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MSDS Material Safety Data Sheet
CAS

111-42-2 102-71-6

File Name: 111-42-2_102-71-6.asp

EC Safety Data Sheet (according to 91/155/EEC)

Product name: Accelerator for DURO SOIL / DRAINSEAL Issue No. 0003
Issued on: 11/10/2002 Printing date: 31/10/2003 Page 1 of 4


1. Substance-/Preparation and company name

Details of the product Accelerator for DURO SOIL / DRAINSEAL;
(Product name and use): Additive for injection material for waterproofing of building
structures


Information about manufacturer/supplier


Germany Switzerland
Manufacturer/Supplier: Tricosal GmbH Tricosal BBZ AG
Address: Von-Helmholtz-Str. 1 Gewerbezentrum Rotfarb
D-89257 Illertissen 9213 Hauptwil (Schweiz)
Telephone: + 49 (0) 73 03 180 - 0 +41 (0) 71 424 6070
Telefax: + 49 (0) 73 03 180 - 280 +41 (0) 71 424 6077
Information Line: + 49 (0) 73 03 180 - 0 +41 (0) 71 424 6070
E-mail info@tricosal.de info@bbz-ag.ch
URL www.tricosal.de




2. Composition / Information on ingredients

Chemical composition: Aqueous preparation on the basis of specific amines
Hazardous ingredients



CAS-No. Name of substance Content Symbol R--phrases

111-42-2 Diethanolamine < 10% Xn 22; 38; 41; 48/22


3. Possible Hazards

Identification of hazard: Not applicable
Information concerning hazards for Irritation is possible after contact with skin and eyes.
man and environment:

This classification system complies with the current EC-lists and company information.


4. First aid measures

General advice: Immediately remove contaminated and soaked clothing.
After inhalation: In case of troubles after inhaling vapour/aerosol provide for fresh air; seek
medical advice
After skin contact: Wash skin with soap and water.
After eye contact: Rinse immediately with plenty of clean water for at least 10 min.; seek medical
advice.
After ingestion: Immediately rinse mouth; drink plenty of water subsequently, seek medical
advice.




MSDS_DUROSOILDRAINSEALAccelerator.doc
EC Safety Data Sheet (according to 91/155/EEC)

Product name: Accelerator for DURO SOIL / DRAINSEAL Issue No. 0003
Issued on: 11/10/2002 Printing date: 31/10/2003 Page 2 of 4

5. Fire Fighting Measures

Foam, Extinguishing powder, CO2 (Carbon Dioxide),
Suitable extinguishing media:
water spray.
Non-suitable extinguishing agent (for safety reason): Water jet spray.
Particular hazards caused by the substance,
Toxic and irritant burnt gases can form in case of fire.
combustion products or developing gases:
Special Protective equipment: Wear self-contained breathing apparatus in case of
fire. Follow the standard safety measures for
handling chemicals in case of fire.


6. Accidental release measures

Personal precautions: Protect eyes and hands; wear personal protective
equipment; avoid inhalation of fumes.
Environmental precautions: Do not allow to enter drains, sewers, water courses
and soil.
Measures for cleaning / collection: Soak up with inert liquid absorbent material (e.g.
universal binders); dispose in accordance with local
regulations.


7. Handling and storage

Handling:
Directions for safe handling: Wear personal protection equipment, provide for
good ventilation, avoid contact with acids.
Directions to prevent fire and explosions: Protect from sources of ignition; protect from heat.
Storage:
Requirements for warehouses and containers: Keep away from acids: store under cool conditions;
keep containers tightly closed; keep out of reach of
children.
Further information for storage conditions: Not available


8. Exposure controls and personal protection
Engineering control measures: Ventilation (see paragraph 7)

Occupational exposure limits (Germany):
CAS-No. Name of substance Type Value Unit

102-71-6 Triethanolamine MAK mg/m?br> 5

111-42-2 Diethanolamine MAK 15 mg/m?br>
Personal protective equipment
Breathing protection: Provide for good ventilation.
Hand protection: Chemical resistant protective gloves (e.g. nitrile rubber).
Eye Protection: Tight fitting safety goggles.
Body protection: Normal working clothes.
Hygiene at working place: Keep away from food and beverages, wash hands before breaks and
at the end of working day. Do not eat, drink or smoke during working.




MSDS_DUROSOILDRAINSEALAccelerator.doc
EC Safety Data Sheet (according to 91/155/EEC)

Product name: Accelerator for DURO SOIL / DRAINSEAL Issue No. 0003
Issued on: 11/10/2002 Printing date: 31/10/2003 Page 3 of 4

9. Physical and chemical properties

Physical state: liquid Colour: red violet Odour: not applicable


Value / Unit
Change in condition: Not determined.
Density (at 20癈): Approx. 1,1 g/ml
Vapour pressure (at 20癈): Not determined.
Viscosity (at 20癈): Low viscous
Solubility in water (at 20癈): miscible
pH-value (at 20癈): Approx. 11
Flash point: Not applicable.
Ignition temperature: Not applicable.
n-octanol-water partition coefficient (log Pow): Not determined.

10. Stability and reactivity

Conditions and substances to avoid: Mixing with acids, inorganic acid chlorides and treatment with nitrous
acids.
Hazardous decomposition products: Exothermic reaction with acid. Mixing with inorganic acid chlorides
develops poisonous gases/vapours.

11. Toxicological information

Primary irritant effect (skin, eyes): Irritation is possible after contact with skin and eyes. Irritation of
respiratory system is possible after formation of breathable aerosols.
Sensitisation: Not applicable
Additional information: None

12. Ecological information

Degradability: Not determined
German WGK: 1 (own classification)
Further ecological information: Do not release product into environment.
Further ecological data: Not available.

13. Disposal considerations

Product:
Recommendation: If recycling is not possible, disposal in accordance with local and
official regulations.

Uncleaned packaging
Recommendation: Disposable in accordance with local and official regulations.

14. Transport information

Land transport

Sea transport Non hazardous goods according to transport regulations

Air transport




MSDS_DUROSOILDRAINSEALAccelerator.doc
EC Safety Data Sheet (according to 91/155/EEC)

Product name: Accelerator for DURO SOIL / DRAINSEAL Issue No. 0003
Issued on: 11/10/2002 Printing date: 31/10/2003 Page 4 of 4


15. Regulatory information

Identification according to EC directives
Code letter and hazard designation of the product:


Xi irritant
Relevant component for hazardous goods labelling: Not applicable

R-S鋞ze: 36 Irritating to eyes.


S-S鋞ze: 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical
advice



National regulations
German WGK 1 (own classification)
Swiss Federal Office of Public Health: BAG T-No. 617384, Poison category 4



16. Other information
Relevant code letter and hazard designation of the product, see section 2:
R 22 Harmful if swallowed.
R 38 Irritating to skin.
R 41 Risk of serious damage to eyes.
R 48/22 Harmful: danger of serious damage to health by prolonged exposure if swallowed.


Changes in comparison with the previous version are marked at the margin with a line


The information of this MSDS is based on the present state of our knowledge. The users working conditions are
beyond our knowledge and control. The product is not to be used for other purposes than those specified under
section 1 without first obtaining written handling instruction.
It is always the responsibility of the user to take all necessary steps in order to fulfil the demand laid down in the
local rules and legislation. The information in this MSDS is meant as a description of the safety requirements of
our product and is not to be considered as a guarantee of product properties.




MSDS_DUROSOILDRAINSEALAccelerator.doc

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