LOCTITE CORPORATION 09/11/96
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 01 of 05
Rearview Mirror Adhesive
ADHESIVE 81844
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Product Name: Rearview Mirror Adhesive
Item No.: ADHESIVE 81844 Part of Kit: 81844
Part No.: 11067-2
Product Type: Anaerobic
2. COMPOSITION, INFORMATION ON INGREDIENTS
Ingredients CAS No. %
Polyurethane methacrylate
resin Proprietary 45-50
Hydroxyalkyl methacrylate 27813-02-1 30-35
Polymeric plasticizer 68332-62-7 10-15
ACRYLIC ACID* 79-10-7 3-5
CUMENE HYDROPEROXIDE* 80-15-9 1-3
Substituted silane 2530-85-0 1-3
1-Acetyl-2-phenylhydrazine 114-83-0 0.1-1
SACCHARIN 81-07-2 0.1-1
* This component is listed as a SARA Section 313 Toxic Chemical.
Ingredients which have exposure limits
Exposure Limits (TWA) ACGIH OSHA OTHER
Ingredients (TLV) (PEL)
Hydroxyalkyl methacrylate None None 3 ppm ceiling
ACRYLIC ACID 2 ppm TWA skin 10 ppm TWA skin 1 ppm TWA skin
5.9 mg/m3 skin 30 mg/m3 skin 3 ppm STEL skin
Exposure Limits (STEL) ACGIH OSHA
Ingredients (TLV) (PEL)
3. HAZARDS IDENTIFICATION
Toxicity: Severe eye irritant. Moderate skin irritant.
Possible inhalation irritant. May be harmful if
swallowed. May cause kidney or liver damage.
Primary Routes of Entry: Eye, skin, inhalation, ingestion.
Signs and symptoms
of Exposure: May cause severe dermatitis on prolonged contact
in sensitive individuals.
Existing Conditions
Aggravated by Exposure: Acrylic acid: Upper respiratory and lung diseases,
dermatitis
LOCTITE CORPORATION 09/11/96
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 02 of 05
Product Name: Rearview Mirror Adhesive
Item No.: ADHESIVE 81844
3. HAZARDS IDENTIFICATION (continued)
Literature Referenced Carcinogen
Ingredients Target Organ and Other Health Effects NTP IARC OSHA
Polyurethane methacrylate
resin No Data NO NO NO
Hydroxyalkyl methacrylate ALG IRR NO NO NO
Polymeric plasticizer No Data NO NO NO
ACRYLIC ACID ALG COR IRR NO N/A NO
CUMENE HYDROPEROXIDE ALG CNS COR IRR MUT NO NO NO
Substituted silane IRR NO NO NO
1-Acetyl-2-phenylhydrazine ALG NO NO NO
SACCHARIN No Data YES 2B NO
-------------------------------------------------------------------------------
Abbreviations
N/A Not Applicable 2B Possibly carcinogenic to humans
ALG Allergen CNS Central nervous system
COR Corrosive IRR Irritant
MUT Mutagen
4. FIRST AID MEASURES
Ingestion: Do not induce vomiting. Keep individual calm.
Obtain medical attention.
Inhalation: Remove to fresh air. If symptoms persist, obtain
medical attention.
Skin Contact: Wash with soap and water.
Eye Contact: Flush at least 15 minutes with water. Obtain
medical attention.
5. FIRE FIGHTING MEASURES
Flash Point: More than 200癋 Method: Tag Closed Cup
Recommended
Extinguishing Agents: Carbon dioxide, foam, dry chemical
Hazardous Products formed
by Fire or Thermal Decomp Irritating organic vapors
Unusual Fire or
Explosion Hazards: None
Explosive Limits:
(% by volume in air)Lower 2.0% Acrylic acid
(% by volume in air)Upper 8.0% Acrylic acid
LOCTITE CORPORATION 09/11/96
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 03 of 05
Product Name: Rearview Mirror Adhesive
Item No.: ADHESIVE 81844
6. ACCIDENTAL RELEASE MEASURES
Steps to be taken in case
of spill or leak: Soak up in an inert absorbent. Store in a partly
filled, closed container until disposal.
7. HANDLING AND STORAGE
Safe Storage: Store below 100癋
(Contact Loctite Customer Service 1-800-243-4874 for shelf Life information)
Handling: Avoid prolonged skin contact. Keep away from eyes.
Avoid breathing vapors.
8. EXPOSURE CONTROLS, PERSONAL PROTECTION
Eyes: Safety glasses or goggles.
Skin: Rubber or plastic gloves.
Ventilation: Sufficient to maintain vapor concentration below
TLV.
See Section 2 for Exposure Limits.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance: Yellowish liquid
Odor: Sharp
Boiling Point: More than 300癋
pH: Does not apply
Solubility in Water: Slight
Specific Gravity 1.1 at 80癋
Volatile Organic Compound
(EPA Method 24) 38.6%; 425 grams per liter
Vapor Pressure: Less than 5 mm at 80癋
Vapor Density: Not available
Evaporation Rate
(Ether = 1) Not available
10. STABILITY AND REACTIVITY
Stability: Stable
Hazardous Polymerization: Will not occur
Incompatibility: None
Hazardous Decomposition
Products (non-thermal): None
11. TOXICOLOGICAL INFORMATION
Estimated oral LD50 more than 5000 mg/kg.
Estimated dermal LD50 more than 2000 mg/kg.
LOCTITE CORPORATION 09/11/96
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 04 of 05
Product Name: Rearview Mirror Adhesive
Item No.: ADHESIVE 81844
12. ECOLOGICAL INFORMATION
No data available
13. DISPOSAL CONSIDERATIONS
Recommended methods of
disposal: Incinerate following EPA and local regulations.
EPA Hazardous Waste
Number NH - Not a RCRA Hazardous Waste Material
14. TRANSPORT INFORMATION
DOT (49 CFR 172)
Domestic Ground Transport
Proper Shipping Name: Unrestricted
Hazard Class or
Division: Unrestricted
Identification Number: None
Marine Pollutant: None
IATA
Proper Shipping Name: Unrestricted
Class or Division: Unrestricted
UN or ID Number: None
15. REGULATORY INFORMATION
CA Proposition 65: WARNING: This product contains chemicals known to
the State of California to cause cancer
and birth defects or other reproductive
harm.
Ethylene oxide, toluene diisocyanate,
toluene
This product contains Saccharin. No Prop65 hazard
warning is necessary if this product is used as
reasonably anticipated.
16. OTHER INFORMATION
Estimated NFPA(R) Code:
Health Hazard: 2
Fire Hazard: 1
Reactivity Hazard: 1
Specific Hazard: Does not apply
Estimated HMIS(R) Code:
Health Hazard: 2
Flammability Hazard: 1
Reactivity Hazards: 1
LOCTITE CORPORATION 09/11/96
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 05 of 05
Product Name: Rearview Mirror Adhesive
Item No.: ADHESIVE 81844
16. OTHER INFORMATION (continued)
Personal Protection: See Section 8.
NFPA is a registered trademark of the National Fire Protection Assn.
HMIS is a registered trademark of the National Paint and Coatings Assn.
Prepared By: Stephen Repetto
Title: Research Chemist, Health and Safety
Company: Loctite Corp., 1001 Tr Br Cr, Rocky Hill CT 06067
(24hr.) Phone: (860) 571-5100
Revision Date: March 15, 1996 Revision: 0027
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LOCTITE CORPORATION 09/11/96
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 01 of 05
Rearview Mirror Adhesive
PRIMER 81844
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Product Name: Rearview Mirror Adhesive
Item No.: PRIMER 81844 Part of Kit: 81844
Part No.: 11067-2
Product Type: Primer
2. COMPOSITION, INFORMATION ON INGREDIENTS
Ingredients CAS No. %
n-HEXANE* 110-54-3 95-100
Organo-copper compound 22221-10-9 0.1-1
* This component is listed as a SARA Section 313 Toxic Chemical.
Ingredients which have exposure limits
Exposure Limits (TWA) ACGIH OSHA OTHER
Ingredients (TLV) (PEL)
n-HEXANE 50 ppm TWA 50 ppm TWA None
176mg/M3 180mg/M3
Organo-copper compound Cu 0.2mg/m3fume Cu 0.1mg/m3 None
Cu 1 mg/m3 dust Cu 1 mg/m3 dust
Exposure Limits (STEL) ACGIH OSHA
Ingredients (TLV) (PEL)
3. HAZARDS IDENTIFICATION
Toxicity: Eye, skin, inhalation, and gastrointestinal
irritant. Moderately toxic by ingestion.
Primary Routes of Entry: Inhalation, skin contact.
Signs and symptoms
of Exposure: Coughing, chest pains, difficulty breathing, lung
irritation, edema (which can be fatal),
gastrointestinal disturbances, nausea, headache,
vomiting, narcosis, coma, and asphyxia.
Existing Conditions
Aggravated by Exposure: Central and peripheral nervous systems, vision
defects, memory diminution.
LOCTITE CORPORATION 09/11/96
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 02 of 05
Product Name: Rearview Mirror Adhesive
Item No.: PRIMER 81844
3. HAZARDS IDENTIFICATION (continued)
Literature Referenced Carcinogen
Ingredients Target Organ and Other Health Effects NTP IARC OSHA
n-HEXANE DEV IRR NER REP NO NO NO
Organo-copper compound No Data NO NO NO
-------------------------------------------------------------------------------
Abbreviations
DEV Developmental IRR Irritant
NER Nervous System REP Reproductive
4. FIRST AID MEASURES
Ingestion: Do not induce vomiting. Keep individual calm.
Obtain medical attention.
Inhalation: Remove to fresh air, apply artificial respiration
if necessary, obtain medical attention.
Skin Contact: Wash with mild soap and water.
Eye Contact: Flush eyes with water for at least 15 minutes.
Obtain medical attention.
5. FIRE FIGHTING MEASURES
Flash Point: 7癋 Method: Tag Closed Cup
Recommended
Extinguishing Agents: Carbon dioxide, foam, dry chemical
Hazardous Products formed
by Fire or Thermal Decomp Oxides of carbon.
Unusual Fire or
Explosion Hazards: Vapors may travel considerable to source of
ignition and flash back.
Explosive Limits: 0.9
6.0
(% by volume in air)Lower 1.2%
(% by volume in air)Upper 7.7%
6. ACCIDENTAL RELEASE MEASURES
Steps to be taken in case
of spill or leak: Maintain adequate ventilation. Extinguish all
sources of ignition. Absorb in an inert absorbent.
Store in a metal container until disposal.
LOCTITE CORPORATION 09/11/96
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 03 of 05
Product Name: Rearview Mirror Adhesive
Item No.: PRIMER 81844
7. HANDLING AND STORAGE
Safe Storage: Store away from sources of ignition. Keep
containers closed when not in use. Avoid exposure
to light.
(Contact Loctite Customer Service 1-800-243-4874 for shelf Life information)
Handling: Avoid skin contact. Keep away from eyes.
Avoid inhalation of vapors.
Do not use near sources of ignition.
8. EXPOSURE CONTROLS, PERSONAL PROTECTION
Eyes: Safety glasses or goggles.
Skin: Rubber or plastic gloves.
Ventilation: Sufficient to maintain vapor concentration below
TLV. Ventilation should be explosion proof.
See Section 2 for Exposure Limits.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance: Blue liquid
Odor: Aliphatic
Boiling Point: 156癋
pH: Does not apply
Solubility in Water: Slight
Specific Gravity 0.7
Volatile Organic Compound
(EPA Method 24) Not available
Vapor Pressure: 132 mm Hg at 68癋
Vapor Density: 3.0
Evaporation Rate
(Ether = 1) 9.2
10. STABILITY AND REACTIVITY
Stability: Stable
Hazardous Polymerization: Will not occur
Incompatibility: Strong oxidizing agents.
Hazardous Decomposition
Products (non-thermal): None
11. TOXICOLOGICAL INFORMATION
See Section 3.
LOCTITE CORPORATION 09/11/96
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 04 of 05
Product Name: Rearview Mirror Adhesive
Item No.: PRIMER 81844
12. ECOLOGICAL INFORMATION
No data available
13. DISPOSAL CONSIDERATIONS
Recommended methods of
disposal: Incinerate following EPA and local regulations.
EPA Hazardous Waste
Number D001 - Hazardous waste per 40CFR 261.21
14. TRANSPORT INFORMATION
DOT (49 CFR 172)
Domestic Ground Transport
Proper Shipping Name: Consumer Commodity (Not more than one liter);
Hexanes solution (More than one liter)
Hazard Class or
Division: ORM-D (Not more than one liter);
Class 3, Packing Group II (More than one liter)
Identification Number: None (Not moer than one liter);
UN 1208 (More tha one liter)
Marine Pollutant: None
IATA
Proper Shipping Name: Hexanes solution
Class or Division: Class 3, Packing Group II
UN or ID Number: UN 1208
15. REGULATORY INFORMATION
CA Proposition 65: Not available
16. OTHER INFORMATION
Estimated NFPA(R) Code:
Health Hazard: 1
Fire Hazard: 3
Reactivity Hazard: 0
Specific Hazard: Does not apply
Estimated HMIS(R) Code:
Health Hazard: 1
Flammability Hazard: 3
Reactivity Hazards: 0
Personal Protection: See Section 8.
NFPA is a registered trademark of the National Fire Protection Assn.
HMIS is a registered trademark of the National Paint and Coatings Assn.
Prepared By: Stephen Repetto
LOCTITE CORPORATION 09/11/96
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 05 of 05
Product Name: Rearview Mirror Adhesive
Item No.: PRIMER 81844
16. OTHER INFORMATION (continued)
Title: Research Chemist, Health and Safety
Company: Loctite Corp., 1001 Tr Br Cr, Rocky Hill CT 06067
(24hr.) Phone: (860) 571-5100
Revision Date: January 22, 1996 Revision: 0001
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