HALOX?XTAIN L-66
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
HALOX
MANUFACTURED BY:
1326 Summer Street
Hammond, IN 46320-2240
PRODUCT NAME: HALOX?XTAIN L-66
Phone: 219-933-1560 (US Central) M-F 8:00 am - 5:00 pm
Emergency Phone: 219-845-0031
Chemtrec: 1-800-424-9300
Product Use: Liquid stain inhibitor, primarily used in the manufacture of architectural coatings.
2. COMPOSITION/INFORMATION ON INGREDIENTS
HAZARDOUS STATEMENT:
This document is prepared pursuant to the OSHA Hazard Communication Standard (29 CFR 1910.1200). In addition,
other substances not 'hazardous' per this OSHA standard may be listed.
Hazardous Components % Composition ACGIH TLV: ACGIH STEL: OSHA PEL: OSHA TWA/STEL Units
STEL: are in:
mg/m3
Sodium Hydroxide 20-30 2 NE 2 NE
1310-73-2
mg/m3
Triethanolamine 10-20 5 NE NE NE
102-71-6
mg/m3
Sodium Aluminate 10-20 NE NE NE NE
11138-49-1
EXPOSURE LIMIT STATEMENT
NE - None established
HMIS
3
HEALTH:
0
FLAMMABILITY:
1
REACTIVITY:
*
PERSONAL PROTECTION:
* Recommended personal protective measures are identified in Section 8.0 of this document.
Date of Last Revision: May 28, 2010 Page 1 of 7
HALOX?XTAIN L-66
3. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW:
Clear liquid. Odorless. Thermal decomposition, as a result of a fire, may cause the generation of toxic gases. Spill
materials and associated run-off should not be allowed to reach waterways.
POTENTIAL ACUTE HEALTH EFFECTS:
EYE CONTACT:
May cause eye irritation. Symptoms may include stinging, tearing, redness, and swelling.
SKIN CONTACT:
May cause irritation or rash.
INGESTION:
May cause abdominal discomfort such as nausea or vomiting. Can cause gastrointestinal irritation.
INHALATION:
Inhalation of vapors or mists may cause irritation in the respiratory tract. Inhalation of vapors, aerosols, and/or mists of
the components of this product may cause damage to contacted tissue.
Routes of Exposure: Inhalation, ingestion, skin and eye contact.
POTENTIAL CHRONIC HEALTH EFFECTS:
Prolonged or repeated inhalation of the components of this product may cause allergic reaction and/or sensitization, as
well as a sore throat. Long-term effects of repeated and prolonged inhalation of these components may result in nervous
system disorders, behavioral changes, decreased motor function, adverse respiratory effects, and decreased blood
pressure. Prolonged or repeated eye contact with components of this product via vapors, mists, or aerosols may result in
burns, conjunctivitis, and/or corneal damage. Prolonged or repeated skin contact may cause irritation and dermatitis.
These symptoms are associated only with specific components of this product, which are present in small quantities.
Medical conditions aggravated by exposure: Any pre-existing lung or pulmonary condition.
4. FIRST AID MEASURES
EYES:
Do not let victim rub eyes. Flush eyes well with water for at least 15 minutes. If irritation persists, seek medical attention.
SKIN:
Remove contaminated clothing. Wash thoroughly with soap and water. Seek medical attention if irritation persists.
INHALATION:
Move person to fresh air. Give artificial respiration if necessary. If breathing is difficult, administer oxygen. Seek medical
attention if symptoms develop or persist.
INGESTION:
If victim is conscious and alert, give 2-4 cupfuls of milk or water. Do not induce vomiting. Seek medical attention if
symptoms develop or persist.
Date of Last Revision: May 28, 2010 Page 2 of 7
HALOX?XTAIN L-66
5. FIRE FIGHTING MEASURES
FLASH POINT (?F) Not applicable.
OSHA FLAMMABILITY CLASSIFICATION: Not Applicable.
EXTINGUISHING MEDIA: This material is not flammable and will not react with commercially available extinguishing
media.
SPECIAL FIREFIGHTING PROCEDURES: Firefighters should wear a positive-pressure self-contained breathing
apparatus (SCBA) and protective fire fighting clothing.
AUTOIGNITION TEMP (?F) Unknown
UNUSUAL FIRE AND EXPLOSION HAZARDS: None.
6. ACCIDENTAL RELEASE MEASURES
ACTION TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED:
Protect against identified hazards through use of personal protection equipment and proper work and hygiene practices.
Limit foot and vehicular traffic to minimize mechanical agitation and dispersion. Remove sources of ignition. Stop the leak.
If necessary, ventilate the space involved. If recovery is not feasible, use an appropriate non-reative sorbent material to
contain and remove spilled product. Transfer used absorbent material to an appropriate container for future disposal.
Notify In-plant Spill Response Coordinator or appropriate party to determine any additional requirements pertaining to spill
response.
CONTAINMENT TECHNIQUES: If this product is to be used in bulk quantities, containment devices such as diked areas
should be used to contain the liquid in the event of a spill.
SPILL RESPONSE EQUIPMENT:
?Broom, wet mop
?Non-reactive absorbent material
?Containers for collection
SPILL RESPONSE PERSONAL PROTECTIVE EQUIPMENT:
?Impermeable gloves (rubber, nitrile, or butyl rubber)
?Chemical resistant coveralls or splash suits
?Chemical/safety impact goggles
?Chemical resistant boot covers
?If airborne concentrations cannot be controlled below the required or recommended exposure limits, respiratory
equipment, as per Section 8.0, may be required.
7. HANDLING AND STORAGE
HANDLING:
Always wear recommended personal protective equipment. Avoid contact with skin and eyes.
STORAGE:
KEEP FROM FREEZING. Store in a dry area, 50 to 140 F (10 to 60 C). Avoid contact with acids, oxidizers, heat, or
flames. Keep containers closed when not in use. Store containers in an appropriate area to minimize the potential for
damage as a result of facility operations.
Note:
Frozen or crystallized material is completely recoverable by subjecting product to 75 to 80 F (24-27 C) temperatures for
approximately 4 hours.
Date of Last Revision: May 28, 2010 Page 3 of 7
HALOX?XTAIN L-66
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
ENGINEERING CONTROLS: General mechanical ventilation is acceptable, as long as concentrations are maintained
below required/recommended limits. Where acceptable concentrations cannot be maintained by general mechanical
ventilation, local exhaust ventilation is recommended.
RESPIRATORY PROTECTION EQUIPMENT: Not required for properly ventilated areas. If vapors or mist should
accumulate, use an appropriate NIOSH/MSHA approved respirator. Utilization of respiratory equipment should be in
accordance with 29 CFR 1910.1025 and 29 CFR 1910.134.
PROTECTIVE GLOVES: To prevent any contact, wear impervious gloves such as neoprene and butyl rubber. Tyvek
coveralls or rubber aprons should be worn if the potential for skin contact with this material exists.
EYE AND FACE PROTECTION: Wear safety glasses with side shields or chemical goggles.
OTHER PROTECTIVE EQUIPMENT: An emergency eye wash is recommended in the work area and should, at a
minimum, meet the requirements under ANSI Z.358.1 for location, design, and operation.
9. PHYSICAL AND CHEMICAL PROPERTIES
212 篎 (100 篊)
Boiling Range/Point
32 篎 (0 篊)
Freezing Point
Not applicable
Melting Point
None established
Vapor Pressure
None established
Vapor Density (AIR=1)
Liquid
Physical State
Clear
Color
Not applicable
Percent Moisture
100%
Solubility in Water
0.00 (0.00)
VOC = lbs/gal (g/L)
(EPA Method 24)
None established
%Volatile by Volume
None established
Evaporation Rate
(Butyl Acetate=1)
10.26 lbs/gal
Density
12.7
pH*
1.23
Specific Gravity (water=1)
*at 10% slurry by weight in water.
Date of Last Revision: May 28, 2010 Page 4 of 7
HALOX?XTAIN L-66
10. STABILITY AND REACTIVITY
STABILITY: Stable.
HAZARDOUS POLYMERIZATION: Will not occur.
HAZARDOUS THERMAL DECOMPOSITION/COMBUSTION PRODUCTS: Oxides of carbon and nitrogen. Oxides of
sodium.
INCOMPATIBILITY (MATERIALS TO AVOID): Strong oxidizing agents, strong acids, strong bases.
CONDITIONS TO AVOID: Incompatible materials, excess heat.
11. TOXICOLOGICAL INFORMATION
No data at this time.
ACUTE ORAL LD50 (mg/kg):
No data at this time.
ACUTE INHALATION LC50:
No data at this time.
ACUTE DERMAL LD50 (mg/kg):
12. ECOLOGICAL INFORMATION
ECOTOXICOLOGICAL INFORMATION: No data at this time
CHEMICAL FATE INFORMATION: No data at this time.
13. DISPOSAL CONSIDERATIONS
DISPOSAL METHOD: Disposal should be made in accordance with federal, state and local regulations.
EMPTY CONTAINERS: Dispose of in accordance with all federal, state, and local regulations or recycle.
14. TRANSPORT INFORMATION
UN 1819, Sodium Aluminate, Solution, 8, PG III, ERG 154
DOT SHIPPING NAME:
UN 1819, Sodium Aluminate, Solution, 8, PG III, ERG 154
AIR FREIGHT
TRANSPORTATION:
UN 1819, Sodium Aluminate, Solution, 8, PG III, ERG 154
OCEAN TRANSPORTATION:
15. REGULATORY INFORMATION
TSCA STATUS:
All components of this product are on the US TSCA Inventory.
CALIFORNIA PROPOSITION 65:
This product is not known to contain any chemicals known to the state of California to cause cancer or birth defects.
However, we do not conduct routine analysis for all listed materials.
Date of Last Revision: May 28, 2010 Page 5 of 7
HALOX?XTAIN L-66
SARA 302 EXTREMELY HAZARDOUS SUBSTANCES LIST:
This product does not contain greater than 1.0% of any chemical substance on the SARA Extremely Hazardous
Substance List.
SARA (311, 312) HAZARD CLASS:
None
SARA SECTION 313 TOXIC CHEMICALS:
None
CANADIAN INVENTORY:
All components are on the Domestic Substance List (DSL).
EINECS REGULATIONS:
All components are on the European Inventory of Existing Commercial Chemical Substances (EINECS).
16. OTHER INFORMATION
DISCLAIMER OF EXPRESSED AND IMPLIED WARRANTIES:
The information in this document is believed to be correct as of the date issued. However, no warranty of merchantability,
fitness for any particular purpose, or any other warranty is expressed or is to be implied regarding the accuracy or
completeness of this information, the results to be obtained from the use of this information or the product, the safety of
this product, or the hazards related to its use. This information and product are furnished on the condition that the person
receiving them shall make his own determination as to the suitability of the product for his particular purpose and on the
condition that he assume the risk of his use thereof.
17. LABEL INFORMATION
WARNING!
SIGNAL WORD:
Corrosive Liquid
May cause eye and skin burns.
TARGET ORGANS:
Do not let victim rub eyes. Flush eyes well with water for at least 15 minutes. If
EYES:
irritation persists, seek medical attention.
Remove contaminated clothing. Wash thoroughly with soap and water. Seek medical
SKIN:
attention if irritation persists.
If victim is conscious and alert, give 2-4 cupfuls of milk or water. Do not induce
INGESTION:
vomiting. Seek medical attention if symptoms develop or persist.
Move person to fresh air. Give artificial respiration if necessary. If breathing is
INHALATION:
difficult, administer oxygen. Seek medical attention if symptoms develop or persist.
Always wear recommended personal protective equipment. Avoid contact with skin,
HANDLING:
eyes and clothing.
KEEP FROM FREEZING. Store in a dry area, 50 to 140 F (10 to 60 C). Avoid contact
STORAGE:
with acids, oxidizers, heat, or flames. Keep containers closed when not in use. Store
containers in an appropriate area to minimize the potential for damage as a result of
facility operations.
Spilled material may be absorbed into the appropriate absorbent material. Collect
IN CASE OF SPILL:
and dispose in accordance with federal, state and local regulations.
Date of Last Revision: May 28, 2010 Page 6 of 7
HALOX?XTAIN L-66
This material is not flammable and will not react with commercially available
EXTINGUISHING MEDIA:
extinguishing media.
This product is not known to contain any chemicals known to the state of California to
CALIFORNIA PROPOSITION 65:
cause cancer or birth defects. However, we do not conduct routine analysis for all
listed materials.
Date of Last Revision: May 28, 2010 Page 7 of 7
|