HMIS
H =2
MATERIAL SAFETY DATA SHEET F =3
R =1
PPE = See Section 8
VOC: Max. content less than 50 g/L
(catalyzed)
Section I
Manufacturer: Siplast, an Icopal Group Company
(800) 643-1591 or (800) 922-8800
Address: 1000 E. Rochelle Blvd., Irving, TX 75062-3940
Emergency Phone No.: CHEMTREC, (800) 424-9300 (U.S.), (703) 527-3887 (outside of U.S.)
Product Class: Liquid-applied Waterproofing System - Component
Trade Name: Parapro Flashing Resin (White)
Section II - Ingredients
ACGIH OSHA
Ingredient Percent TLV PEL
205 mg/m3
Methyl methacrylate 15 - 25 50 ppm 100 ppm
CAS #80-62-6
82 mg/m3
2-ethylhexyl acrylate 5 - 12 10 ppm Not Available
CAS #103-11-7 German MAK
Various acrylates 8 -20 Not Established 100 ppm
CAS #Confidential
1,1'-(p-Tolylimino)- <2 Not Available Not Available
dipropan-2-ol
CAS #38668-48-3
1-Isopropyl-2,2diethyl- <2 Not Available Not Available
trimethylenediisobutyrate
CAS #6845-50-0
10 mg/m3 3
Titanium dioxide 8 - 12 5 mg/m
(total dust)
CAS #13463-67-7 (total dust)
Crystalline Silica as Quartz has been found to be carcinogenic according to NTP and IARC. This same
component is not classified as carcinogenic by OSHA. See Section V.
Section III - Physical Data Section IV - Fire and Explosion Data
Appearance: White DOT Category: UN1263 Paint
Odor: Typical acrylate odor Hazard Class: 3
Physical state: Liquid Label: Flammable
Ignition Point: 536癋 (280癈) Packaging Group: II
Evaporation Rate (Butyl Acetate = 1): Not Flash Point: >50癋 (10癈)
Established LEL %: 1.7 UEL %: 8.2 (for methylmethacrylate)
Vapor Density (Air = 1): Not Established Extinguishing Media: Use foam, carbon dioxide, dry
% Volatile by Volume: Not Established powder, or water spray. Do not use high pressure
Solubility in H2O: Insoluble water. Fight fire from a safe distance due to
Vapor Pressure: Not determined explosion hazard. Use water spray only to cool
Viscosity: 38 - 42 dPa*s @20癈 containers in fire area.
Density: ~ 1.34 g/cm3 Special Procedures: Use self-contained breathing
apparatus and full protective clothing.
Trade Name: Parapro Flashing Resin (White)
Page Two
Section V - Health Hazard Data Carcinogenicity:
NTP: No
EMERGENCY AND HAZARDS OVERVIEW: IARC: No
ROUTES OF ENTRY: Inhalation, skin, and eye contact. OSHA: No
Human Effects and Symptoms of Overexposure:
WARNING! FLAMMABLE. Emergency and First Aid Procedures:
Harmful if inhaled, swallowed, or absorbed through SKIN: Remove contaminated clothing and shoes.
the skin. Causes skin, eye, and respiratory irritation. Wash with soap or mild detergent and large amounts
May cause skin and respiratory sensitization. of water. Do not use solvents or thinners. Get
This product contains: medical attention if irritation occurs. Wash clothing
Methyl methacrylate and 2-ethylhexyl acrylate cause before reuse.
skin, eye, and respiratory irritation. High EYES: Hold eyes open and flush for at least 15
concentrations can cause symptoms of central minutes with large amounts of water. Seek medical
nervous system depression, such as headache, attention.
INHALATION: Remove to fresh air immediately. If
nausea, dizziness, drowsiness, and confusion.
Both acrylates can cause dermal and respiratory breathing has stopped, give artificial respiration. If
sensitization. Once a person is sensitized, contact breathing is difficult, administer oxygen. Consult
with even a small amount may cause outbreaks of physician if irritation of respiratory passage occurs.
INGESTION: Do not induce vomiting. Give two glasses
dermatitis with symptoms such as skin redness,
of water to dilute stomach contents. Never give
itching, rash, and swelling. This can spread from the
anything by mouth to an unconscious person.
hands or arms to other parts of the body. Persons
Consult a physician immediately.
with respiratory sensitization can experience
symptoms of bronchial asthma such as wheezing,
Section VI - Reactivity Data
difficult breathing, sneezing and runny or blocked
nose at low airborne concentrations that have no
Stability: Stable
effect on unsensitized people. IARC has classified 2-
Hazardous Decomposition Products: Carbon
ethylhexyl acrylate as class 3, not classifiable as to
monoxide, carbon dioxide, oxides of nitrogen,
its carcinogenicity to humans.
hydrocarbon by-products, and black smoke.
Various acrylates, which may cause skin, eye, and Polymerization: Avoid high temperatures. Product
respiratory irritation and sensitization. may polymerize at > 140癋 (60癈). Polymerization is
exothermic and may cause container damage and/or
1,1'-(p-Tolylimino)-dipropan-2-ol which is toxic when fire.
ingested or inhaled.
Materials to Avoid: Avoid strong acids, bases, and
1-Isopropyl-2,2dimethyltrimethylenediisobutyrate, oxidizing agents to avoid exothermic reactions.
which according to the manufacturer, may cause skin Avoid initiators that produce free radicals, and avoid
irritation. peroxides and metal-ions.
Section VII - Spill or Leak Procedures
Titanium dioxide, may cause mechanical irritation to
the eye and respiratory passages and has ACGIH
and OSHA exposure limits. However, this product is Steps to be Taken
Wearing appropriate personal protective equipment,
sold as a liquid preparation and, when used as
contain spills onto inert absorbent and place in
intended, does not generate dust. Thus the product
suitable containers.
as such does not pose a respiration hazard
Disposal Information: Incinerate or dispose of in
attributable to these components. IARC has
accordance with Federal, State, or Local regulations.
classified titanium dioxide as class 3, not classifiable
Waste Disposal Methods: Avoid contamination of
as to its carcinogenicity to humans.
ground water or waterways. Do not discharge into
sewer system.
Trade Name: Parapro Flashing Resin (White)
Page Three
Section VIII - Special Protection Information Section IX - Special Precautions
Respirator: If airborne concentration poses a health Handling: Do not smoke. Keep away from open fire,
hazard, becomes irritating or exceeds recommended flame, or any ignition source. Vapors may form
limits, use a NIOSH approved respirator in explosive mixtures with air. Avoid skin and eye
accordance with OSHA Respirator Protection contact. Avoid breathing fumes. Do not eat, drink, or
requirements under 29 CFR 1910.134. smoke in application area.
Engineering Controls: Use local exhaust ventilation Storage: Store closed containers in cool, dry area
or respiratory protection to maintain employee away from heat, direct sunlight, oxidizing agents, and
exposure below TLV. strong acids and alkalis. Keep away from open fire,
Skin Protection: Clothing suitable to prevent skin flame, or any ignition source. Keep in well-ventilated
contact. Use butyl rubber gloves and apply barrier areas.
creams. Do not use PE or PVC gloves as these Regulatory Information (Not meant to be all
materials absorb acrylates. Check suitability inclusive): All components of this product are on the
recommendations by protective equipment TSCA Inventory.
manufacturers, especially toward chemical
This product contains the toxic chemical listed below,
breakthrough resistance.
Eye: Safety goggles with side shields. which is subject to the supplier notification
requirements of Section 313 of the Superfund
Amendments and Reauthorization Act
(EPCRA/"SARA") and the requirements of 40 CFR
Part 372.
PRODUCT CAS # MAX %
Methyl methacrylate 80-62-6 25
The information and recommendations contained herein are, to the best of Siplast's knowledge and belief, accurate and reliable as of the date
issued. Siplast does not warrant or guarantee their accuracy or reliability, and should not be liable for any loss or damage arising out of the use
thereof. User should satisfy himself that he has all current data relevant to his particular use.
Rev 10/07
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