HMIS
H =2
MATERIAL SAFETY DATA SHEET F =3
R =1
PPE = See Section 8
VOC: Max. content less than 50 g/L
(catalyzed)
Section I
Manufacturer: Siplast, an Icopal Group Company
(800) 643-1591 or (800) 922-8800
Address: 1000 E. Rochelle Blvd., Irving, TX 75062-3940
Emergency Phone No.: CHEMTREC, (800) 424-9300 (U.S.), (703) 527-3887 (outside of U.S.)
Product Class: Liquid-applied Waterproofing System - Component
Trade Name: Parapro Flashing Resin (Grey)
Section II - Ingredients
ACGIH OSHA
Ingredient Percent TLV PEL
205 mg/m3
Methyl methacrylate 15 - 25 50 ppm 100 ppm
CAS #80-62-6
82 mg/m3
Ethylhexyl acrylate 11 - 20 10 ppm Not Available
CAS #103-11-7 German MAK
Various acrylates 15 - 30 Not Established 100 ppm
CAS #Confidential
1,1'-(p-Tolylimino)- <2 Not Available Not Available
dipropan-2-ol
CAS #38668-48-3
1-Isoproply-2,2diethyl- <2 Not Available Not Available
trimethylenediisobutyrate
CAS #6845-50-0
0.05 mg/m3 10 mg/m3
Silicon dioxide, Quartz <4
CAS #4808-60-7 (as respirable quartz dust) %SiO2+2
10 mg/m3 3
Titanium dioxide <5 5 mg/m
(total dust)
CAS #13463-67-7 (total dust)
10 mg/m3 80 mg/m3
Silicon dioxide, amorphous <3
CAS #7631-86-9 (total dust) %SiO2
Crystalline Silica as Quartz has been found to be carcinogenic according to NTP and IARC. This same
component is not classified as carcinogenic by OSHA. See Section V.
Section III - Physical Data Section IV - Fire and Explosion Data
Appearance: Grey DOT Category: UN1263 Paint
Odor: Methyl methacrylate Hazard Class: 3
Physical state: Liquid Label: Flammable
Ignition Point: 536癋 (280癈) Packaging Group: II
Evaporation Rate (Butyl Acetate = 1): Not Flash Point: >50癋 (10癈)
Established LEL %: 1.7 UEL %: 8.2 (for methylmethacrylate)
Vapor Density (Air = 1): Not Established Extinguishing Media: Foam, carbon dioxide, dry
% Volatile by Volume: Not Established powder, high-pressure water spray. Use water spray
Solubility in H2O: Insoluble only to cool containers in fire area.
Vapor Pressure: Not determined Special Procedures: Use self-contained breathing
Viscosity: 25 - 35 dPas (Haake viscosimeter) apparatus and full protective clothing.
Density: Approx. 1.4 g/ml @ 20癈
Trade Name: Parapro Flashing Resin (Grey)
Page Two
Section V - Health Hazard Data Crystalline silica as Quartz, which may cause
mechanical irritation of the eyes. High concentrations
EMERGENCY AND HAZARDS OVERVIEW: of dust may cause coughing and mild, temporary
ROUTES OF ENTRY: Skin and eye contact with liquids, irritation. Quartz dust can accumulate in the lungs.
and inhalation. Prolonged or repeated exposure to fine airborne
Human Effects and Symptoms of Overexposure: crystalline silica dust may cause severe scarring of
This product is harmful when inhaled or ingested and the lungs, a disease called silicosis.
can cause skin, eye, and respiratory irritation as well
NOTE: This product is sold as a liquid preparation
as skin and respiratory sensitization.
This product contains: and, when used as intended, does not generate dust.
Methyl methacrylate and ethylhexyl acrylate, which Thus the product as such does not pose a respiration
may cause skin, eye, and respiratory irritation. High hazard attributable to the above three compounds.
concentrations can cause symptoms of central
LD50 oral, rat for 1,1'-(p-Tolylimino)-dipropan-2-01:
nervous system depression, such as headache,
100 mg/kg
nausea, dizziness, drowsiness, and confusion.
Both acrylates can cause dermal and respiratory
sensitization. Once a person is sensitized, contact Butylbenzyl phthalate, which according to the
with even a small amount may cause outbreaks of manufacturer may cause skin and eye irritation.
dermatitis with symptoms such as skin redness,
Carcinogenicity:
itching, rash, and swelling. This can spread from the
NTP: Yes (Quartz - see entry above)
hands or arms to other parts of the body. Persons
IARC: Yes (Quartz - see entry above)
with respiratory sensitization can experience
OSHA: No
symptoms of bronchial asthma such as wheezing,
difficult breathing, sneezing and runny or blocked
Emergency and First Aid Procedures:
nose at low airborne concentrations that have no
SKIN: Remove contaminated clothing and shoes.
effect on unsensitized people.
Wash with soap or mild detergent and large amounts
Various acrylates, which may cause skin, eye, and of water. Do not use solvents or thinners. Get
respiratory irritation and sensitization. medical attention if irritation occurs. Wash clothing
before reuse.
1,1'-(p-Tolylimino)-dipropan-2-ol which is toxic when EYES: Hold eyes open and flush for at least 15
ingested or inhaled. minutes with large amounts of water. Seek medical
attention.
1-Isopropyl-2,2dimethyltrimethylenediisobutyrate, INHALATION: Remove to fresh air immediately. If
which according to the manufacturer, may cause skin breathing has stopped, give artificial respiration. If
irritation. breathing is difficult, administer oxygen. Consult
physician if irritation of respiratory passage occurs.
Titanium Dioxide, which may cause lung damage and INGESTION: Do not induce vomiting. Give two glasses
has an ACGIH exposure limit. of water to dilute stomach contents. Never give
anything by mouth to an unconscious person.
Amorphous silicon dioxide, which because of its Consult a physician immediately.
particulate properties, may cause mechanical
Section VI - Reactivity Data
irritation to the eye and respiratory passages and has
ACGIH and OSHA exposure limits. However, this
Stability: Stable
product is sold as a liquid preparation and, when
Hazardous Decomposition Products: Carbon
used as intended, does not generate dust. Thus the
monoxide, carbon dioxide, oxides of nitrogen,
product as such does not pose a respiration hazard
hydrocarbon by-products, and black smoke.
attributable to these components.
Polymerization: Avoid high temperatures. Product
may polymerize at > 140癋 (60癈). Polymerization is
exothermic and may cause container damage and/or
fire.
Trade Name: Parapro Flashing Resin (Grey)
Page Three
Section IX - Special Precautions
Materials to Avoid: Avoid strong acids, bases, and
oxidizing agents to avoid exothermic reactions.
Avoid initiators that produce free radicals, and avoid Handling: Do not smoke. Keep away from open fire,
peroxides and metal-ions. flame, or any ignition source. Vapors may form
explosive mixtures with air. Avoid skin and eye
Section VII - Spill or Leak Procedures contact. Avoid breathing fumes. Do not eat, drink, or
smoke in application area.
Steps to be Taken Storage: Store closed containers in cool, dry area
Wearing appropriate personal protective equipment, away from heat, direct sunlight, oxidizing agents, and
contain spills onto inert absorbent and place in strong acids and alkalis. Keep away from open fire,
suitable containers. flame, or any ignition source. Keep in well-ventilated
Disposal Information: Incinerate or dispose of in areas.
accordance with Federal, State, or Local regulations. Regulatory Information (Not meant to be all
Waste Disposal Methods: Avoid contamination of inclusive): All components of this product are on the
ground water or waterways. TSCA Inventory.
This product contains the toxic chemical listed below,
Section VIII - Special Protection Information which is subject to the supplier notification
requirements of Section 313 of the Superfund
Respirator: If airborne concentration poses a health Amendments and Reauthorization Act
hazard, becomes irritating or exceeds recommended (EPCRA/"SARA") and the requirements of 40 CFR
limits, use a NIOSH approved respirator in Part 372.
accordance with OSHA Respirator Protection
requirements under 29 CFR 1910.134. PRODUCT CAS # MAX %
Engineering Controls: Use local exhaust ventilation Methyl methacrylate 80-62-6 25
or respiratory protection to maintain employee
exposure below TLV.
Skin Protection: Clothing suitable to prevent skin
contact. Use butyl rubber gloves and apply barrier
creams. Do not use PE or PVC gloves as these
materials absorb acrylates. Check suitability
recommendations by protective equipment
manufacturers, especially toward chemical
breakthrough resistance.
Eye: Safety goggles with side shields.
The information and recommendations contained herein are, to the best of Siplast's knowledge and belief, accurate and reliable as of the date
issued. Siplast does not warrant or guarantee their accuracy or reliability, and should not be liable for any loss or damage arising out of the use
thereof. User should satisfy himself that he has all current data relevant to his particular use.
Rev 10/07
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