Material Safety Data Sheet
Freeman 705 Resin
Date of Preparation: June 1, 2010
Section 1 Chemical Product and Company Identification
HMIS
Product/Chemical Name: Freeman 705 Resin
2
H
Chemical Family: Epoxy Resin
1
F
CAS Number: N/A
0
R
Other Designations: N/A
PPE
General Use: N/A
Sec.8.
Manufacturer: Freeman Manufacturing and Supply Company, 1101 Moore Road, Avon, OH 44011
Phone (440) 934-1902, FAX (440) 934-7200, Hours of Operation 8-5,
Emergency phone number 1-800-424-9300
Section 2 Composition/Information on Ingredients
Ingredient Name CAS Number
Bisphenol A Epoxy Resin 25068-38-6
Diglycidyl Ether 17557-23-2
Ingredient OSHA ACGIH
PEL STEL TLV STEL
none estab. none estab. none estab. none estab.
Bisphenol A Epoxy Resin
Diglycidyl Ether none estab. none estab. none estab. none estab.
Section 3 Hazards Identification
Emergency Overview
Causes eye, and skin irritation. May cause skin sensitization.
Potential Health Effects
Primary Entry Routes: Skin; Inhalation from heated vapors.
Acute Effects:
Inhalation: Because of its low volatility this product is not likely to be an inhalation hazard.
Eye: Causes irritation
Skin: Causes irritation May cause skin sensitization, an allergic reaction, which becomes evident on
reexposure to this material.
Ingestion: Swallowing may cause abdominal irritation, nausea, vomiting, and diarrhea.
Medical Conditions Aggravated by Long-Term Exposure: Skin and eye conditions.
Chronic Effects: N/A
Carcinogenicity: IARC, NTP, and OSHA do not list any of the components as carcinogenic.
Section 4 First Aid Measures
Inhalation: Remove to fresh air. If breathing is difficult, give oxygen and/or artificial respiration.
Eye Contact: Flush with plenty of water for 15 minutes and get medical attention.
Skin Contact: Wash thoroughly with soap and water. Remove contaminated clothing and launder before reuse.
Destroy contaminated shoes.
Ingestion: Do not induce vomiting. Never give anything by mouth to an unconscious person, Get medical attention.
Freeman 705 Resin
Section 5 Fire Fighting Measures
Flash Point: > 260癋 (>127 癈)
NFPA
Flash Point Method: estimated
LEL: Not established 1
0
UEL: Not established 2
--
Extinguishing Media: CO2, or dry chemical
Unsuitable Media: Water or foam may cause frothing.
Fire-Fighting Equipment: Use self-contained breathing apparatus.
Fire and Explosion Hazards: Decomposition and combustion products may be toxic.
Section 6 Accidental Release Measures
Spill /Leak Procedures: Stop spill at source. Dike area and contain. Clean up remainder with absorbent materials
such as sand or vermiculite. Mop up and dispose of.
Section 7 Handling and Storage
Handling & Storage: Use with adequate ventilation. Avoid prolonged breathing of vapor. Avoid prolonged or
repeated contact with skin. Wear safety goggles or face shield. Wear gloves, apron and footwear impervious to this
material. Wash clothing before reuse. Store at ambient temperatures. . Keep container tightly closed and upright
when not in use to prevent leakage.
Section 8 Exposure Controls/Personal Protection
Ventilation: Local exhaust recommended. General mechanical is acceptable. Provide general or local exhaust
ventilation systems to maintain airborne concentrations below OSHA PELs (Sec. 2).
Respiratory Protection: Use a NIOSH approved respirator when vapor/mist exposure is likely.
Eye Protection: Wear splash-proof chemical goggles.
Skin Protection: Wear impermeable gloves.
Safety Stations: Make emergency eyewash stations, safety/quick-drench showers, and washing facilities available in
work area.
Comments: Never eat, drink, or smoke in work areas. Practice good personal hygiene after using this material,
especially before eating, drinking, smoking, using the toilet, or applying cosmetics.
Section 9 Physical and Chemical Properties
Appearance and Odor: White soft paste, mild epoxy Water Solubility: Slight
odor Boiling Point: Not determined
Vapor Pressure: Not determined % Volatile: Negligible
Vapor Density (Air=1): > 1 Evaporation Rate: Not determined
pH: Not determined
Specific Gravity (H2O=1, at 4 癈): 1.6
Section 10 Stability and Reactivity
Stability: Stable.
Conditions to Avoid: Excessive heat for prolonged period.
Chemical Incompatibilities: Strong oxidizing agents, acids and bases
Hazardous Decomposition Products: Combustion may form toxic materials, such as carbon dioxide, carbon
monoxide.
Hazardous Polymerization: Will not occur. Avoid inadvertent mixture with epoxy curing agents.
Page 2 of 3
Freeman 705 Resin
Section 11 Toxicological Information
Acute Inhalation Exposure Effects: Respiratory irritant.
Skin Irritation: Irritant.
Eye Irritation: Irritant.
Sensitization: Possible in susceptible individuals.
Carcinogenicity: IARC, NTP, and OSHA do not list any of the components as carcinogenic.
Section 12 Ecological Information
No Known evidence of adverse effects from available information
Section 13 Disposal Considerations
Disposal: Use safety containers for disposal. Contact your supplier or a licensed contractor for detailed
recommendations. Follow applicable Federal, state, and local regulations
Section 14 Transport Information
DOT Transportation Data (49 CFR 172.101):
Shipping Name: Resin Compounds, N.O. I
Section 15 Regulatory Information
US Federal Regulations:
OSHA (Occupational Safety and Health Act): This Material Safety Data Sheet has been prepared in compliance with
the federal OSHA Hazard Communication Standard 29 CFR 1910.1200. This product is considered to be a
hazardous chemical under that standard.
RCRA (Resource Conservation and Recovery Act): Not a hazardous waste under RCRA (40 CFR 261).
SARA Toxic Chemical (40 CFR 372.65): This product contains the following toxic chemical subject to the reporting
requirements of Section 313 of SARA Title III of 1986 and of 40 CFR 372.
TSCA Inventory Status: All ingredients listed on TSCA inventory requirements.
State Regulations: This product is not known to contain any components for which the State of California has found
to cause cancer, birth defects or other reproductive harm.
Section 16 Other Information
Disclaimer: The following supersedes Buyer's documents. SELLER MAKES NO REPRESENTATION OR
WARRANTY, EXPRESSED OR IMPLIED, INCLUDING ANY WARRANTY OF MERCHANTABILITY OR
FITNESS FOR A PARTICULAR PURPOSE. No statements herein are to be construed as inducements to infringe any
relevant patent. Under no circumstances shall Seller be liable for incidental, consequential or indirect damages for
alleged negligence, breach of warranty, strict of liability arising in connection with the product(s). Buyer's sole remedy
and Seller's sole liability for any claims shall be Buyer's purchase price. Data and results are based on controlled lab
work and must be confirmed by Buyer by testing for its intended conditions of use. The product(s) has not been tested
for, and is therefore not recommended for, uses for which prolonged contact with mucous membranes, abraded skin, or
blood is intended; or for uses for which implantation within the human body is intended.
Page 3 of 3
Material Safety Data Sheet
Freeman 705-15 Hardener
Date of Preparation: February 9, 2010
Section 1 Chemical Product and Company Identification
HMIS
Product/Chemical Name: Freeman 705-15 Hardener
2
H
Chemical Family: Amine
1
F
CAS Number: N/A
0
R
Other Designations: N/A
PPE
General Use: Epoxy Curing Agent
Sec.8.
Manufacturer: Freeman Manufacturing and Supply Company, 1101 Moore Road, Avon, OH 44011
Phone (440) 934-1902, FAX (440) 934-7200, Hours of Operation 8-5,
Emergency phone number 1-800-424-9300
Section 2 Composition/Information on Ingredients
Ingredient Name CAS Number
Polyamine adduct Proprietary
Imidazole 931-36-2
Ingredient OSHA ACGIH
PEL STEL TLV STEL
none estab. none estab. none estab. none estab.
Polyamine Adduct
none estab. none estab. none estab. none estab.
Imidazole
Section 3 Hazards Identification
Emergency Overview
Irritant
Potential Health Effects
Primary Entry Routes: Skin; Inhalation from heated vapors.
Acute Effects:
Inhalation: Vapor is irritating to the upper respiratory system and mucous membranes.
Eye: Product can cause severe eye irritation, swelling and/or chemical burn. Contact lenses should not be
worn when working with this material.
Skin: Skin contact may result in irritation or chemical burn.
Ingestion: Liquid causes damages to mucous membrane if swallowed.
Medical Conditions Aggravated by Long-Term Exposure: Skin and eye conditions.
Chronic Effects: N/A
Carcinogenicity: IARC, NTP, and OSHA do not list any components as carcinogens
Section 4 First Aid Measures
Inhalation: Remove to fresh air. If breathing is difficult, give oxygen and/or artificial respiration.
Eye Contact: Flush with plenty of water for 15 minutes and get medical attention.
Skin Contact: Wash thoroughly with soap and water. Remove contaminated clothing and launder before reuse.
Destroy contaminated shoes.
Ingestion: Do not induce vomiting. Get medical attention.
Freeman 705-15 Hardener
Section 5 Fire Fighting Measures
Flash Point: 220癋 (104 癈)
NFPA
Flash Point Method: PMCC
LEL: Not established 1
0
UEL: Not established 2
--
Extinguishing Media: Foam, water, CO2, or dry chemical
Fire-Fighting Equipment: Use self-contained breathing apparatus.
Fire and Explosion Hazards: Decomposition and combustion products may be toxic.
Section 6 Accidental Release Measures
Spill /Leak Procedures: Stop spill at source. Dike area and contain. Clean up remainder with absorbent materials
such as sand or vermiculite. Mop up and dispose of.
Section 7 Handling and Storage
Handling & Storage: Use with adequate ventilation. Avoid prolonged breathing of vapor. Avoid prolonged or
repeated contact with skin. Wear safety goggles or face shield. Wear gloves, apron and footwear impervious to this
material. Wash clothing before reuse. Store at ambient temperatures. . Keep container tightly closed and upright
when not in use to prevent leakage.
Section 8 Exposure Controls/Personal Protection
Ventilation: Local exhaust recommended. General mechanical is acceptable. Provide general or local exhaust
ventilation systems to maintain airborne concentrations below OSHA PELs (Sec. 2).
Respiratory Protection: Use a NIOSH approved respirator when vapor/mist exposure is likely.
Eye Protection: Wear splash-proof chemical goggles.
Skin Protection: Wear impermeable gloves.
Safety Stations: Make emergency eyewash stations, safety/quick-drench showers, and washing facilities available in
work area.
Comments: Never eat, drink, or smoke in work areas. Practice good personal hygiene after using this material,
especially before eating, drinking, smoking, using the toilet, or applying cosmetics.
Section 9 Physical and Chemical Properties
Appearance and Odor: Amber liquid, amine odor Water Solubility: Moderate
Boiling Point: Not determined
Vapor Pressure: < 1 mm Hg @ 70癋
% Volatile: Not determined
Vapor Density (Air=1): Not determined
Evaporation Rate: Not determined
VOC Content: 0 lbs/gal
pH: Not determined
Specific Gravity (H2O=1, at 4 癈): 1.06
Section 10 Stability and Reactivity
Stability: Stable.
Conditions to Avoid: Excessive heat for prolonged period.
Chemical Incompatibilities: Strong oxidizing agents, acids and bases, secondary aliphatic amines and mercaptans.
Hazardous Decomposition Products: Combustion may form toxic materials, such as carbon dioxide, carbon
monoxide and nitrogen oxides
Hazardous Polymerization: Will not occur. Avoid inadvertent mixing with epoxy resins
Page 2 of 3
Freeman 705-15 Hardener
Section 11 Toxicological Information
Sensitization: Causes allergic skin and respiratory sensitivity in some people.
Skin: Irritation: . May cause burns.
Eye: Irritation: May cause burns.
Carcinogenicity: IARC, NTP, and OSHA do not list any components as carcinogens.
Section 12 Ecological Information
No Known evidence of adverse effects from available information
Section 13 Disposal Considerations
Disposal: Use safety containers for disposal. Contact your supplier or a licensed contractor for detailed recommendations.
Follow applicable Federal, state, and local regulations
Section 14 Transport Information
DOT Transportation Data (49 CFR 172.101):
Shipping Name: Liquid Plastic, N.O. I.
Hazard Class: Not Regulated
Section 15 Regulatory Information
US Federal Regulations:
OSHA (Occupational Safety and Health Act): This Material Safety Data Sheet has been prepared in compliance with
the federal OSHA Hazard Communication Standard 29 CFR 1910.1200. This product is considered to be a
hazardous chemical under that standard.
RCRA (Resource Conservation and Recovery Act): Not a hazardous waste under RCRA (40 CFR 261).
SARA 311/312 Codes:
SARA Toxic Chemical (40 CFR 372.65): This product contains the following toxic chemical subject to the reporting
requirements of Section 313 of SARA Title III of 1986 and of 40 CFR 372.
TSCA Inventory Status: All ingredients listed on TSCA inventory requirements.
State Regulations:
CA Proposition: No component listed
May contain trace amounts of triethylenetetraamine (CAS # 112-24-3) which is on the Pennsylvania and New Jersey
Right to Know lists
May contain trace amounts of aminoethylpiperazine (140-31-8) which is on the Pennsylvania, New Jersey and
Massachusetts Right to Know lists
Section 16 Other Information
Disclaimer: The following supersedes Buyer's documents. SELLER MAKES NO REPRESENTATION OR
WARRANTY, EXPRESSED OR IMPLIED, INCLUDING ANY WARRANTY OF MERCHANTABILITY OR
FITNESS FOR A PARTICULAR PURPOSE. No statements herein are to be construed as inducements to infringe any
relevant patent. Under no circumstances shall Seller be liable for incidental, consequential or indirect damages for
alleged negligence, breach of warranty, strict of liability arising in connection with the product(s). Buyer's sole remedy
and Seller's sole liability for any claims shall be Buyer's purchase price. Data and results are based on controlled lab
work and must be confirmed by Buyer by testing for its intended conditions of use. The product(s) has not been tested
for, and is therefore not recommended for, uses for which prolonged contact with mucous membranes, abraded skin, or
blood is intended; or for uses for which implantation within the human body is intended.
Page 3 of 3
Material Safety Data Sheet
Freeman 705-45 Hardener
Date of Preparation: January 24, 2007 Revision:
Section 1 - Chemical Product and Company Identification
Product/Chemical Name: Freeman 705-45 Hardener HMIS
Chemical Family: Amine 2
H
CAS Number: N/A 1
F
Other Designations: N/A 0
R
General Use: N/A PPE
Manufacturer: Freeman Manufacturing and Supply Company, 1101 Moore Road, Avon, OH 44011, Sec. 8
Phone (440)934-1902, FAX (440)934-7200, Hours of Operation 8-5, Emergency Phone Number 800-424-9300.
Emergency Overview
Irritant
Section 2 - Composition / Information on Ingredients
Ingredient Name CAS Number
Polyamine Adduct 68610-56-0
Ingredient OSHA PEL ACGIH TLV
TWA STEL TWA STEL
none estab. none estab. none estab. none estab.
Polyamine Adduct
Section 3 - Physical and Chemical Properties
Physical State: Liquid pH: N/A
Appearance and Odor: Light yellow , amine odor. Water Solubility: Slightly
Odor Threshold: N/A Other Solubilities: N/A
Viscosity: 100-1000 cps Boiling Point: N/A
Vapor Pressure: <1 mm Hg at 20 癈 Freezing/Melting Point: N/A
Vapor Density (Air=1): >1 %Solid: 100%
% Volatile: 0%
Specific Gravity (H2O=1, at 4 癈): 1.07
Evaporation Rate: N/A
Section 4 - Fire-Fighting Measures
NFPA
Flash Point: 200 癋 (93癈)
Flash Point Method: SETA
1
Burning Rate: N/A
0
2
Autoignition Temperature: N/A
--
LEL: N/E
UEL: N/E
Flammability Classification: N/A
Extinguishing Media: Water, fog, foam, dry chemical, CO2.
Unusual Fire or Explosion Hazards: Container areas exposed to intense heat or flame should be cooled with water to prevent
pressure build-up and/or weakening of container structure.
Hazardous Combustion Products: N/A
Fire-Fighting Instructions: Do not enter confined fire space without full protective hear including a positive pressure, self-
contained, NIOSH approved breathing apparatus. Cool fire exposed container with water. Do not release runoff from fire
control methods to sewers or waterways.
Fire-Fighting Equipment: Because fire may produce toxic thermal decomposition products, wear a self-contained breathing
apparatus (SCBA) with a full face piece operated in pressure-demand or positive-pressure mode.
Freeman 705-45 Hardener Revision:
Section 5 - Stability and Reactivity
Stability: Freeman 705-45 Hardener is stable at room temperature in closed containers under normal storage and handling
conditions.
Polymerization: Hazardous polymerization cannot occur. Avoid mixing resin and hardener in uncontrollable quantities.
Chemical Incompatibilities: Incompatible with strong oxidizing agents, strong acids and bases, secondary aliphatic amines and
mercaptans.
Conditions to Avoid: Avoid high temperatures, open flames and unscheduled contact with curing agents.
Hazardous Decomposition Products: Thermal oxidative decomposition of Freeman 705-15 Hardener can produce carbon
dioxide, carbon monoxide, by products may include oxides of nitrogen when burned.
Section 6 - Health Hazard Information
Potential Health Effects
Primary Entry Routes: Inhalation, skin
Target Organs: N/A
Acute Effects N/A
Signs and Symptoms:
Inhalation: Vapor is irritating to the upper respiratory system and mucous membranes.
Eye: Product can cause severe eye irritation, swelling and/or chemical burn. Contact lenses should not be worn when working
with this material.
Skin: Skin contact may result in irritation or chemical burn.
Ingestion: Liquid causes damage to mucous membrane if swallowed.
Carcinogenicity: IARC, NTP, and OSHA do not list any component as carcinogenic.
Medical Conditions Aggravated by Long-Term Exposure: N/A
Chronic Effects: N/A
Emergency and First Aid Procedures
Inhalation: Remove victim to fresh air.
Eye Contact: Flush eyes with generous amounts of water for at least 15 minutes. Get medical attention immediately.
Skin Contact: Immediately wash skin with soap and water. Wash contaminated clothing before reuse.
Ingestion: If swallowed do not induce vomiting. Give large amounts of water or milk if available. Call a physician. Treatment
based on judgment of the physician in response to reactions of the patient.
After first aid, get appropriate in-plant, paramedic, or community medical support.
Note to Physicians: N/A
Special Precautions/Procedures: N/A
Section 7 - Spill, Leak, and Disposal Procedures
Precautions: Store at ambient temperatures in well ventilated area. Avoid sparks, open flames and extreme heat. Store
separately from epoxy resins. Protect container from physical damage. Container, even those that have been emptied, can
contain product residues. Handle in accordance with good industrial practices. Avoid prolonged or repeated contact with skin.
Wash with soap before eating, drinking, smoking, applying cosmetics, or using toilet facilities. Launder contaminate clothing
before use.
Spill /Leak Procedures: Use cautious judgment when cleaning spills.
Small Spills: May be collected with adsorbent material, such as clay or sand.
Large Spills: Should be diked and contained with absorbent materials. Flush area with water spray to remove residue. Dispose
of flush legally.
Containment: For large spills, dike far ahead of liquid spill for later disposal. Do not release into sewers or waterways.
Regulatory Requirements: Follow applicable OSHA regulations (29 CFR 1910.120).
Disposal: Contact your supplier or a licensed contractor for detailed recommendations. Follow applicable Federal, state, and
local regulations.
Disposal Regulatory Requirements: N/A
Container Cleaning and Disposal: N/A
Ecological Information: N/A
EPA Regulations:
RCRA Hazardous Waste Number: Not listed (40 CFR 261.33)
RCRA Hazardous Waste Classification (40 CFR 261.): Not classified
CERCLA Hazardous Substance (40 CFR 302.4) listed/unlisted specific per RCRA, Sec. 3001; CWA, Sec. 311 (b)(4); CWA,
Sec. 307(a), CAA, Sec. 112
Page 2 of 3
Revision: Freeman 705-45 Hardener
CERCLA Reportable Quantity (RQ), lb (kg)
SARA 311/312 Codes:
SARA Toxic Chemical (40 CFR 372.65): Not listed
SARA EHS (Extremely Hazardous Substance) (40 CFR 355): Not listed, Threshold Planning Quantity (TPQ)
OSHA Regulations:
Air Contaminant (29 CFR 1910.1000, Table Z-1, Z-1-A): Not listed
OSHA Specifically Regulated Substance (29CFR 1910)
State Regulations: None Applicable
Section 8 - Exposure Controls / Personal Protection
Engineering Controls: N/A
Ventilation: Use only with adequate ventilation. Local exhaust is recommended. General Mechanical can be used as a backup
system. Provide general or local exhaust ventilation systems to maintain airborne concentrations below OSHA PELs (Sec. 2).
Local exhaust ventilation is preferred because it prevents contaminant dispersion into the work area by controlling it at its
source.
Administrative Controls: N/A
Respiratory Protection: Wear NIOSH approved respiratory protection where exposure limits are exceeded or in the absence of
proper environmental control. Seek professional advice prior to respirator selection and use. Follow OSHA respirator
regulations (29 CFR 1910.134) and, if necessary, wear a MSHA/NIOSH-approved respirator. Select respirator based on its
suitability to provide adequate worker protection for given working conditions, level of airborne contamination, and presence of
sufficient oxygen. For emergency or nonroutine operations (cleaning spills, reactor vessels, or storage tanks), wear an SCBA.
Protective Clothing/Equipment: Wear chemically protective gloves, boots, aprons, and gauntlets to prevent prolonged or
repeated skin contact. Wear protective eyeglasses or chemical safety goggles, per OSHA eye- and face-protection regulations
(29 CFR 1910.133). Contact lenses are not eye protective devices. Appropriate eye protection must be worn instead of, or in
conjunction with contact lenses.
Safety Stations: Make emergency eyewash stations, safety/quick-drench showers, and washing facilities available in work area.
Contaminated Equipment: Separate contaminated work clothes from street clothes. Launder before reuse. Remove this
material from your shoes and clean personal protective equipment.
Comments: Never eat, drink, or smoke in work areas. Practice good personal hygiene after using this material, especially before
eating, drinking, smoking, using the toilet, or applying cosmetics
Section 9 - Special Precautions and Comments
Handling Precautions:
Storage Requirements:
DOT Transportation Data (49 CFR 172.101):
Shipping Name: Liquid Plastic, N.O. I. Packaging Authorizations Quantity Limitations
Shipping Symbols: a) Exceptions: a) Passenger, Aircraft, or Railcar:
Hazard Class: Not Regulated b) Non-bulk Packaging: b) Cargo Aircraft Only:
ID No.: c) Bulk Packaging:
Packing Group: Vessel Stowage Requirements
Label: a) Vessel Stowage:
Special Provisions (172.102): b) Other:
Prepared By:
Revision Notes:
Disclaimer: The following supersedes Buyer's documents. SELLER MAKES NO REPRESENTATION OR WARRANTY,
EXPRESSED OR IMPLIED, INCLUDING ANY WARRANTY OF MERCHANTABILITY OR FITNESS FOR A
PARTICULAR PURPOSE. No statements herein are to be construed as inducements to infringe any relevant patent. Under no
circumstances shall Seller be liable for incidental, consequential or indirect damages for alleged negligence, breach of warranty,
strict of liability arising in connection with the product(s). Buyer's sole remedy and Seller's sole liability for any claims shall be
Buyer's purchase price. Data and results are based on controlled lab work and must be confirmed by Buyer by testing for its
intended conditions of use. The product(s) has not been tested for, and is therefore not recommended for, uses for which
prolonged contact with mucous membranes, abraded skin, or blood is intended; or for uses for which implantation within the
human body is intended.
Page 3 of 3
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