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353-87-2 110-16-7 80-15-9 114-83-0

File Name: 353-87-2_110-16-7_80-15-9_114-83-0.asp

                                                                                   SAFETY DATA SHEET
Loctite Corporation 243
Environmental Health & Safety Affairs 0128561 8.00 IE EA 30.04.2003 MSDS_IE
Health & Regulatory Affairs - Europe

This safety data sheet has been prepared in accordance with the requirements of EC Directives
1999/45/EC and 2001/58/EC and provides information relating to the safe handling and use of
the product.

1. PRODUCT AND COMPANY INFORMATION
0128561
Product Code
243
Trade Name
Henkel Loctite Adhesives Ltd.
Manufacturer/Supplier
Watchmead,
Address
Welwyn Garden City,
Herts., AL7IJB.
UK
01 707 358800
Phone Number
01 707 358900
Fax Number
+353-1-4599301/+353-87-2629625/+353-1-4046444
Emergency Phone Number

2. COMPOSITION / INFORMATION ON INGREDIENTS
Product based on polyethyleneglycol dimethacrylate.
Nature
Anaerobic thread sealant.
Hazardous Components in Product for EC
Component Name CAS EINEC Concentration R Phrases Classification
Maleic Acid 110-16-7 203-742-5 0.10 - 0.40 R22, R36/37/38 Xn
Cumene Hydroperoxide 80% 80-15-9 201-254-7 0.10 - 0.95 R7, R21/22, R23, R34, R48/20/22, O, T, N
R51/53
1-Acetyl-2-phenylhydrazine 114-83-0 204-055-3 0.10 - 0.30 R68/22, R21, R43 Xn

3. HAZARD IDENTIFICATION
This product is not classified as hazardous.
Prolonged contact with skin, particularly damaged skin, may cause sensitization or dermatitis in
sensitive individuals.

4. FIRST AID MEASURES
First Aid - Inhalation
Should not be a problem as product is of low volatility. However, if feeling unwell remove patient
to fresh air.
First Aid - Skin
Wash skin with plenty of soap and water. Seek medical advice if irritation develops.
First Aid - Eyes
Flush eyes immediately with plenty of water for at least 15 minutes. Seek medical advice if
irritation develops.
First Aid - Ingestion
Give plenty of water to drink. Do not induce vomiting. Obtain medical attention.

5. FIRE FIGHTING MEASURES
Non flammable product (flash point is greater than 100癈 (CC)).
If product is involved in fire extinguish with dry powder, foam or carbon dioxide.
Trace amounts of toxic fumes may be released on incineration and the use of breathing
apparatus is recommended.

6. ACCIDENTAL RELEASE MEASURES
Ventilate area.
For small spills wipe up with paper towel and place in container for disposal.

Page 1 of 4
MSDS_IE
SAFETY DATA SHEET
Loctite Corporation 243
Environmental Health & Safety Affairs 0128561 8.00 IE EA 30.04.2003 MSDS_IE
Health & Regulatory Affairs - Europe

6. ACCIDENTAL RELEASE MEASURES
For large spills absorb onto inert absorbent material and place in sealed container for disposal.
Wash spillage site thoroughly with soap and water or detergent solution.

7. HANDLING AND STORAGE
Handling
Use in well ventilated area. Avoid contact with skin and eyes.
Prolonged or repeated skin contact should be avoided to minimise any risk of sensitisation.
Storage
Store in original containers at 8癈-21癈 and do not return residual materials to containers as
contamination may reduce the shelf life of the bulk product.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Good industrial hygiene practices should be observed.
Use in well ventilated area. Avoid contact with skin and eyes. In circumstances where there is a
potential for prolonged or repeated skin contact, the use of disposable gloves (polyethylene,
natural rubber or equivalent ester-resistant material) is recommended. Safety glasses should be
worn.

9. PHYSICAL AND CHEMICAL PROPERTIES
Liquid.
Physical State
Blue. Opaque.
Colour
Characteristic.
Odour
Not soluble in water.
pH
> 150
Boiling Range/Point (癈)
>100
Flash Point (CC) (癈)
1.08.
Specific Gravity
Immiscible.
Solubility in Water (kg/m?
Miscible
Solubility in Acetone
<0.1
Vapour Pressure (mmHg
@25癈)
N/A
Explosion Limits (%)

10. STABILITY AND REACTIVITY
Non reactive to water.
Non reactive to oxidising agents except for peroxides.
Polymerisation may occur after some time in the absence of air and/or the presence of a metal;
However, the product is adequately stabilised to ensure that premature polymerisation does not
occur under normal conditions of use.

11. TOXICOLOGICAL INFORMATION
Inhalation
Due to the low volatility of the product there are no hazards associated with inhalation under
normal conditions of use.
Skin
Although it is not a common sensitizer there may be a risk of sensitization on prolonged or
repeated contact with damaged skin.




Page 2 of 4
MSDS_IE
SAFETY DATA SHEET
Loctite Corporation 243
Environmental Health & Safety Affairs 0128561 8.00 IE EA 30.04.2003 MSDS_IE
Health & Regulatory Affairs - Europe

11. TOXICOLOGICAL INFORMATION
Eyes
May cause mild irritation to the eyes.
Ingestion
May cause irritation to the digestive tract.

12. ECOLOGICAL INFORMATION
Keep away from drains and open waters.
There should be precautions taken against environmental damage caused by articles containing
this product.

13. DISPOSAL CONSIDERATIONS
Dispose of in accordance with all applicable local and national regulations. Contribution of this
product to waste is very insignificant in comparison to article in which it is used.

14. TRANSPORT INFORMATION
None
UN Number
Not classified.
Air (IATA)
Not classified.
Sea (IMO)
Not classified.
Road (ADR)/Rail (RID)

15. REGULATORY INFORMATION
1-Acetyl-2-phenylhydrazine.
Contains
May produce an allergic reaction
Labelling
Information
None.
R phrases
S26 In case of contact with eyes, rinse immediately with
S phrases
plenty of water and seek medical advice.
S28 After contact with skin, wash immediately with
plenty of soap and water.
N/A
Voluntary Labelling

16. OTHER INFORMATION
30 April 2003
MSDS data revised
Hazardous Components in Product for EC
Component Name R Phrases
Maleic Acid R22, R36/37/38
Cumene Hydroperoxide 80% R7, R21/22, R23,
R34, R48/20/22,
R51/53
1-Acetyl-2-phenylhydrazine R68/22, R21, R43
R21 R21 Harmful in contact with skin.
R21/22 R21/22 Harmful in contact with skin and if swallowed.
R22 R22 Harmful if swallowed.
R23 R23 Toxic by inhalation.
R34 R34 Causes burns.
R36/37/38 R36/37/38 Irritating to eyes, respiratory system and skin.
R43 R43 May cause sensitisation by skin contact.
R48/20/22 R48/20/22 Harmful: danger of serious damage to health by prolonged
exposure through inhalation and if swallowed.
R51/53 R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in
the aquatic environment.
R68/22 R68/22 Harmful: possible risk of irreversible effects if swallowed.
R7 R7 May cause fire.

Page 3 of 4
MSDS_IE
SAFETY DATA SHEET
Loctite Corporation 243
Environmental Health & Safety Affairs 0128561 8.00 IE EA 30.04.2003 MSDS_IE
Health & Regulatory Affairs - Europe

Component Name R Phrases


Prepared by:

Dr Hanns Misiak
HRA Specialist
Health & Regulatory Affairs - Europe

Further Information may be obtained from:-


Loctite Corporation,
Health and Regulatory Affairs - Europe,
Tallaght Business Park,
Whitestown, Dublin 24,
Ireland.

Tel: +353-1-4046444.
Fax: +353-1-4510806.

The information in this safety data sheet was obtained from reputable sources and to the best of
our knowledge is accurate and current at the mentioned date. Neither Loctite nor its subsidiary
companies accept any liability arising out of the use of the information provided here or the use,
application or processing of the product(s) described herein. Attention of users is drawn to the
possible hazards from improper use of the product(s). This safety data sheet was prepared in
accordance with Commission Directive 2001/59/EC adapting to technical progress for the 28th
time Council Directive 67/548/EEC and Commission Directive 1999/45/EC.




Page 4 of 4
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