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MSDS Material Safety Data Sheet
CAS

114-76-1

File Name: 114-76-1.asp

                                                                    MATERIAL SAFETY DATA SHEET
1 CHEMICAL PRODUCT & COMPANY IDENTIFICATION

TRADE NAME B-PHENYLPYRUVIC ACID, SODIUM SALT

CAS NUMBER 114-76-1
ROI NUMBER 0676P

SYNONYMS Phenylpyruvic acid, sodium salt


Research Organics
MANUFACTURER/
4353 E 49th Street
SUPPLIER
Cleveland, Ohio
44125 USA

TELEPHONE NUMBERS - 24 HOUR EMERGENCY ASSISTANCE:
INFOTRAC 800-535-5053
TELEPHONE NUMBERS - GENERAL ASSISTANCE:
Product Information 800-321-0570

2 COMPOSITION / INFORMATION ON INGREDIENTS

Ingredient CAS Number Percentage* Exposure Limits/Health Hazards

B-PHENYLPYRUVIC ACID, SODIUM 114-76-1 100 % No Exposure limits established by OSHA or
SALT ACGIH

MAY BE IRRITATING, MAY BE HARMFUL.

*Values do not reflect absolute minimums and maximums; those values may vary from time to time.

3 HAZARDS IDENTIFICATION
Emergency Overview
CAUTION! May be harmful, may be irritating. To the best of our knowledge, the chemical, physical and
toxicological properties have not been thoroughly investigated.


Potential Health Effects Skin
This material May cause skin irritation. Reddening, itching and inflammation may result.
May be absorbed through the skin.
Potential Health Effect Eyes
Direct contact may cause irritation, redness, tearing and blurred vision.
Potential Health Effects Inhalation
May cause irritation to the respiratory tract.
This material may cause injury or illness if inhaled.
Potential Health Effect Ingestion
May be harmful if swallowed.
If ingested, this material may cause irritation to the mouth, throat and gastrointestinal tract.

Effective Date: 4/12/2005 ND = No Data NA = Not Applicable Replaces Sheet Dated 8/22/2001 Page 1 of 6
Catalog Number 0676P Trade Name B-PHENYLPYRUVIC ACID, SODIUM SALT
Special Toxic Effects
CAUTION! THE TOXICOLOGICAL PROPERTIES OF THIS MATERIAL HAVE NOT BEEN FULLY INVESTIGATED.

Target Organs
ND

4 FIRST AID MEASURES
Skin
Immediately flush skin with plenty of water, for at least 15 minutes, while removing contaminated clothing and
shoes. Contaminated clothing must be laundered before reuse. Get medical attention if irritation develops or
persists.

Eyes
Flush immediately with large amounts of water for at least 15 minutes. Eyelids should be held away from the
eyeball to ensure thorough rinsing.
Get medical attention if irritation persists.
Inhalation
Safely remove victim to fresh air. If not breathing, institute cardiopulmonary resuscitation (CPR). If breathing is
difficult, ensure clear airway and give oxygen.
Get medical attention.

Ingestion
If swallowed, wash out mouth with water provided person is conscious.
Never give anything by mouth to an unconscious person.
Get medical attention.
5 FIRE FIGHTING MEASURES
Hazardous Combustion Products
MAY EMIT TOXIC FUMES UNDER FIRE CONDITIONS.
Extinguishing Media
Use extinguisher media appropriate for surrounding fire.
Basic Fire Fighting Procedure
As in any fire, wear self-contained breathing apparatus pressure-demand, (MSHA/NIOSH approved or equivalent)
and full protective gear. Evacuate the area and fight fire from a safe distance.
Unusual Fire and Explosion Hazards
None known to manufacturer.
ND (Solid)
Flash Point Temperature
ND
Autoignition Temperature
ND
Flammability Limits in Air Lower
ND
Flammability Limits in Air Upper
6 ACCIDENTAL RELEASE MEASURES
Emergency Action
Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind. (See Personal Protection
Information Section.)

Environmental Precautions
Isolate hazard area and deny entry. Keep unnecessary people away. Take immediate steps to stop and contain
the spill. Caution should be exercised regarding personnel safety and exposure to the spilled material.

Effective Date: 4/12/2005 ND = No Data NA = Not Applicable Replaces Sheet Dated 8/22/2001 Page 2 of 6
Catalog Number 0676P Trade Name B-PHENYLPYRUVIC ACID, SODIUM SALT
Spill or Leak Procedure
Vacuum or sweep up material and place in a disposal container. Clean up spills immediately under quailfied
supervision observing precautions in Protective Equipment section. Avoid clean up procedures that generate dust
or result in water pollution.
After removal, scrub the contaminated area with detergent and flush thoroughly with water. Absorb wash liquid
and place in the disposable container. Do not flush to sewer. Avoid runoff into storm sewers and ditches which
lead to waterways.
7 HANDLING AND STORAGE
Handling
DO NOT GET IN EYES, ON SKIN OR CLOTHING.
Minimize dust generation during handling and contact.
Wash hands thoroughly before eating, drinking or smoking.
Storage
Store in refrigerator.
Keep containers tightly closed and upright when not in use.

Storage Hazards
Store away from strong oxidizers.

8 EXPOSURE CONTROLS / PERSONAL PROTECTION
Engineering Contols
Facilities using or storing this material must be equipped with an eyewash station and safety shower.
Local exhaust ventilation, process enclosures, and other forms of engineering controls are the preferred means for
controlling exposures.
Eye Protection PPE
Do not wear contact lenses when working with this substance.
Avoid eye contact with this material. Wear chemical safety goggles.
Skin Protection PPE
Avoid skin contact with this material. Use appropriate chemical protective gloves when handling.
Showering and changing into street clothing after work is recommended.
Respiratory Protection PPE
A NIOSH/MSHA approved air purifying respirator is recommended where airborne concentrations are expected to
exceed exposure limits. Protection provided by air purifying respirators is limited.
Use a positive pressure air supplied respirator if there is any potential for an uncontrolled release, exposure levels
are not known, or any other circumstance where air purifing respirators may not provide adequate protection.
9 PHYSICAL AND CHEMICAL PROPERTIES
Appearance
WHITE POWDER
Boiling Point ND
Melting Point ND
Freezing Point ND
Vapor Density ND
Vapor Pressure ND
Specific Gravity ND
Molecular Formula C9H7O3Na
Molecular Weight 186.1
pH ND

10 STABILITY REACTIVITY

Effective Date: 4/12/2005 ND = No Data NA = Not Applicable Replaces Sheet Dated 8/22/2001 Page 3 of 6
Catalog Number 0676P Trade Name B-PHENYLPYRUVIC ACID, SODIUM SALT
Stability/Incompatibility
Stable under normal conditions of use.
Incompatible with strong oxidizing agents.
Decomposition Products
Combustion may produce CO and CO2.
Hazardous Polymerization
Will not occur.
11 TOXICOLOGICAL INFORMATION

CAUTION! THE TOXICOLOGICAL PROPERTIES OF THIS MATERIAL HAVE NOT BEEN FULLY
INVESTIGATED. FOLLOW GOOD LABORATORY PRACTICES WHEN HANDLING.
Routes of Exposure

Inhalation, ingestion, skin and eye contact.
LD50
RTECS # Not Listed
NO ORAL LD50 IN RATS INFORMATION IS AVAILABLE.
REGISTRY OF THE TOXIC EFFECTS OF CHEMICAL SUBSTANCES(RTECS)
Carcinogenicity

NOT LISTED BY IARC, NTP OR OSHA AS A CARCINOGEN
12 ECOLOGICAL INFORMATION
EcoToxicological Information
DATA NOT YET AVAILABLE.
Chemical Fate Information
DATA NOT YET AVAILABLE.
13 DISPOSAL CONSIDERATIONS
Waste Disposal
Under RCRA, it is the responsibility of the user of the product to determine, at the time of disposal, whether the
product meets RCRA criteria for hazardous waste.
If the material is determined to be a hazardous waste, the transportation, storage, treatment and disposal of this
waste material must be conducted in compliance with 40 CFR 262, 263, 264, 268 and 270. Disposal can occur
only in properly permitted facilities.
14 TRANSPORTATION INFORMATION
Department of Transportation (DOT) Requirements
Proper Shipping Name CHEMICALS, N.O.S
Hazard Class NA (SOLID) UN/NA Code NA
Packaging Group NA
Reportable Quantity None
Labels Required NA
Marine Pollutant (49 CFR 172.101 Appendix B) No

15 REGULATORY INFORMATION
Federal Regulations
This product is NOT on the EPA Toxic Substances Control Act (TSCA) inventory. The following
notices are required by 40 CFR 720.36 (C) for those products NOT on the inventory list: (i) This
product is supplied solely for use in Research and Development by



Effective Date: 4/12/2005 ND = No Data NA = Not Applicable Replaces Sheet Dated 8/22/2001 Page 4 of 6
Catalog Number 0676P Trade Name B-PHENYLPYRUVIC ACID, SODIUM SALT
or under the supervision of a technically qualified individual as defined by 40 CFR 720.0 et.sec. (ii)
The health risks of this product have not fully been determined. Any information that is or
becomes available will be supplied on a Material Safety
Data Sheet. Uses other than for Research and Development may constitute a violation of TSCA.
State Regulations
Based on available information this material does not contain any components or
chemicals currently known to the State of California to cause cancer, birth defects or
reproductive harm at levels which would be subject to Proposition 65.
Reformulation, use or processing of this product may affect its composition and would
require re-evaluation
International Regulations

International Phrases
R- ND Not Determined




S- 36/37/39 Wear suitable protective clothing, gloves & eye/face protection.




EINECS - 204-053-2
SARA TITLE III RATINGS
Immediate Delayed Fire Pressure Reactivity SARA 313
Hazard Hazard Hazard Hazard Hazard Chemical


NFPA Ratings
Health Flammability Reactivity Special Hazards

- - - -

HMIS RATINGS
Health Flammabilty Reactivity Personal Protection
Equipment
1 0 0 E



16 OTHER INFORMATION
Disclaimer




Effective Date: 4/12/2005 ND = No Data NA = Not Applicable Replaces Sheet Dated 8/22/2001 Page 5 of 6
Catalog Number 0676P Trade Name B-PHENYLPYRUVIC ACID, SODIUM SALT
The data contained in this Material Safety Data Sheet relates only to the specific material
designated herein. It does not relate to use in combination with any other material or in any
process. Research Organics, Inc. provides the information contained herein in good faith but
make no representation as to its comprehensiveness or accuracy. Individuals receiving this
information must exercise their independent judgment in determining it appropriateness for a
particular purpose. Research Organics, Inc. makes no representations, or warranties, either
expressed or implied, of merchantability, fitness for a particular purpose with respect to the
information refers. Accordingly, Research Organics, Inc. will not be responsible for damages
resulting from the use of reliance upon this information. In no instance is any Research
Organics, Inc. product offered for drug, food, food additive or clinical use in humans.
This material is sold for research and development only. Use in any applications other than
research and development may require prior approval from the EPA or inclusion on the
TSCA inventory.

8/22/2001
Completed On: 4/12/2005 Replaces Sheet Dated:

Completed By: Environmental and Safety Department




Effective Date: 4/12/2005 ND = No Data NA = Not Applicable Replaces Sheet Dated 8/22/2001 Page 6 of 6
Catalog Number 0676P Trade Name B-PHENYLPYRUVIC ACID, SODIUM SALT

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