HINDUSTAN POLYAMIDES AND FIBRES LTD.
MATERIAL SAFETY DATA SHEET
STYRALLYL ACETATE
01 - IDENTIFICATION OF THE SUBSTANCE AND OF THE COMPANY
Product name : STYRALLYL ACETATE
Intended use Perfumery and Flavor Ingredient
Company : Hindustan Polyamides and Fibres Limited (HPFL)
1004, Peninsula Towers, 10 th Floor,
Peninsula Corporate Park, G.K. Marg,
Lower Parel, Mumbai-400013, India
Tel : 91-22-66513400 ; Fax : 91-22-66513434
salomi@hpfl-india.com
02 - HAZARDS IDENTIFICATION
General : Prolonged or repeated contact with skin and
eyes by inhalation may cause irritation.
Hazard Symbol : None
Risk Phrase : None
Environment : When Spilled, can contaminate soil, ground and
surface waters.
03 - COMPOSITION/INFORMATION ON INGREDIENTS
Chemical name : 1- Phenyl Ethyl Acetate
Synonyms : alpha-Phenyl Ethyl Acetate OR
Phenyl Methyl Carbinyl Acetate OR
alpha-Methyl Benzyl Acetate OR
Methyl Phenyl Carbinyl Acetate OR
Gardenol OR Gardenia
Formula : C10H12O2
Molecular weight : 164.20
CAS Number : 93-92-5
EINECS/ELINCS No.: 202-288-5
FEMA : 2684
FDA Reg. : 172.515
CoE No. : 573
Flavis No. : 09.178
JECFA No. : 801
HS Code : 2915.39.90
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HINDUSTAN POLYAMIDES AND FIBRES LTD.
MATERIAL SAFETY DATA SHEET
STYRALLYL ACETATE
04 -FIRST-AID MEASURES
Inhalation : Remove to fresh air. Obtain medical advise if required
Eye Exposure : Flush immediately with water for at least 15 minutes.
Seek medical advise if irritation persists.
Skin Exposure : Remove contaminated clothing. Wash the exposed
area with water and soap. Seek medical advise if
symptoms persist.
Ingestion : Rinse mouth with water and seek medical advise. Do
not induce vomiting.
Others :Take Risk and Safety Phrases in account- Section 15.
05 -FIRE-FIGHTING MEASURES
Extinguishing Media : Carbon dioxide, Dry Chemical, foam. Do not use
direct water jet on burning material.
Unusual Fire/Explosion Hazards :
Toxic Gases (Carbon dioxide, carbon monoxide and
acrid fumes) are released on burning. Closed containers
will build pressure at elevated temperatures. During
such condition, keep containers cooled with water
spray.
06 -ACCIDENTAL RELEASE MEASURES
Personal Precautions : Avoid inhalation and contact with skin and eyes. A
self contained breathing apparatus is recommended in
case of major spillages. Remove ignition sources,
Provide ventilation. Contain large spills with sand or
inert adsorbent material and dispose according to
local regulations.
Environmental Precautions
: Keep away from drains, surface and ground
water and soil.
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HINDUSTAN POLYAMIDES AND FIBRES LTD.
MATERIAL SAFETY DATA SHEET
STYRALLYL ACETATE
07 -HANDLING AND STORAGE
Handling : Follow good manufacturing and industrial hygiene
practices. Use Safety Goggles and other safety
measures while handling the material
Storage : Store in a cool, dry and well ventilated place away
from heat source. Store in tightly closed containers.
Fire protection : Keep away from source of ignition and naked
flame.
08 -EXPOSURE CONTROLS / PERSONAL PROTECTION
Occupational Exposure limits:
EU OEL 8 h (mg/m3) : Not determined
EU STEL 15 mn (mg/m3) : Not determined
Respiratory protection: Avoid inhalation of vapors. Use in well ventilated
area.
Hand protection : The use of chemical resistant gloves recommended
Eye protection : Use safety goggles while handling the material.
Skin protection : Avoid contact with the skin
Ventilation : Provide adequate ventilation. Use local exhaust if
necessary.
09 -PHYSICAL AND CHEMICAL PROPERTIES
Appearance : Liquid
Colour : Colourless
Odour : Green, Fruity, Floral, Fresh, Gardenia Musty
Taste : Sweet, Woody
Boiling point (癈) : 213 at 760 mm Hg,
94 -95 at 12 mm Hg
Flash point (癈) : 95 (CLOSED CUP)
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HINDUSTAN POLYAMIDES AND FIBRES LTD.
MATERIAL SAFETY DATA SHEET
STYRALLYL ACETATE
Vapor pressure (hPa) : 0.1333 at 20癈
Specific gravity (25/25 癈) : 1.024
Water solubility (mg/L) : 1218.000 at 20癈
Partition coeff. (log Pow) : 2.5 OECD 117
10 -STABILITY AND REACTIVITY
Stability & reactivity :No significant hazard, by itself or in contact
with water. Avoid contact with strong acids,
alkaline and oxidizing gents.
Decomposition :Carbon dioxide, Carbon Monoxide and
unidentified organic compounds may form
during combustion.
11 -TOXICOLOGICAL INFORMATION (Lit.Ref.-RIFM fct 14, p 611 (1976)
No.178)
Not regulated for specific Health hazard (EEC directive 92/2/EC)
Oral LD50 : Rat ?>5000 mg/kg
Dermal LD50 : Rabbit - >8000 mg/kg
Skin Irritation : No irritation : Rabbit, 24 hrs, 100 % undiluted
: No irritation ?Human, 48 hrs, 4 % Petrolatum
Skin Sensitization : No sensitisation (Human Max test, 4.0 %, in PTLTM)
Carcinogenicity : Per OSHA, IARC, NTP, ACGIH, OEHHA-Prop 65,
RTECS : No
Reproductive toxin : Per OSHA, IARC, NTP, ACGIH, OEHHA-Prop 65,
RTECS : No
12 -ECOLOGICAL INFORMATION
Not Regulated for Environmental hazard
LC50 for Fish : 21.00 mg/l, 96 h, OECD 2003
EC50 for Bacteria : 729.00 mg/l, OECD 209 / ISO 8192
LC50 Algae : 65.00 mg/l, 24 h, 92/69/EC
Biodegradability : Readily biodegradable OECD 301F 28d
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HINDUSTAN POLYAMIDES AND FIBRES LTD.
MATERIAL SAFETY DATA SHEET
STYRALLYL ACETATE
13 -DISPOSAL CONSIDERATIONS
Dispose according to local regulations. Avoid disposing into drainage systems
and into environment.
14 -TRANSPORT INFORMATION
RID/ADR Not restricted
IMDG Not restricted
ICAO/IATA Not restricted
15 -REGULATORY INFORMATION
Label STYRALLYL ACETATE
EINECS/ELINCS : 202-288-5
16 -OTHER INFORMATION
Water endangering class (WGK): 1 (Slightly hazardous to water)
NFPA rating :Health ?1 Flammability- 2 Reactivity - 0
This chemical substance is not classified in the Annex I of Directive 67/548/EEC.
DISCLAIMER :
The information and recommendation contained in this data sheet represent, to the
best of HPFL's knowledge and belief, an accurate and reliable representation as to the
known data for this material. The data have been obtained from literature and or
referred from other sources available and HPFL cannot guarantee their accuracy,
reliability and completeness nor can HPFL assume any liability for any loss or
damage arising out of the use of these data. It is the user's responsibility to evaluate
this information in a prudent manner and to use it in a manner that is consistent for its
particular purpose.
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