MATERIAL SAFETY DATA SHEET
This MSDS Complies With 29 CFR 1910.1200 (The Hazard Communication Standard)
This material safety data sheet conforms to the requirements of ANSI Z400.1
SECTION 1 ?CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
FR WG 300-D ?FR WG 300-D
Manufacturer/Supplier: Emergency Spill Information:
American Chemical Technologies, Inc.
485 E. Van Riper Road, Fowlerville, MI 48836 INFOTRAC 1-800-535-5053
Office: 517-223-0300 Fax: 517-223-1703 24 HOURS/DAY, 7 DAYS/WEEK
SECTION 2 ?COMPOSITION/INFORMATION ON INGREDIENTS
Component CAS# Range % by wt.
Water 7732-18-5 35% - 45%
Diethylene Glycol 111-46-68 20% - 40%
Polyalkylene Glycol 52624-57-4 5% - 15%
Diisopropylaminoethanol 96-80-0 1% - 3%
Morpholine 110-91-8 0.1% - 1%
OSHA PEL 20 ppm 70 mg/m3; skin designation
ACGIH TWA value 20 ppm; skin designation
SECTION 3 ?HAZARDS IDENTIFICATION
Emergency Overview: WARNING: MAY CAUSE EYE, SKIN, AND RESPIRATORY
TRACT IRRITATION. MAY CAUSE LIVER DAMAGE BASED ON ANIMAL DATA.
MAY CAUSE KIDNEY DAMAGE BASED ON ANIMAL DATA. MAY CAUSE LUNG
DAMAGE BASED ON ANIMAL DATA.
Potential Health Effects:
Eye Contact: No significant health hazard identified.
Skin Contact: Prolonged or repeated contact may cause skin irritation.
Inhalation: No significant health hazards identified.
Ingestion: Do not take internally. Harmful or fatal if swallowed.
HMIS III rating: (Health:1) (Flammability:1) (Physical hazard:0) (Protection: )
NFPA Code: (Health:1) (Flammability:1) (Reactivity:0)
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American Chemical Technologies, Inc. FR WG 300-D
SECTION 4 ?FIRST AID MEASURES
Eyes: Immediately flush with water for at least 15 minutes, occasionally lifting the upper and
lower eyelids. If irritation develops call a physician.
Skin: Wash affected areas with soap and water. Remove and launder contaminated clothing
before reuse. If irritation develops, get medical attention.
Inhalation: Move to fresh air. Aid in breathing if necessary, and get medical attention.
Ingestion: Immediately rinse mouth and then drink plenty of water, do not induce vomiting,
seek medical attention. Never induce vomiting or give anything by mouth of the victim is
unconscious or having convulsions.
Primary Routes of Entry: The primary routes of exposure to this material are eye or skin
contact, and inhalation. Prolonged or repeated skin or eye contact may result in irritation.
Vapors or mists of diethylene glycol may be irritating to the respiratory tract. The effects of
ingestion include nausea, diarrhea, dizziness, drowsiness, kidney damage and possible coma.
Chronic overexposure to diethylene glycol may result in kidney and liver damage. Breathing
mists by inhalation or ingestion.
Effects of Chronic Overexposure: No information found for this mixture.
Medical Conditions Aggravated by Exposure: None known.
SECTION 5 ?FIRE FIGHTING MEASURES
Flashpoint: None* Method: C.O.C.
UEL: Not applicable. LEL: Not applicable.
Autoignition Temperature: None **.
Flammability Classification: Not Flammable.
Extinguishing Media: Agents approved for Class B (e.g., dry chemical, carbon dioxide, foam,
steam) or water fog.
Fire Fighting Equipment: Fire fighters should wear an approved self-contained breathing
apparatus and turn-out gear.
Hazardous Combustion Products: None.
*After water has been completely evaporated, flash point is 250 癋.
**After water has been completely evaporated, auto-ignition temperature is 765 癋.
SECTION 6 ?ACCIDENTAL RELEASE MEASURES
Spill Mitigation Procedures:
Spill should be contained, solidified, and placed in suitable containers for disposal. This material
is not regulated under RCRA or CERCLA ("superfund").
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American Chemical Technologies, Inc. FR WG 300-D
SECTION 7 ?HANDLING AND STORAGE
Handling: No special requirements if handled with reasonable care.
Storage: Store in a cool dry place. Keep container closed. Avoid prolonged contact with skin
or clothing. Avoid extreme heat.
SECTION 8 ?EXPOSURE CONTROLS/PERSONAL PROTECTION
Eye: Chemical goggles; also wear a face-shield in compliance with OSHA regulations if
splashing hazard exists.
Skin: Wear chemical impermeable gloves if prolonged or repeated contact is likely.
Inhalation: Use local ventilation to limit exposure. If vapors or mists are generated wear
NIOSH/MSHA approved respirator.
Engineering Controls: Control airborne concentrations below the exposure guidelines.
Other Protective Equipment: Gloves, coveralls, apron, boots as necessary to prevent skin
contact. Eye wash fountains and safety showers must be easily accessible. Wear protective
clothing as necessary to prevent contact. Avoid inhalation of vapors/mists. Keep away from
food/drink and animal feeding stuffs. Take off immediately all contaminated clothing. Handle
in accordance with good industrial hygiene and safety practice.
SECTION 9 ?CHEMICAL AND PHYSICAL PROPERTIES
Appearance and Odor : Slightly hazy, red liquid with slight glycol odor
pH : 9.6
Vapor Pressure : Not determined.
Vapor Density : Not determined
Boiling Point : 215 癋
Pour Point : -53 癋
Solubility in water : Soluble
Specific Gravity : 1.08 (water = 1)
Bulk Density : 8.99 lbs./gal
SECTION 10 ?STABILITY AND REACTIVITY
Stability: Stable.
Conditions to Avoid: Extreme heat.
Materials to Avoid: Segregate from acids and bases. Segregate from strong oxidizing agents.
Hazardous Decomposition: None identified.
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American Chemical Technologies, Inc. FR WG 300-D
SECTION 11 ?TOXICOLOGICAL INFORMATION
Existing Medical Conditions Aggravated by Exposure to this Material: No information
found for this mixture.
Animal Toxicology Acute Toxicity:
Rat, Oral Ld: >2000 mg/kg
Rabbit, Skin Irritation: non-irritant (OECD 404)
Rabbit, Eye Irritation: non-irritant (OECD 405)
Information on Diethylene glycol (DEG): Chronic overexposure via ingestion may produce
liver and kidney damage. DEG has been known to produce reproductive toxicity in experimental
animals at very high gavage doses.
Information on Morpholine: At sublethal doses, morpholine caused tearing of the eyes,
irritation and inactivity. Repeated skin applications with morpholine caused skin, liver, and
kidney injury in rabbits. Rats and guinea pigs exposed to 18,000 ppm morpholine exhibited eye
and respiratory irritation. Repeated exposures cause lung, liver, and kidney injury. In a 13-week
inhalation study with rats, morpholine caused nasal lesions at 100 and 250 ppm; no effects were
seen at 25 ppm. In an industry sponsored study, morpholine was not carcinogenic to rats at 10,
50, or 100 ppm; but did cause ophthalmic and nasal lesions.
SECTION 12 ?ECOLOGICAL INFORMATION
Aquatic Toxicity: No data available.
Fish Toxicity: LC >1000 mg/1 (Fathead Minnow, 96 Hr.)
SECTION 13 ?DISPOSAL INFORMATION
Waste Disposal Method: DO NOT discharge into waterways or sewer systems. Dispose of in
accordance with all local, state and federal regulations.
Waste Disposal: This product does not meet the criteria of a hazardous waste as defined under
40 CFR 261, in that it does not exhibit the characteristics of hazardous waste of subpart C, nor is
it listed as a hazardous waste under subpart D. As a non-hazardous liquid waste, it should be
disposed of in accordance with local, state and federal regulations by incineration. Care must be
taken to prevent environmental contamination from the use of this material. The user of this
material has the responsibility to dispose of unused material, residues and containers in
compliance with all relevant local, state and federal laws and regulations regarding treatment,
storage and disposal for hazardous and non-hazardous wastes.
SECTION 14 ?TRANSPORTATION INFORMATION
Dot Hazard Classification: Not Regulated
ICAO/IATA Not Regulated
IMDG (Ambient) Not Regulated
IMDG (Elevated) Not Determined
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American Chemical Technologies, Inc. FR WG 300-D
IMDG EMS Not Regulated
IMDG MFAG Not Regulated
IMO Marine Bulk Not Determined
USCG Compatibility Not Determined
TDG Bulk (Ambient) Not Regulated
TDG Bulk (Elevated) Not Available
TDG Non-Bulk Not Regulated
U.S. DOT Bulk (Ambient) Not Regulated
U.S. DOT Bulk (Elevated) Not Available
U.S. DOT Non-Bulk Not Regulated
DOT NAERG Not Regulated
SECTION 15 ?REGULATORY INFORMATION
U.S. TSCA Inventory: All components of this material are on the US TSCA Inventory.
SARA Section 311/312: Hazard category: ACUTE
Sara Section 313: This product does not contain greater than 1.0% (greater than 0.1%
for carcinogenic substance) of any chemical substances listed
under SARA Section 313.
TDG Regulated Limits: None known
CERCLA Hazardous Substances: None known.
OSHA hazard category: ACGIH TLV established
State Regulations
State RTK
CAS Number Chemical Name State RTK
111-46-6 diethylene glycol PA
110-91-8 morpholine MA, NJ, PA
CA Prop. 65: This product contains a chemical(s) known to the state of
California to cause cancer and birth defects or other reproductive
harm.
U.S. Fuel Registration: Not applicable.
U.S. Dept. of Agriculture: This product has not been filed with the USDA to support H2
approvals.
U.S. Tariff Heading #: Not available
Schedule B #: Not available
FDA Approval: Not applicable
EEC EINECS: All components are incompliance with the EC Seventh
Amendment Directive 92/32/EEC.
Finnish Registration : Not registered
Sweden Registration : Not registered
Norway Registration : Not registered
Danish Registration : Not registered
Switzerland Bag T Reg. #: Not registered
Japan METI All components are in compliance with the Chemical Substances
Control Law of Japan.
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American Chemical Technologies, Inc. FR WG 300-D
Australia: All components are in compliance with chemical notification
requirements in Australia.
Canada: All components are in compliance with the Canadian
Environmental Protection Act and are present on the
Domestic Substances List. This product has been classified
in accordance with the hazard criteria of the CPR and the
MSDS contains all the information required by the CPR.
Switzerland: All components are in compliance with the Environmentally
Hazardous Substances Ordinance in Switzerland.
Korea: All components are in compliance in Korea.
Korean Registration #: Not registered
Philippines: All components are in compliance with the Philippines Toxic
Substances and Hazardous and Nuclear Wastes Control Act
of 1990 (R.A. 6969).
China: This product may require notification in China.
China Registration Number: Not registered
New Zealand Registration Number: Not registered
Malta Registration Number: Not registered
Ukraine Registration Number: Not registered
This product does not contain and is not manufactured with Class I or Class II ozone-depleting
substances.
SECTION 16 ?SPECIAL PRECAUTIONS
Caution!!! Do not take internally. Avoid contact with skin, eyes and clothing. Upon contact
with skin or eyes, wash with water.
Prepared By: Mark D. Latunski
Date Revised: 08/17/2009
Supersedes: 08/11/2008
Date Prepared: 07/20/2001
The information provided herein is believed to be accurate to the best of the company's
knowledge as of the date of its issue. We do not warrant or guarantee the information provided
and will not be held liable for any loss or damage from its use.
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