MATERIAL SAFETY DATA SHEET
PART I What is the material and what do I need to know in an emergency?
1. PRODUCT IDENTIFICATION
Jasco Painters Wipes
TRADE NAME (AS LABELED):
PRODUCT CODES: 0305
PRODUCT USE: Cleaner & Remover
SUPPLIER/MANUFACTURER'S NAME: Jasco Chemical
ADDRESS: 200 Westerly Road
Bellingham, WA 98226
CHEMTREC EMERGENCY NO.: 1-800-424-9300 (United States)
1-703-527-3887 (International Collect)
BUSINESS PHONE: 1-800-729-9029
DATE OF PREPARATION: August, 2007
This product is sold to consumers for household use in containers of relatively small volume (i.e. 5 gallon or less in size). This
MSDS has been developed to address safety concerns affecting those individuals working in warehouses and other places where
large numbers of these containers are stored, as well as those affecting potential users of this product in industrial /occupational
settings. All pertinent health, safety and environmental information have been presented in this document, per the requirements of the
US Federal OSHA Hazard Communication Standard (29 CFR 1910.1200) and Canadian WHMIS.
2. COMPOSITION and INFORMATION ON INGREDIENTS
CHEMICAL NAME CAS # % w/w EXPOSURE LIMITS IN AIR
ACGIH-TLV OSHA-PEL NIOSH-REL
TWA STEL TWA STEL TWA STEL IDLH
mg/m3 mg/m3 mg/m3 mg/m3 mg/m3 mg/m ppm
3
Propylene glycol 107-98-2 7 - 13 369 553 NE NE 360 540 NE
monomethyl ether
Dipropylene glycol 34590-94-8 7 - 13 606 909 600 NE 600 900 600
monomethyl ether
d-Limonene 5989-27-5 3-7 NE NE NE NE NE NE NE
Triethanolamine 102-71-6 1-5 5 NE NE NE NE NE NE
Sorbitan monolaurate 9005-64-5 1-5 NE NE NE NE NE NE NE
Water and ingredients present in Balance The ingredients in the balance of this product do not contribute significant
concentrations of less than 1% (or less hazards beyond those described in this document. All pertinent health, safety
than 0.1% if carcinogens) and environmental information have been presented, per the requirements of
the US Federal OSHA Hazard Communication Standard (29 CFR 1910.1200)
and Canadian WHMIS.
NE = Not Established. See Section 16 for Definitions of Terms Used.
NOTE (1): ALL WHMIS required information is included in appropriate sections based on the ANSI Z400.1-1998 format. This product has been classified in
accordance with the hazard criteria of the CPR and the MSDS contains all the information required by the CPR.
3. HAZARD IDENTIFICATION
EMERGENCY OVERVIEW:
PHYISCAL DESCRIPTION: This product is a colorless to light yellow liquid with a sweet lemon-like odor, saturated on disposable
towels.
HEALTH HAZARD: This product can cause irritation to the eyes or skin. If vapors or mists of this product are inhaled, irritation
of the nose or throat could occur.
FIRE HAZARD: This product requires considerable pre-heating before ignition and combustion will occur.
REACTIVITY HAZARD: This product is stable under ordinary conditions of use and storage.
ENVIRONMENTAL HAZARD: This product does not normally present a significant hazard to aquatic or terrestrial life in
consumer quantities.
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SYMPTOMS OF OVEREXPOSURE BY ROUTE OF EXPOSURE:
The most significant routes of occupational overexposure are inhalation and contact with skin and eyes. The symptoms of
overexposure to this product are as follows:
INHALATION: Vapors or mists of this product can cause irritation to the respiratory tract. High concentrations of Propylene glycol
monomethyl ether and Dipropylene glycol monomethyl ether, components of this product, can cause central nervous system
depression characterized by headache, nausea, dizziness, confusion, unconsciousness, coma, and death.
CONTACT WITH SKIN or EYES: Contact can cause eye or skin irritation. Prolonged skin contact can result in dermatitis.
Propylene glycol monomethyl ether and Dipropylene glycol monomethyl ether, components of this product, can cause excessive
tearing.
SKIN ABSORPTION: Propylene glycol monomethyl ether and Dipropylene glycol monomethyl ether, components of this product,
can potentially be absorbed through intact skin.
INGESTION: If the product is swallowed, irritation of the mouth, throat, and other tissues of the gastro-intestinal system can
occur. Ingestion of large amounts may cause irritation, pain, vomiting, and diarrhea. If vomiting results in aspiration, chemical
pneumonia could follow.
INJECTION: Accidental injection of this product can cause burning, reddening, and swelling in addition to the wound. Symptoms of
such exposure can include those described under "Inhalation", "Contact with Skin or Eyes," and "Ingestion".
Hazardous Materials Identification System (HMIS)
Health 2*
Flammability 1
Physical Hazard 0
Protective Equipment C
See Section 16 for Definition of Ratings
HEALTH EFFECTS OR RISKS FROM EXPOSURE: An Explanation in Lay Terms.
ACUTE: Depending on the duration of contact, overexposures can irritate the eyes, skin, mucous membranes, and the central
nervous system.
CHRONIC: Long-term skin or eye contact can result in dermatitis or eye irritation. Over exposure could cause adverse effects to
liver, kidney and central nervous system.
TARGET ORGANS: Acute: Eyes, skin, and central nervous system. Chronic: Eyes, skin, central nervous system, liver, and
kidneys.
PART II What should I do if a hazardous situation occurs?
4. FIRST-AID MEASURES
Victims of chemical exposure must be taken for medical attention if any adverse effects occur. Take a copy of label and MSDS to
physician or health professional with victim.
SKIN EXPOSURE: If this product contaminates the skin, immediately begin decontamination with running water. Remove exposed
or contaminated clothing, taking care not to contaminate eyes. Victim must seek immediate medical attention if any adverse exposure
symptoms develop.
EYE EXPOSURE: If this product enters the eyes, open victim's eyes while under gently running water. Use sufficient force to open
eyelids. Have victim "roll" eyes. Minimum flushing is for 15 minutes. Victim must seek medical attention.
INHALATION: If vapors, mists, or sprays of this product are inhaled, remove victim to fresh air. Victim must seek immediate
medical attention if any adverse exposure symptoms develop. If necessary, use artificial respiration to support vital functions.
INGESTION: If this product is swallowed, CALL PHYSICIAN OR POISON CONTROL CENTER FOR MOST CURRENT
INFORMATION. DO NOT INDUCE VOMITING, unless directed by medical personnel. Have victim rinse mouth with water, if
conscious. Never induce vomiting or give a diluent (e.g., water) to someone who is unconscious, having convulsions, or unable to
swallow. If contaminated individual is convulsing, maintain an open airway and obtain immediate medical attention.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Persons with pre-existing skin disorders, eye problems, impaired
liver, kidney, respiratory or lymphoid system function can be more susceptible to health effects associated with overexposures to this
product.
RECOMMENDATIONS TO PHYSICIANS: Treat symptoms and eliminate overexposure.
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5. FIRE-FIGHTING MEASURES
FLASH POINT: Wipe Solution is > 212F
AUTOIGNITION TEMPERATURE: Not applicable.
FLAMMABLE LIMITS (in air by volume, %):
Lower: Not applicable.
Upper: Not applicable.
FIRE EXTINGUISHING MATERIALS:
Use extinguishing material suitable to the surrounding fire.
Water Spray: OK. Carbon Dioxide: OK
Foam: OK Dry Chemical: OK
Halon: OK Other: Any "ABC" Class.
UNUSUAL FIRE AND EXPLOSION HAZARDS: When involved in
a fire, this material can decompose, generating dusts, irritating fumes and
toxic gases (e.g., Carbon monoxide, Carbon dioxide, and oxides of Nitrogen).
Explosion Sensitivity to Mechanical Impact: Not sensitive under normal
conditions.
Explosion Sensitivity to Static Discharge: Not sensitive under normal
conditions.
SPECIAL FIRE-FIGHTING PROCEDURES: Incipient fire responders s
hould wear eye protection. Structural firefighters must wear Self-Contained
Breathing Apparatus and full protective equipment. Move containers from
fire area if it can be done without risk to personnel. If possible, prevent
runoff water from entering storm drains, bodies of water, or other
environmentally sensitive areas.
6. ACCIDENTAL RELEASE MEASURES
SPILL AND LEAK RESPONSE: Trained personnel using pre-planned procedures should respond to uncontrolled releases. Proper
protective equipment should be used. In case of a spill, clear the affected area and protect people.
RESPONSE TO INCIDENTAL RELEASES: Personnel who have received basic chemical safety training can generally handle
small-scale releases, such as 1 container of this product. Respond to incidental chemical releases by wearing gloves, goggles, and
appropriate body protection.
RESPONSE TO NON-INCIDENTAL RELEASES: Respond to non-incidental chemical releases of this product, such as the
simultaneous puncturing of several containers, by clearing the impacted area and contacting appropriate emergency personnel.
Clean up should only be done by qualified personnel. Responders should wear the level of protection appropriate to the type of
chemical released, the volume of the material spilled, and the location where the incident has occurred. Minimum Personal
Protective Equipment should be Level B: triple-gloves, chemical resistant apron, boots, and splash goggles and Self-Contained
Breathing Apparatus. Level B should also be used when oxygen levels are below 19.5% or are unknown.
RESPONSE EQUIPMENT AND PROCEDURES: Absorb spilled liquid with polypads or other suitable absorbent materials.
Decontaminate the area thoroughly. Prevent spill rinsate from contamination of storm drains, sewers, soil or groundwater. Place all
spill residues in a suitable container and seal. Dispose of in accordance with applicable U.S. Federal, State, or local procedures or
appropriate standards of Canada (see Section 13, Disposal Considerations).
PART III How can I prevent hazardous situations from occurring?
7. HANDLING and STORAGE
WORK PRACTICES AND HYGIENE PRACTICES: As with all chemicals, avoid getting this product ON YOU or IN YOU. Wash
thoroughly after using this product. Do not eat or drink while using this material. Avoid generating dusts, mists or sprays of this
product. Remove contaminated clothing immediately.
STORAGE AND HANDLING PRACTICES: All employees who handle this material should be trained to use it safely. Open
containers carefully on a stable surface. Empty containers can contain residual material; therefore, empty containers should be
handled with care. Store containers in a cool, dry location, away from direct sunlight, sources of intense heat, or where freezing is
possible. Store away from incompatible materials (see Section 10, Stability and Reactivity). Keep container tightly closed when not
in use. Inspect all incoming containers before storage, to ensure containers are properly labeled and not damaged.
PROTECTIVE PRACTICES DURING MAINTENANCE OF CONTAMINATED EQUIPMENT: Follow practices indicated in
Section 6 (Accidental Release Measures). Make certain that application equipment is locked and tagged-out safely if necessary.
Collect all rinsates and dispose of according to applicable U.S. Federal, State, or local procedures or appropriate Canadian standards.
8. EXPOSURE CONTROLS - PERSONAL PROTECTION
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VENTILATION AND ENGINEERING CONTROLS: Use with adequate ventilation to ensure exposure levels are maintained below
the limits provided in Section 2 (Composition and Information on Ingredients). Ensure eyewash/safety shower stations are available
near areas where this product is used.
RESPIRATORY PROTECTION: None needed under normal conditions of use. Use NIOSH approved respirators if ventilation is
inadequate to control dusts, mists, fumes or vapors. Maintain airborne contaminate concentrations below guidelines listed in Section 2
(Composition and Information on Ingredients). Oxygen levels below 19.5% are considered IDLH by OSHA. In such atmospheres use
of a full-face-piece pressure/demand SCBA or a full face-piece, supplied air respirator with auxiliary self-contained air supply is
required under OSHA's Respiratory Protection Standard (29 CFR 1910.134).
EYE PROTECTION: For consumer use, wearing eye protection (such as splash goggles) is advisable. However, for specific
industrial applications, enhanced eye protection can be necessary. Use approved safety goggles or safety glasses, as described in
OSHA 29 CFR 1910.133. If necessary, refer to U.S. OSHA 29 CFR 1910.133, or appropriate Canadian standards.
HAND PROTECTION: For consumer use, wearing protective gloves is recommended. For specific industrial applications, wear
chemical impervious gloves (e.g., Neoprene or Nitrile). If necessary, refer to U.S. OSHA 29 CFR 1910.138 or the appropriate
standards of Canada.
BODY PROTECTION: For consumer use, no specific body protection is normally needed. For specific industrial applications, body
protection is not normally needed. Use body protection appropriate for task (e.g., Tyvek suit, rubber apron). If a hazard of injury to
the feet exists due to falling objects, rolling objects, where objects can pierce the soles of the feet or where employee's feet can be
exposed to electrical hazards, use foot protection, as described in U.S. OSHA 29 CFR 1910.136.
HMIS PERSONAL PROTECTIVE EQUIPMENT RATING: Industrial Use situations: C; Safety glasses, gloves and body
protection.
9. PHYSICAL and CHEMICAL PROPERTIES
RELATIVE VAPOR DENSITY (air = 1): Not available. EVAPORATION RATE (BuAc =1): Not available.
SPECIFIC GRAVITY: Not available. MELTING/FREEZING POINT: Not available.
SOLUBILITY IN WATER: Soluble. BOILING POINT: Not available.
VAPOR PRESSURE, mm Hg @ 20癈: Not available. pH: > 7 (alkaline).
ODOR THRESHOLD: Not available.
COEFFICIENT OF OIL/WATER DISTRIBUTION (PARTITION COEFFICIENT): Not available.
Weight % V.O.C.: Not available.
APPEARANCE, ODOR AND COLOR: This product is a colorless to light yellow liquid with a sweet lemon-like odor, saturated on
disposable towels.
HOW TO DETECT THIS SUBSTANCE (warning properties): The appearance and odor of this product may act as warning
properties in the event of an accidental release.
10. STABILITY and REACTIVITY
STABILITY: Stable under normal circumstances of use and handling.
DECOMPOSITION PRODUCTS: Thermal decomposition of this product may generate irritating fumes, and toxic gases (e.g.,
Carbon monoxide, Carbon dioxide, and oxides of Nitrogen).
MATERIALS WITH WHICH SUBSTANCE IS INCOMPATIBLE: This product is not compatible with strong bases, strong acids,
and powerful oxidizers.
HAZARDOUS POLYMERIZATION: Will not occur.
CONDITIONS TO AVOID: Avoid contact with incompatible chemicals.
PART IV Is there any other useful information about this material?
11. TOXICOLOGICAL INFORMATION
TOXICITY DATA: There are currently no toxicity data available for this product; the following toxicology information is available
for components greater than 1% in concentration.
The following data are available for Propylene glycol monomethyl ether:
Skin-Rabbit, adult 500 mg open Mild irritation effects
Eye effects-Rabbit, adult 230 mg Mild irritation effects
Inhalation-Rat TCLo:3000 ppm/6H (6-15D preg):Teratogenic effects
Inhalation-Human TCLo:3000 ppm: NOSE, Central nervous system effects ,Gastrointestinal tract effects
Oral-Rat LD50:5660 mg/kg
Inhalation-Rat LCLo:7000 ppm/4H
Intraperitoneal-Rat LD50:3720 mg/kg
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Subcutaneous-Rat LD50:7800 mg/kg
Intravenous-Rat LD50:4200 mg/kg
Oral-Mouse LD50:11,700 mg/kg
Intravenous-Mouse LD50:5300 mg/kg
The following data are available for Sorbitan monolaurate:
Skin-Human 15 mg/3D-I Mild irritation effects
Intraperitoneal-Mouse TDLo:2500 mg/kg (9D preg):Reproductive effects
Intraperitoneal-Mouse TDLo:1 g/kg (9D preg):Teratogenic effects
Intraperitoneal-Rat LD50:3850 mg/kg
Intravenous-Rat LD50:770 mg/kg
Intraperitoneal-Mouse LD50:2640 mg/kg
Intravenous-Mouse LD50:2970 mg/kg
The following data are available for Dipropylene glycol monomethyl ether:
Eye effects-Human 8 mg Mild irritation effects
Skin-Rabbit, adult 500 mg open Mild irritation effects
Eye effects-Rabbit, adult 238 mg Mild irritation effects
Oral-Rat LD50:5660 mg/kg
Oral-Dog, adult LD50:7500 mg/kg
Skin-Rat LD50:9500 mg/kg
The following data are available for Triethanolamine:
Skin-Human 15 mg/3D-I Mild irritation effects
Skin-Rabbit, adult 560 mg/24H Mild irritation effects
Eye effects-Rabbit, adult 10 mg Mild irritation effects
Oral-Mouse TDLo:16 g/kg/64W-C:Carcinogenic effects
Oral-Mouse TD:154 g/kg/61W-C:Carcinogenic effects
Oral-Rat LD50:8 g/kg
Oral-Mouse LD50:7400 mg/kg
Intraperitoneal-Mouse LD50:1450 mg/kg
Oral-Guinea Pig, adult LD50:5300 mg/kg
The following data are available for d-Limonene:
Oral-Rat TDLo:20,083 mg/kg (9-15D preg):Reproductive effects
Oral-Rat TDLo:20,083 mg/kg (9-15D preg):Teratogenic effects
Oral-Rat TDLo:38,625 mg/kg/2Y-C:Carcinogenic effects
Oral-Mouse TDLo:67 g/kg/39W-I:Equivocal tumorigenic agent
Oral-Rat LD50:4400 mg/kg
Intraperitoneal-Rat LD50:3600 mg/kg
Intravenous-Rat LD50:110 mg/kg
Oral-Mouse LD50:5600 mg/kg
Intraperitoneal-Mouse LD50:600 mg/kg
Intraduodenal-Mouse LDLo:1 g/kg
SUSPECTED CANCER AGENT: The following table summarizes the carcinogenicity listing for the components of this product.
"NO" indicates that the substance is not considered to be, or suspected to be, a carcinogen by the listed agency.
CHEMICAL IARC NTP NIOSH OSHA ACGIH PROP 65
Propylene glycol NO NO NO NO NO NO
monomethyl ether
Dipropylene glycol NO NO NO NO NO NO
monomethyl ether
d-Limonene NO NO NO NO NO NO
Triethanolamine 3 NO NO NO NO NO
Sorbitan monolaurate NO NO NO NO NO NO
Note: See section 16 for definition of ratings.
IRRITANCY OF PRODUCT: This product can be irritating to contaminated tissue.
Page 5 of 8
SENSITIZATION TO THE PRODUCT: d-Limonene and Triethanolamine, components of this product, are reported to be skin
sensitizers.
TOXICOLOGICAL SYNERGISTIC PRODUCTS: None.
REPRODUCTIVE TOXICITY INFORMATION: Listed below is information concerning the effects of this product and its
components on the human reproductive system.
Mutagenicity: When used as directed, this product is not expected to produce mutagenic effects in humans.
Embryotoxicity: When used as directed, this product is not expected to produce embryotoxic effects in humans.
Teratogenicity: When used as directed, this product is not expected to produce teratogenic effects in humans
Reproductive Toxicity: When used as directed, this product is not expected to produce reproductive toxicity in humans.
A mutagen is a chemical that causes permanent changes to genetic material (DNA) such that the changes will propagate through
generational lines. An embryotoxin is a chemical that causes damage to a developing embryo (i.e. within the first eight weeks of
pregnancy in humans), but the damage does not propagate across generational lines. A teratogen is a chemical that causes damage to
a developing fetus, but the damage does not propagate across generational lines. A reproductive toxin is any substance that interferes
in any way with the reproductive process.
BIOLOGICAL EXPOSURES INDICES (BEIs): There are no BEI's established for any component of this product at this time.
12. ECOLOGICAL INFORMATION
ALL WORK PRACTICES MUST BE AIMED AT ELIMINATING ENVIRONMENTAL CONTAMINATION.
ENVIRONMENTAL STABILITY: The following environmental data is available for components of this product: None.
EFFECT OF MATERIAL ON PLANTS or ANIMALS: This product is not anticipated to cause significant effects on terrestrial plants
or animals if released in small, consumer-sized volumes. This product may be harmful to animal life if large volumes of it are
released into the environment. Refer to Section 11 (Toxicological Information) for specific animal data.
EFFECT OF CHEMICAL ON AQUATIC LIFE: This product is not anticipated to cause significant effects on aquatic plants or
animals if released in small, consumer-sized volumes. This product may be harmful to contaminated aquatic life (especially if large
volumes of it are released into an aquatic environment). The following aquatic toxicity data is available for components of this
product:
The following data are available for Propylene glycol monomethyl ether:
Rainbow trout: LC50 = 19202 mg/L (96 hr)
Fathead minnow: LC50 = 15886 mg/L (96 hr)
Bluegill/sunfish: LC50 = 21742 mg/L (96 hr)
Flea: EC50 = 10457 mg/L (96 hr)
The following data are available for Triethanolamine:
Goldfish: LC50 = 5000 mg/L (96 hr)
13. DISPOSAL CONSIDERATIONS
PREPARING WASTES FOR DISPOSAL: Consumer Waste: Dispose of according to pertinent state and local household waste and
requirements. Industrial Use: Waste disposal must be in accordance with appropriate U.S. Federal, State, and local regulations or
with regulations of Canada.
EPA WASTE NUMBER: Wastes consisting only of this product are not regulated; however, the specific RCRA codes depend on the
exact nature of the discarded material.
14. TRANSPORTATION INFORMATION
THIS PRODUCT IS NOT HAZARDOUS PER 49 CFR 172.101, THE U.S. DEPARTMENT OF TRANSPORTATION.
PROPER SHIPPING NAME: Not regulated.
HAZARD CLASS NUMBER and DESCRIPTION: Not regulated.
UN IDENTIFICATION NUMBER: Not regulated.
DOT LABEL(S) REQUIRED: Not regulated.
PACKAGING GROUP: Not regulated.
NORTH AMERICAN RESPONSE GUIDEBOOK NUMBER (2000): Not regulated.
MARINE POLLUTANT: No component is designated as a DOT Marine Pollutant.
TRANSPORT CANADA TRANSPORTATION OF DANGEROUS GOODS REGULATIONS: This product is not regulated for
shipping by Transport Canada.
15. REGULATORY INFORMATION
ADDITIONAL U.S. REGULATIONS:
EPA REPORTING REQUIREMENTS: The following reporting requirements are applicable to components of this product:
Page 6 of 8
CHEMICAL SECTION 302 SECTION 304 SECTION 313
(40 CFR 355, Appendix A) (40 CFR Table 302.4) (40 CFR 372.65)
Propylene glycol monomethyl NO NO NO
ether
Dipropylene glycol NO NO NO
monomethyl ether
d-Limonene NO NO NO
Triethanolamine NO NO NO
Sorbitan monolaurate NO NO NO
U.S. SARA SECTION 311/312 FOR PRODUCT: Acute health effects; chronic health effects, flammable.
U.S. TSCA INVENTORY STATUS: The components of this product are listed on the TSCA Inventory.
OTHER U.S. FEDERAL REGULATIONS: Not applicable.
CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT (PROPOSITION 65): No component of this
product is found on either the Proposition 65 Carcinogen List or the Adverse Reproductive Effects List.
ANSI LABELING (Z129.1):
CAUTION! COMBUSTIBLE LIQUID AND VAPOR. HARMFUL OR FATAL IF SWALLOWED, INHALED OR ABSORBED
THROUGH THE SKIN. EYE, SKIN, AND RESPIRATORY TRACT IRRITANT.
ANSI LABEL PRECAUTIONS:
Do not breathe vapors or mist. Do not swallow or take internally. Do not get in eyes, on skin, or on clothing. Wash thoroughly
after handling. Keep container closed. Use only in a well-ventilated area. Keep away from heat, sparks and flame.
15. REGULATORY INFORMATION - Continued
ENVIRONMENTAL HAZARDS: Do not discharge effluent containing this product into streams, ponds, estuaries, oceans or other
waters unless in accordance with the requirements of a National Pollutant Discharge Elimination System (NPDES) permit and the
permitting authority has been notified in writing prior to discharge. Do not discharge effluent containing this product to sewer systems
without previously notifying the local sewage treatment plant authority. For guidance, contact your State Water Board or Regional
Office of the EPA.
ADDITIONAL CANADIAN REGULATIONS:
CANADIAN DSL/NDSL INVENTORY STATUS: The components of this product are listed on the DSL Inventory.
CANADIAN WHMIS SYMBOLS:
D2B - Poisonous and infectious material - Other effects - Toxic
This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR) and
the MSDS contains all the information required by the CPR.
16. OTHER INFORMATION
Disclaimer: As the handling and use of products under user's conditions are beyond our control, no warranty, expressed or
implied, including, but not limited to merchantability or fitness for a particular use, is made concerning this product. The user
assumes all risk of use or handling whether or not in accordance with any directions or suggestions of the supplier. Seller shall not
be liable to purchaser or any other person for loss or damages directly or indirectly arising from the use of our products, from
breach of any warranty or from any other cause, the exclusive remedy against the seller being to require replacement or repair of
defective goods.
DEFINITIONS OF TERMS
A large number of abbreviations and acronyms appear on a MSDS. Some of these, which are commonly used, include the following:
CAS #: This is the Chemical Abstract Service Number that uniquely identifies each compound.
ACGIH - American Conference of Governmental Industrial Hygienists, a Permissible Exposure Limits are based in the 1989 PELs and the June, 1993
professional association which establishes exposure limits. Air Contaminants Rule (Federal Register: 58: 35338-35351 and 58: 40191).
TLV - Threshold Limit Value - an airborne concentration of a substance that Both the current PELs and the vacated PELs are indicated. The phrase,
represents conditions under which it is generally believed that nearly all "Vacated 1989 PEL," is placed next to the PEL that was vacated by Court
workers may be repeatedly exposed without adverse effect. The duration must Order.
be considered, including the 8-hour Time Weighted Average (TWA), the 15- IDLH - Immediately Dangerous to Life and Health - This level represents a
minute Short Term Exposure Limit, and the instantaneous Ceiling Level (C). concentration from which one can escape within 30-minutes without suffering
Skin absorption effects must also be considered. escape-preventing or permanent injury. The DFG - MAK is the Republic of
OSHA - U.S. Occupational Safety and Health Administration. Germany's Maximum Exposure Level, similar to the U.S. PEL. NIOSH is
PEL - Permissible Exposure Limit - This exposure value means exactly the the National Institute of Occupational Safety and Health, which is the research
same as a TLV, except that it is enforceable by OSHA. The OSHA arm of the U.S. Occupational Safety and Health Administration (OSHA).
Page 7 of 8
NIOSH issues exposure guidelines called Recommended Exposure Levels FLAMMABILITY LIMITS IN AIR:
(RELs). When no exposure guidelines are established, an entry of NE is made Much of the information related to fire and explosion is derived from the
for reference. National Fire Protection Association (NFPA). Flash Point - Minimum
HAZARD RATINGS: temperature at which a liquid gives off sufficient vapors to form an ignitable
HAZARDOUS MATERIALS IDENTIFICATION SYSTEM: Health mixture with air. Autoignition Temperature: The minimum temperature
Hazard: 0 (minimal acute or chronic exposure hazard); 1 (slight acute or required to initiate combustion in air with no other source of ignition. LEL -
chronic exposure hazard); 2 (moderate acute or significant chronic exposure the lowest percent of vapor in air, by volume, that will explode or ignite in the
hazard); 3 (severe acute exposure hazard; onetime overexposure can cause presence of an ignition source. UEL - the highest percent of vapor in air, by
permanent injury and may be fatal); 4 (extreme acute exposure hazard; volume, that will explode or ignite in the presence of an ignition source.
onetime overexposure can be fatal). Flammability Hazard: 0 (minimal hazard); TOXICOLOGICAL INFORMATION:
1 (materials that require substantial pre-heating before burning); 2 (combustible Possible health hazards as derived from human data, animal studies, or from
the results of studies with similar compounds are presented. Definitions of
liquid or solids; liquids with a flash point of 38-93癈 [100-200癋]); 3 (Class IB
some terms used in this section are: LD50 - Lethal Dose (solids & liquids)
and IC flammable liquids with flash points below 38癈 [100癋]); 4 (Class IA
which kills 50% of the exposed animals; LC50 - Lethal Concentration (gases)
flammable liquids with flash points below 23癈 [73癋] and boiling points
which kills 50% of the exposed animals; ppm concentration expressed in parts
below 38癈 [100癋]. Reactivity Hazard: 0 (normally stable); 1 (material that
of material per million parts of air or water; mg/m3 concentration expressed in
can become unstable at elevated temperatures or which can react slightly with
weight of substance per volume of air; mg/kg quantity of material, by weight,
water); 2 (materials that are unstable but do not detonate or which can react
administered to a test subject, based on their body weight in kg. Other
violently with water); 3 (materials that can detonate when initiated or which
measures of toxicity include TDLo, the lowest dose to cause a symptom and
can react explosively with water); 4 (materials that can detonate at normal
TCLo the lowest concentration to cause a symptom; TDo, LDLo, LDo, TC,
temperatures or pressures).
TCo, LCLo, and LCo, the lowest dose (or concentration) to cause lethal or
NATIONAL FIRE PROTECTION ASSOCIATION: Health Hazard: 0
toxic effects. BEI - Biological Exposure Indices, represent the levels of
(material that on exposure under fire conditions would offer no hazard beyond
determinants which are most likely to be observed in specimens collected from
that of ordinary combustible materials); 1 (materials that on exposure under
a healthy worker who has been exposed to chemicals to the same extent as a
fire conditions could cause irritation or minor residual injury); 2 (materials
worker with inhalation exposure to the TLV. Ecological Information: EC is
that on intense or continued exposure under fire conditions could cause
the effect concentration in water.
temporary incapacitation or possible residual injury); 3 (materials that can on
Data from several sources are used to evaluate the cancer-causing potential of
short exposure could cause serious temporary or residual injury); 4 (materials
the material. The sources and ratings are: IARC - the International Agency
that under very short exposure could cause death or major residual injury).
for Research on Cancer; 1 = Carcinogenic to humans, 2A, 2B = Probably
Flammability Hazard and Reactivity Hazard: Refer to definitions for
carcinogenic to humans, 3 = Unclassifiable as to carcinogenicity in humans,
"Hazardous Materials Identification System".
and 4 = Probably not carcinogenic to humans. NTP - the National
Toxicology Program; K =Known to be a human carcinogen, and R =
Reasonably anticipated to be a human carcinogen. RTECS - the Registry of
Toxic Effects of Chemical Substances. OSHA - Occupational Safety and
Health Administration and CAL/OSHA - California's subunit of the
Occupational Safety and Health Administration; Ca = Carcinogen defined with
no further categorization. ACGIH ?American Conference of Governmental
Industrial Hygienists; A1 = Confirmed human carcinogen, A2 = Suspected
human carcinogen, A3 = Confirmed animal carcinogen with unknown
relevance to humans, A4 = Not classifiable as a human carcinogen, and A5 =
Not suspected as a human carcinogen. NIOSH ?U.S. National Institute for
Occupational Safety and Health; Ca = Potential occupational carcinogen, with
no further categorization. EPA ?U.S. Environmental Protection; A = Human
carcinogen, B = Probable human carcinogen, C = Possible human
carcinogen, D = Not classifiable as to human carcinogenicity, E = Evidence
of Non-carcinogenicity for humans, K = Known human carcinogen, L =
Likely to produce cancer in humans, CBD = Cannot be determined, NL =
Not likely to be carcinogenic in humans, and I = Data are inadequate for an
assessment of human carcinogenic potential.
REGULATORY INFORMATION:
This section explains the impact of various laws and regulations on the
material. EPA is the U.S. Environmental Protection Agency. WHMIS is the
Canadian Workplace Hazardous Materials Information System. DOT and TC
are the U.S. Department of Transportation and the Transport Canada,
respectively. Superfund Amendments and Reauthorization Act (SARA); the
Canadian Domestic/Non-Domestic Substances List (DSL/NDSL); the U.S.
Toxic Substance Control Act (TSCA); Marine Pollutant status according to the
DOT; the Comprehensive Environmental Response, Compensation, and
Liability Act (CERCLA or Superfund); and various state regulations. This
section also includes information on the precautionary warnings that appear on
a material's industrial package label.
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