Material/Product Safety Data Sheet
(MSDS-PSDS)
MP High Energy
Lithium-Ion multi-cell battery pack
Date 07/2009
1. Identification of the Substance or Preparation and Company
Rechargeable lithium-ion
Product multi-cell battery packs
Saft Ferak a.s.
Okr Frydek Mistek
Production sites
73904 Raskovice 247
Czech-Republic
www.saftbatteries.com (section "Contact")
Emergency contacts
+ 1(703)537 38 87 (CHEMTREC US Service Center)
within the USA : 800 424 93 00
2. Composition and Information on Ingredients
Each cell consists of a hermetically sealed metallic container containing a number of chemicals and materials of
construction of which the following could potentially be hazardous upon release.
There is no potential for exposure to these ingredients unless the cell leaks, or opens, following high temperature,
mechanical or electrical abuse.
Content* (wt. %)
Ingredient CAS # ACGIH (TLV) OSHA (PEL)
0
Lithium (in spite of their name,
these batteries do not
metal
contain lithium metal)
5 mg/m3
0.02 mg/m3 8 hours
LiCoO2 19-35 % 12190-79-3 as dust and fumes
(Lithium as dust and fumes
cobalt oxide)
12-15 %
EA (Ethyl Acetate) 141-78-6
None established None established
EC (Ethylene Carbonate)
Organic 96-49-1
DMC
solvents 616-38-6
(Di Methyl Carbonate)
LiPF6
3% None established
None established
21324-40-3
(Lithium
Hexafluoro
phosphate)
None established
PVDF 24937-79-9
<1% None established
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0.1 mg/m3 as fume
0.2 mg/m3 as fume
Copper 3
7440-50-8
9-18 % 3
1.0 mg/m as dust and mist
1.0 mg/m as dust and mist
(Cu)
Aluminium
10.0 mg/m3, as dust 2.0 mg/m3, as soluble salt
7429-50-5
17-27 %
(Al)
Graphite 7782-42-5
3.5 mg/m3, TWA for carbon 2.0 mg/m3, as dust
13-18%
and Carbon 1333-86-4
Steel, Nickel,
and inert Balance Balance
components
* Quantities may vary a little with cell model
ACGIH : American Council of Governmental Industrial Hygienists
TLV : Threshold Limit Value is personal exposure limit, determined y ACGIH.
3. Hazards Identification
The rechargeable lithium-ion batteries described in this Product Safety Data Sheet are sealed units which are not
hazardous when used according to the recommendations of the manufacturer and as long as their integrity is
maintained.
Do not short circuit, puncture, incinerate, crush, immerse in water, force discharge or expose to temperatures above
the declared operating temperature range of the product. Risk of fire or explosion.
Under normal conditions of use, the active materials and liquid electrolyte contained in the cells and batteries are not
exposed to the outside, provided the battery integrity is maintained and seals remain intact. Risk of exposure only in
case of abuse (mechanical, thermal, electrical) which leads to the activation of safety valves and/or the rupture of the
battery container. Electrolyte leakage, electrode materials reaction with moisture/water or battery vent/explosion/fire
may follow, depending upon the circumstances.
4. First Aid Measures (in case of leaking or accidentally opened cells)
In case of accumulator breakage or burst, please evacuate employees from the contaminated area and ensure
maximal ventilation in order to break-up corrosive gas, smoke and unpleasant odors.
If it occurs, by accident, following measures must be taken:
Not anticipated under normal use.
Inhalation Remove from exposure. Remove to fresh air. Rest and keep warm.
In severe cases obtain medical attention.
Not anticipated under normal use.
Skin contact Wash off skin thoroughly with water. Remove contaminated clothing and wash before
reuse. In severe cases obtain medical attention.
Not anticipated under normal use.
Eye contact
Irrigate thoroughly with water for at least 15 minutes. Obtain medical attention.
Not anticipated under normal use.
Ingestion Wash out mouth thoroughly with water and give plenty of water to drink. Obtain
medical attention.
All cases of eye contamination, persistent skin irritation and casualties who have
swallowed this substance or been affected by breathing its vapours should be seen by
Further treatment
a doctor.
5. Fire Fighting Measures
Dry chemical type or CO2 extinguishers, Halon, or copious quantities of water or water-based foam can be used to
MSDS ?Intensium High Energy July 2009
cool down burning Li-ion cells and batteries. During water application, caution should be exercised as burning pieces
of flammable particles may be ejected from the fire.
In case of fire, it is recommended to wear self-contained breathing apparatus, to avoid contact with irritant fumes.
Evacuate all persons from immediate area of fire.
Do not re-enter the area until it has been adequately purged of the fire vapour and extinguishing agent.
6. Accidental Release Measures
In case of electrolyte leakage from a cell or battery, do not inhale the gas as possible.
Remove personnel from area.
If the skin has come into contact with the electrolyte, it should be washed thoroughly with water.
Using protective glasses and gloves, sand or earth should be used to absorb any exuded material.
Seal leaking battery (unless hot) and contaminated absorbent material in plastic bag and dispose of as Special
Waste in accordance with local regulations.
7. Handling and Storage
Do not crush, pierce, short (+) and (-) battery terminals with conductive (i.e. metal)
goods, which would end up into excessive heating.
Do not directly heat or solder. Do not throw into fire.
Handling
Do not mix batteries of different types and brands. Do not mix new and used batteries.
Keep batteries in non conductive (i.e. plastic) trays.
Do not disassemble, mutilate or mechanically abuse cells and batteries.
Store in a cool (preferably below 30癈) and ventilated area, away from moisture,
sources of heat, open flames, food and drink. Keep adequate clearance between walls
and batteries. Temperature above 70癈 may result in battery leakage and rupture.
Storage
Since short circuit can cause burn, leakage and rupture hazard, keep batteries in
original packaging until use and do not jumble them.
Follow Manufacturers recommendations regarding maximum recommended currents
and operating temperature range.
Applying pressure on deforming the battery may lead to disassembly followed by eye,
skin and throat irritation.
Other
Do not immerse in water.
The Li-ion cells and batteries are not designed to be recharged from external power
sources besides specific Li-ion charger models approved by Saft.
Connecting to inappropriate power supplies can result in fire or explosion.
8. Exposure Controls & Personal Protection
Occupational
See section 2
exposure standard
Respiratory
In all fire situations, use self-contained breathing apparatus.
protection
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Hand
In the event of leaking or ruptured cells, wear gloves.
protection
Eye
Safety glasses are recommended in case of leaking or ruptured cells
protection
In the event of leakage or ruptured cells, wear chemical apron.
Other
9. Physical and Chemical Properties
Note: The following points are not applicable unless in case of leaking or damaged batteries with internal components sipping out.
Solid object with cylindrical or prismatic shape
Appearance
Odourless (unless in case of damaged product with leaking electrolyte)
Odour
Not applicable
pH
Not applicable
Flash point
Not applicable
Flammability
> 2 g/cm3
Relative density
Not applicable, unless inner components are exposed
Solubility (water)
Not applicable
Solubility (other)
10. Stability and Reactivity
The product is stable under conditions described in Section 7.
Heating above 70癈 or incinerate. Deformation. Mutilation. Crushing. Piercing.
Conditions to avoid.
Disassembly. Short circuiting. Exposition over a long period to humid conditions.
Strong mineral acids, alkali solutions, strong oxidising materials and conductive
Materials to avoid
materials
Hazardous
HF, CO, CO2
decomposition Products
11. Toxicological Information
None, unless battery ruptures. In the event of exposure to internal contents, corrosive
Signs & symptoms fumes will be very irritating to skin, eyes and mucous membranes. Overexposure can
cause symptoms of non-fibrotic lung injury and membrane irritation.
Lung irritant.
Inhalation
Skin irritant
Skin contact
Eye irritant.
Eye contact
Tissue damage to throat and gastro-respiratory tract if swallowed.
Ingestion
Medical conditions
In the event of exposure to internal contents, eczema, skin allergies, lung injuries,
generally aggravated
asthma and other respiratory disorders may occur.
by exposure
12. Ecological Information
None known if used/disposed of correctly.
Mammalian effects
None known if used/disposed of correctly.
Eco-toxicity
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Bioaccumulation
None known if used/disposed of correctly.
potential
None known if used/disposed of correctly.
Environmental fate
13. Disposal Considerations
Do not incinerate, or subject cells to temperatures in excess of 70oC. Such abuse can result in loss of seal, leakage,
and/or cell explosion. Dispose of or recycle in accordance with appropriate local regulations.
14. Transport Information
For the single cell batteries and multicell battery packs which are restricted to transport
(assigned to the Miscellaneous Class 9), use Class 9 Miscellaneous Dangerous Goods and UN
Label for conveyance Identification Number labels.
In all cases, refer to the product transport certificate issued by the Manufacturer.
UN 3480, for Li-ion batteries transported in bulk
Un number
Lithium-ion batteries
Shipping name
II
Packing group
9033
IMDG Code
CAS
4.1-06
EmS No.
No
Marine pollutant
Class 9
ADR Class
15. Regulatory Information
Regulations specifically applicable to the product:
- ACGIH and OSHA: see exposure limits of the internal ingredients of the battery in section 2.
- IATA/ICAO (air transportation): UN 3480
- IMDG (sea transportation) : UN 3480
- Transportation within the US-DOT, 49 Code of Federal Regulations
16. Other information
This information has been compiled from sources considered to be dependable and is, to the best of our knowledge
and belief, accurate and reliable as of the date compiled.
This information relates to the specific materials designated and may not be valid for such material used in
combination with any other materials or in any process. It is the user's responsibility to satisfy himself as to the
suitability and completeness of this information for his particular use.
Saft does not accept liability for any loss or damage that may occur, whether direct, indirect, incidental or
consequential, from the use of this information. Saft does not offer warranty against patent infringement.
MSDS ?Intensium High Energy July 2009
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