TLV 2ppm 8h TWA.
Good industrial hygiene practices should be observed.
Safety glasses should be worn.
In circumstances where there is a potential for prolonged or repeated skin contact, the use of
polyvinyl chloride or nitrile rubber gauntlets or equivalent solvent resistant gloves is
recommended.
9. PHYSICAL AND CHEMICAL PROPERTIES
Liquid.
Physical State
Amber.
Colour
Sharp. Acrylic.
Odour
Not determined.
pH
Not determined.
Boiling Range/Point (癈)
>100
Flash Point (CC) (癈)
1.05 g/ccm.
Specific Gravity
Immiscible.
Solubility in Water (kg/m?
Partially soluble
Solubility in Acetone
Less than 3 at 20 癈.
Vapour Pressure (mmHg
@25癈)
Not determined.
Explosion Limits (%)
10. STABILITY AND REACTIVITY
Non reactive to water. Non reactive to oxidising agents except for peroxides. Destabilised by
reducing agents.
11. TOXICOLOGICAL INFORMATION
Inhalation
Irritating to respiratory system.
Skin
This product is classified as a skin irritant. May cause sensitisation by skin contact.
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MSDS_IE
SAFETY DATA SHEET
Loctite Corporation 319 Rear View Mirror Bonder
Environmental Health & Safety Affairs 0150319 14.00 IE EA 14.04.2003 MSDS_IE
Health & Regulatory Affairs - Europe
11. TOXICOLOGICAL INFORMATION
Eyes
This product may cause severe damage to the eyes.
Ingestion
May irritate the digestive tract. Ingestion of large quantities may cause damage to liver or
kidneys.
12. ECOLOGICAL INFORMATION
The product should not go into drains or surface water.
13. DISPOSAL CONSIDERATIONS
Dispose of in accordance with local and national regulations. Incinerate or bury in legal landfill.
14. TRANSPORT INFORMATION
None
UN Number
Not classified.
Air (IATA)
Not classified.
Sea (IMO)
Not classified.
Road (ADR)/Rail (RID)
15. REGULATORY INFORMATION
Hydroxypropyl Methacrylate
Contains
Acrylic acid.
Irritant
Labelling
Information
R37/38 Irritating to respiratory system and skin.
R phrases
R41 Risk of serious damage to eyes.
R43 May cause sensitisation by skin contact.
S24/25 Avoid contact with skin and eyes.
S phrases
S26 In case of contact with eyes, rinse immediately with
plenty of water and seek medical advice.
S28 After contact with skin, wash immediately with
plenty of
soap and water.
S37/39 Wear suitable gloves and eye/face protection.
-
Voluntary Labelling
16. OTHER INFORMATION
14 April 2003
MSDS data revised
Hazardous Components in Product for EC
Component Name R Phrases
Hydroxypropyl Methacrylate R36, R43
1-Acetyl-2-phenylhydrazine R68/22, R21, R43
Cumene Hydroperoxide 80% R7, R21/22, R23,
R34, R48/20/22,
R51/53
Acrylic acid R10, R20/21/22,
R35, R50
R10 R10 Flammable.
R20/21/22 R20/21/22 Harmful by inhalation, in contact with skin and if swallowed.
R21 R21 Harmful in contact with skin.
R21/22 R21/22 Harmful in contact with skin and if swallowed.
R23 R23 Toxic by inhalation.
R34 R34 Causes burns.
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MSDS_IE
SAFETY DATA SHEET
Loctite Corporation 319 Rear View Mirror Bonder
Environmental Health & Safety Affairs 0150319 14.00 IE EA 14.04.2003 MSDS_IE
Health & Regulatory Affairs - Europe
Component Name R Phrases
R35 R35 Causes severe burns.
R36 R36 Irritating to eyes.
R43 R43 May cause sensitisation by skin contact.
R48/20/22 R48/20/22 Harmful: danger of serious damage to health by prolonged
exposure through inhalation and if swallowed.
R50 R50 Very toxic to aquatic organisms.
R51/53 R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in
the aquatic environment.
R68/22 R68/22 Harmful: possible risk of irreversible effects if swallowed.
R7 R7 May cause fire.
Prepared by:
Dr. Sandra Wade
Senior HRA Specialist
Health & Regulatory Affairs - Europe
Further Information may be obtained from:-
Loctite Corporation,
Health and Regulatory Affairs - Europe,
Tallaght Business Park,
Whitestown,
Dublin 24,
Ireland.
Tel: +353-1-4046444.
Fax: +353-1-4510806.
The information in this safety data sheet was obtained from reputable sources and to the best of
our knowledge is accurate and current at the mentioned date. Neither Loctite nor its subsidiary
companies accept any liability arising out of the use of the information provided here or the use,
application or processing of the product(s) described herein. Attention of users is drawn to the
possible hazards from improper use of the product(s).
This safety data sheet was prepared in accordance with Commission Directive 2001/59/EC
adapting to technical progress for the 28th time Council Directive 67/548/EEC and Commission
Directive 1999/45/EC.
Supersedes Safety Data Sheet No: 12 dated 29/10/02.
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