Maitland Road, Lion Barn Business Park, Needham Market, Suffolk, IP6 8NZ
Tel.: + 44 (0) 1449 726800 Fax: + 44 (0) 1449 721719
info@masterchemical.co.uk www.masterchemical.com
SAFETY DATA SHEET
1. IDENTIFICATION OF THE SUBSTANCE OR PREPARATION AND THE COMPANY/UNDERTAKING
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1.1 Identification of the product: TRIM E708
Intended use: CHEMICAL EMULSION/SOLUBLE OIL CONCENTRATE
1.2 Identification of the company: MASTER CHEMICAL EUROPE LTD. See above address
2. COMPOSITION/INFORMATION ON INGREDIENTS
2.1 General:
Product contains: Petroleum oil, anionic and non-ionic emulsifiers, corrosion inhibitors, antifoam and water.
Product does not contain: Nitrites, Chlorine, phenol, silicones, secondary amines (DEA), PCBs and PtBBA
2.2 Hazardous ingredients, giving the product its hazard classification:
o
CAS N Hazard %
Alkenyl succinic acid
67762-77-0/102-71-6/1310-73-2 Xi;R41 R52/53 <3.0
derivative-salt
3,3'-methylene bis(5- Xn;R22 Xi;R36/37/38,
66204-44-2 <3.0
methyloxazolidine) R41, R52
Fatty acid amide 8002-12-9/78-96-6 Xi;R36 <2.0
Exposure limit values exist for the following constituent: Mineral Oil, concentration <65% (see section 8)
3. HAZARDS IDENTIFICATION
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3.1 Important health hazards: TRIM E708 is not classified as a health or environmental hazard
3.2 Other hazards: Spilled product may result in slippery floors.
4. FIRST-AID MEASURES
4.1 Eyes: In case of eye contact with the concentrate, flush with running water for 15 minutes and seek medical
attention
4.2 Skin: In case of skin contact with the concentrate, wash with soap and water. Diluted product is not irritating to the
skin when used as recommended and good personal hygiene is practised. Remove severely contaminated
clothes. Launder before re-use. If irritation persists, seek medical advice.
4.3 Ingestion: If concentrate or mix is swallowed, seek medical attention immediately and obtain treatment. DO NOT
INDUCE VOMITING.
4.4 Inhalation: Not expected to be a probable route of exposure to the product concentrate
5. FIRE-FIGHTING MEASURES
5.1 Extinguishing media: Water, foam or CO2
5.2 Special fire fighting procedures: None
5.3 Unusual fire and explosion hazards: None
5.4 Hazardous combustion products: Thermal decomposition may produce carbon oxides.
6. ACCIDENTAL RELEASE MEASURES
6.1 Personal precautions: goggles, oil resistant gloves
6.2 Methods for cleaning up:
Contain the spill, collect on absorbent material and discard as directed by local regulations that may apply. Flush
area thoroughly with water.
Revision: Issue No 4: 24/03/06 Page 1 of 4
Replaces SDS: 19/01/06 F:\MSDSCURR\E708.doc
Maitland Road, Lion Barn Business Park, Needham Market, Suffolk, IP6 8NZ
Tel.: + 44 (0) 1449 726800 Fax: + 44 (0) 1449 721719
info@masterchemical.co.uk www.masterchemical.com
7. HANDLING AND STORAGE
7.1 Handling: Avoid contact with the concentrate.
Use only as recommended on the Product Data sheet
7.2 Storage: Store at room temperature.
If frozen, thaw completely at room temperature
8. EXPOSURE CONTROLS AND PERSONAL PROTECTION
8.1 Exposure Limit Values:
-3 -3
The following limits apply to `Oil mist, mineral' OES 5mg.m (8 h. TWA); STEL 10mg.m (15 min)
8.2 Personal Protective Equipment
Respiratory protection: None
Ventilation: General room ventilation should be sufficient
Protective gloves: Recommended when handling concentrate
Eye protection: Safety glasses
Other protective clothing: None
Work/Hygiene practices: Good personal hygiene should always be practised.
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Physical State liquid
9.2 Appearance Amber coloured
9.3 Odour mild
9.4 Ph 9.2 at 10% dilution
9.5 Boiling point/range (癈) >100
9.6 Flash Point (癈)(PMCC) >100
9.7 Flammability ?autoignition temp. (癈) Not determined
9.8 Explosive properties none
9.9 Oxidising properties none
9.10 Vapour pressure (mbar @ 20癈) negligible
3
9.11 Density (kg/m ) 954
9.12 Solubility in water complete
9.13 Solubility in fat / solvent miscible
9.14 Partition coefficient (log Pow) Not determined
9.15 Viscosity (mPa.s @ 40癈) Not determined
9.16 Vapour density not applicable
9.17 Evaporation rate Negligible
9.18 Melting/Solidification Point (癈) <0
10. STABILITY AND REACTIVITY
10.1 Stability: Stable under normal conditions
10.2 Conditions to avoid: None
10.3 Materials to avoid Strong oxidisers, acids and alkalis
10.4 Hazardous polymerisation Will not occur
Revision: Issue No 4: 24/03/06 Page 2 of 4
Replaces SDS: 19/01/06 F:\MSDSCURR\E708.doc
Maitland Road, Lion Barn Business Park, Needham Market, Suffolk, IP6 8NZ
Tel.: + 44 (0) 1449 726800 Fax: + 44 (0) 1449 721719
info@masterchemical.co.uk www.masterchemical.com
11. TOXICOLOGICAL INFORMATION
The following information is derived using the conventional method as recommended by EC guidelines given in Directive
1999/45/EC and CHIP3 Regulations 2002, as well as experience from this and similar products.
11.1 Acute Toxicity
-oral No toxic components present in preparation
-inhalation Not expected to be a probable route of exposure to the product
concentrate
-dermal No evidence of acute effects
11.2 Corrosivity/Irritation
-eye Concentrate is not classified as eye irritant but may cause
transient irritation
-skin Mild skin irritation (redness and dryness of hands) may be
experienced when the diluted product has been contaminated
by certain oils, by dissolved metals or when mix ratio is too
strong. When problems occur, use of water resistant barrier
creams may be a temporary control measure.
-respiratory tract Inhalation of diluted mix can occur in applications where high
mist levels are generated. Concentrations of mist in the working
atmosphere must be kept as low as possible. National
regulations may apply (see 16).
11.3 Sensitisation
-skin No evidence of sensitisation effects
-respiratory No evidence of sensitisation effects
11.4 Repeated-dose toxicity No data available on effects of repeated skin contact
11.5 Mutagenicity No evidence of mutagenicity
11.6 Carcinogenicity No evidence of carcinogenicity
11.7 Reproductive toxicity No evidence of reproductive toxicity
12. ECOLOGICAL INFORMATION
Ecotoxicity No significant levels of ecotoxic components present
Mobility Disperses in water
Persistence and degradability Not readily biodegradable
Bioaccumulative potential No data available
Other adverse effects Due to the composition of mineral oil containing water soluble
metalworking fluids, these products should not be allowed into
the aquatic environment before treatment
13. DISPOSAL CONSIDERATIONS
Disposal procedures must comply with local regulations. If pre-treatment is needed, chemical `cracking' or ultra-filtration
may be used.
Revision: Issue No 4: 24/03/06 Page 3 of 4
Replaces SDS: 19/01/06 F:\MSDSCURR\E708.doc
Maitland Road, Lion Barn Business Park, Needham Market, Suffolk, IP6 8NZ
Tel.: + 44 (0) 1449 726800 Fax: + 44 (0) 1449 721719
info@masterchemical.co.uk www.masterchemical.com
14. TRANSPORT INFORMATION
Transport Classification Not classified as hazardous for transport
14.1 UN Number N/A
14.2 Hazard Class N/A
14.3 PSN N/A
14.4 Packing Group N/A
14.5 Marine Pollutant No
15. REGULATORY INFORMATION
EC Label: Not classified as hazardous for supply (CHIP3 regulations)
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Label Name TRIM E708
Symbols N/A
Risk Phrases N/A
Safety Phrases N/A
Special Phrases Safety data sheet available for professional user on request
EC Directives Dangerous Substances Directive 67/548/EEC and Dangerous
Preparations Directive 1999/45/EC.
Statutory Instruments The Chemicals (Hazard Information and Packaging for Supply)
Regulations 2002 (CHIP3)
The Health and Safety at Work, etc. Act 1974
The Consumer Protection Act 1987
The Environmental Protection Act 1990
The Control of Substances Hazardous to Health Regulations
1999
16. OTHER INFORMATION
Hazard symbols and Risk phrases not detailed elsewhere:
Xn;R22: Harmful; Harmful if swallowed
Xi;R36/37/38 R41: Irritant; Irritating to respiratory system and skin, Risk of serious damage to eyes
R52/53: Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment
For additional technical information see the Product Data sheet.
UK EH40 (2002) ?Occupational Exposure Limits
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UK HSG 193 - COSHH Essentials
-
UK HSE Guidance Notes:
-
INDG365 ?Working safely with metalworking fluids - a guide for employees
HSG 231 ?Working safely with metalworking fluids - Good practice manual
Germany: TRGS 611.
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All sections have been amended in this revision to comply with requirements of CHIP3 2002 and SDS ACoP L130
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