MATERIAL SAFETY DATA SHEET
ALSAN RS 287 BASE
HMIS PROTECTIVE CLOTHING TRANSPORT OF DANGEROUS GOODS
1
PAINT
3 CLASS 3
UN 1263
0
P.G.: II
G
SECTION II. CHEMICAL PRODUCT AND COMPANY INFORMATION
Product name: Alsan RS 287 Base
Use: Base liquid for mixing colors onsite
Manufacturer: Soprema, Inc.
310 Quadral Drive
Wadsworth, Ohio 44281
UNITED STATES
Distributor: Soprema, Inc.
310 Quadral Drive
Wadsworth, Ohio 44281
UNITED STATES
In case of emergency: SOPREMA (8:00am to 5:00pm - Eastern time): (800) 356-3521
CHEMTREC (USA) (24h.): (800) 424-9300
CANUTEC (Canada): (613) 996-6666
International: (703) 527-3887
EMERGENCY OVERVIEW!!!
Highly flammable. Irritating to respiratory system and skin. May cause sensitisation by skin contact.
SECTION II. COMPOSITION AND INFORMATION ON INGREDIENTS
Component CAS# % by weight
Methyl methacrylate 80-62-6 25-50%
2-ethylhexyl acrylate 103-11-7 10-25%
1,1'-(p-tolylimino)dipropan-2-ol 38668-48-3 < 1%
TSCA: all ingredients are listed
Alsan RS 287 Base Revised: July 13, 2009 Page 1 of 6
SECTION III. POTENTIAL HEALTH EFFECTS
Information concerning particular hazards for human and environment:
The product has to be labelled due to the calculation procedure of international guidelines.
Highly flammable.
Irritating to respiratory system and skin.
May cause sensitisation by skin contact.
SECTION IV. FIRST AID MEASURES
GENERAL Immediately remove any clothing soiled by the product.
SKIN Immediately wash with water and soap and rinse thoroughly. If skin irritation continues, consult a doctor.
EYES Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
INHALATION Take affected persons into fresh air and keep quiet. Seek medical treatment in case of complaints.
INGESTION Do not induce vomiting; immediately call for medical help.
SECTION V. FIRE-FIGHTING MEASURES
Extinguishing media CO2, powder or water spray. Fight larger fire with alcohol resistant foam.
For safety reasons unsuitable extinguishing agents Water with full jet
Special hazards caused by the substance, its prod-
Can form explosive gas-air mixtures.
ucts of combustion or resulting gases
Protective equipment Wear self-contained respiratory protective device.
Additional information Cool endangered receptacles with water spray.
SECTION VI. ACCIDENTAL RELEASE MEASURES
?Person-related safety precautions:
Wear protective equipment. Keep unprotected persons away.
Ensure adequate ventilation
Use respiratory protective device against the effects of fumes/dust/aerosol.
?Measures for environmental protection:
Do not allow to enter sewers/ surface or ground water.
?Measures for cleaning/collecting:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Ensure adequate ventilation.
Do not flush with water or aqueous cleansing agents
Dispose contaminated material as waste according to SECTION XIII.
SECTION VII. HANDLING AND STORAGE
HANDLING:
?Information for safe handling:
Open and handle receptacle with care.
Ensure good interior ventilation, especially at floor level. (Fumes are heavier than air).
?Information about fire - and explosion protection:
Fumes can combine with air to form an explosive mixture.
Highly volatile, flammable constituents are released during processing.
Keep ignition sources away - Do not smoke.
Protect against electrostatic charges.
STORAGE:
?Requirements to be met by storerooms and receptacles:
Store in a cool location.
Store only in the original receptacle.
?Information about storage in one common storage facility:
Store away from oxidizing agents.
?Further information about storage conditions:
Keep receptacle tightly sealed.
Store in cool, dry conditions in well sealed receptacles.
Alsan RS 287 Base Revised: July 13, 2009 Page 2 of 6
SECTION VIII. EXPOSURE CONTROLS / PERSONAL PROTECTION
Components with limit values that required monitoring at the workplace:
410 mg/m3, 100 ppm
PEL
410 mg/m3, 50 ppm
REL
80-62-6 methyl methacrylate
Short-term value: 410 mg/m3, 100 ppm
TLV
Long-term value: 205 mg/m3, 50 ppm
2 mg/m3
REL
8002-74-2 Paraffin waxes and
Hydrocarbon waxes 2 mg/m3
TLV
Additional information: The lists that were valid during the creation were used as basis
PERSONAL PROTECTIVE EQUIPMENT
The usual precautionary measures are to be adhered to when handling chemicals.
Keep away from foodstuffs, beverages and feed.
General protective and hygenic mea-
Do not eat or drink while working.
sures:
Wash hands before breaks and at the end of work.
Avoid contact with the eyes and skin.
In case of brief exposure or low pollution use respiratory filter device. In case of intensive
Respiratory protection:
or longer exposure use self-contained respiratory protective device.
Hand protection: Butyl rubber gloves
Eye protection: Tightly sealed goggles
Body Protection: Protective work clothing
SECTION IX. PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL FORM Liquid
COLOR Colorless
ODOR Ester-like
FLASH POINT 50 癋 (10 癈)
MELTING POINT Undetermined
BOILING POINT 101 癋 (214 癈)
SELF-IGNITING Product is not self-igniting
Product is not explosive. However, formation of explosive air/vapor mixtures are
DANGER OF EXPLOSION
possible
Lower: 0.8 Vol%
EXPLOSIVE LIMITS
Upper: 12.5 Vol%
VAPOR PRESSURE at 68癋 (20 癈) 47 hPa (35mm Hg)
VISCOSITY
70 s (ISO 6mm)
Kinematic @ 68癋 (20 癈)
SOLUBILITY IN / MISCIBILITY WITH
Not miscuble or difficult to mix
WATER
SOLVENT CONTENT VOC: 0.1%
SOLIDS CONTENT 65.5%
0.97 g/cm3
DENSITY @ 68癋 (20 癈)
SECTION X. STABILITY AND REACTIVITY
THERMAL DECOMPOSITION / CONDITIONS TO BE AVOIDED:
No decomposition if used according to specifications.
DANGEROUS REACTIONS:
Exothermic reaction. Reacts with peroxides and other radical forming substances.
DANGEROUS DECOMPOSITION PRODUCTS:
Carbon monoxide
Alsan RS 287 Base Revised: July 13, 2009 Page 3 of 6
SECTION XI. TOXICOLOGICAL INFORMATION
ACUTE TOXICITY
Primary irritant effect:
- on the skin: Irritant to skin and mucous membranes.
- on the eye: No irritating effect.
Sensitization:
Sensitization prossible through skin contact.
Additional toxicological information:
The product shows the following dangers according to the calculation method of the General EU
Classification Guidelines for Preparations as issued in the latest version:
Irritant
SECTION XII. ECOLOGICAL INFORMATION
?General notes:
Water hazard class 2 (Self-assessment): hazardous for water
Do not allow product to reach ground water, water course or sewage system.
Danger to drinking water if even small quantities leak into the ground.
SECTION XIII. DISPOSAL CONSIDERATIONS
?Product:
?Recommendation
Must not be disposed together with household garbage. Do not allow product to reach sewage system.
?Uncleaned packaging:
?Recommendation: Disposal must be made according to official regulations.
SECTION XIV. TRANSPORTATION INFORMATION
DOT regulations:
Hazard class: 3
Identification number: UN1263
Packaging group: III
Proper shipping name (technical name): PAINT
Label: 3
LAND TRANSPORT ADR/RID (cross border):
ADR/RID class: 3 Flammable liquids
Danger code (Kemler): 33
UN Number: 1263
Packaging group: III
Hazard label: 3
Description of goods: 1263 PAINT
MARITIME TRANSPORT IMDG:
IMDG Class: 3
UN Number: 1263
Label: 3
Packaging group: III
EMS Number: F-E, S-E
Marine pollutant: No
Proper shipping name: PAINT
AIR TRANSPORT ICAO-TI and IATA-DGR:
ICAO/IATA Class: 3
UN/ID Number: 1263
Label: 3
Packaging group: III
Proper shipping name: PAINT
Alsan RS 287 Base Revised: July 13, 2009 Page 4 of 6
SECTION XV. REGULATORY INFORMATION
SARA
Section 355 (extremely hazardous substances):
None of the ingredient is listed
Section 313 (Specific toxic chemical listings):
80-62-6 methyl methacrylate
TSCA (Toxic Substances Control Act):
80-62-6 methyl methacrylate
103-11-7 2-ethylhexyl acrylate
8002-74-2 Paraffin waxes and Hydrocarbon waxes
38668-48-3 1,1'-(p-tolylimino)dipropan-2-ol
108-65-6 2-methoxy-1-methylethyl acetate
123-86-4 n-butyl acetate
PROPOSITION 65
Chemicals known to cause cancer:
None of the ingredients listed.
Chemicals known to cause reproductive toxicity for females:
None of the ingredients listed.
Chemicals known to cause reproductive toxicity for males:
None of the ingredients listed.
Chemicals known to cause developmental toxicity:
None of the ingredients listed.
CANCEROGENITY CATEGORIES
EPA (Environmental Protection Agency)
80-62-6 methyl methacrylate
IARC (International Agency for Research on Cancer)
80-62-6 methyl methacrylate
103-11-7 2-ethylhexyl acrylate
NTP (National Toxicology Program)
None of the ingredients is listed.
TLV (Threshold Limit Value estabilshed by ACGIH)
80-62-6 methyl methacrylate
NIOSH-Ca (National Institute for Occupational Safety and Heath)
None of the ingredients is listed.
OSHa-Ca (Occupational Safety and Heath Administration)
None of the ingredients is listed.
?Product related hazard informations:
The product has been classified and marked in accordance with directives on hazardous materials.
?Hazard symbols:
Irritant
Highly flammable
?Hazard-determining components of labelling:
methyl methacrylate
2-ethylhexyl acrylate
Alsan RS 287 Base Revised: July 13, 2009 Page 5 of 6
SECTION XV. REGULATORY INFORMATION
?Risk phrases:
Highly flammable.
Irritating to eyes, respiratory system and skin.
May cause sensitisation by skin contact.
?Safety phrases:
Keep away from sources of ignition - No smoking.
Avoid contact with skin.
Wear suitable gloves.
Use only in well-ventilated areas.
This material and its container must be disposed of as hazardous waste.
SECTION XVI. OTHER INFORMATION
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
Glossary:
ACGIH: American Conference of Governmental Industrial Hygienists
ANSI: American National Standards Institute
ASTM: American Society for Testing and Materials
CAS: Chemical Abstract Services
CFR: Code of Federal Regulations (United States)
CSA: Canadian Standardisation Association
DOT: Department of Transportation (United States)
DSL: Domestic Substances List (Canada)
EPA: Environmental Protection Agency (United States)
HMIS: Hazardous Material Information System
IARC: International Agency for Research on Cancer
LC50: (Lethal concentration50) Concentration of a substance in air that causes dead of 50% mortality of a defined animal popula-
tion
LD50: (Lethal dose50) Single dose of a substance that, when administrated by a define route in an animal assay, is expected to
cause the death of 50% of a defined animal population.
NFPA: National Fire Protection Association (United States)
NIOSH: National Institute for Occupational Safety and Health
NTP: National Toxicology Program
OSHA: Occupational Safety & Health Administration (United States)
PEL: Permissible Exposure Limit
RCRA: Resource Conservation and Recovery Act (United States)
RTECS: Registry of Toxic Effects of Chemical Substances
TDG: Transportation of Dangerous Goods
TLV: Threshold Limit Value
TWA: Time-weighted average
TSCA: Toxic Substances Control Act (United States)
WHMIS: Workplace Hazardous Materials Information System (Canada)
Reference:
Supplier MSDS
This MSDS has been prepared by: SOPREMA, INC.
For information: 800-543-3085
The Material Safety Data Sheets of SOPREMA are available on Internet at the following site: HTTP://WWW.SOPREMA.US
Justification of the update:
New MSDS.
This MSDS contains all the information required by ANSI Z-400.1-1998 standard (United States), by regulation 29 CFR Part
1910.1200 of the Hazard Communication Standard of OSHA, and is in accordance with standard DORS/88-66 OF WHMIS Canada.
To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier or
any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained here-
in. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown
hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are
the only hazards that exist.
Alsan RS 287 Base Revised: July 13, 2009 Page 6 of 6
|