Material Safety Data Sheet
Hazardous according to criteria of NOHSC Australia
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND THE COMPANY/UNDERTAKING
Degacote C2 Flexible Top Coat
Product Name:
Synonyms:
CAS-No.:
Molecular Formula:
Supplier: TCP Pty Ltd
ACN: 006 584 498
ABN: 41 006 584 498
Street Address: 1 Shelley Court
Kilsyth Vic 3137
Australia
Telephone: + 613 9725 9590
Facsimile: + 613 9723 3662
Emergency telephone numbers: Jack Mitchell 03 5286 1436
Bill Gorman 03 9735 0697
2. COMPOSITION/INFORMATION ON INGREDIENTS
Recommended use: Binder or coloured top coat for floor coating.
Appearance: Colourless to yellowish, slightly turbid liquid with ester-like odour.
CHEMICAL ENTITY CAS NO. PROPORTION
Methyl methacrylate 80-62-6 HIGH
2-Ethylhexyl acrylate 103-11-7 HIGH
N1N-bis-(2-hydroxypropyl)-p-toluidine 38668-48-3 VLOW
Stoddard Solvent 8052-41-3 VLOW
(2-hydroxy-4-methoxyphenyl)-phenyl-methanone 131-57-7 VLOW
100%
PROPORTION (% weight per weight):
VHIGH>60 HIGH 30-60 MED 10-29 LOW 1-9 VLOW <1
All the constituents of this material are listed on the Australian Inventory of Chemical Substances (AICS).
3. HAZARDS IDENTIFICATION
This material is hazardous according to health criteria of NOHSC Australia.
Hazard Category:
Xi Irritant
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Material Safety Data Sheet
Risk Phrase(s):
R36/37/38: Irritating to eyes, respiratory system and skin.
R43: May cause sensitisation by skin contact.
Classified as Dangerous Goods by the criteria of the Australia Dangerous Goods Code (ADG Code) for
Transport by Road and Rail.
Class: 3 Flammable Liquid
Poisons Schedule (Aust): Not Applicable
4. FIRST AID MEASURES
If poisoning occurs, contact a doctor or Poisons Information Centre (Phone Australia 131 126; New Zealand 03
474 7000).
Inhalation: Remove victim from exposure ?avoid becoming a casualty. Remove contaminated clothing and
loosen remaining clothing. Allow patient to assume most comfortable position and keep warm. Keep at rest until
fully recovered. If breathing laboured and patient cyanotic (blue), ensure airways are clear and have a qualified
person give oxygen through a facemask. If breathing has stopped apply artificial respiration at once. In the
event of cardiac arrest, apply external cardiac massage. Seek immediate medical advice.
Skin contact: For gross contamination, immediately drench with water and remove clothing. Continue to wash
skin with plenty of water (and soap if material is insoluble). If swelling, redness, blistering or irritation occurs
seek medical assistance. For skin burns, cover with a clean, dry dressing until medical help is available. If
blistering occurs, do NOT break blisters. If skin contact occurs, immediately remove contaminated clothing and
wash skin thoroughly. If swelling, redness, blistering or irritation occurs seek medical assistance.
Eye contact: Immediately irrigate with copious quantities of water for 15 minutes. Eyelids to be held open.
Remove clothing if contaminated and wash skin. Urgently seek medical assistance.
Ingestion: Immediately rinse mouth with water. If swallowed, do NOT induce vomiting. Give a glass of
water. If vomiting occurs give further water. Seek immediate medical advice.
Notes to physician: Treat symptomatically.
5. FIRE-FIGHTING MEASURES
Specific hazards: Flammable liquid. May form flammable vapour mixtures with air. Flameproof equipment
necessary in area where this chemical is being used. Nearby equipment must be earthed. Avoid all ignition
sources. All potential sources of ignition (open flames, pilot lights, furnaces, spark producing switches and
electrical equipment etc.) must be eliminated both in and near the work area. Do NOT smoke. Vapour may
travel a considerable distance to source of ignition and flash back. Electrical requirements for work area should
be assessed according to AS3000.
Fire fighting further advice: If safe to do so, remove containers from path of fire. Keep containers cool with
water spray. On burning may emit toxic fumes. Fire fighters to wear self-contained breathing apparatus and
suitable protective clothing if risk of exposure to vapour or products of combustion.
Suitable extinguishing media: If material is involved in a fire use foam, dry agent (carbon dioxide, dry chemical
powder).
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Material Safety Data Sheet
6. ACCIDENTAL RELEASE MEASURES
SMALL SPILLS
Wear protective equipment to prevent skin and eye contamination. Avoid inhalation of vapours. Wipe up with
absorbent (clean rag or paper towels). Collect and seal in properly labelled containers or drums for disposal.
LARGE SPILLS
Shut off all possible sources of ignition. Clear area of all unprotected personnel. Avoid accidents, clean up
immediately. Wear protective equipment to prevent skin and eye contamination and the inhalation of vapours.
Work up wind or increase ventilation. Contain ?prevent run off into drains and waterways. Use absorbent (soil,
sand or other inert material). Use a spark-free shovel. Collect and seal in properly labelled containers or drums
for disposal.
7. HANDLING AND STORAGE
Handling: Avoid skin and eye contact and inhalation of vapour, mist or aerosols.
Store in a cool place and out of direct sunlight at a temperature not exceeding 250C. Store
Storage:
away from incompatible materials described in Section 10. Store away from sources of heat or ignition. Keep
containers closed when not in use ?check regularly for leaks.
This material is classified as a Dangerous Good Class 3 Flammable Liquid as per the criteria of the Australian
Dangerous Goods Code and must be stored in accordance with the relevant regulations.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
National occupational exposure limits
No value assigned for this specific material by the National Occupational Health and Safety Commission
(NOHSC Australia).
However for:
TWA STEL CARCINOGEN NOTICES
ppm mg/m3 ppm mg/m3 CATEGORY
Methyl methacrylate 100 410 - - - Sk, Sen
Stoddard solvent - 790 - - - -
As published by the National Occupational Health & Safety Commission (NOHSC Australia).
TWA ?The time-weighted average airborne concentration over an eight-hour working day, for a five-day working
week over an entire working life.
STEL (Short Term Exposure Limit) ?the average airborne concentration over a 15 minute period which should
not be exceeded at any time during a normal eight-hour workday.
`Sk' Notice ?absorption through the skin may be a significant source of exposure. The exposure standard is
invalidated if such contact should occur.
`Sen' notice ?sensitiser. The substance can cause a specific immune response in some people. An affected
individual may subsequently react to exposure to minute levels of that substance.
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Material Safety Data Sheet
These Exposure Standards are guides to be used in the control of occupational health hazards. All atmospheric
contamination should be kept to as low a level as is workable. These exposure standards should not be used as
fine dividing lines between safe and dangerous concentrations of chemicals. They are not a measure of relative
toxicity.
If the directions for use on the product label are followed, exposure of individuals using the product should not
exceed the above standard. The standard was created for workers who are routinely, potentially exposed during
product manufacture.
Engineering measures: Ensure ventilation is adequate and that air concentrations of components are
controlled below quoted Exposure Standards. Use with local exhaust ventilation or while wearing appropriate
respirator. Vapour heavier than air ?prevent concentration in hollows or sumps. DO NOT enter confined
spaces where vapour may have collected. Keep containers closed when not in use.
Personal protection equipment: OVERALLS, SAFETY SHOES, CHEMICAL GOGGLES, GLOVES,
RESPIRATOR.
Wear overalls, chemical goggles and impervious gloves. Use with adequate ventilation. If inhalation risk exists
wear organic vapour/particulate respirator meeting the requirements of AS/NZS 1715 and AS/NZS 1716.
Available information suggests that gloves made from butyl rubber should be suitable for intermittent contact.
However, due to variations in glove construction and local conditions, the user should make a final assessment.
Always wash hands before smoking, eating, drinking or using the toilet. Wash contaminated clothing and other
protective equipment before storing or re-using.
9. PHYSICAL AND CHEMICAL PROPERTIES
Form / Colour / Odour: Colourless, slightly turbid liquid with ester-like odour.
Solubility: Slightly soluble in water.
Density: 0.97 Paraffin Separation (C): <15
Rel Vapour Density (air = 1): >1 Boiling Point (C): approx. 100
Vapour Pressure (20 C): 40 hPa Decomp. Point (C): N App
Flash Point (C): 10* Sublimation Point: N App
Flammability Limits (%): 2.1-12.5* pH: N App
Autoignition Temp (C): 430* Viscosity (23 C) 200-400 mPa.s
% Volatile by volume: N AV Evaporation Rate: N Av
Solubility in water (g/L): 20 (n-Butyl acetate=1)
*values for methyl methacrylate
(Typical values only ?consult specification sheet)
(N Av = Not Available N App = Not Applicable)
10. STABILITY AND REACTIVITY
Stability: This material can undergo polymerisation with the evolution of heat in the presence of radical forming
substances (eg. peroxides), reducing agents and heavy metal ions.
11. TOXICOLOGICAL INFORMATION
No adverse health effects expected if the product is handled in accordance with this Safety Data Sheet and the
product label. Symptoms or effects that may arise if the product is mishandled and overexposure occurs are:
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Material Safety Data Sheet
Acute Effects
Inhalation: Material is irritant to mucous membranes and respiratory tract.
Skin contact: Contact with skin will result in irritation. A skin sensitiser. Repeated or prolonged skin contact
may lead to allergic contact dermatitis. Can be absorbed through the skin with resultant toxic effects.
Eye contact: A severe eye irritant.
Ingestion: Swallowing can result in nausea, vomiting, diarrhoea, abdominal pain and irritation to the
gastrointestinal tract.
Long Term Effects: Repeated exposure to high levels of methyl methacrylate may produce adverse effects on
the heart, lungs, liver and kidneys.
Acute toxicity / Chronic toxicity
Methyl methacrylate
Oral LD50 (rat): >5,000 mg/kg
4hr Inhalation LC50 (rat): 29.8 mg/L
Dermal LD50 (rat): >5,000
A skin sensitiser: guinea pig
2-Ethylhexyl acrylate
Oral LD50 (rat): >2,000 mg/kg
Inhalation LCL0 (mouse): 0.6 mg/L
Dermal LD50 (rat): >5,000
A skin sensitiser: guinea pig
N1N-bis-(2-hydroxypropyl)-p-toluidine
Oral LD50 (rat): 172 mg/kg
Stoddard Solvents
This product contains Stoddard Solvent with <0.1% (w/w) Benzene and is therefore not classified as a
Group 2B Carcinogen.
12. ECOLOGICAL INFORMATION
Avoid contaminating waterways.
Methyl methacrylate
Readily biodegradable: 94% in 14 days
96hr LC50 flow through (oncorhynchus mykiss): >79 mg/L
48hr EC50 flow through (daphnia magna): 69 mg/L
21 day NOEC flow through (daphnia magna): 37 mg/L
8 day EC3 (scenedesmus quadricauda): 37 mg/L cell proliferation test
EC0 (pseudomonas putida): 100 mg/L
2-Ethylhexyl acrylate
48 day EC50 (daphnia magna): 17.45 mg/L
13. DISPOSAL CONSIDERATIONS
Refer to State / Territory Land Waste Management Authority.
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Material Safety Data Sheet
14. TRANSPORT INFORMATION
Road and Rail Transport
Classified as Dangerous Goods by the criteria of the Australian Dangerous Goods Code (ADG Code) for
Transport by Road and Rail.
UN No.: 1866
Class-primary: 3 Flammable Liquid
Packing group: II
Hazchem code: 3[Y]E
Proper Shipping Name: RESIN SOLUTION (contains METHYL METHACRYLATE)
Segregation Dangerous Goods: Not to be loaded with explosives (Class 1), flammable gases (Class 2.1), if
both are in bulk, toxic gases (Class 2.3), spontaneously combustible substances (Class 4.2), oxidising agents
(Class 5.1), organic peroxides (Class 5.2) or radioactive substances (Class 7), however exemptions may apply.
Marine Transport
Classified as Dangerous Goods by the criteria of the International Maritime Dangerous Goods Code (IMDG
Code) for transport by sea.
UN No: 1866
Class-primary: 3 Flammable Liquid
Packing Group: II
Proper Shipping Name: RESIN SOLUTION (contains METHYL METHACRYLATE)
Air Transport:
Classified as Dangerous Goods by the criteria of the International Air Transport Association (IATA)
Dangerous Goods Regulations for transport by air.
UN No: 1866
Class-primary: 3 Flammable Liquid
Packing Group: II
Proper Shipping Name: RESIN SOLUTION (contains METHYL METHACRYLATE)
15. REGULATORY INFORMATION
Hazardous according to criteria of NOHSC Australia.
Hazard Category:
Xi Irritant
Risk Phrase(s)
R36/37/38: Irritating to eyes, respiratory system and skin.
R43: May cause sensitisation by skin contact.
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Material Safety Data Sheet
Safety Phrase(s)
S24: Avoid contact with skin.
S36/37/39: Wear suitable protective clothing, gloves and eye/face protection.
S38: In case of insufficient ventilation, wear suitable respiratory equipment.
Poisons Schedule (Aust): Not applicable.
This material is listed on the Australian Inventory of Chemical Substances (AICS).
16. OTHER INFORMATION
Literary reference
This Material Safety Data Sheet has been prepared by TCP Pty Ltd from information provided by Degussa
Australia.
For further information about this product contact:
Name: Jack Mitchell
Phone: 03 9725 9590
Reason(s) for issue: To meet requirements of NOHSC: 2011 (2003)
Material Safety Data Sheets are updated frequently. Please ensure that you have a current copy.
This MSDS summarises at the date of issue our best knowledge of the health and safety hazard information of
the product, and in particular how to safely handle and use the product in the workplace. Since TCP Pty Ltd
cannot anticipate or control the conditions under which the product may be used, each user must, prior to usage,
review this MSDS in the context of how the user intends to handle and use the product in the workplace.
If clarification or further information is needed to ensure that an appropriate assessment can be made, the user
should contact this company.
Our responsibility for product as sold is subject to our standard terms and conditions, a copy of which is sent to
our customers and is also available upon request.
Product name: Degacote C2 Ref: TCP HSDS\MSDS NEW: C2.doc(hg)
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