Search    ENTER KEYWORD
MSDS Material Safety Data Sheet
CAS

102-71-6 64-02-8 7732-18-5

File Name: 102-71-6_64-02-8_7732-18.asp

                          GENERAL HARDNESS (GH) TEST SOLUTION
Chemwatch Material Safety Data Sheet CHEMWATCH 4650-37
Issue Date: Tue 4-Oct-2005 CD 2005/3 Page 1 of 16



Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION


PRODUCT NAME
GENERAL HARDNESS (GH) TEST SOLUTION

STATEMENT OF HAZARDOUS NATURE
CONSIDERED A HAZARDOUS SUBSTANCE ACCORDING TO OSHA 29 CFR
1910.1200.

SUPPLIER
Company: Aquarium Pharmaceuticals Incorporated Company: Aquarium Pharmaceuticals Incorporated
Address: Address:
50 East Hamilton Street PO Box 218
Chalfont Chalfont
PA, 18914 PA, 18914-0218
USA USA
Telephone: +1 215 822 8181 Telephone: +1 215 822 8181
Emergency Tel: +1800 222 1222 (US Only)


PRODUCT USE
Hardness test solution for products 58 and 34.

SYNONYMS
"Solution ID# 3338"


Section 2 - COMPOSITION / INFORMATION ON INGREDIENTS

NAME CAS RN %
triethanolamine 102-71-6 10-30
EDTA tetrasodium salt 64-02-8 1-5
water 7732-18-5 >60


Section 3 - HAZARDS IDENTIFICATION


CANADIAN WHMIS SYMBOLS




EMERGENCY OVERVIEW

RISK
Irritating to eyes.
Harmful by inhalation, in contact with skin and if swallowed.
Cumulative effects may result following exposure*.

continued...
GENERAL HARDNESS (GH) TEST SOLUTION
Chemwatch Material Safety Data Sheet CHEMWATCH 4650-37
Issue Date: Tue 4-Oct-2005 CD 2005/3 Page 2 of 16
Section 3 - HAZARDS IDENTIFICATION

Possible skin sensitizer*.
Exposure may produce irreversible effects*. *(limited evidence)

POTENTIAL HEALTH EFFECTS

ACUTE HEALTH EFFECTS


SWALLOWED
Accidental ingestion of the material may be harmful; animal experiments indicate
that ingestion of less than 150 gram may be fatal or may produce serious damage
to the health of the individual.
There is some evidence to suggest that this material can cause, if swallowed
once, irreversible damage of organs.

EYE
This material can cause eye irritation and damage in some persons.

SKIN
Skin contact with the material may be harmful; systemic effects may result
following absorption.
The material is not thought to be a skin irritant (as classified using animal
models). Temporary discomfort, however, may result from prolonged dermal
exposures. Good hygiene practice requires that exposure be kept to a minimum and
that suitable gloves be used in an occupational setting.
There is some evidence to suggest that this material, on a single contact with
skin, can cause irreversible damage of organs.
Toxic effects may result from skin absorption.
Entry into the blood-stream, through, for example, cuts, abrasions or lesions,
may produce systemic injury with harmful effects. Examine the skin prior to the
use of the material and ensure that any external damage is suitably protected.

INHALED
Harmful by inhalation.
The material is not thought to produce respiratory irritation (as classified
using animal models). Nevertheless inhalation of the material, especially for
prolonged periods, may produce respiratory discomfort and occasionally,
distress.
Inhalation of vapors or aerosols (mists, fumes), generated by the material
during the course of normal handling, may be harmful.
There is some evidence to suggest that this material can cause, if inhaled once,
irreversible damage of organs.

CHRONIC HEALTH EFFECTS
Substance accumulation, in the human body, may occur and may cause some concern
following repeated or long-term occupational exposure. There has been some
concern that this material can cause cancer or mutations but there is not enough
data to make an assessment. There is limited evidence that, skin contact with
this product is more likely to cause a sensitization reaction in some persons
compared to the general population. Prolonged or chronic exposure to
alkanolamines may result in liver, kidney or nervous system injury. Repeated
inhalation may aggravate asthma and inflammatory or fibrotic pulmonary disease.
Results of repeated exposure tests with diethanolamine (DEA) in laboratory
animals include anaemia (rats) and effects on the kidneys (rats and mice) and
liver (mice). DEA produces nervous system injury in dogs and rats. Heart and
salivary gland lesions have also been seen in mice treated cutaneously with DEA

continued...
GENERAL HARDNESS (GH) TEST SOLUTION
Chemwatch Material Safety Data Sheet CHEMWATCH 4650-37
Issue Date: Tue 4-Oct-2005 CD 2005/3 Page 3 of 16
Section 3 - HAZARDS IDENTIFICATION

and in mice receiving DEA in drinking water. Rats given high doses of DEA
developed anaemia and testicular lesions. Exaggerated doses of DEA produced
heart and nervous system effects in other animals. Changes in other organs were
judged to be secondary due to the poor health of animals subjected to extremely
high doses of DEA. Rats, rabbits and guinea pigs exposed to high vapour
concentrations of volatile monoethanolamine (MEA) (up to 1250 ppm) for periods
of up to 5 weeks developed pulmonary, hepatic and renal lesions. Dogs, rats and
guinea pigs exposed to 100 ppm MEA for 30 days, became apathetic and developed
poor appetites. Animal tests also indicate that inhalation exposure to MEA may
result in nervous system injury. All species exposed to airborne MEA experienced
dermal effects, varying from ulceration to hair loss probably resulting from
contact with the cage. An increased incidence of skeletal variations, suggestive
of a slight developmental delay was seen in the foetuses of rats given 1500
mg/kg/day DEA cutaneously; this also produced significant maternal toxicity. No
foetal malformations, however, were seen in rats nor in rabbits receiving
identical treatment. The foetus of rats given high doses of MEA by gavage,
showed an increased rate of embryofoetal death, growth retardation, and some
malformations including hydronephrosis and hydroureter. The high doses required
to produce these effects bring into question the relevance of this finding to
humans. There is some evidence that embryofoetotoxicity and teratogenicity does
not occur in rats when MEA is administered by dermal application to the mother.
The National Toxicology Program (NTP) concluded that there is clear evidence of
liver tumours and some evidence of kidney tumours in mice exposed dermally to
DEA over their lifetime. Chronic skin painting studies in mice of both sexes
produced liver tumours and an increased incidence of kidney tumours in male
mice. The significance of these findings to humans is unclear as DEA is neither
genotoxic, mutagenic nor clastogenic, and did not induce tumours in rats or
transgenic mice similarly treated. Alkanolamines (especially those containing a
secondary amine moiety) may react with nitrites or other nitrosating agents to
form carcinogenic N-nitrosamines. Alkanolamines are metabolised by biosynthetic
routes to ethanolamine and choline and incorporated into phospholipids. They are
excreted predominantly unchanged with a half-life of approximately one week. In
the absence of sodium nitrite, no conversion to carcinogenic N-nitrosamines was
observed. Diethanolamine competitively inhibits the cellular uptake of choline,
in vitro, and hepatic changes in choline homeostasis, consistent with choline
deficiency, are observed in vivo. Many amines are potent skin and respiratory
sensitisers and certain individuals especially those described as "atopic" (i.e.
those predisposed to asthma and other allergic responses) may show allergic
reactions when chronically exposed to alkanolamines. In a study with coconut
diethanolamide, the National Toxicology Program (Technical Report Series 479),
showed clear evidence of carcinogenic activity in male B6C3F1 mice based on
increased incidences of hepatic and renal tubule neoplasms and in female B6C3F1
mice based on increased incidences of hepatic neoplasms. There was equivocal
evidence of carcinogenic activity in female F344/N rats based on a marginal
increase in the incidence of renal tube neoplasms. These increases were
associated with the concentration of free diethanolamine present as a
contaminant in the diethanolamine condensate. Exposure to rats to coconut oil
diethanolamine condensate by dermal application in ethanol for 2 years resulted
in epidermal hyperplasia, sebaceous gland hyperplasia, hyperkeratosis and
parakeratosis in males and females and ulcer in females at the site of
application. There were increases in the incidences of chronic inflammation,
epithelial hyperplasia, and epithelial ulcer in the forestomach of female rats.
The severity of nephropathy in dosed female rats were increased. Exposure of
mice to coconut oil diethanolamine condensate by dermal application for 2 years
resulted in increased incidences of eosinophilic foci of the liver in males.
Increased incidences of epidermal hyperplasia, sebaceous gland hyperplasia, and

continued...
GENERAL HARDNESS (GH) TEST SOLUTION
Chemwatch Material Safety Data Sheet CHEMWATCH 4650-37
Issue Date: Tue 4-Oct-2005 CD 2005/3 Page 4 of 16
Section 3 - HAZARDS IDENTIFICATION

hyperkeratosis in males and females, ulcer in males, and parakeratosis and
inflammation in females at the site of application and of follicular cell
hyperplasia in the thyroid gland of males and females, were chemical related.
Injection of EDTA and it salts can cause severe kidney damage with tissue death
and internal bleeding, bone marrow depression and critically low levels of
calcium.


Section 4 - FIRST AID MEASURES


SWALLOWED
- IF SWALLOWED, REFER FOR MEDICAL ATTENTION, WHERE POSSIBLE, WITHOUT DELAY.
- Where Medical attention is not immediately available or where the patient is
more than 15 minutes from a hospital or unless instructed otherwise:
- For advice, contact a Poisons Information Center or a doctor.
- Urgent hospital treatment is likely to be needed.
- If conscious, give water to drink.
- INDUCE vomiting with fingers down the back of the throat, ONLY IF CONSCIOUS.
Lean patient forward or place on left side (head-down position, if possible) to
maintain open airway and prevent aspiration.
NOTE: Wear a protective glove when inducing vomiting by mechanical means.
- In the mean time, qualified first-aid personnel should treat the patient
following observation and employing supportive measures as indicated by the
patient's condition.
- If the services of a medical officer or medical doctor are readily available,
the patient should be placed in his/her care and a copy of the MSDS should be
provided. Further action will be the responsibility of the medical specialist.
- If medical attention is not available on the worksite or surroundings send the
patient to a hospital together with a copy of the MSDS.

EYE
If this product comes in contact with the eyes:
- Wash out immediately with fresh running water.
- Ensure complete irrigation of the eye by keeping eyelids apart and away from
eye and moving the eyelids by occasionally lifting the upper and lower lids.
- If pain persists or recurs seek medical attention.
- Removal of contact lenses after an eye injury should only be undertaken by
skilled personnel.

SKIN
If skin contact occurs:
- Immediately remove all contaminated clothing, including footwear
- Flush skin and hair with running water (and soap if available).
- Seek medical attention in event of irritation.

INHALED
- If fumes or combustion products are inhaled remove from contaminated area.
- Lay patient down. Keep warm and rested.
- Prostheses such as false teeth, which may block airway, should be removed,
where possible, prior to initiating first aid procedures.
- Apply artificial respiration if not breathing, preferably with a demand valve
resuscitator, bag-valve mask device, or pocket mask as trained. Perform CPR if
necessary.
- Transport to hospital, or doctor.


continued...
GENERAL HARDNESS (GH) TEST SOLUTION
Chemwatch Material Safety Data Sheet CHEMWATCH 4650-37
Issue Date: Tue 4-Oct-2005 CD 2005/3 Page 5 of 16
Section 4 - FIRST AID MEASURES

NOTES TO PHYSICIAN
Treat symptomatically.


Section 5 - FIRE FIGHTING MEASURES

Flash Point (癋): Not Applicable
Lower Explosive Limit (%): Not Applicable
Upper Explosive Limit (%): Not Applicable
Autoignition Temp (癋): Not Applicable

EXTINGUISHING MEDIA
The product contains a substantial proportion of water, therefore there are no
restrictions on the type of extinguishing media which may be used. Choice of
extinguishing media should take into account surrounding areas.
Though the material is non-combustible, evaporation of water from the mixture,
caused by the heat of nearby fire, may produce floating layers of combustible
substances.
In such an event consider:
- foam
- dry chemical powder
- carbon dioxide.

FIRE FIGHTING
- Alert Emergency Responders and tell them location and nature of hazard.
- Wear breathing apparatus plus protective gloves for fire only.
- Prevent, by any means available, spillage from entering drains or water
course.
- Use fire fighting procedures suitable for surrounding area.
- Do not approach containers suspected to be hot.
- Cool fire exposed containers with water spray from a protected location.
- If safe to do so, remove containers from path of fire.
- Equipment should be thoroughly decontaminated after use.

GENERAL FIRE HAZARDS/HAZARDOUS COMBUSTIBLE PRODUCTS
- Non combustible.
- Not considered to be a significant fire risk.
- Expansion or decomposition on heating may lead to violent rupture of
containers.
- Decomposes on heating and may produce toxic fumes of carbon monoxide (CO).
- May emit acrid smoke.
Decomposition may produce toxic fumes of, carbon dioxide (CO2), nitrogen oxides
(NOx), other pyrolysis products typical of burning organic material.
May emit poisonous fumes.
May emit corrosive fumes.

FIRE INCOMPATIBILITY
None known.


Section 6 - ACCIDENTAL RELEASE MEASURES


MINOR SPILLS
- Clean up all spills immediately.
- Avoid breathing vapors and contact with skin and eyes.

continued...
GENERAL HARDNESS (GH) TEST SOLUTION
Chemwatch Material Safety Data Sheet CHEMWATCH 4650-37
Issue Date: Tue 4-Oct-2005 CD 2005/3 Page 6 of 16
Section 6 - ACCIDENTAL RELEASE MEASURES

- Control personal contact by using protective equipment.
- Contain and absorb spill with sand, earth, inert material or vermiculite.
- Wipe up.
- Place in a suitable labeled container for waste disposal.

MAJOR SPILLS
Moderate hazard.
- Clear area of personnel and move upwind.
- Alert Emergency Responders and tell them location and nature of hazard.
- Wear breathing apparatus plus protective gloves.
- Prevent, by any means available, spillage from entering drains or water
course.
- Stop leak if safe to do so.
- Contain spill with sand, earth or vermiculite.
- Collect recoverable product into labeled containers for recycling.
- Neutralize/decontaminate residue.
- Collect solid residues and seal in labeled drums for disposal.
- Wash area and prevent runoff into drains.
- After clean up operations, decontaminate and launder all protective clothing
and equipment before storing and re-using.
- If contamination of drains or waterways occurs, advise emergency services.


ACUTE EXPOSURE GUIDELINE LEVELS (AEGL) (in ppm)


AEGL 1: The airborne concentration of a substance above which it is predicted
that the general population, including susceptible individuals, could
experience notable discomfort, irritation, or certain asymptomatic nonsensory
effects. However, the effects are not disabling and are transient and
reversible upon cessation of exposure.
AEGL 2: The airborne concentration of a substance above which it is predicted
that the general population, including susceptible individuals, could
experience irreversible or other serious, long-lasting adverse health effects
or an impaired ability to escape.
AEGL 3: The airborne concentration of a substance above which it is predicted
that the general population, including susceptible individuals, could
experience life-threatening health effects or death.

EMERGENCY RESPONSE PLANNING GUIDELINES (ERPG)
The maximum airborne concentration below which it is believed that nearly all
individuals could be exposed for up to one hour WITHOUT experiencing or developing

life-threatening health effects is:
triethanolamine 500 mg/m?br> water 500 mg/m?br>
irreversible or other serious effects or symptoms which could
impair an individual's ability to take protective action is:
triethanolamine 20 mg/m?br> water 500 mg/m?br>
other than mild, transient adverse effects
without perceiving a clearly defined odour is:
triethanolamine 5 mg/m?br> water 500 mg/m?br>
continued...
GENERAL HARDNESS (GH) TEST SOLUTION
Chemwatch Material Safety Data Sheet CHEMWATCH 4650-37
Issue Date: Tue 4-Oct-2005 CD 2005/3 Page 7 of 16
Section 6 - ACCIDENTAL RELEASE MEASURES


The threshold concentration below which most people.
will experience no appreciable risk of health effects:
triethanolamine 5 mg/m?br> water 500 mg/m?br>
American Industrial Hygiene Association (AIHA)

Ingredients considered according exceed the following cutoffs
Very Toxic (T+) >= 0.1% Toxic (T) >= 3.0%
R50 >= 0.25% Corrosive (C) >= 5.0%
R51 >= 2.5%
else >= 10%
where percentage is percentage of ingredient found in the mixture


Section 7 - HANDLING AND STORAGE


PROCEDURE FOR HANDLING
DO NOT allow clothing wet with material to stay in contact with skin.
DO NOT USE brass or copper containers / stirrers.
Alkanolamines and iron may produced unstable complexes. Monoethanolamine (MEA)
and iron form a trisethanolamino-iron complex. This material may spontaneously
decompose at temperatures between 130 and 160 degrees C. and is suspected of
causing a fire in a nearly empty storage tank containing a "heel" of MEA in
contact with carbon steel coils. If steam coil heating is used, low pressure
steam in stainless steel coils should be considered. Drum heating should also be
reviewed and, where possible, temperatures should be maintained below 130
degrees C.
- Avoid all personal contact, including inhalation.
- Wear protective clothing when risk of exposure occurs.
- Use in a well-ventilated area.
- Avoid contact with moisture.
- Avoid contact with incompatible materials.
- When handling, DO NOT eat, drink or smoke.
- Keep containers securely sealed when not in use.
- Avoid physical damage to containers.
- Always wash hands with soap and water after handling.
- Work clothes should be laundered separately. Launder contaminated clothing
before re-use.
- Use good occupational work practice.
- Observe manufacturer's storing and handling recommendations.
- Atmosphere should be regularly checked against established exposure standards
to ensure safe working conditions are maintained.

RECOMMENDED STORAGE METHODS
- Polyethylene or polypropylene container.
- Packing as recommended by manufacturer
- Check all containers are clearly labeled and free from leaks.


STORAGE REQUIREMENTS
- Store in original containers.
- Keep containers securely sealed.
- Store in a cool, dry, well-ventilated area.

continued...
GENERAL HARDNESS (GH) TEST SOLUTION
Chemwatch Material Safety Data Sheet CHEMWATCH 4650-37
Issue Date: Tue 4-Oct-2005 CD 2005/3 Page 8 of 16
Section 7 - HANDLING AND STORAGE

- Store away from incompatible materials and foodstuff containers.
- Protect containers against physical damage and check regularly for leaks.
- Observe manufacturer's storing and handling recommendations.


Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION


EXPOSURE CONTROLS
Source Material TWA TWA STEL STEL Peak Peak
ppm mg/m? ppm mg/m? ppm mg/m?br> _________________________ ________________ _____ _____ _____ _____ _____ _____
US California Permissible Triethanolamine -- 5
Exposure Limits for
Chemical Contaminants
Canada Saskatchewan Triethanolamine 5 10
Occupational Health and
Safety Regulations -
Contamination Limits
Canadian British Columbia Triethanolamine 5
Occupational Exposure
Limits
No data available: EDTA tetrasodium salt as (CAS: 64-02-8) / (CAS: 10378-23-1) / (CAS: 13235-36-4)
No data available: water as (CAS: 7732-18-5)

ODOUR SAFETY FACTOR (OSF)
OSF=0.77 (triethanolamine)
Exposed individuals are NOT reasonably expected to be warned, by smell, that the
Exposure Standard is being exceeded.
Odor Safety Factor (OSF) is determined to fall into either Class C, D or E.
The Odor Safety Factor (OSF) is defined as:
OSF= Exposure Standard (TWA) ppm/ Odor Threshold Value (OTV) ppm
Classification into classes follows:

Class OSF Description
A 550 Over 90% of exposed
individuals are aware by
smell that the Exposure
Standard (TLV-TWA for
example) is being
reached, even when
distracted by working
activities
B 26-550 Idem for 50-90% of
persons being distracted
C 1-26 Idem for less than 50% of
persons being distracted
D 0.18-1 0-50% of persons aware of
being tested perceive by
smell that the Exposure
Standard is being reached
E <0.18 Idem for less than 10% of
persons aware of being
tested

Amoore and Hautala * have determined that it is only at an OSF value of 26 that

continued...
GENERAL HARDNESS (GH) TEST SOLUTION
Chemwatch Material Safety Data Sheet CHEMWATCH 4650-37
Issue Date: Tue 4-Oct-2005 CD 2005/3 Page 9 of 16
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION

50% of distracted persons can detect the substance at the Exposure Standard
value. In the case of alerted persons, an OSF of 26 means that 99% of them can
detect the odor at the Exposure Standard value. It is ONLY for substances
belonging to Class A and B that there is a reasonable chance of being warned in
time, that the Exposure Standard is being exceeded. * Journal Applied
Toxicology: Vol 3, 1983, p272
NOTE: The use of the OSF may be inappropriate for mixtures where substances mask
the odor of others.

EXPOSURE STANDARDS FOR MIXTURE
"Worst Case" computer-aided prediction of spray/ mist or fume/ dust components
and concentration:

"Worst Case" computer-aided prediction of spray/ mist or fume/ dust components
and concentration:
Composite Exposure Standard for Mixture (TWA) :100 mg/m?

INGREDIENT DATA
TRIETHANOLAMINE:
Exposure at or below the TLV-TWA is thought to minimise the potential for
skin and eye irritation, and acute effects (including liver, kidney and
nerve damage) and chronic effects (including cancer and allergic contact
dermatitis).

EDTA TETRASODIUM SALT:
Dusts not otherwise classified, as inspirable dust;
ES TWA: 10 mg/m?

WATER:
No exposure limits set by NOHSC or ACGIH.

PERSONAL PROTECTION
Glasses:
Chemical goggles.
Gloves:
PVC chemical resistant type.
Respirator:
Type AK-P Filter of sufficient capacity

EYE
- Safety glasses with side shields.
- Chemical goggles.
- Contact lenses pose a special hazard; soft lenses may absorb irritants and all
lenses concentrate them. DO NOT wear contact lenses.

HANDS/FEET
Wear chemical protective gloves, eg. PVC.
Wear safety footwear or safety gumboots, eg. Rubber.
NOTE: The material may produce skin sensitisation in predisposed individuals.
Care must be taken, when removing gloves and other protective equipment, to
avoid all possible skin contact.

OTHER
- Overalls.
- P.V.C. apron.
- Barrier cream.

continued...
GENERAL HARDNESS (GH) TEST SOLUTION
Chemwatch Material Safety Data Sheet CHEMWATCH 4650-37
Issue Date: Tue 4-Oct-2005 CD 2005/3 Page 10 of 16
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION

- Skin cleansing cream.
- Eye wash unit.

RESPIRATOR
Selection of the Class and Type of respirator will depend upon the level of
breathing zone contaminant and the chemical nature of the contaminant.
Protection Factors (defined as the ratio of contaminant outside and inside the
mask) may also be important.

Breathing Zone Maximum Protection Half-face Full-Face
Level ppm (volume) Factor Respirator Respirator
1000 10 AK-1 P -
1000 50 - AK-1 P
5000 50 Airline* -
5000 100 - AK-2 P
10000 100 - AK-3 P
100+ Airline* *

* - Continuous Flow ** - Continuous-flow or positive pressure demand.

The local concentration of material, quantity and
conditions of use determine the type of personal
protective equipment required.
Use appropriate NIOSH-certified respirator based on informed professional
judgement. In conditions where no reasonable estimate of exposure can be
made, assume the exposure is in a concentration IDLH and use NIOSH-certified
full face pressure demand SCBA with a minimum service life of 30 minutes, or
a combination full facepiece pressure demand SAR with auxiliary self-contained
air supply. Respirators provided only for escape from IDLH atmospheres shall be
NIOSH-certified for escape from the atmosphere in which they will be used.

ENGINEERING CONTROLS
Local exhaust ventilation usually required. If risk of overexposure exists, wear
an approved respirator. Correct fit is essential to obtain adequate protection
an approved self contained breathing apparatus (SCBA) may be required in some
situations. Provide adequate ventilation in warehouse or closed storage area.


Section 9 - PHYSICAL AND CHEMICAL PROPERTIES


PHYSICAL PROPERTIES
Liquid.
Mixes with water.

Molecular Weight: Not Applicable Boiling Range (癈): Not Available
Melting Range (癈): Not Available Specific Gravity (water=1): 1.056
Solubility in water (g/L): Miscible pH (as supplied): 10.7-11.3
pH (1% solution): Not Available Vapor Pressure (kPa): Not Available
Volatile Component (%vol): Not Available Evaporation Rate: Not Available
Relative Vapor Density (air=1): Not Available Flash Point (癈): Not Applicable
Lower Explosive Limit (%): Not Applicable Upper Explosive Limit (%): Not Applicable
Autoignition Temp (癈): Not Applicable Decomposition Temp (癈): Not Available
State: Liquid



continued...
GENERAL HARDNESS (GH) TEST SOLUTION
Chemwatch Material Safety Data Sheet CHEMWATCH 4650-37
Issue Date: Tue 4-Oct-2005 CD 2005/3 Page 11 of 16
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

APPEARANCE
Dark green alkaline solution with a slight odor; mixes with water.


Section 10 - CHEMICAL STABILITY AND REACTIVITY INFORMATION


CONDITIONS CONTRIBUTING TO INSTABILITY
- Presence of incompatible materials.
- Product is considered stable.
- Hazardous polymerization will not occur.

STORAGE INCOMPATIBILITY
Avoid strong acids, bases.



Section 11 - TOXICOLOGICAL INFORMATION


General Hardness (GH) Test Solution
Not available. Refer to individual constituents.
unless otherwise specified data extracted from RTECS - Register of Toxic Effects
of Chemical Substances

TRIETHANOLAMINE:
TOXICITY IRRITATION
Oral (rat) LD50: 8000 mg/kg Skin (human): 15 mg/3d (int)-mild
Oral (rat) LD50: 4920 ul/kg Skin (rabbit): 560 mg/24 hr- mild
Oral (rat) LD50: 5560 mg/kg (calc.) Eye (rabbit): 5.62 mg - SEVERE
Oral (rat) LD50: 4.92 ml/kg (female) * Eye (rabbit): 10 mg - mild
Oral (rat) LD50: 8.57 ml/kg (male) * Eye (rabbit): 0.1 ml -
Dermal (rat) LD50: >16000 mg/kg minor iritis,
Dermal (rabbit) LD50: 16 ml/kg * minor conjunctival irritation
Intraperitoneal (rat) LD50: 1510 mg/kg Skin (rabbit): 4 h occluded
Oral (mouse) LD50: 5846 mg/kg no irritation *
Intraperitoneal (mouse) LD50: 1450 mg/kg
Oral (rabbit) LD50: 2200 mg/kg
Dermal (rabbit) LD50: >20000 mg/kg
Oral (g.pig) LD50: 2200 mg/kg
(occluded, male or female) with significant discharge;
Kill rate 1/5 * no corneal injury *
Lachrymation, diarrhoea, convulsions, urinary tract changes, changes in
bladder weight, changes in testicular weight, changes in thymus weight,
changes in liver weight, dermatitis after systemic exposure, kidney,
ureter, bladder tumours recorded.
Equivocal tumourigen by RTECS criteria.
* Union Carbide
The substance is classified by IARC as Group 3:
NOT classifiable as to its carcinogenicity to humans.
Evidence of carcinogenicity may be inadequate or limited in animal testing.
NOTE: Substance has been shown to be mutagenic in at least one assay, or belongs
to a family of chemicals producing damage or change to cellular DNA.
Limited evidence of a carcinogenic effect*.

EDTA TETRASODIUM SALT:

continued...
GENERAL HARDNESS (GH) TEST SOLUTION
Chemwatch Material Safety Data Sheet CHEMWATCH 4650-37
Issue Date: Tue 4-Oct-2005 CD 2005/3 Page 12 of 16
Section 11 - TOXICOLOGICAL INFORMATION

TOXICITY IRRITATION
Oral (rat) LD50: 2000-3200 mg/kg* Skin (rabbit):500 mg/24h-Moderate
Eyes (rabbit): 1.9 mg
Eyes (rabbit):100 mg/24h-Moderate
*[BASF]

WATER:
TOXICITY IRRITATION
No significant acute toxicological data identified in literature search.


Section 12 - ECOLOGICAL INFORMATION

DO NOT discharge into sewer or waterways.
Refer to data for ingredients, which follows:

TRIETHANOLAMINE:
Fish LC50 (96hr.) (mg/l): 3500 (24hr
Daphnia magna EC50 (48hr.) (mg/l): 2.5
Algae IC50 (72hr.) (mg/l): 1.8-47
log Kow (Sangster 1997): -1
log Pow (Verschueren 1983): 0.75428571
BOD20: 6.20%
ThOD: 2.04

log Kow : -1.32- -1.75
Koc : 3
Half-life (hr) air :4
Henry's atm m?/mol: 3.38E-19
BOD 5 if unstated: nil-0.17
COD : 1.5
ThOD : 2.04; 1.61 p/p
ThOD (measured) 1.52 mg/mg (Union Carbide)
ThOD (calculated) 1.61 mg/mg (Union Carbide)
BCF : <1
Biodegradability:
96% DOC reduction (OECD Method 301E)
BOD
Day 5: 8%
Day 10: 9%
Day 20: 66%
Passes Sturm, AFNOR tests for biodegradability.
Reaches more than 70% mineralisation in OECD test for inherent
biodegradability (Zahn-Wellens test)
Theoretical oxygen demand ThOD) is calculated at 1.61 p/p. Degradation is
expected in the atmospheric environment within minutes to hours.
Material is practically non-toxic to aquatic organisms on an acute basis
(LC50 >100 mg/l in most sensitive species)
Fish LC50 (96 h): fathead minnow (Pimephales promelas) 1800-11800 mg/l
fathead minnow 5600 mg/l (Union Carbide)
bluegill (Leuciscus idus) 7930 mg/l
goldfish (Carrassius auratus) 5000 mg/l
Daphnia magna LC50 (24 h): 1390 - 2038 mg/l
Daphnia magna LC50 (48 h): 947 mg/l (Union Carbide)
Algae LC50 (48 h): 750 mg/l
Brine shrimp LC50: (Artemia salina) 5600 mg/l

continued...
GENERAL HARDNESS (GH) TEST SOLUTION
Chemwatch Material Safety Data Sheet CHEMWATCH 4650-37
Issue Date: Tue 4-Oct-2005 CD 2005/3 Page 13 of 16
Section 12 - ECOLOGICAL INFORMATION

Maximum aceeptable toxicant concentration (MATC): 22 mg/l
Algal growth inhibition (Scenedesmus subspicatus) EC50: 470-750 mg/l
Inhibition of bacteria in effluent: 50% inhibition: >10000 mg/l
Inhibitory concentration (IC50) is OECD "Activated Sludge, Respiration
Inhibition Test" (Guideline 209) is >1000 mg/l. Material has shown a
potential to biodegrade. Attains >99% degradation in activated sludge in
24 hours. Attains >99% degradation in soil is 1-14 days.
Bioconcentration potential is low (BCF less than 100 or log Kow less
than 3). Log octanol/ water partition coefficient (log Kow) is estimated
using the Pomona-Medchem structural fragment to be -1.746. Potential for
the mobility in soil is very high (Koc betweeen 0 and 50).
Henry's Law Constant (H) is estimated to be 3.38E-19 atm.m?mol (25 C)
Log soil organic carbon partition coefficient (log Koc) is estimated to be
0.48.
When released into soil the material is expected to degrade without
significant evaporation. A half-life of between 1 to 10 days is expected.
When released into water, the material is expected to degrade with a
half-life of about 1 to 10 days. Beacuse the material has a log
octanol-water coefficient of less than 3 it is not expected to
bioaccumulate. Release to air is expected to produce photolytic
degradation resulting in hydroxyl radicals. The material is expected to be
removed from the atmosphere by dry and wet deposition (half-life between
1 and 10 days).

EDTA TETRASODIUM SALT:
Not readily biodegradable. Harmful to aquatic organisms.
May cause long term adverse effects in the aquatic environment. [ORICA]
Toxicity to fish: LC50 (96h): >500 mg/l (Leuciscus idus)
Toxicity to daphnae (acute): EC50 (48h): >100 mg/l
Toxicity to algae EC50 (72h): 10-100 mg/l
COD Value: 570 mg O2/g
BOD5-Value: 20 mg O2/g
Toxicity to bacteria: 50 mg/l Warburg test


Section 13 - DISPOSAL CONSIDERATIONS


Disposal Instructions
All waste must be handled in accordance with local, state and federal
regulations.
- Recycle wherever possible.
- Consult manufacturer for recycling options or consult Waste Management
Authority for disposal if no suitable treatment or disposal facility can be
identified.
- Dispose of by: Burial in a licensed land-fill or Incineration in a licensed
apparatus (after admixture with suitable combustible material)
- Decontaminate empty containers. Observe all label safeguards until containers
are cleaned and destroyed.
Puncture containers to prevent re-use and bury at an authorized landfill.




continued...
GENERAL HARDNESS (GH) TEST SOLUTION
Chemwatch Material Safety Data Sheet CHEMWATCH 4650-37
Issue Date: Tue 4-Oct-2005 CD 2005/3 Page 14 of 16


Section 14 - TRANSPORTATION INFORMATION

DOT Information
Shipping Name: None
Hazard Class: None
SubRisk: None
UN/NA Number: None
Packing Group: None
Additional Shipping Information:
International Transport Regulations:
IMO: None


Section 15 - REGULATORY INFORMATION




RISK
Harmful by inhalation, in contact with skin and if swallowed.
Irritating to eyes.

US Federal Regulations
A. General Product Information
In addition to Federal and State regulation, local regulations may
apply. Check with your local regulatory authorities.


B. Component Information
This material contains one or more of the following chemicals required
to be identified under SARA Section 302 (40 CFR 455 Appendix A)
SARA Section 313 (40 CFR 372.65) and/or CERCLA (40 CFR 302.4): None
-------------------------------------------------------------------

Component TSCA
triethanolamine Y
EDTA tetrasodium salt Y

State Regulations
A. General Product Information

B. Component Information
The following components appear on one or more of the following state
hazardous substance lists.

Component CAS No CA FL MA MN NJ PA
triethanolamine 102-71-6 N Y Y Y N Y
EDTA tetrasodium salt 64-02-8 N N N N N N
Y=Yes this material appears on that state's hazardous substances list.
N=No this material does not appear on that state's hazardous substances list.

continued...
GENERAL HARDNESS (GH) TEST SOLUTION
Chemwatch Material Safety Data Sheet CHEMWATCH 4650-37
Issue Date: Tue 4-Oct-2005 CD 2005/3 Page 15 of 16
Section 15 - REGULATORY INFORMATION

Other Regulations
A. General Product Information
All components are listed in the European Inventory of New and
Existing Chemical Substances (EINECS)
B. Component Information
CANADA
The following component(s) are identified under the Canadian
Hazardous Products Act Ingredient Disclosure List:

Component CAS No % Min Conc.
triethanolamine 102-71-6 10-30 1% item 1621 (1663)
All of this product's components are on the Canadian Domestic
.

REGULATIONS
triethanolamine (CAS: 102-71-6) is found on the following regulatory lists
Canadian Domestic Substances List (DSL)
US Toxic Substances Control Act (TSCA)
US TSCA Section 8 (d) - Health and Safety Data Reporting
US EPA Other (Inert) Pesticide Ingredients in Pesticide Products, List 2:
Potentially Toxic Other Ingredients/High Priority for Testing inerts
US Minnesota Hazardous Substance List
US EPA High Production Volume Program Chemical List
Canadian Ingredient Disclosure List (SOR/88-64)
US DOE Temporary Emergency Exposure Limits (TEELs)
US Food Additive Database
Canada Saskatchewan Occupational Health and Safety Regulations - Contamination
Limits
US California OEHHA/ARB - Acute Reference Exposure Levels and Target Organs
(RELs) - Respiratory

EDTA tetrasodium salt (CAS: 64-02-8) is found on the following regulatory lists
Canadian Domestic Substances List (DSL)
US Toxic Substances Control Act (TSCA)
US EPA High Production Volume Program Chemical List
US DOE Temporary Emergency Exposure Limits (TEELs)
US Food Additive Database
US California OEHHA/ARB - Acute Reference Exposure Levels and Target Organs
(RELs) - Respiratory
EDTA tetrasodium salt (CAS: 10378-23-1) is found on the following regulatory
lists
US DOE Temporary Emergency Exposure Limits (TEELs)
US California OEHHA/ARB - Acute Reference Exposure Levels and Target Organs
(RELs) - Respiratory

water (CAS: 7732-18-5) is found on the following regulatory lists
Canadian Domestic Substances List (DSL)
US Toxic Substances Control Act (TSCA)
US DOE Temporary Emergency Exposure Limits (TEELs)
US Californian Proposition 65 - Priority List for the Development of MADLs for
Chemicals Causing Reproductive Toxicity

No data available for EDTA tetrasodium salt as CAS: 13235-36-4.




continued...
GENERAL HARDNESS (GH) TEST SOLUTION
Chemwatch Material Safety Data Sheet CHEMWATCH 4650-37
Issue Date: Tue 4-Oct-2005 CD 2005/3 Page 16 of 16


Section 16 - OTHER INFORMATION

Reasonable care has been taken in the preparation of this information, but the
author makes no warranty of merchantability or any other warranty, expressed or
implied, with respect to this information. The author makes no representations
and assumes no liability for any direct, incidental or consequential damages
resulting from its use. For additional technical information please call our
toxicology department on +800 CHEMCALL.

Issue Date: Tue 4-Oct-2005
Print Date: Thu 6-Oct-2005

This document is copyright. Apart from any fair dealing for the purposes of
private study, research, review or criticism, as permitted under the Copyright
Act, no part may be reproduced by any process without written permission from
CHEMWATCH. TEL (+61 3) 9572 4700.
CARBONATE HARDNESS (KH) TEST SOLUTION
Chemwatch Material Safety Data Sheet CHEMWATCH 4650-3
Issue Date: Mon 3-Oct-2005 CD 2005/3 Page 1 of 7



Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION


PRODUCT NAME
CARBONATE HARDNESS (KH) TEST SOLUTION

STATEMENT OF HAZARDOUS NATURE
Not considered a hazardous substance according to OSHA 29
CFR 1910.1200.

SUPPLIER
Company: Aquarium Pharmaceuticals Incorporated Company: Aquarium Pharmaceuticals Incorporated
Address: Address:
50 East Hamilton Street PO Box 218
Chalfont Chalfont
PA, 18914 PA, 18914-0218
USA USA
Telephone: +1 215 822 8181 Telephone: +1 215 822 8181
Emergency Tel: +1800 222 1222 (US Only)


PRODUCT USE
Test solution for products 34P, 58 and 59.

SYNONYMS
"Solution ID# 3339"


Section 2 - COMPOSITION / INFORMATION ON INGREDIENTS

NAME CAS RN %
non hazardous ingredients 100


Section 3 - HAZARDS IDENTIFICATION


CANADIAN WHMIS SYMBOLS
None

EMERGENCY OVERVIEW

RISK

POTENTIAL HEALTH EFFECTS

ACUTE HEALTH EFFECTS


SWALLOWED
The material has NOT been classified as "harmful by ingestion". This is because
of the lack of corroborating animal or human evidence. The material may still be
damaging to the health of the individual, following ingestion, especially where
pre-existing organ (e.g. liver, kidney) damage is evident. Present definitions
of harmful or toxic substances are generally based on doses producing mortality

continued...
CARBONATE HARDNESS (KH) TEST SOLUTION
Chemwatch Material Safety Data Sheet CHEMWATCH 4650-3
Issue Date: Mon 3-Oct-2005 CD 2005/3 Page 2 of 7
Section 3 - HAZARDS IDENTIFICATION

(death) rather than those producing morbidity (disease, ill-health).
Gastrointestinal tract discomfort may produce nausea and vomiting. In an
occupational setting however, unintentional ingestion is not thought to be cause
for concern.

EYE
Although the liquid is not thought to be an irritant, direct contact with the
eye may produce transient discomfort characterized by tearing or conjunctival
redness (as with windburn).

SKIN
The material is not thought to produce adverse health effects or skin irritation
following contact (as classified using animal models). Nevertheless, good
hygiene practice requires that exposure be kept to a minimum and that suitable
gloves be used in an occupational setting.

INHALED
The material is not thought to produce adverse health effects or irritation of
the respiratory tract (as classified using animal models). Nevertheless, good
hygiene practice requires that exposure be kept to a minimum and that suitable
control measures be used in an occupational setting.

CHRONIC HEALTH EFFECTS
Long-term exposure to the product is not thought to produce chronic effects
adverse to the health (as classified using animal models); nevertheless exposure
by all routes should be minimized as a matter of course.


Section 4 - FIRST AID MEASURES


SWALLOWED
- Immediately give a glass of water.
- First aid is not generally required. If in doubt, contact a Poisons
Information Center or a doctor.

EYE
If this product comes in contact with eyes:
- Wash out immediately with water.
- If irritation continues, seek medical attention.
- Removal of contact lenses after an eye injury should only be undertaken by
skilled personnel.

SKIN
If skin or hair contact occurs:
- Flush skin and hair with running water (and soap if available).
- Seek medical attention in event of irritation.

INHALED
- If fumes or combustion products are inhaled remove from contaminated area.
- Other measures are usually unnecessary.

NOTES TO PHYSICIAN
Treat symptomatically.



continued...
CARBONATE HARDNESS (KH) TEST SOLUTION
Chemwatch Material Safety Data Sheet CHEMWATCH 4650-3
Issue Date: Mon 3-Oct-2005 CD 2005/3 Page 3 of 7


Section 5 - FIRE FIGHTING MEASURES

Flash Point (癋): Not Applicable
Lower Explosive Limit (%): Not Applicable
Upper Explosive Limit (%): Not Applicable
Autoignition Temp (癋): Not Applicable

EXTINGUISHING MEDIA
- There is no restriction on the type of extinguisher which may be used.
Use extinguishing media suitable for surrounding area.

FIRE FIGHTING
- Use water delivered as a fine spray to control fire and cool adjacent area.
- DO NOT approach containers suspected to be hot.
- Cool fire exposed containers with water spray from a protected location.
- If safe to do so, remove containers from path of fire.
- Equipment should be thoroughly decontaminated after use.

GENERAL FIRE HAZARDS/HAZARDOUS COMBUSTIBLE PRODUCTS
- Non combustible.
- Not considered to be a significant fire risk.
- Expansion or decomposition on heating may lead to violent rupture of
containers.
- Decomposes on heating and may produce toxic/ irritating fumes.
- May emit acrid smoke.

FIRE INCOMPATIBILITY
None known.


Section 6 - ACCIDENTAL RELEASE MEASURES


MINOR SPILLS
- Clean up all spills immediately.
- Avoid breathing vapors and contact with skin and eyes.
- Control personal contact by using protective equipment.
- Contain and absorb spill with sand, earth, inert material or vermiculite.
- Wipe up.
- Place in a suitable labeled container for waste disposal.

MAJOR SPILLS
- Clear area of personnel and move upwind.
- Alert Emergency Responders and tell them location and nature of hazard.
- Control personal contact by using protective equipment.
- Prevent spillage from entering drains, sewers or water courses.
- Recover product wherever possible.
- Put residues in labeled containers for disposal.
- If contamination of drains or waterways occurs, advise emergency services.


ACUTE EXPOSURE GUIDELINE LEVELS (AEGL) (in ppm)


AEGL 1: The airborne concentration of a substance above which it is predicted
that the general population, including susceptible individuals, could

continued...
CARBONATE HARDNESS (KH) TEST SOLUTION
Chemwatch Material Safety Data Sheet CHEMWATCH 4650-3
Issue Date: Mon 3-Oct-2005 CD 2005/3 Page 4 of 7
Section 6 - ACCIDENTAL RELEASE MEASURES

experience notable discomfort, irritation, or certain asymptomatic nonsensory
effects. However, the effects are not disabling and are transient and
reversible upon cessation of exposure.
AEGL 2: The airborne concentration of a substance above which it is predicted
that the general population, including susceptible individuals, could
experience irreversible or other serious, long-lasting adverse health effects
or an impaired ability to escape.
AEGL 3: The airborne concentration of a substance above which it is predicted
that the general population, including susceptible individuals, could
experience life-threatening health effects or death.


Section 7 - HANDLING AND STORAGE


PROCEDURE FOR HANDLING
- Limit all unnecessary personal contact.
- Wear protective clothing when risk of exposure occurs.
- Use in a well-ventilated area.
- When handling DO NOT eat, drink or smoke.
- Always wash hands with soap and water after handling.
- Avoid physical damage to containers.
- Use good occupational work practice.
- Observe manufacturer's storing and handling recommendations.

RECOMMENDED STORAGE METHODS
- Polyethylene or polypropylene container.
- Packing as recommended by manufacturer
- Check all containers are clearly labeled and free from leaks.


STORAGE REQUIREMENTS
- Store in original containers.
- Keep containers securely sealed.
- Store in a cool, dry, well-ventilated area.
- Store away from incompatible materials and foodstuff containers.
- Protect containers against physical damage and check regularly for leaks.
- Observe manufacturer's storing and handling recommendations.
Segregate from alkalis, oxidizing agents and chemicals readily decomposed by
acids, i.e. cyanides, sulfides, carbonates.


Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION


EXPOSURE CONTROLS

Not available. Refer to individual constituents.

PERSONAL PROTECTION
Glasses:
Chemical goggles.
Gloves:
When handling larger quantities:
General purpose rubber glove.
Respirator:

continued...
CARBONATE HARDNESS (KH) TEST SOLUTION
Chemwatch Material Safety Data Sheet CHEMWATCH 4650-3
Issue Date: Mon 3-Oct-2005 CD 2005/3 Page 5 of 7
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION

EYE
- Safety glasses with side shields; or as required,
- Chemical goggles.
- Contact lenses pose a special hazard; soft lenses may absorb irritants and all
lenses concentrate them.

HANDS/FEET
Wear general protective gloves, e.g.. light weight rubber gloves.

OTHER
No special equipment needed when handling small quantities.
OTHERWISE:
- Overalls.
- Barrier cream.
- Eyewash unit.



The local concentration of material, quantity and
conditions of use determine the type of personal
protective equipment required.
Use appropriate NIOSH-certified respirator based on informed professional
judgement. In conditions where no reasonable estimate of exposure can be
made, assume the exposure is in a concentration IDLH and use NIOSH-certified
full face pressure demand SCBA with a minimum service life of 30 minutes, or
a combination full facepiece pressure demand SAR with auxiliary self-contained
air supply. Respirators provided only for escape from IDLH atmospheres shall be
NIOSH-certified for escape from the atmosphere in which they will be used.

ENGINEERING CONTROLS
General exhaust is adequate under normal operating conditions. If risk of
overexposure exists, wear an approved respirator. Correct fit is essential to
obtain adequate protection. Provide adequate ventilation in warehouse or closed
storage areas.


Section 9 - PHYSICAL AND CHEMICAL PROPERTIES


PHYSICAL PROPERTIES
Liquid.
Mixes with water.

Molecular Weight: Not Applicable Boiling Range (癈): Not Available
Melting Range (癈): Not Available Specific Gravity (water=1): 0.997 approx.
Solubility in water (g/L): Miscible pH (as supplied): 1.20-1.45
pH (1% solution): Not Available Vapor Pressure (kPa): Not Available
Volatile Component (%vol): Not Available Evaporation Rate: Not Available
Relative Vapor Density (air=1): Not Available Flash Point (癈): Not Applicable
Lower Explosive Limit (%): Not Applicable Upper Explosive Limit (%): Not Applicable
Autoignition Temp (癈): Not Applicable Decomposition Temp (癈): Not Available
State: Liquid

APPEARANCE
Reddish orange solution with no odor; mixes with water.


continued...
CARBONATE HARDNESS (KH) TEST SOLUTION
Chemwatch Material Safety Data Sheet CHEMWATCH 4650-3
Issue Date: Mon 3-Oct-2005 CD 2005/3 Page 6 of 7


Section 10 - CHEMICAL STABILITY AND REACTIVITY INFORMATION


CONDITIONS CONTRIBUTING TO INSTABILITY
- Presence of incompatible materials.
- Product is considered stable.
- Hazardous polymerization will not occur.

STORAGE INCOMPATIBILITY
Avoid contamination of water, foodstuffs, feed or seed.
Avoid storage with highly alkaline solutions.



Section 11 - TOXICOLOGICAL INFORMATION


Carbonate Hardness (KH) Test Solution
Not available. Refer to individual constituents.
unless otherwise specified data extracted from RTECS - Register of Toxic Effects
of Chemical Substances


Section 12 - ECOLOGICAL INFORMATION



Section 13 - DISPOSAL CONSIDERATIONS


Disposal Instructions
All waste must be handled in accordance with local, state and federal
regulations.
- Recycle wherever possible.
- Consult manufacturer for recycling options or consult Waste Management
Authority for disposal if no suitable treatment or disposal facility can be
identified.
- Dispose of by: Burial in a licensed land-fill or Incineration in a licensed
apparatus (after admixture with suitable combustible material)
- Decontaminate empty containers. Observe all label safeguards until containers
are cleaned and destroyed.


Section 14 - TRANSPORTATION INFORMATION

DOT Information
Shipping Name: None
Hazard Class: None
SubRisk: None
UN/NA Number: None
Packing Group: None
Additional Shipping Information:
International Transport Regulations:
IMO: None



continued...
CARBONATE HARDNESS (KH) TEST SOLUTION
Chemwatch Material Safety Data Sheet CHEMWATCH 4650-3
Issue Date: Mon 3-Oct-2005 CD 2005/3 Page 7 of 7


Section 15 - REGULATORY INFORMATION


RISK

US Federal Regulations
A. General Product Information
In addition to Federal and State regulation, local regulations may
apply. Check with your local regulatory authorities.


B. Component Information
This material contains one or more of the following chemicals required
to be identified under SARA Section 302 (40 CFR 455 Appendix A)
SARA Section 313 (40 CFR 372.65) and/or CERCLA (40 CFR 302.4): None
-------------------------------------------------------------------

Component TSCA

State Regulations
A. General Product Information

B. Component Information
The following components appear on one or more of the following state
hazardous substance lists.

Component CAS No CA FL MA MN NJ PA
Y=Yes this material appears on that state's hazardous substances list.
N=No this material does not appear on that state's hazardous substances list.

Other Regulations
A. General Product Information
All components are listed in the European Inventory of New and
Existing Chemical Substances (EINECS)
B. Component Information
CANADA
All of this product's components are on the Canadian Domestic
.


Section 16 - OTHER INFORMATION

Reasonable care has been taken in the preparation of this information, but the
author makes no warranty of merchantability or any other warranty, expressed or
implied, with respect to this information. The author makes no representations
and assumes no liability for any direct, incidental or consequential damages
resulting from its use. For additional technical information please call our
toxicology department on +800 CHEMCALL.

Issue Date: Mon 3-Oct-2005
Print Date: Thu 6-Oct-2005

This document is copyright. Apart from any fair dealing for the purposes of
private study, research, review or criticism, as permitted under the Copyright
Act, no part may be reproduced by any process without written permission from
CHEMWATCH. TEL (+61 3) 9572 4700.

Search    ENTER KEYWORD
ALL PAGES On Chemical Property IN THIS GROUP
NAMECAS
7732-18-5_75-28-5_144-55-8_102-71-6.asp 7732-18-5 75-28-5 144-55-8 102-71-6
1310-73-2_102-71-6_11138-49.asp 1310-73-2 102-71-6 11138-49-1
64-17-5_102-71-6_7732-18-5_68476-85.asp 64-17-5 102-71-6 7732-18-5 68476-85-7
12069-69-1_68424-85-1_64-17-5_141-43-5_102-71-6.asp 12069-69-1 68424-85-1 64-17-5 141-43-5 102-71-6
5989-27-5_68647-72-3_102-71-6_7631-86-9.asp 5989-27-5 68647-72-3 102-71-6 7631-86-9
138-87-4_111-42-2_102-71.asp 138-87-4 111-42-2 102-71-6
5131-66-8_34590-94-8_872-50-4_102-71-6_9043-30.asp 5131-66-8 34590-94-8 872-50-4 102-71-6 9043-30-5
8002-09-3_2807-30-9_102-71-6.asp 8002-09-3 2807-30-9 102-71-6
7732-18-5_64741-65-7_102-71-6_61790-58-2_57-11-4_31778-15-1.asp 7732-18-5 64741-65-7 102-71-6 61790-58-2 57-11-4 31778-15-1
1319-77-3_67-63-0_1310-73-2_102-71-6_120-32-1_90-43-7_56-35.asp 1319-77-3 67-63-0 1310-73-2 102-71-6 120-32-1 90-43-7 56-35-9
141-43-5_34590-94-8_7732-18-5_34398-01-1_107-98-2_102-71-6_27323-41-7.asp 141-43-5 34590-94-8 7732-18-5 34398-01-1 107-98-2 102-71-6 27323-41-7 64-02-8
77-92-9_12069-69-1_141-43-5_102-71-6_7440-50-8.asp 77-92-9 12069-69-1 141-43-5 102-71-6 7440-50-8
7732-18-5_112-34-5_102-71-6_29385-43.asp 7732-18-5 112-34-5 102-71-6 29385-43-1
n653941316.asp N/A
111-42-2_102-71-6.asp 111-42-2 102-71-6
102-71-6_1336-21-6_64-17-5_68989-01-5_124-38.asp 102-71-6 1336-21-6 64-17-5 68989-01-5 124-38-9
112-34-5_25498-49-1_68131-39-5_68439-57-6_61790-12-3_102-71-6.asp 112-34-5 25498-49-1 68131-39-5 68439-57-6 61790-12-3 102-71-6 7732-18-5
102-71-6_64-02-8_7732-18.asp 102-71-6 64-02-8 7732-18-5
64742-52-5_102-71-6_107-41.asp 64742-52-5 102-71-6 107-41-5
64-17-5_57-55-6_102-71-6_7732-18.asp 64-17-5 57-55-6 102-71-6 7732-18-5
141-43-5_102-71-6_25-59-1.asp 141-43-5 102-71-6 25-59-1
7732-18-5_102-71-6_36653-82-4_253-14-0_57-11-4_50-70-4_9004-99.asp 7732-18-5 102-71-6 36653-82-4 253-14-0 57-11-4 50-70-4 9004-99-3 63148-62-9
151-21-3_68891-38-3_8051-30-7_61789-40-0_102-71.asp 151-21-3 68891-38-3 8051-30-7 61789-40-0 102-71-6
67762-77-0_66204-44-2_8002-12-9.asp 67762-77-0 66204-44-2 8002-12-9
75-09-2_67-63-0_102-71-6_25155-50-9_7778-50-9.asp 75-09-2 67-63-0 102-71-6 25155-50-9 7778-50-9
102-71-6_67-63-0_7732-18-5_61790-12-3.asp 102-71-6 67-63-0 7732-18-5 61790-12-3
141-43-5_1330-43-4_27344-41-8_57-55-6_102-71-6_64-17-5_7732-18-5.asp 141-43-5 1330-43-4 27344-41-8 57-55-6 102-71-6 64-17-5 7732-18-5 68131-39-5 68-04-2 90194-45-9 9004-82-4
7732-18-5_122-99-6_102-71-6_28348-53-0_50-81-7.asp 7732-18-5 122-99-6 102-71-6 28348-53-0 50-81-7
9046-10-0_102-71-6_110-85-0_31326-29-1_80-05-7.asp 9046-10-0 102-71-6 110-85-0 31326-29-1 80-05-7
102-71-6.asp 102-71-6
11-28-0_102-71-6_111-42-2.asp 11-28-0 102-71-6 111-42-2
67784-80-9_110615-47-9_1643-20-5_68140-00-1_61789-40-0_68585-34.asp 67784-80-9 110615-47-9 1643-20-5 68140-00-1 61789-40-0 68585-34-2 102-71-6
102-71-6_141-43-5.asp 102-71-6 141-43-5
102-71-6_67762-90-7.asp 102-71-6 67762-90-7
102-71-6.asp 102-71-6
102-71-6_110-85-0_31326-29-1_80-05-7_9046-10.asp 102-71-6 110-85-0 31326-29-1 80-05-7 9046-10-0
102-71-6.asp 102-71-6
107-98-2_34590-94-8_5989-27-5_102-71-6_9005-64.asp 107-98-2 34590-94-8 5989-27-5 102-71-6 9005-64-5
102-71-6_111-41-1_13826-83-0_7440-31-5_1314-13-2_7440-66.asp 102-71-6 111-41-1 13826-83-0 7440-31-5 1314-13-2 7440-66-6
12069-69-1_68424-85-1_64-17-5_141-43-5_102-71-6.asp 12069-69-1 68424-85-1 64-17-5 141-43-5 102-71-6
5064-31-3_139-89-9_102-71-6_141-43-5_111-42-2_119345-04.asp 5064-31-3 139-89-9 102-71-6 141-43-5 111-42-2 119345-04-9
64-19-7_82640-05-9_7647-14-5_133986-51-3_102-71-6_7732-18.asp 64-19-7 82640-05-9 7647-14-5 133986-51-3 102-71-6 7732-18-5
627-93-0_1119-40-0_14807-96-6_57-11-4_9004-74-4_9004-34-6_1302-78.asp 627-93-0 1119-40-0 14807-96-6 57-11-4 9004-74-4 9004-34-6 1302-78-9 8006-54-0 102-71-6 8009-03-8 112945-52-5 577-11-7 5989-27-5
102-71-6.asp 102-71-6
7732-18-5_102-71-6_4080-31-3.asp 7732-18-5 102-71-6 4080-31-3
75-09-2_67-56-1.asp 75-09-2 67-56-1
34590-94-8_1330-20-7_102-71-6.asp 34590-94-8 1330-20-7 102-71-6
102-71-6_111-42-2_111-76-2_79-14-1_1300-72-7_61789-39-7.asp 102-71-6 111-42-2 111-76-2 79-14-1 1300-72-7 61789-39-7
5989-27-5_68647-72-3_102-71-6_7631-86-9.asp 5989-27-5 68647-72-3 102-71-6 7631-86-9
7791-18-6_7487-88-9_102-71-6.asp 7791-18-6 7487-88-9 102-71-6


HBCChem,Inc

Chemical Information Net chemcas.orgCopyright Reserved

Trading Lead

Leputech HPLC Laboratory