MATERIAL SAFETY DATA SHEET
Prepared to U.S. OSHA, CMA, ANSI and Canadian WHMIS Standards .This Material Safety Data Sheet is offered pursuant to OSHA's Hazard
Communication Standard (29 CFR 1910.1200). Other government regulations must be reviewed for applicability to these products.
WARNING: PRODUCT COMPONENTS PRESENT HEALTH AND SAFETY HAZARDS. READ AND UNDERSTAND THIS MATERIAL SAFETY DATA
SHEET (M.S.DS.). ALSO, FOLLOW YOUR EMPLOYER'S SAFETY PRACTICES. This product may contain Chromium and/or Nickel which are listed
by OSHA, NTP, or IARC as being a carcinogen or potential carcinogen. Use of this product may expose you or others to fumes and gases at levels
exceeding those established by the American Conference of Governmental Industrial Hygienists (ACGIH) or the Occupational Safety and Health
Administration (OSHA) The information contained herein relates only to the specific product. If the product is combined with other materials, all
component properties must be considered. BE SURE TO CONSULT THE LATEST VERSION OF THE MSDS. MATERIAL SAFETY DATA SHEETS ARE
www.harrisproductsgroup.com
salesinfo@jwharris.com 513-754-2000
AVAILABLE FROM HARRIS PRODUCTS GROUP
STATEMENT OF LIABILITY-DISCLAIMER
To the best of the Harris Products Group knowledge, the information and recommendations contained in this publication are reliable and accurate as of the
date prepared. However, accuracy, suitability, or completeness are not guaranteed, and no warranty, guarantee, or representation, expressed or implied,
is made by Harris Products Group as to the absolute correctness or sufficiency of any representation contained in this and other publications; Harris
Products Group. assumes no responsibility in connection therewith; nor can it be assumed that all acceptable safety measures are contained in this and
other publications, or that other or additional measures may not be required under particular or exceptional conditions or circumstances . Data may be
changed from time to time.
PART I What is the material and what do I need to know in an emergency?
1. PRODUCT IDENTIFICATION
STAY CLEAN?ALUMINUM FLUX
TRADE NAME (AS LABELED):
CHEMICAL NAME/CLASS: Organic Amine Mixture
SYNONYMS: Not Applicable
PRODUCT USE: Soldering Operations
DOCUMENT NUMBER: 0138
SUPPLIER/MANUFACTURER'S NAME: HARRIS PRODUCTS GROUP.
ADDRESS: 4501 Quality Place, Mason, Ohio 45140
EMERGENCY PHONE: CHEMTREC: 1-800-424-9300
BUSINESS PHONE: 513-754-2000 FAX 513-754-8778
DATE OF PREPARATION: July 12, 2007
2. COMPOSITION and INFORMATION ON INGREDIENTS
CHEMICAL NAME CAS # % w/w EXPOSURE LIMITS IN AIR
ACGIH-TLV OSHA-PEL NIOSH OTHER
TWA STEL TWA STEL IDLH
3 3 3 3 3 3
mg/m mg/m mg/m mg/m mg/m mg/m
Triethanolamine 102-71-6 30-60 5 NE NE NE NE NE
Aminoethylethanolamine 111-41-1 35 NE NE NE NE NE NE
Ammonium Fluoborate 13826-83-0 20 2.5 NE 2.5 NE 250 DFG MAKs:
TWA = 2.5
Exposure limits are for
(Inhalable
inorganic, solid Fluoride
Fraction)
compounds, as F
PEAK = 5稭AK 30
min., average
value
Carcinogen: IARC-
3, TLV-A4
Tin, Metal 7440-31-5 10 2 NE 2 NE 100 (as NIOSH REL:
Sn) TWA = 2
NE = Not Established. See Section 16 for Definitions of Terms Used. Single values are maximum, unless otherwise noted.
NOTE (1): ALL WHMIS required information is included in appropriate sections based on the ANSI Z400.1-1998 format. This product has been classified in
accordance with the hazard criteria of the CPR and the MSDS contains all the information required by the CPR.
2. COMPOSITION and INFORMATION ON INGREDIENTS (Continued)
STAY CLEAN?ALUMINUM FLUX MSDS July 2, 2004
PAGE 1 OF 9
CHEMICAL NAME CAS # % w/w EXPOSURE LIMITS IN AIR
ACGIH-TLV OSHA-PEL NIOSH OTHER
TWA STEL PEL STEL IDLH
3 3 3 3 3 3
mg/m mg/m mg/m mg/m mg/m mg/m
Zinc Oxide 5 (fume) 10 5 (fume) 10 NIOSH RELs:
1314-13-2 10 500
(fume) (fume, TWA = 5 (fume & dusts)
5 (total
Exposure limits given are 10 (dust)
Vacated STEL = 10 (fume), 15
dust)
for dust and fume.
1989 (ceiling, 15 minutes,
15 (dust,
PEL) dusts)
respirable
DFG MAKs:
dust)
TWA = 1.5 (Respirable
5 (dust, fraction, fume)
respirable Carcinogen: EPA-D
dust,
Vacated
1989 PEL)
Zinc 7440-66-6 5 5 (fume) 10 5 (fume) 10 500 NIOSH RELs:
(fume) (fume, TWA = 5 (fume & dusts)
10 (dust) 5 (total
(exposure limits are for
Vacated STEL = 10 (fume), 15
dust)
zinc oxide, fume & dust)
1989 (ceiling, 15 minutes,
15 (dust,
PEL) dusts)
respirable
DFG MAKs:
dust)
TWA = 1.5 (Respirable
5 (dust,
fraction, fume)
respirable
Carcinogen: EPA-D
dust,
Vacated
1989 PEL)
NE = Not Established. See Section 16 for Definitions of Terms Used. Single values are maximum, unless otherwise noted.
NOTE (1): ALL WHMIS required information is included in appropriate sections based on the ANSI Z400.1-1998 format. This product has been classified in
accordance with the hazard criteria of the CPR and the MSDS contains all the information required by the CPR.
3. HAZARD IDENTIFICATION
EMERGENCY OVERVIEW: This product is a viscous, amber liquid with a strong ammonia odor. This product is a
primary irritant and can be mildly to moderately irritating to contaminated tissue (depending on the concentration and
duration of contact); prolonged contact may result in tissue damage and skin sensitization. This product must be
substantially pre-heated before ignition can occur. Thermal decomposition of this product will produce toxic fumes and
vapors or zinc oxides, fluoride compounds, carbon monoxide, carbon dioxide and oxides of nitrogen and tin. This product
is not reactive. Emergency responders must wear personal protective equipment suitable for the situation to which they
are responding.
SYMPTOMS OF OVER-EXPOSURE BY ROUTE OF EXPOSURE: The most significant routes of over-exposure for this
product are inhalation of fumes generated during use and contact with skin and eyes. The symptoms of overexposure to this
product are as follows:
INHALATION: Inhalation of large amounts of particulates generated by these products during soldering operations may be
physically irritating and cause deposits of dust in nasal passages. Heating of this product during soldering operations will
result in irritating fumes from the Triethanolamine component of this product. Symptoms of exposure to these fumes may
include coughing, and irritation of throat and nose. In addition, metal fume fever can be caused by inhalation of zinc oxide
fumes formed in air from soldering or heating of zinc metal and zinc oxide. Symptoms of metal fume fever include flu-like
symptoms, metallic taste, fever, chills, cough, weakness, chest pain, muscle pain, cardiac abnormalities, and increased white
blood cell count. Damage to lungs can occur. Some workers develop a short-term resistance after continuous, repeated
exposure to zinc oxide fumes and subsequent symptoms of metal fume fever. This resistance to the effects of metal fume
fever produced by Zinc Oxide is quickly lost after short absence from exposure. Thermal decomposition of the Ammonium
Fluoborate component of this product can evolve fluoride compounds, which are potentially damaging to tissues of the
respiratory system, and in high concentration can cause hypercalcmia, a condition of excess calcium in the blood.
STAY CLEAN?ALUMINUM FLUX MSDS July 2, 2004
PAGE 2 OF 9
3. HAZARD IDENTIFICATION (Continued)
CONTACT WITH SKIN or EYES: This product is mildly to moderately
irritating to the skin. Prolonged skin contact can result in tissue damage. HAZARDOUS MATERIAL IDENTIFICATION SYSTEM
Triethanolamine, a component of this product, is a skin sensitizer. When
heated to decomposition, this product can evolve fluoride compounds,
HEALTH (BLUE) 2
which, in high concentration can cause burns, penetrating to bone.
Repeated or prolonged exposures to the flux, especially in high
concentrations, can cause allergy-like symptoms (e.g., rashes, welts) and
dermatitis (dry, red, cracked skin). If the flux enters the eyes, mild irritation
may occur and result in redness and watering. Severe contact exposures (RED) 1
FLAMMABILITY
may result in damage to the cornea and other eye tissue. Note: If the
product is heated before use, and the temperature of the heated product
will be above 37癈 (100癋); skin or eye contact with the heated product can
result in thermal burns.
REACTIVITY (YELLOW) 0
SKIN ABSORPTION: Skin absorption is not anticipated to be a
significant route of over-exposure to the components of this product;
however, thermal decomposition of this product can result in the
PROTECTIVE EQUIPMENT C/D
production of fluoride compounds, which can penetrate intact skin. In
cases of serious contamination with residue from thermal decomposition,
burns that penetrate to the bone can occur. EYES HANDS BODY
RESPIRATORY
INGESTION: If this flux is ingested, nausea, vomiting, and diarrhea may
occur (depending on the amount of the product swallowed). Severe
SEE SECTION 8 SEE SECTION 8
ingestion exposures may result in damage to the tissues of the
gastrointestinal system, shock, cardiac disturbances, vasomotor depression
(depression of the contraction and dilation of blood vessels) hypocalcemia, For routine applications.
and death.
INJECTION: Though not a likely route of occupational exposure for this See Section 16 for Definition of Ratings
product, injection of this product (via punctures or lacerations in the skin)
may cause local reddening, tissue swelling, and discomfort.
OTHER HEALTH EFFECTS: Repeated or chronic exposure to this product via inhalation and ingestion may result in
damage to the kidneys and liver (based on animal studies), due to the presence of Triethanolamine.
HEALTH EFFECTS OR RISKS FROM EXPOSURE: An Explanation in Lay Terms. Symptoms associated with over-
exposure to this product are as follows:
ACUTE: The chief acute health hazards associated with this product would be the potential for mild to moderate irritation of
contaminated skin and eyes. Prolonged contact to product or to decomposition products may cause burns and in extreme
cases, may result in fluoride poisoning (hypercalcemia). Though unlikely to occur during occupational use, ingestion of large
quantities may be fatal.
CHRONIC: Chronic skin over-exposure to this product during soldering operations may produce dermatitis (red, inflamed
skin). The product contains a skin sensitizer; repeated or prolonged exposures to the flux, especially in large quantities can
cause allergy-like symptoms (i.e., rashes, welts). Chronic overexposure to this product via ingestion or inhalation may result
in damage to the kidneys and liver. Refer to Section 11 (Toxicological Information) for additional data on the components of
this product.
TARGET ORGANS: ACUTE: Eyes, skin, respiratory system. CHRONIC: Skin, liver, kidneys, bones.
PART II What should I do if a hazardous situation occurs?
4. FIRST-AID MEASURES
Victims of chemical exposure must be taken for medical attention, if adverse health effects occur. Rescuers should be taken
for medical attention, if necessary. Take copy of label and MSDS to health professional with victim.
SKIN EXPOSURE: In the event of skin-over-exposure, rinse affected area with a soap and water solution. If skin contact
results in irritation, the minimum flushing is for 15 minutes. Victim must seek medical attention if adverse health effects
occur, or if skin contact has resulted in a thermal burn.
EYE EXPOSURE: If this product enters the eyes, open victim's eyes while under gentle running water. Use sufficient force
to open eyelids. Have victim "roll" eyes. Minimum flushing is for 15 minutes. Victim must seek medical attention if adverse
health effects occur, or if eye contact has resulted in a thermal burn.
INHALATION: If this product is inhaled, remove victim to fresh air. Have victim blow nose.
STAY CLEAN?ALUMINUM FLUX MSDS July 2, 2004
PAGE 3 OF 9
4. FIRST-AID MEASURES (Continued)
INGESTION: If this product is swallowed, CALL PHYSICIAN OR POISON CONTROL CENTER FOR MOST CURRENT
INFORMATION. DO NOT INDUCE VOMITING, unless directed by medical personnel. Have victim rinse mouth with water,
if conscious. If victim vomits naturally, position head lower than chest to prevent aspiration into the lungs. Never induce
vomiting or give diluents (milk or water) to someone who is unconscious, having convulsions, or who cannot swallow.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Skin disorders and other conditions of the Target Organs (see
Section 3, Hazard Identification) may be aggravated by prolonged over-exposures to this product.
RECOMMENDATIONS TO PHYSICIANS: Treat symptoms and eliminate overexposure. If exposure has resulted in
hypercalcemia, treatment with calcium gluconate should be administered.
5. FIRE-FIGHTING MEASURES
FLASH POINT (Closed Cup): 179-185癈 (354-365癋) [for Triethanolamine]
NFPA RATING
AUTOIGNITION TEMPERATURE: Not determined.
FLAMMABLE LIMITS (in air by volume, %): FLAMMABILITY
Lower (LEL): Not applicable.
Upper (UEL): Not applicable.
1
FIRE EXTINGUISHING MATERIALS:
Water Spray: YES (for cooling) Carbon Dioxide: YES 0
2
HEALTH REACTIVITY
Halon: YES Foam: YES
Dry Chemical: YES Other: Any "ABC" Class.
UNUSUAL FIRE AND EXPLOSION HAZARDS: This product is a primary
irritant and presents a potential contact hazard to firefighters. This product must
OTHER
be substantially preheated before ignition can occur. During a fire, irritating
and toxic gases (i.e. carbon monoxide, carbon dioxide, fluoride and zinc See Section 16 for
compounds, oxides of tin and nitrogen) may be generated. Definition of Ratings
Explosion Sensitivity to Mechanical Impact: Not sensitive.
Explosion Sensitivity to Static Discharge: Not sensitive.
SPECIAL FIRE-FIGHTING PROCEDURES: Incipient fire responders should wear eye protection. Structural firefighters
must wear Self-Contained Breathing Apparatus and full protective equipment. Move fire-exposed containers if it can be done
without risk to firefighters. If possible, firefighters should control run-off water to prevent environmental contamination. Rinse
contaminated equipment with soapy water before returning such equipment to service.
6. ACCIDENTAL RELEASE MEASURES
SPILL AND LEAK RESPONSE: Uncontrolled releases should be responded to by trained personnel using pre-planned
procedures. Proper protective equipment should be used. In case of a large, uncontrolled release, clear the affected area
and protect people. In the event of a non-incidental release of this product, minimum Personal Protective Equipment should
be Level D: gloves (rubber gloves over latex gloves), safety goggles, face-shield, and appropriate body protection.
Level C (which includes an air-Purifying Respirator with an organic vapor cartridge) should be worn in the event
excessive splashes or sprays will be generated. Level B Protection (which includes Self-Contained Breathing
Apparatus) during spill response situations in which the oxygen level is below 19.5% or is unknown. Absorb spilled
flux with polypads or other suitable absorbent. Rinse residue with soap and water solution. If the heated product has been
spilled, allow the material to cool before clean-up procedures begin. Decontaminate the area thoroughly. Place all spilled
residues in a suitable container and seal. DO NOT STORE THIS PRODUCT IN GLASS, OR EXPOSE IT TO OTHER
SILICATE BASED MATERIAL. Dispose of in accordance with U.S. Federal, State, and local hazardous waste disposal
regulations, or the appropriate Standards of Canada and its Provinces (see Section 13, Disposal Considerations).
PART III How can I prevent hazardous situations from occurring?
7. HANDLING and STORAGE
WORK PRACTICES AND HYGIENE PRACTICES: As with all chemicals, avoid getting this product ON YOU or IN YOU.
Wash thoroughly after using this product. Do not eat, drink, smoke, or apply cosmetics while handling this product.
STORAGE AND HANDLING PRACTICES: All employees who handle this material should be trained to handle it safely.
Standard safety practices associated with soldering operations should be followed when using this product. Open
containers slowly, on a stable surface. Avoid the accidental exposure of this material to open flames, hot surfaces, or other
sources of ignition. (continued on following page)
STAY CLEAN?ALUMINUM FLUX MSDS July 2, 2004
PAGE 4 OF 9
7. HANDLING and STORAGE (Continued)
STORAGE AND HANDLING PRACTICES (continued): Store this product in a cool, dry location, away from direct sunlight,
sources of intense heat, or where freezing is possible. This product should not be stored in glass or other silicate-based
containers, due to the presence of Ammonium Fluoborate. Store away from incompatible chemicals (see Section 10,
Stability and Reactivity). Keep container tightly closed when not in use. Inspect all incoming containers before storage to
ensure they are properly labeled and not damaged.
8. EXPOSURE CONTROLS - PERSONAL PROTECTION
VENTILATION AND ENGINEERING CONTROLS: No special ventilation systems or engineering controls are normally
required when using this product. Prudent practice is to ensure eyewash/safety shower stations are available near areas
where this product is used.
RESPIRATORY PROTECTION: No respiratory protection is normally required when using this product. Maintain airborne
contaminant concentrations below guidelines listed in Section 2 (Composition and Information on Ingredients), if applicable If
respiratory protection is needed, U.S. Federal OSHA Standard (29 CFR 1910.134), applicable U.S. State regulations, or the
Canadian CSA Standard Z94.4-93 and applicable standards of Canadian Provinces. Respiratory Protection is
recommended to be worn during welding operations. Oxygen levels below 19.5% are considered IDLH by OSHA. In such
atmospheres, use of a full-facepiece pressure/demand SCBA or a full facepiece, supplied air respirator with auxiliary self-
contained air supply is required under OSHA's Respiratory Protection Standard (1910.134-1998).For additional information
the NIOSH recommended respiratory protection guidelines for Ammonium Fluoborate (as Fluoride Compounds) are
provided, as follows:
CONCENTRATION RESPIRATORY PROTECTION
Up to 12.5 mg/m3: Dust and mist respirator.
Up to 25 mg/m3: Dust and mist respirator except single-use and quarter-mask respirator; or SAR
Up to 62.5 mg/m3: SAR operated in a continuous-flow mode; or powered air- purifying respirator with dust and mist filters.
UP TO 125 mg/m3: Full-facepiece respirator with high-efficiency particulate filter(s); or full-facepiece
SCBA; or full-facepiece SAR. UP TO 250 mg/m3: Positive pressure, full-facepiece SAR.
Emergency or Planned Entry into Unknown Concentrations or IDLH Conditions: Positive pressure, full-facepiece SCBA; or
positive pressure, full-facepiece SAR with an auxiliary positive pressure SCBA. .
Escape: Full-facepiece respirator with high-efficiency particulate filter; or escape-type SCBA.
EYE PROTECTION: Safety glasses or goggles. In the event, the heated product is used, or operations involve potential
splashes and sprays, a face-shield is recommended. If necessary, refer to U.S. OSHA 29 CFR 1910.133, or appropriate
Canadian Standards. If necessary, refer to U.S. OSHA 29 CFR 1910.138, or appropriate Standards of Canada.
HAND PROTECTION: Wear butyl rubber, nitrile rubber, or polyfluorinated polyethylene gloves for routine industrial use. If
necessary, refer to U.S. OSHA 29 CFR 1910.138, or appropriate Standards of Canada.
BODY PROTECTION: None normally needed for normal circumstances of use. Use body protection appropriate for task
(i.e. apron, coveralls, chemically resistant boots). If a hazard of injury to the feet exists due to falling objects, rolling objects,
where objects may pierce the soles of the feet or where employee's feet may be exposed to electrical hazards, use foot
protection, as described in U.S. OSHA 29 CFR 1910.136.
9. PHYSICAL and CHEMICAL PROPERTIES
RELATIVE VAPOR DENSITY (air = 1): > 1.0 EVAPORATION RATE (nBuAc = 1): > 1
SPECIFIC GRAVITY (water = 1): Not established. FREEZING/MELTING POINT: Not established.
SOLUBILITY IN WATER: Complete solubility. BOILING POINT: Not established.
VAPOR PRESSURE, mm Hg @ 24癈: Not applicable. pH: Not applicable.
ODOR THRESHOLD: Not applicable.
COEFFICIENT OF OIL/WATER DISTRIBUTION (PARTITION COEFFICIENT): Not applicable.
APPEARANCE AND COLOR: This product is a viscous, amber liquid with a strong ammonia odor.
HOW TO DETECT THIS SUBSTANCE (warning properties): The appearance and odor may act as distinguishing
characteristics of this product in event of accidental release.
10. STABILITY and REACTIVITY
STABILITY: Stable.
DECOMPOSITION PRODUCTS: Carbon oxides, a variety organic molecules, tin compounds, zinc oxides, nitrogen oxides
and ammonia.
MATERIALS WITH WHICH SUBSTANCE IS INCOMPATIBLE: This product is not compatible with strong oxidizing agents,
strong acids, and strong bases. Due to the presence of Ammonium Fluoborate, this product is incompatible with glass or
other silicate-based substances.
HAZARDOUS POLYMERIZATION: Will not occur.
CONDITIONS TO AVOID: Avoid exposing this product to incompatible materials.
STAY CLEAN?ALUMINUM FLUX MSDS July 2, 2004
PAGE 5 OF 9
PART IV Is there any other useful information about this material?
11. TOXICOLOGICAL INFORMATION
TOXICITY DATA: The following human toxicological data are available for the components of this product. Other data for
animals are available but are not presented in this Material Safety Data Sheet.
ZINC: ZINC OXIDE:
Skin Irritancy (human) = 300 mg/ 3 days/ intermittent; mild LDLo (oral, human) = 500 mg/kg
3 3
TCLo (inhalation, human) = 124 mg/m / 50 minutes; pulmonary system TCLo (inhalation, human) = 6000 mg/m ; pulmonary system effects
effects, skin
SUSPECTED CANCER AGENT: The components of this product are listed as follows:
AMMONIUM FLUORBORATE (as a Barium Compound): EPA-D (Not Classifiable as to Human Carcinogenicity); EPA-NL (Not Likely to be Carcinogenic
in Humans); ACGIH TLV-A4 (Not Classifiable as a Human Carcinogen)
ZINC: EPA-D (Not Classifiable as to Human Carcinogenicity (inadequate human and animal evidence of carcinogenicity or no data available)
ZINC OXIDE: EPA-D (Not Classifiable as to Human Carcinogenicity (inadequate human and animal evidence of carcinogenicity or no data available)
The other components of this product are not found on the following lists: FEDERAL OSHA Z LIST, NTP, CAL/OSHA, and
therefore are not considered to be, nor suspected to be, cancer-causing agents by these agencies.
IRRITANCY OF PRODUCT: This product is mildly to moderately irritating to contaminated tissue.
SENSITIZATION TO THE PRODUCT: The Triethanolamine component of the product is a skin sensitizer; subsequent
contact with very small amounts of this product may result in allergic reaction in susceptible individuals, causing symptoms
such as rashes, redness and welts.
REPRODUCTIVE TOXICITY INFORMATION: Listed below is information concerning the effects of this product and its
components are on the human reproductive system.
Mutagenicity: This product is not reported to produce mutagenic effects in humans.
Embryotoxicity This product is not reported to produce embryotoxic effects in humans.
Teratogenicity: This product is not reported to cause teratogenic effects in humans.
Reproductive Toxicity: This product is not reported to cause reproductive effects in humans.
A mutagen is a chemical, which causes permanent changes to genetic material (DNA) such that the changes will propagate
through generational lines. An embryotoxin is a chemical, which causes damage to a developing embryo (i.e. within the first eight
weeks of pregnancy in humans), but the damage does not propagate across generational lines. A teratogen is a chemical, which
causes damage to a developing fetus, but the damage does not propagate across generational lines. A reproductive toxin is
any substance, which interferes in any way with the reproductive process.
ACGIH BIOLOGICAL EXPOSURE INDICES: Currently, there is an ACGIH Biological Exposure Index (BEIs) determined for
Ammonium Fluoborate (as a fluoride).
CHEMICAL DETERMINANT SAMPLING TIME BEI
FLUORIDES
?Fluorides in urine ?Prior to shift ?3 mg/g creatinine
?End of shift ?10 mg/g creatinine
12. ECOLOGICAL INFORMATION
ALL WORK PRACTICES MUST BE AIMED AT ELIMINATING ENVIRONMENTAL CONTAMINATION.
ENVIRONMENTAL STABILITY: Metal components of this product will react with water and air to form a variety of stable
metal oxides. Environmental data are available for the components of this product as follows:
AMINOETHYLETHANOLAMINE: KOW = -1.39 (est.). Water Solubility: Miscible. BOD > 30%, 2 weeks. BCF = 0.05 (est). Aminoethylethananolamine
does not bioconcentrate significantly in most aquatic organisms. Aminoethylethanolamine should be readily degraded by natural bacteria.
AMMONIUM FLUOBORATE: Water Solubility: 25 g/100 cc at 16癈; 97 g/100 cc at 100癈; 23.592 lb/100 lb at 80癈. BOD > 30%, 2 weeks. BCF = 0.05
(est). Ammonium Fluoborate compounds are biodegradable and will not accumulate in the food chain.
ZINC: Solubility: Insoluble in water. Biological Half-Life for normal humans 162-500 days. Bioconcentration: The Bioconcentration Factor in edible
portions of Crassostrea virgina, adult oyster) is 16,700 (total zinc).
EFFECT OF MATERIAL ON PLANTS or ANIMALS: This product may be harmful to plant and animals, depending on the
quantity and duration of over-exposure.
EFFECT OF CHEMICAL ON AQUATIC LIFE: This product may be harmful to aquatic lifeforms, depending on the quantity
and duration of over-exposure. The following aquatic toxicity data are available for the components of this product:
AMMONIUM FLUOBORATE: ZINC:
TLM (Mosquito fish) = 500 ppm/ 96 hours Odorless zinc poisoning causes inflamed gills in fish. Laboratory studies of
Atlantic salmon, rainbow trout, carp, and goldfish have shown avoidance
reactions by these fish to zinc in water.
STAY CLEAN?ALUMINUM FLUX MSDS July 2, 2004
PAGE 6 OF 9
13. DISPOSAL CONSIDERATIONS
PREPARING WASTES FOR DISPOSAL: Waste disposal must be in accordance with appropriate U.S. Federal, State, and
local regulations, or the appropriate standards of Canada and its Provinces. This product, if unaltered by use, may be
disposed of by treatment at a permitted facility or as advised by your local hazardous waste regulatory authority.
U.S. EPA WASTE NUMBER: Wastes of this product should be tested for D002 (Characteristic/Corrosivity).
14. TRANSPORTATION INFORMATION
THIS PRODUCT IS HAZARDOUS (Per 49 CFR 172.101) BY THE U.S. DEPARTMENT OF TRANSPORTATION.
PROPER SHIPPING NAME: Corrosive liquids, n.o.s.(Aminoethylethanolamine, Ammonium Fluoborate)
HAZARD CLASS NUMBER and DESCRIPTION: 8 (Corrosive)
UN IDENTIFICATION NUMBER: UN 1760
PACKING GROUP: PG III
DOT LABEL(S) REQUIRED: 8 (Corrosive)
NOTE: Consumer commodity shipments of this product 1-gallon or less in volume may be renamed "Consumer
Commodity" and reclassed as ORM-D material. Refer to 49 CFR 173.154(c) for additional information.
NORTH AMERICAN EMERGENCY RESPONSE GUIDEBOOK NUMBER, 2000: 154
MARINE POLLUTANT: The components of this product are not designated by the Department of Transportation to be
Marine Pollutants (49 CFR 172.101, Appendix B).
TRANSPORT CANADA TRANSPORTATION OF DANGEROUS GOODS REGULATIONS: This product is considered as
dangerous goods, per regulations of Transport Canada. Use the above U.S. DOT information for the preparation of
Canadian Shipments.
15. REGULATORY INFORMATION
ADDITIONAL U.S. REGULATIONS:
U.S. SARA REPORTING REQUIREMENTS: The components of this product are subject to the reporting requirements of
Sections 302, 304, and 313 of Title III of the Superfund Amendments and Reauthorization Act, and are listed as follows:
CHEMICAL NAME SARA 302 SARA 304 SARA 313
(40 CFR 355, Appendix A) (40 CFR Table 302.4) (40 CFR 372.65)
Ammonium Fluoborate NO YES NO
Zinc NO YES YES (fume or dust)
Zinc Oxide NO NO YES (as Zinc Compound)
U.S. SARA THRESHOLD PLANNING QUANTITY: There are no specific Threshold Planning Quantities for the components
of this product. The default Federal MSDS submission and inventory requirement filing threshold of 10,000 lbs (4,540 kg)
therefore applies, per 40 CFR 370.20.
U.S. CERCLA REPORTABLE QUANTITY (RQ): Ammonium Fluoborate = 5000 lb (2270 kg); Zinc = 1000 lb (454 kg)
(Applicable only to particles of zinc which are 100 micrometers in diameter or less)
U.S. TSCA INVENTORY STATUS: The components of this product are listed on the TSCA Inventory.
OTHER U.S. FEDERAL REGULATIONS: Not applicable.
U.S. STATE REGULATORY INFORMATION: Components of this product are covered under specific State regulations, as
denoted below:
Alaska-Designated Toxic and Hazardous Michigan - Critical Materials Register: Zinc. Pennsylvania-Hazardous Substance List: Zinc,
Tin, Aminoethylethanolamine,
Substances: No. Minnesota-List of Hazardous Substances: Tin.
Triethanolamine.
California-Permissible Exposure Limits for Missouri-Employer Information/Toxic
Rhode Island-Hazardous Substance List: Zinc,
Chemical Contaminants: Tin. Substance List: Tin.
Tin, Triethanolamine.
Florida-Substance List: Zinc, Tin, (2- New Jersey-Right to Know Hazardous
Texas-Hazardous Substance List: No.
aminoethyl) ethanolamine, Triethanolamine. Substance List: Zinc, Tin,
West Virginia-Hazardous Substance List:
Illinois-Toxic Substance List: Zinc, Tin, Aminoethylethanolamine.
Ammonium Fluoborate.
Ammonium Fluoborate. North Dakota-List of Hazardous Chemicals,
Wisconsin-Toxic and Hazardous Substances:
Kansas-Section 302/313 List: Zinc. Reportable Quantities: Zinc, Ammonium
Ammonium Fluoborate.
Massachusetts-Substance List: Zinc, Tin, (2- Fluoborate.
aminoethyl) ethanolamine, Triethanolamine.
CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT (PROPOSITION 65): No component of this
product is on the California Proposition 65 lists. The State of California requires the following information: WARNING: This
product may contain chemicals, and when used may produce fumes or gases containing chemicals, known to the State of
California to cause cancer, and/or birth defects (or other reproductive harm.)
STAY CLEAN?ALUMINUM FLUX MSDS July 2, 2004
PAGE 7 OF 9
15. REGULATORY INFORMATION (Continued)
ADDITIONAL CANADIAN REGULATIONS:
CANADIAN DSL/NDSL INVENTORY STATUS: The components of this product are on the DSL Inventory.
OTHER CANADIAN REGULATIONS: Not applicable.
CANADIAN ENVIRONMENTAL PROTECTION ACT (CEPA) PRIORITIES SUBSTANCES LISTS: Ammonium Fluoborate
(as an Inorganic Fluoride) is classified as Toxic on the CEPA First Priorities Substance Lists.
CANADIAN WHMIS SYMBOLS: Class E: Corrosive Material
Class D2B: Other Toxic Effects-Sensitization
16. OTHER INFORMATION
PREPARED BY: CHEMICAL SAFETY ASSOCIATES, Inc.
9163 Chesapeake Drive, San Diego, CA 92123-1002
858/565-0302
DATE OF PRINTING: July 13, 2007
This Material Safety Data Sheet is offered pursuant to OSHA's Hazard Communication Standard (29 CFR 1910.1200). Other government regulations
must be reviewed for applicability to this product. The information contained herein relates only to the specific product. If the product is combined with
other materials, all component properties must be considered. To the best of the Harris Products Group knowledge, the information and
recommendations contained in this publication are reliable and accurate as of the date of issue. However, accuracy, suitability, or completeness are not
guaranteed, and no warranty, guarantee, or representation, expressed or implied, is made by Harris Products Group. as to the absolute correctness or
sufficiency of any representation contained in this and other publications Harris Products Group. assumes no responsibility in connection therewith; nor
can it be assumed that all acceptable safety measures may not be required under particular or exceptional conditions or circumstances. Data may be
changed from time to time. Be sure to consult the latest edition.
STAY CLEAN?ALUMINUM FLUX MSDS July 2, 2004
PAGE 8 OF 9
DEFINITIONS OF TERMS
A large number of abbreviations and acronyms appear on a MSDS. Some of these, which are commonly used, include the following:
CAS #: This is the Chemical Abstract Service Number, which uniquely identifies each constituent.
EXPOSURE LIMITS IN AIR: FLAMMABILITY LIMITS IN AIR:
Much of the information related to fire and explosion is derived from the
ACGIH - American Conference of Governmental Industrial Hygienists, a
National Fire Protection Association (NFPA). Flash Point - Minimum
professional association which establishes exposure limits. TLV -
temperature at which a liquid gives off sufficient vapors to form an ignitable
Threshold Limit Value - an airborne concentration of a substance, which
mixture with air. Autoignition Temperature: The minimum temperature
represents conditions under which it is generally believed that nearly all
required to initiate combustion in air with no other source of ignition. LEL -
workers, may be repeatedly exposed without adverse effect. The duration
the lowest percent of vapor in air, by volume, that will explode or ignite in the
must be considered, including the 8-hour Time Weighted Average (TWA),
presence of an ignition source. UEL - the highest percent of vapor in air, by
the 15-minute Short Term Exposure Limit, and the instantaneous Ceiling
volume, that will explode or ignite in the presence of an ignition source.
Level (C). Skin absorption effects must also be considered.
OSHA - U.S. Occupational Safety and Health Administration. TOXICOLOGICAL INFORMATION:
PEL - Permissible Exposure Limit - This exposure value means exactly the Human and Animal Toxicology: Possible health hazards as derived from
same as a TLV, except that it is enforceable by OSHA. The OSHA human data, animal studies, or from the results of studies with similar
Permissible Exposure Limits are based in the 1989 PELs and the June, compounds are presented. Definitions of some terms used in this section
1993 Air Contaminants Rule (Federal Register: 58: 35338-35351 and 58: are: LD50 - Lethal Dose (solids & liquids) which kills 50% of the exposed
40191). Both the current PELs and the vacated PELs are indicated. The animals; LC50 - Lethal Concentration (gases) which kills 50% of the exposed
phrase, "Vacated 1989 PEL," is placed next to the PEL which was vacated animals; ppm concentration expressed in parts of material per million parts
by Court Order. IDLH - Immediately Dangerous to Life and Health - This 3
of air or water; mg/m concentration expressed in weight of substance per
level represents a concentration from which one can escape within 30- volume of air; mg/kg quantity of material, by weight, administered to a test
minutes without suffering escape-preventing or permanent injury. The DFG - subject, based on their body weight in kg. Other measures of toxicity include
MAK is the Republic of Germany's Maximum Exposure Level, similar to the TDLo, the lowest dose to cause a symptom and TCLo the lowest
U.S. PEL. NIOSH is the National Institute of Occupational Safety and concentration to cause a symptom; TDo, LDLo, and LDo, or TC, TCo,
Health, which is the research arm of the U.S. Occupational Safety and LCLo, and LCo, the lowest dose (or concentration) to cause lethal or toxic
Health Administration (OSHA). NIOSH issues exposure guidelines called effects. Cancer Information: The sources are: IARC - the International
Recommended Exposure Levels (RELs). When no exposure guidelines are Agency for Research on Cancer; NTP - the National Toxicology Program,
established, an entry of NE is made for reference. RTECS - the Registry of Toxic Effects of Chemical Substances, OSHA and
HAZARD RATINGS: CAL/OSHA. IARC and NTP rate chemicals on a scale of decreasing
HAZARDOUS MATERIALS IDENTIFICATION SYSTEM: Health Hazard: 0 potential to cause human cancer with rankings from 1 to 4. Subrankings
(minimal acute or chronic exposure hazard); 1 (slight acute or chronic (2A, 2B, etc.) are also used. Other Information: BEI - ACGIH Biological
Exposure Indices, represent the levels of determinants which are most likely
exposure hazard); 2 (moderate acute or significant chronic exposure
to be observed in specimens collected from a healthy worker who has been
hazard); 3 (severe acute exposure hazard; onetime overexposure can result
exposed to chemicals to the same extent as a worker with inhalation
in permanent injury and may be fatal); 4 (extreme acute exposure hazard;
exposure to the TLV. Ecological Information: EC is the effect
onetime overexposure can be fatal). Flammability Hazard: 0 (minimal
concentration in water. BCF = Bioconcentration Factor, which is used to
hazard); 1 (materials that require substantial pre-heating before burning); 2
determine if a substance will concentrate in lifeforms which consume
(combustible liquid or solids; liquids with a flash point of 38-93癈 [100-
contaminated plant or animal matter. Coefficient of Oil/Water Distribution
200癋]); 3 (Class IB and IC flammable liquids with flash points below 38癈
is represented by log Kow or log Koc and is used to assess a substance's
[100癋]); 4 (Class IA flammable liquids with flash points below 23癈 [73癋]
behavior in the environment.
and boiling points below 38癈 [100癋]. Reactivity Hazard: 0 (normally
REGULATORY INFORMATION:
stable); 1 (material that can become unstable at elevated temperatures or
This section explains the impact of various laws and regulations on the
which can react slightly with water); 2 (materials that are unstable but do not
material. U.S.: EPA is the U.S. Environmental Protection Agency. DOT is
detonate or which can react violently with water); 3 (materials that can
the U.S. Department of Transportation. SARA is the Superfund
detonate when initiated or which can react explosively with water); 4
Amendments and Reauthorization Act. TSCA is the U.S. Toxic Substance
(materials that can detonate at normal temperatures or pressures).
Control Act. CERCLA (or Superfund) refers to the Comprehensive
NATIONAL FIRE PROTECTION ASSOCIATION: Health Hazard: 0
Environmental Response, Compensation, and Liability Act. Labeling is per
(material that on exposure under fire conditions would offer no hazard
the American National Standards Institute (ANSI Z129.1). CANADA:
beyond that of ordinary combustible materials); 1 (materials that on
CEPA is the Canadian Environmental Protection Act. WHMIS is the
exposure under fire conditions could cause irritation or minor residual injury);
Canadian Workplace Hazardous Materials Information System. TC is
2 (materials that on intense or continued exposure under fire conditions
Transport Canada. DSL/NDSL are the Canadian Domestic/Non-Domestic
could cause temporary incapacitation or possible residual injury); 3
Substances Lists. The CPR is the Canadian Product Regulations. This
(materials that can on short exposure could cause serious temporary or
section also includes information on the precautionary warnings, which
residual injury); 4 (materials that under very short exposure causes death or
appear, on the materials package label.
major residual injury). Flammability Hazard and Reactivity Hazard: Refer to
definitions for "Hazardous Materials Identification System".
STAY CLEAN?ALUMINUM FLUX MSDS July 2, 2004
PAGE 9 OF 9
|