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MSDS Material Safety Data Sheet
CAS

27813-02-1 68332-62-7 79-10-7 80-15-9 109-16-0 2530-85-0 114-83-0 81-07-2

File Name: 27813-02-1_68332-62-7_79-10-7_80-15-9_109-16-0_2530-85-0_114-83-0.asp

HENKEL LOCTITE CORPORATION    1001 TROUT BROOK CROSSING                  10/22/04
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100

MATERIAL SAFETY DATA SHEET Page 01 of 05

Loctite(R) Part B Adhesive
37438B

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Name: Loctite(R) Part B Adhesive
Item No.: 37438B Part of Kit: 37438
Product Type: Anaerobic

2. COMPOSITION, INFORMATION ON INGREDIENTS


Ingredients CAS No. %

Polyurethane methacrylate
resin Proprietary 45-50
Hydroxyalkyl methacrylate 27813-02-1 30-35
Polymeric plasticizer 68332-62-7 10-15
ACRYLIC ACID* 79-10-7 3-5
CUMENE HYDROPEROXIDE* 80-15-9 1-3
Polyglycol dimethacrylate 109-16-0 1-3
Substituted silane 2530-85-0 1-3
1-Acetyl-2-phenylhydrazine 114-83-0 0.1-1
Saccharin 81-07-2 0.1-1

* This component is listed as a SARA Section 313 Toxic Chemical.


The polyurethane methacrylate resin is registered with the state of
New Jersey as a trade secret: NJ TSRN 06-070-1067-5068P.


Ingredients which have exposure limits

Exposure Limits (TWA) ACGIH OSHA OTHER
Ingredients (TLV) (PEL)

Hydroxyalkyl methacrylate None None 1 ppm TWA
3 ppm STEL
ACRYLIC ACID 2 ppm TWA skin 10 ppm TWA skin 1 ppm TWA skin
5.9 mg/m3 skin 30 mg/m3 skin 3 ppm STEL skin
CUMENE HYDROPEROXIDE None None 1ppm(6mg/m3)
Skin(WEEL)

Exposure Limits (STEL) ACGIH OSHA
Ingredients (TLV) (PEL)


3. HAZARDS IDENTIFICATION

Toxicity: Severe eye irritant. Moderate skin irritant.
Possible inhalation irritant. May be harmful if
swallowed. May cause kidney or liver damage.
HENKEL LOCTITE CORPORATION 1001 TROUT BROOK CROSSING 10/22/04
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100

MATERIAL SAFETY DATA SHEET Page 02 of 05

Product Name: Loctite(R) Part B Adhesive
Item No.: 37438B

3. HAZARDS IDENTIFICATION (continued)

Primary Routes of Entry: Eye, skin, inhalation, ingestion.
Signs and Symptoms
of Exposure: May cause severe dermatitis on prolonged contact
in sensitive individuals.
Existing Conditions
Aggravated by Exposure: Acrylic acid: Upper respiratory and lung diseases,
dermatitis

Literature Referenced Carcinogen
Ingredients Target Organ and Other Health Effects NTP IARC OSHA

Polyurethane methacrylate
resin No Data NO NO NO
Hydroxyalkyl methacrylate ALG IRR NO NO NO
Polymeric plasticizer NR NO NO NO
ACRYLIC ACID AC4 ALG COR IRR KID LIV NO N/A NO
CUMENE HYDROPEROXIDE ALG CNS COR IRR MUT NO NO NO
Polyglycol dimethacrylate ALG IRR NO NO NO
Substituted silane ALG IRR NO NO NO
1-Acetyl-2-phenylhydrazine ALG BLO KID MUT SOM NO NO NO
Saccharin NTO NO N/A NO
-------------------------------------------------------------------------------

Abbreviations

N/A Not Applicable AC4 ACGIH-Unclassifiable as human carc.
ALG Allergen BLO Blood
CNS Central nervous system COR Corrosive
IRR Irritant KID Kidney
LIV Liver MUT Mutagen
NR No Records NTO No Target Organs
SOM Some evidence of carcinogenicity


4. FIRST AID MEASURES

Ingestion: Do not induce vomiting. Keep individual calm.
Obtain medical attention.
Inhalation: Remove to fresh air. If symptoms persist, obtain
medical attention.
Skin Contact: Wash with soap and water.
Eye Contact: Flush at least 15 minutes with water. Obtain
medical attention.
HENKEL LOCTITE CORPORATION 1001 TROUT BROOK CROSSING 10/22/04
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100

MATERIAL SAFETY DATA SHEET Page 03 of 05

Product Name: Loctite(R) Part B Adhesive
Item No.: 37438B

5. FIRE FIGHTING MEASURES

Flash Point: More than 200癋 Method: Tag Closed Cup
Recommended
Extinguishing Agents: Carbon dioxide, foam, dry chemical
Special Firefighting
Procedures: Not available
Hazardous Products formed
by Fire or Thermal Decomp Irritating organic vapors
Unusual Fire or
Explosion Hazards: None

Explosive Limits:
(% by volume in air)Lower 2.0% Acrylic acid
(% by volume in air)Upper 8.0% Acrylic acid

6. ACCIDENTAL RELEASE MEASURES

Steps to be taken in case
of spill or leak: Soak up in an inert absorbent. Store in a partly
filled, closed container until disposal.

7. HANDLING AND STORAGE

Safe Storage: Store below 100癋
(Contact Loctite Customer Service 1-800-243-4874 for shelf life information)
Handling: Avoid prolonged skin contact. Keep away from eyes.
Avoid breathing vapors.

8. EXPOSURE CONTROLS, PERSONAL PROTECTION

Eyes: Safety glasses or goggles.
Skin: Rubber or plastic gloves.
Ventilation: Sufficient to maintain vapor concentration below
TLV.
Respiratory Not available

See Section 2 for Exposure Limits.

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance: Light amber liquid
Odor: Sharp
Boiling Point: More than 300癋
pH: Does not apply
Solubility in Water: Slight
Specific Gravity 1.1 at 80癋
Volatile Organic Compound
(EPA Method 24) 38.6%; 425 grams per liter
Vapor Pressure: Less than 5 mm at 80癋
HENKEL LOCTITE CORPORATION 1001 TROUT BROOK CROSSING 10/22/04
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100

MATERIAL SAFETY DATA SHEET Page 04 of 05

Product Name: Loctite(R) Part B Adhesive
Item No.: 37438B

9. PHYSICAL AND CHEMICAL PROPERTIES (continued)

Vapor Density: Not available
Evaporation Rate
(Ether = 1) Not available

10. STABILITY AND REACTIVITY

Stability: Stable
Hazardous Polymerization: Will not occur
Incompatibility: None
Conditions to Avoid: Not available
Hazardous Decomposition
Products (non-thermal): None

11. TOXICOLOGICAL INFORMATION

Estimated oral LD50 more than 5000 mg/kg.
Estimated dermal LD50 more than 2000 mg/kg.

12. ECOLOGICAL INFORMATION

No data available

13. DISPOSAL CONSIDERATIONS

Recommended methods of
disposal: Incinerate following EPA and local regulations.
EPA Hazardous Waste
Number NH - Not a RCRA Hazardous Waste Material

14. TRANSPORTATION INFORMATION

DOT (49 CFR 172)
Domestic Ground Transport
Proper Shipping Name: Unrestricted
Hazard Class or
Division: Unrestricted
Identification Number: None
Marine Pollutant: None
IATA
Proper Shipping Name: Unrestricted
Class or Division: Unrestricted
UN or ID Number: None

15. REGULATORY INFORMATION

CA Proposition 65: WARNING: This product contains chemicals known to
the State of California to cause cancer
and birth defects or other reproductive
HENKEL LOCTITE CORPORATION 1001 TROUT BROOK CROSSING 10/22/04
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100

MATERIAL SAFETY DATA SHEET Page 05 of 05

Product Name: Loctite(R) Part B Adhesive
Item No.: 37438B

15. REGULATORY INFORMATION (continued)

harm.
Ethylene oxide, toluene diisocyanate,
toluene

16. OTHER INFORMATION

Estimated NFPA(R) Code:
Health Hazard: 2
Fire Hazard: 1
Reactivity Hazard: 1
Specific Hazard: Does not apply

Estimated HMIS(R) Code:
Health Hazard: 2
Flammability Hazard: 1
Reactivity Hazards: 1
Personal Protection: See Section 8.

NFPA is a registered trademark of the National Fire Protection Assn.
HMIS is a registered trademark of the National Paint and Coatings Assn.

Prepared By: Stephen Repetto
Title: Senior Regulatory Specialist, Health & Regulatory
Company: Henkel Loctite Corporation, Rocky Hill CT 06067
(24hr.) Phone: (860) 571-5100
Revision Date: October 21, 2004 Revision: 0031

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114-76-1.asp 114-76-1
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27813-02-1_68332-62-7_79-10-7_80-15-9_2530-85-0_114-83-0_81-07.asp 27813-02-1 68332-62-7 79-10-7 80-15-9 2530-85-0 114-83-0 81-07-2 110-54-3 22221-10-9
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868-77-9_80-15-9_114-83-0_95-53-4.asp 868-77-9 80-15-9 114-83-0 95-53-4
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112945-52-5_80-15-9_114-83-0_122-60-1_150-76.asp 112945-52-5 80-15-9 114-83-0 122-60-1 150-76-5
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18268-70-7_25852-47-5_868-77-9_80-15-9_613-48-9_114-83-0_110-16-7.asp 18268-70-7 25852-47-5 868-77-9 80-15-9 613-48-9 114-83-0 110-16-7 81-07-2 112945-52-5
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