Toxicity: Eye irritant.
Oral LD50 more than 10,000 mg/kg.
Estimated dermal LD50 more than 2000 mg/kg.
Primary Routes of Entry: 4,4' Methylenedianiline: Skin contact or
absorbtion.
Signs and Symptoms
of Exposure: May cause dermatitis on prolonged contact in
sensitive individuals.
Existing Conditions
Aggravated by Exposure: 4,4'-Methylenedianiline: Liver ailments.
Literature Referenced Carcinogen
Ingredients Target Organ and Other Health Effects NTP IARC OSHA
Polyglycol dimethacrylate ALG IRR NO NO NO
Bisphenol A fumarate resin ALG IRR NO NO NO
Maleimide No Data NO NO NO
Polymeric plasticizer No Data NO NO NO
SILICA, AMORPHOUS, FUMED,
CRYSTALLINE-FREE NUI NO N/A NO
CUMENE HYDROPEROXIDE ALG CNS COR IRR MUT NO NO NO
SACCHARIN No Data YES 2B NO
1-Acetyl-2-phenylhydrazine ALG NO NO NO
4,4'-METHYLENE DIANILINE AC3 ALG IRR LIV MUT YES 2B YES
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Abbreviations
N/A Not Applicable 2B Possibly carcinogenic to humans
AC3 ACGIH animal carcinogen. ALG Allergen
CNS Central nervous system COR Corrosive
IRR Irritant LIV Liver
MUT Mutagen NUI Nuisance dust
4. FIRST AID MEASURES
Ingestion: Do not induce vomiting. Keep individual calm.
Obtain medical attention.
Inhalation: Does not apply
Skin Contact: Wash with soap and water.
Eye Contact: Flush at least 15 minutes with water. Obtain
medical attention.
5. FIRE FIGHTING MEASURES
Flash Point: More than 200癋 Method: Tag Closed Cup
Recommended
Extinguishing Agents: Carbon dioxide, foam, dry chemical
Special Firefighting
Procedures: Not available
Hazardous Products formed
by Fire or Thermal Decomp Irritating organic vapors
Explosive Limits:
(% by volume in air)Lower Not available
(% by volume in air)Upper Not available
6. ACCIDENTAL RELEASE MEASURES
Steps to be taken in case
of spill or leak: Soak up in an inert absorbent. Store in partly
filled, closed container until disposal.
7. HANDLING AND STORAGE
Safe Storage: Store below 100癋
(Contact Loctite Customer Service 1-800-243-4874 for shelf life information)
Handling: Avoid prolonged skin contact. Keep away from eyes.
8. EXPOSURE CONTROLS, PERSONAL PROTECTION
Eyes: Safety glasses or goggles.
Skin: Rubber or plastic gloves.
Ventilation: Does not apply
Respiratory Does not apply
See Section 2 for Exposure Limits.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance: Orange-red gel
Odor: Mild
Boiling Point: More than 300癋
pH: Does not apply
Solubility in Water: Slight
Specific Gravity 1.08 at 80癋
Volatile Organic Compound
(EPA Method 24) 11.4%
Vapor Pressure: Less than 5mm at 80癋
Vapor Density: Not available
Evaporation Rate
(Ether = 1) Not available
10. STABILITY AND REACTIVITY
Stability: Stable
Hazardous Polymerization: Will not occur
Incompatibility: None
Recommended methods of
disposal: Incinerate following EPA and local regulations.
EPA Hazardous Waste
Number NH - Not a RCRA Hazardous Waste Material
14. TRANSPORTATION INFORMATION
DOT (49 CFR 172)
Domestic Ground Transport
Proper Shipping Name: Unrestricted
Hazard Class or
Division: Unrestricted
Identification Number: None
Marine Pollutant: None
IATA
Proper Shipping Name: Unrestricted
Class or Division: Unrestricted
UN or ID Number: None
15. REGULATORY INFORMATION
CA Proposition 65: WARNING: This product contains a chemical known to
the State of California to cause cancer.
4,4'-Methylene Dianiline
This product contains Saccharin. No Prop65 hazard
warning is necessary if this product is used as
reasonably anticipated.
16. OTHER INFORMATION
Estimated NFPA(R) Code:
Health Hazard: 1
Fire Hazard: 1