February 9, 1998 Foam MSDS 816b
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VF3AFFF-MS
TECHNICAL DATA MATERIAL SAFETY
DATA SHEET
THE VIKING CORPORATION
210 N. Industrial Park Road
Hastings, MI 49058 U.S.A.
Telephone: (616) 945-9501
Fax: (616) 945-9599
DIVISION: VIKING FOAM
TRADE NAME: VIKING 3% AQUEOUS FILM FORMING FOAM
VIKING ID NUMBER: V3AFFF-MS
ISSUED: JANUARY 1, 1998
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DOCUMENT: F012998
1. INGREDIENT C.A.S. NO. PERCENT
WATER .................................................................................... 7732-18-5 69.0 - 71.0
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ETHANOL, 2-(2-BUTOXYETHOXY) -..................................... 112-34-5 19 - 21
ALKYL SULFATE SALTS(2) +(5808P,
5806P) .............................................................................. TradeSecret 4.0 - 6.0
AMPHOTERIC FLUOROALKYLAMIDE
DERIVATIVE +(5803P) .................................................... TradeSecret 1 - 5
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TRIETHANOLAMINE .............................................................. 102-71-6 0.5 - 1.5
PERFLUOROALKYL SULFONATE SALTS(5)
+(5804P) ........................................................................... TradeSecret 0.5 - 1.5
1H-BENZOTRIAZOLE, METHYL-........................................... 29385-43-1 0 - 0.1
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New Jersey Trade Secret Registry Number (EIN) 04499600-+
NOTE:
The ingredients of this product are included on TSCA.
THIS PRODUCT CONTAINS THE FOLLOWING TOXIC CHEMICAL OR CHEMICALS SUBJECT TO THE REPORTING RE-
QUIREMENTS OF SECTION 313 OF TITLE III OF THE EMERGENCY PLANNING AND COMMUNITY RIGHT-TO-KNOW
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ACT OF 1986 AND 40 CFR PART 372:
ETHANOL, 2-(2-BUTOXYETHOXY)-
2. PHYSICAL DATA
BOILING POINT: ...................................................ca. 100 C
VAPOR PRESSURE..............................................ca 29.3 mmHg
Calc. @ R.T.
VAPOR DENSITY: .................................................ca. 0.62 Air = 1
Calc. @ R.T.
EVAPORATION RATE: .........................................< 1.0 Butyl Acetate = 1
SOLUBILITY IN WATER: ......................................Miscible
SP. GRAVITY:........................................................ca. 1.0 Water = 1
PERCENT VOLATILE: ..........................................ca. 90 %
VOLATILE ORGANICS: ........................................206 gms/liter
VOC LESS H20 & EXEMPT SOLVENT pH:.........747 gms/liter
pH:..........................................................................ca. 8.5
VISCOSITY: ...........................................................N/D
MELTING POINT: ..................................................N/A
APPEARANCE AND ODOR: ................................Clear, amber colored liquid
Abbreviations: N/D - Not Determined N/A ?Not Applicable
Form No. 012998 New page issued February 9, 1998
February 9, 1998
Foam MSDS 816c
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VF3AFFF-MS
TECHNICAL DATA MATERIAL SAFETY
DATA SHEET
MSDS: VIKING VF3AFFF-MS AQUEOUS FILM FORMING FOAM
JANUARY 1, 1998 PAGE: 2 of 5
3. FIRE AND EXPLOSION HAZARD DATA
FLASH POINT: ...............................................Setaflash
None (Setaflash CC)
FLAMMABLE LIMITS ?LEL: ........................N/A
FLAMMABLE LIMITS ?UEL: ........................N/A
AUTOIGNITION TEMPERATURE: ................N/A
EXTINGUISHING MEDIA:
Product is a fire-extinguishing agent.
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SPECIAL FIRE FIGHTING PROCEDURES:
Not applicable
UNUSUAL FIRE AND EXPLOSION HAZARDS:
See Hazardous Decomposition section for products of combustion.
4. REACTIVITY DATA
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STABILITY: Stable
INCOMPATIBILITY ?MATERIALS TO AVOID:
Not applicable
HAZARDOUS POLYMERIZATION: Will Not Occur
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HAZARDOUS DECOMPOSITION PRODUCTS:
Carbon Monoxide and Carbon dioxide, Oxides of Nitrogen, Oxides of Sulfur, Hydrogen Fluoride
Thermal decomposition of usage concentrations does not present a hazard.
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5. ENVIRONMENTAL INFORMATION
SPILL RESPONSE:
Observe precautions from other sections. Contain spill. Cover with absorbent material. Collect
spilled material. Clean up residue with water. Place in a U.S. DOT approved container and seal.
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RECOMMENDED DISPOSAL:
Bleed spent solutions and small product quantities, generally <5 gal., to a wastewater treatment system
Reduce discharge rate if foaming occurs. Incinerate bulk product in an industrial or commercial incinerator.
Combustion products will include HF. Disposal alternative: Dispose of completely absorbed waste product
in a facility permitted to accept chemical wastes. Since regulations vary, consult applicable regulations or
authorities before disposal. U.S. EPA Hazardous Waste No.: None
ENVIRONMENTAL DATA:
A 3M Product Environmental Data Sheet (PED) is available.
EPCRA HAZARD CLASS:
FIRE HAZARD: No PRESSURE: No REACTIVITY: No ACUTE: Yes CHRONIC: Yes
6. SUGGESTED FIRST AID
EYE CONTACT:
Immediately flush eyes with large amounts of water for at least 15 minutes. Get immediate medical
attention.
Abbreviations: N/D - Not Determined N/A ?Not Applicable
February 9, 1998 Foam MSDS 816d
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VF3AFFF-MS
TECHNICAL DATA MATERIAL SAFETY
DATA SHEET
MSDS: VIKING VF3AFFF-MS AQUEOUS FILM FORMING FOAM
JANUARY 1, 1998 PAGE: 3 of 5
6. SUGGESTED FIRST AID (continued)
SKIN CONTACT:
Flush skin with large amounts of water. If irritation persists, get medical attention.
INHALATION:
If signs/symptoms occur, remove person to fresh air. If signs/symptoms continue, call a physician.
IF SWALLOWED:
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Drink two glasses of water. Call a physician.
7. PRECAUTIONARY INFORMATION
EYE PROTECTION:
Avoid eye contact with vapor, spray, or mist. Wear vented goggles.
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SKIN PROTECTION:
Avoid skin contact. Wear appropriate gloves when handling this material. A pair of gloves made from
the following materials(s) are recommended: butyl rubber.
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VENTILATION PROTECTION:
Use with adequate dilution ventilation.
RESPIRATORY PROTECTION:
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Avoid breathing of vapors, mists or spray. Select one of the following NIOSH approved respirators
based on airborne concentration of contaminants and in accordance with OSHA regulations: Half-
mask organic vapor respirator with dust/mist prefilter.
PREVENTION OF ACCIDENTAL INGESTION:
Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and
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water. Wash hands after handling and before eating.
RECOMMENDED STORAGE:
Store in a cool place. Store away from heat. Store out of direct sunlight. Keep container dry. Keep
container in well-ventilated area.
FIRE AND EXPLOSION AVOIDANCE:
Keep container tightly closed.
EXPOSURE LIMITS
INGREDIENTS VALUE UNIT TYPE AUTH SKIN*
WATER...................................................................... NONE NONE NONE NONE
ETHANOL, 2-(2-BUTOXYETHOXY) -....................... 35 ppm TWA CMRG
ALKYL SULFATE SALTS(2) +(5805P, 5806P)......... NONE NONE NONE NONE
AMPHOTERIC FLUOROALKYLAMIDE
DERIVATIVE +(5803P) ........................................ NONE NONE NONE NONE
TRIETHANOLAMINE ................................................ 5 mg/m3 TWA ACGIH
PERFLUOROALKYL SULFONATE SALTS (5)
+(5804P)............................................................... 0.1 mg/m3 TWA 3M Y
Abbreviations: N/D - Not Determined N/A ?Not Applicable
February 9, 1998
Foam MSDS 816e
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VF3AFFF-MS
TECHNICAL DATA MATERIAL SAFETY
DATA SHEET
MSDS: VIKING VF3AFFF-MS AQUEOUS FILM FORMING FOAM
JANUARY 1, 1998 PAGE: 4 of 5
7. PRECAUTIONARY INFORMATION (continued)
EXPOSURE LIMITS
INGREDIENTS VALUE UNIT TYPE AUTH SKIN*
1H-BENZOTRIAZOLE, METHYL- ............................. NONE NONE NONE NONE
* SKIN NOTATION: Listed substances indicated with "Y" under SKIN refer to the potential contribution to the
overall exposure by the cutaneous route including mucous membrane and eye, either by airborne or, more
particularly, by direct contact with the substance. Vehicles can alter skin absorption.
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SOURCE OF EXPOSURE LIMITED DATA:
- ACGIH: American Conference of Governmental Industrial Hygienists
- AIHA: American Industrial Hygiene Assoc. Workplace Environmental Exposure Level
- 3M: 3M Medical Department Guideline LE
- CMRG: Chemical Manufacture Recommended Guidelines
- NONE: None Established
8. HEALTH HAZARD DATA
EYE CONTACT:
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Moderate Eye Irritation: signs/symptoms can include redness, swelling, pain, tearing, and hazy vision
SKIN CONTACT:
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Moderate Skin Irritation (after prolonged or repeated contact): signs/symptoms can include redness, swelling,
itching, and dryness.
Prolonged or repeated exposure may cause:
May be absorbed through the skin in harmful amounts.
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INHALATION:
Single overexposure, above recommended guidelines, may cause:
Central Nervous System Depression: signs/symptoms can include headache, dizziness, drowsiness,
incoordination, slowed reaction time, slurred speech, giddiness and unconsciousness.
Irritation (upper respiratory): signs/symptoms can include soreness of the nose and throat, coughing
and sneezing.
Prolonged or repeated overexposure, above recommended guidelines, may cause:
Blood disorders: signs/symptoms can include prolonged weakness and fatigue.
Bone Marrow Depression: signs/symptoms can include prolonged weakness and fatigue.
Kidney Effects: signs/symptoms can include reduced urine volume, blood in urine and back pain.
Liver Effects: signs/symptoms can include yellow skin (jaundice) and tenderness of upper abdomen.
Abbreviations: N/D - Not Determined N/A ?Not Applicable
February 9, 1998 Foam MSDS 816f
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VF3AFFF-MS
TECHNICAL DATA MATERIAL SAFETY
DATA SHEET
MSDS: VIKING VF3AFFF-MS AQUEOUS FILM FORMING FOAM
JANUARY 1, 1998 PAGE: 5 of 5
8. HEALTH HAZARD DATA (continued)
Pulmonary Edema: signs/symptoms can include coughing, congestion, difficulty breathing, which can
result in respiratory failure and death.
IF SWALLOWED:
Ingestion is not a likely route of exposure to this product.
OTHER HEALTH HAZARD INFORMATION:
A 3M Product Toxicity Summary Sheet is available.
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9. EMERGENCY INFORMATION
For Chemical Emergency Spill, Leak, Fire or Exposure:
LECALL CHEMTREC?br>
(Day or night)
800-424-9300
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703-527-3887 (Outside the US)
(Collect calls accepted)
800-262-8200
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(Health and safety information)
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Abbreviations: N/D - Not Determined N/A ?Not Applicable
The information on this Data Sheet represents our current data and best opinion as to the proper use in handling
of this material under normal conditions. Any use of the material which is not in conformance with this Data
Sheet or which involves using the material in combination with any other material or any other process is the
responsibility of the user.
Form No. 012998 New page issued February 9, 1998
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