Product name: Naftolan UV 33 Page 1 / 8
Solutia Inc. Material Safety Data Sheet Date: 12/13/2006
Reference Number: 000000009557 Version 5./E
Solutia Inc.
Material Safety Data Sheet
1. PRODUCT AND COMPANY IDENTIFICATION
Product name: Naftolan UV 33
Reference Number: 000000009557 Date: 12/13/2006
Company Information:
United States: Canada:
Solutia Inc. Solutia Canada Inc.
575 Maryville Center Drive, P.O. Box 66760 6800 St. Patrick Street
St. Louis, MO 63166-6760 LaSalle, PQ H8N 2H3
Emergency telephone: Chemtrec: 1-800-424-9300 Emergency telephone: CANUTEC: 1-613-996-6666
International Emergency telephone: Chemtrec: 703-527-3887 Non-Emergency telephone: 1-314-674-6661
Non-Emergency telephone: 1-314-674-6661
Mexico: Brazil:
Solutia MEXICO, S. DE R.L. DE C.V. Solutia Brazil Ltd.
Prol. Paseo de la Reforma 2654 Avenue Carlos Marcondes, 1200
Local 501, Piso-5 CEP: 12241-420-S鉶 Jos?dos Campos/SP-Brazil
Col. Lomas Altas Emergency telephone: 55 12 3932 7100 (PABX)
11950 Mexico, D.F. Non-Emergency telephone: 55 11 3146 1800 (PABX)
Emergency telephone: SETIQ: (in Mexico) 01-800-002-1400
Non-Emergency telephone: (in Mexico) 01-55-5259-6800
2. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Form: liquid
Colour: colourless
Odour: characteristic
WARNING STATEMENTS
DANGER!
Flammable liquid and vapour
Causes severe burns.
May cause sensitization by skin contact.
POTENTIAL HEALTH EFFECTS
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Solutia Inc. Material Safety Data Sheet Date: 12/13/2006
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Likely routes of exposure: eye and skin contact
inhalation
Eye contact: Corrosive to eyes.
Skin contact: Causes severe skin burns
Inhalation: Severely irritating if inhaled.
Harmful if inhaled
Ingestion: Harmful if swallowed.
Refer to Section 11 for toxicological information.
3. COMPOSITION/INFORMATION ON INGREDIENTS
Components CAS No. Average Concentration Units
concentration range
n-butyl acrylate 141-32-2 >=25.0 - <50.0 %
2-ethylhexyl acrylate 103-11-7 >=25.0 - <=50.0 %
acrylic acid 79-10-7 <12.5 %
methyl methacrylate 80-62-6 <12.5 %
methacrylic acid 79-41-4 <5.0 %
Ethanone, 2,2-dimethoxy-1,2-diphenyl- 24650-42-8 <0.2 %
4. FIRST AID MEASURES
If in eyes: Immediately flush with plenty of water for at least 15 minutes.
If easy to do, remove any contact lenses.
Get medical attention.
If on skin: Immediately wash with soap and plenty of water.
Remove contaminated clothing.
Get medical attention.
Wash contaminated clothing before re-use.
If inhaled: Remove patient to fresh air.
Get medical attention.
If not breathing, give artificial respiration.
If swallowed: Rinse mouth thoroughly with water.
Give water to drink.
Do not induce vomiting.
Get medical attention.
5. FIRE FIGHTING MEASURES
Upper explosion limit: 26 %(V)
Lower explosion limit: 0.8 %(V)
Hazardous products of combustion: None known;
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Solutia Inc. Material Safety Data Sheet Date: 12/13/2006
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Extinguishing media: Water spray, foam, dry chemical, or carbon dioxide
Unsuitable extinguishing media: Never use
water jet
Unusual fire and explosion hazards: Decomposes in a fire giving off toxic gas.
Fire fighting equipment: Firefighters, and others exposed, wear self-contained breathing apparatus.
Equipment should be thoroughly decontaminated after use.
Miscellaneous advice: Take precautionary measures against static discharges.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions: Ensure adequate ventilation.
Use personal protection recommended in section 8.
Environmental Keep out of drains and water courses.
precautions:
Methods for cleaning up: Contain large spills with dikes and transfer the material to appropriate containers for
reclamation or disposal. Absorb remaining material or small spills with an inert material
and then place in a chemical waste container. Flush spill area with water.
Refer to Section 13 for disposal information and Sections 14 and 15 for reportable quantity information.
7. HANDLING AND STORAGE
Handling
Avoid contact with eyes, skin and clothing.
Do not taste or swallow.
Take precautionary measures against static discharges.
Use with adequate ventilation.
Keep away from heat, sparks, and flame.
Keep container closed.
Container hazardous when empty. Observe all recommended safety precautions until container is cleaned,
reconditioned or destroyed. The reuse of this material's container for non industrial purposes is prohibited and any
reuse must be in consideration of the data provided in this material safety data sheet.
Storage
Temperature: < 25 C
General: Do not expose to extreme temperatures.
Provide sufficient air above product to avoid early polymerization.
Protect from frost.
Keep only in the original container in a cool, well-ventilated place.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Airborne exposure limits: (ml/m3 = ppm)
n-butyl acrylate ACGIH TLV: 2 ml/m3 ; 11 mg/m3 ; ; 8-hr TWA
The ACGIH has designated this component as having confirmed potential for worker
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Solutia Inc. Material Safety Data Sheet Date: 12/13/2006
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sensitization as a result of either dermal contact or inhalation exposure based on the
weight of scientific evidence.
OSHA PEL: 10 ml/m3 ; 55 mg/m3 ; ; 8-hr TWA
Mexican OEL: 10 ml/m3 ; 55 mg/m3 ; ; 8-hr TWA
acrylic acid ACGIH TLV: 2 ml/m3 ; 5.9 mg/m3 ; ; 8-hr TWA
* skin absorption of this material may add to the overall exposure.
OSHA PEL: 10 ml/m3 ; 30 mg/m3 ; skin * ; 8-hr TWA
* skin absorption of this material may add to the overall exposure.
methyl methacrylate ACGIH TLV: 50 ml/m3 ; 205 mg/m3 ; ; 8-hr TWA
ACGIH TLV: 100 ml/m3 ; 410 mg/m3 ; ; 15-min STEL
The ACGIH has designated this component as having confirmed potential for worker
sensitization as a result of either dermal contact or inhalation exposure based on the
weight of scientific evidence.
OSHA PEL: 100 ml/m3 ; 410 mg/m3 ; ; 8-hr TWA
Mexican OEL: 100 ml/m3 ; 410 mg/m3 ; ; 8-hr TWA
Mexican OEL: 125 ml/m3 ; 510 mg/m3 ; ; 15-min STEL
methacrylic acid ACGIH TLV: 20 ml/m3 ; ; 8-hr TWA
OSHA PEL: 20 ml/m3 ; 70 mg/m3 ; ; 8-hr TWA
Eye protection: Wear safety goggles if splash potential exists.
Hand protection: Wearing protective gloves is recommended.
Nitrile (rubber)
Care must be taken to prevent skin contact.
Body protection: Wear full protective clothing if exposed to splashes.
Consult the glove/clothing manufacturer to determine the appropriate type
glove/clothing for a given application.
Have safety shower available at locations where skin contact can occur.
Launder contaminated clothing and clean protective equipment before reuse.
Respiratory protection: Use approved respiratory protection equipment when airborne exposure is excessive.
Consult the respirator manufacturer to determine the appropriate type of equipment for
a given application.
Ventilation: Provide natural or mechanical ventilation to minimize exposure.
If practical, use local mechanical exhaust ventilation at sources of air contamination
such as processing equipment.
Components referred to herein may be regulated by specific Canadian provincial legislation. Please refer to exposure
limits legislated for the province in which the substance will be used.
9. PHYSICAL AND CHEMICAL PROPERTIES
Flash point: 33 C
Autoignition temperature: > 200 C
Density: 0.96 g/cm3 @ 20 C
Boiling point : 100 C
Water solubility: Partly miscible with water.
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Solutia Inc. Material Safety Data Sheet Date: 12/13/2006
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Viscosity : 30 mPa.s @ 20 C
NOTE: These physical data are typical values based on material tested but may vary from sample to sample.
Typical values should not be construed as a guaranteed analysis of any specific lot or as specifications for the
product.
10. STABILITY AND REACTIVITY
Conditions to avoid: Exposure to sunlight
Do not expose to extreme temperatures.
All sources of ignition.
Materials to avoid: Contact with peroxides.
Contact with reducing agents.
radical components
Hazardous reactions: Exothermic polymerization is possible.
Hazardous decomposition nitrogen oxides (NOx);
products:
11. TOXICOLOGICAL INFORMATION
Data obtained on components are summarized below:
Components
Data from Solutia studies and/or the available scientific literature on the components of this material which have
been identified as hazardous chemicals under the criteria of the OSHA Hazard Communication Standard (29 CFR
1910.1200) or the Canadian Hazardous Products Act are discussed below if present.
n-butyl acrylate Corrosive to eyes.
Irritating to respiratory system.
Can cause respiratory tract injury leading to lung edema.
Moderately irritating to skin.
May cause sensitization by skin contact.
Produced dermal sensitization (guinea pigs).
Repeated inhalation exposure produced multiple organ effects.
Effects on offspring only observed with maternal toxicity.
No birth defects were noted in rats given the active ingredient orally during pregnancy.
Chronic exposure to animals produced no increase in tumour incidence.
No genetic effects were observed in standard tests using bacterial cells and whole
animals.
Genetic effects were observed in standard tests with animal cells.
2-ethylhexyl acrylate Irritating to eyes, skin and respiratory tract.
May cause sensitization in susceptible individuals.
Toxic following oral administration.
Practically nontoxic after skin application in animal studies.
Produced tumours at the site of application.
The weight of the evidence indicates that this material is mutagenic in in vitro assays.
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Solutia Inc. Material Safety Data Sheet Date: 12/13/2006
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acrylic acid Can be irritating or corrosive to the eyes, skin, mucous membranes and respiratory tract.
May cause allergic skin reaction.
Absorption through the skin may cause nausea and vomiting.
Irritating to respiratory system.
Moderately toxic following oral administration.
Moderately toxic after skin application in animal studies.
Slightly toxic based on animal inhalation exposure studies.
Repeated oral administration produced multiple organ effects.
Caused increased leukemia in laboratory animals.
Produced birth defects in animals.
The weight of the evidence indicates that this material is mutagenic.
methyl methacrylate Practically nontoxic following oral administration.
Practically nontoxic based on animal inhalation exposure studies.
Practically nontoxic after skin application in animal studies.
Moderately irritating to eyes (rabbit).
Moderately irritating to skin (rabbit).
May cause sensitization by skin contact.
Repeated exposure produced respiratory tract irritation in animal models.
12. ECOLOGICAL INFORMATION
Solutia has not conducted environmental toxicity or biodegradation studies with this material.
13. DISPOSAL CONSIDERATIONS
US EPA RCRA Status: This material when discarded is not a hazardous waste as that term is defined by the
Resource, Conservation and Recovery Act (RCRA), 40 CFR 261.
Disposal considerations: Incineration
Incineration
Miscellaneous advice: Local, state, provincial, and national disposal regulations may be more or less stringent.
Consult your attorney or appropriate regulatory officials for information on such
disposal.
This product should not be dumped, spilled, rinsed or washed into sewers or public
waterways.
14. TRANSPORT INFORMATION
The data provided in this section is for information only. Please apply the appropriate regulations to properly
classify your shipment for transportation.
US DOT
Proper shipping name: CORROSIVE LIQUID, FLAMMABLE N.O.S.
n-butyl acrylate , acrylic acid
Hazard Class: 8, 3
Hazard Identification number: UN2920
Packing Group: Packing Group II
Transport label: Corrosive, Flammable
Canadian TDG
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Solutia Inc. Material Safety Data Sheet Date: 12/13/2006
Reference Number: 000000009557 Version 5./E
Proper shipping name: CORROSIVE LIQUID, FLAMMABLE N.O.S.
n-butyl acrylate , acrylic acid
Hazard Class: 8, 3
Hazard Identification number: UN2920
Packing Group: Packing Group II
Transport label: Corrosive, Flammable
Reportable Quantity/Limit
US DOT RQ 1,000 lb methyl methacrylate
Package size containing reportable amount: 8,000 lb
US DOT RQ 5,000 lb acrylic acid
Package size containing reportable amount: 40,000 lb
ICAO/IATA Class
Other: See DOT Information
15. REGULATORY INFORMATION
All components are in compliance with U.S. TSCA, EU EINECS, Canadian DSL, Australian AICS, Japanese
the following inventories: ENCS, Korean, Phillipine PICCS, Chinese
Canadian WHMIS classification: B2 - Flammable Liquids
D2(B) - Materials Causing Other Toxic Effects
E - Corrosive Material
SARA Hazard Notification:
Hazard Categories Under Title III Immediate
Rules (40 CFR 370): Delayed
Section 302 Extremely Hazardous Not applicable
Substances:
Section 313 Toxic Chemical(s): n-butyl acrylate acrylic acid methyl methacrylate
CERCLA Reportable Quantity:
1000 lbs methyl methacrylate
5000 lbs acrylic acid
For this/these chemicals, release of more than the Reportable Quantity to the environment in a 24 hour period
requires notification to the National Response Center (800-424-8802 or 202-426-2675).
This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products
Regulation and the MSDS contains all the information required by the Canadian Controlled Products Regulation.
Refer to Section 11 for OSHA/HPA Hazardous Chemical(s) and Section 13 for RCRA classification.
Safety data sheet also created in accordance with Brazilian law NBR 14725
16. OTHER INFORMATION
Product name: Naftolan UV 33 Page 8 / 8
Solutia Inc. Material Safety Data Sheet Date: 12/13/2006
Reference Number: 000000009557 Version 5./E
Product use: Plastic resins
Reason for revision: New Product
Health Fire Reactivity Additional Information
Suggested NFPA Rating 3 2 2
Suggested HMIS Rating: 3 2 2 C
Prepared by the Solutia Hazard Communication Group. Please consult Solutia @ 314-674-6661 if further
information is needed.
TM, ?is a registered trademark of Solutia Inc.
SOLUTIA is a trademark of Solutia Inc.
Responsible Care?is a registered trademark of the American Chemistry Council.
Although the information and recommendations set forth herein (hereinafter "Information") are presented
in good faith and believed to be correct as of the date hereof, Solutia Inc. makes no representations as to
the completeness or accuracy thereof. Information is supplied upon the condition that the persons
receiving same will make their own determination as to its suitability for their purposes prior to use. In no
event will Solutia Inc. be responsible for damages of any nature whatsoever resulting from the use of or
reliance upon Information. NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESS OR
IMPLIED, OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE OR OF ANY
OTHER NATURE ARE MADE HEREUNDER WITH RESPECT TO INFORMATION OR THE
PRODUCT TO WHICH INFORMATION REFERS.
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