Bayer CropScience
SAFETY DATA SHEET according to Regulation (EU) No. 1907/2006
COYOTE EC300 4X3L BOT IE 1/7
Version 1 / IRL Revision Date: 20.08.2007
102000011056 Print Date: 07.03.2008
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Product information
Trade name COYOTE EC300 4X3L BOT IE
Product code (UVP) 06347924
Usage Fungicide
Company Bayer CropScience Ltd
Bayer Ltd
The Atrium, Blackthorn Road
Sandyford
Dublin 18
Ireland
Telephone +353-1-2999313
Responsible Department Email: ukinfo@bayercropscience.com
Emergency telephone number 1800-409-399
2. HAZARDS IDENTIFICATION
Risk advice to man and the environment
Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical nature
Emulsifiable concentrate (EC)
Trifloxystrobin 75 g/l, Fluoxastrobin 75 g/l, Prothioconazole 150 g/l
Hazardous components
Chemical Name CAS-No. / Symbol(s) R-phrase(s) Concentration [%]
EINECS-No.
Fluoxastrobin 361377-29-9 N R50/53 12.90
Trifloxystrobin 141517-21-7 Xi, N R43, R50/53 6.50
Prothioconazole 178928-70-6 N R51/53 6.50
2-Ethylhexanol propylene 64366-70-7 Xn R20, R52/53 > 1.00 - < 25.00
ethyleneglycol ether
Alkylarylpolyglycol ether 104376-75-2 R52/53 > 1.00 - < 25.00
Citric acid 77-92-9 Xi R36 > 1.00 - < 20.00
201-069-1
gamma-Butyrolactone 96-48-0 Xn R22, R36 > 25.00
202-509-5
For the full text of the R phrases mentioned in this Section, see Section 16.
Bayer CropScience
SAFETY DATA SHEET according to Regulation (EU) No. 1907/2006
COYOTE EC300 4X3L BOT IE 2/7
Version 1 / IRL Revision Date: 20.08.2007
102000011056 Print Date: 07.03.2008
4. FIRST AID MEASURES
General advice
Move out of dangerous area. Place and transport victim in stable position (lying sideways).
Remove contaminated clothing immediately and dispose of safely.
Inhalation
Move to fresh air. Keep patient warm and at rest. Call a physician or poison control center
immediately.
Skin contact
Wash off immediately with soap and plenty of water. If symptoms persist, call a physician.
Eye contact
In case of eye contact, remove contact lens and rinse immediately with plenty of water, also
under the eyelids, for at least 15 minutes.
Ingestion
Do NOT induce vomiting. Rinse mouth. Call a physician or poison control center
immediately.
Notes to Physician
Treatment
Treat symptomatically.
5. FIRE-FIGHTING MEASURES
Suitable Extinguishing Media
Water spray
Carbon dioxide (CO2)
Foam
Sand
Specific hazards during fire fighting
In the event of fire the following can be released:
carbon monoxide (CO)
Hydrogen cyanide (hydrocyanic acid)
hydrogen chloride (HCl)
nitrogen oxides (NOx)
Hydrogen fluoride
Sulphur oxides
Special protective equipment for fire-fighters
In the event of fire and/or explosion do not breathe fumes.
In the event of fire, wear self-contained breathing apparatus.
Further information
Contain the spread of the fire-fighting media.
Do not allow run-off from fire fighting to enter drains or water courses.
6. ACCIDENTAL RELEASE MEASURES
Personal Precautions
Avoid contact with spilled product or contaminated surfaces.
Use personal protective equipment.
Bayer CropScience
SAFETY DATA SHEET according to Regulation (EU) No. 1907/2006
COYOTE EC300 4X3L BOT IE 3/7
Version 1 / IRL Revision Date: 20.08.2007
102000011056 Print Date: 07.03.2008
Environmental Precautions
Do not allow to get into surface water, drains and ground water.
If the product contaminates rivers, lakes or drains inform respective authorities.
Methods for Cleaning Up
Clean contaminated floors and objects thoroughly, observing environmental regulations.
Keep in suitable, closed containers for disposal.
Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder).
Additional Advice
Information regarding personal protective equipment, see section 8.
Information regarding waste disposal, see section 13.
7. HANDLING AND STORAGE
Handling
Advice on safe handling
Use only in area provided with appropriate exhaust ventilation.
Storage
Requirements for storage areas and containers
Keep containers tightly closed in a dry, cool and well-ventilated place.
Store in original container.
Store in a place accessible by authorized persons only.
Advice on common storage
Keep away from food, drink and animal feedingstuffs.
Storage stability
Storage temperature > -10 - < 40 癈
Suitable materials
Tinplate with interior lacquer
Coextruded containers with an internal barrier layer made of ethylene vinyl alcohol
copolymer (EVOH)
Coextruded containers with an internal barrier layer made of polyamide (PA).
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Personal protective equipment
In normal use and handling conditions please refer to the label and/or leaflet. In all other cases
the following recommendations would apply.
Respiratory Protection Wear respirator with an organic vapours and gas filter mask
(protection factor 10) conforming to EN140 type A or equivalent.
Respiratory protection should only be used to control residual risk of
short duration activities, when all reasonably practicable steps have
been taken to reduce exposure at source e.g. containment and/or
local extract ventilation. Always follow respirator manufacturer's
instructions regarding wearing and maintenance.
Hand Protection Wear CE Marked (or equivalent) nitrile rubber gloves (minimum
thickness 0,40 mm). Wash when contaminated. Dispose of when
contaminated inside, when perforated or when contamination
Bayer CropScience
SAFETY DATA SHEET according to Regulation (EU) No. 1907/2006
COYOTE EC300 4X3L BOT IE 4/7
Version 1 / IRL Revision Date: 20.08.2007
102000011056 Print Date: 07.03.2008
outside cannot be removed. Wash hands always before eating,
drinking, smoking or using the toilet.
Eye protection Wear goggles conforming to EN166 (Field of Use 5 or equivalent).
Skin and body protection Wear standard coverall and type 6 suit.
Wear two layers of clothing wherever possible. Polyester/cotton or
cotton overalls should be worn under chemical protection suit and
should be professionally laundered frequently.
If chemical protection suit is splashed, sprayed or significantly
contaminated, decontaminate as far as possible, then carefully
remove and dispose of as advised by manufacturer.
Hygiene measures
Avoid contact with skin, eyes and clothing.
Keep working clothes separately.
Remove soiled clothing immediately and clean thoroughly before using again.
Garments that cannot be cleaned must be destroyed (burnt).
Wash hands before breaks and immediately after handling the product.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance
Form liquid
Colour yellow to brown
Odour aromatic
Safety data
Flash point 102 癈
Ignition temperature 365 癈
Density approx. 1.16 g/cm?at 20 癈
Water solubility emulsifiable
Surface tension 35.9 mN/m
Explosivity Not explosive
10. STABILITY AND REACTIVITY
Conditions to Avoid Extremes of temperature and direct sunlight.
Hazardous Reactions No hazardous reactions when stored and handled according to
prescribed instructions.
11. TOXICOLOGICAL INFORMATION
Bayer CropScience
SAFETY DATA SHEET according to Regulation (EU) No. 1907/2006
COYOTE EC300 4X3L BOT IE 5/7
Version 1 / IRL Revision Date: 20.08.2007
102000011056 Print Date: 07.03.2008
Acute Oral Toxicity LD50 (rat) > 5,000 mg/kg
Acute Inhalation Toxicity LC50 (rat) > 4.826 mg/l
Exposure time: 4 h
Determined in the form of a respirable aerosol.
Acute Dermal Toxicity LD50 (rat) > 4,000 mg/kg
Skin Irritation No skin irritation. (rabbit)
Eye Irritation Slight irritant effect - does not require labelling. (rabbit)
Sensitization Non-sensitizing. (guinea pig)
OECD Test Guideline 406, Magnusson & Kligman test
12. ECOLOGICAL INFORMATION
Ecotoxicity effects
Toxicity to Fish LC50 (Rainbow trout (Oncorhynchus mykiss)) 0.219 mg/l
Exposure time: 96 h
Toxicity to daphnia EC50 (Water flea (Daphnia magna)) 0.25 mg/l
Exposure time: 48 h
Toxicity to algae EC50 (Pseudokirchneriella subcapitata) 2.09 mg/l
Growth rate Exposure time: 72 h
13. DISPOSAL CONSIDERATIONS
Product
It is best to use all of the product in accordance with label directions. If it is necessary to
dispose of unused product, please follow container label instructions and applicable local
guidelines.
Contaminated packaging
Small containers (< 10 l or < 10 kg) should be rinsed thoroughly using an integrated pressure
rinsing device, or, by manually rinsing three times.
Add washings to sprayer at time of filling.
Dispose of empty and cleaned packaging safely.
Follow advice on product label and/or leaflet.
Waste key for the unused product
020108 agrochemical waste containing dangerous substances
14. TRANSPORT INFORMATION
ADR/RID/ADNR
UN-Number 3082
Labels 9
Packaging group III
Hazard no. 90
Bayer CropScience
SAFETY DATA SHEET according to Regulation (EU) No. 1907/2006
COYOTE EC300 4X3L BOT IE 6/7
Version 1 / IRL Revision Date: 20.08.2007
102000011056 Print Date: 07.03.2008
Description of the goods ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S.
(FLUOXASTROBIN, PROTHIOCONAZOLE SOLUTION)
IMDG
UN-Number 3082
Labels 9
Packaging group III
EmS F-A , S-F
Marine pollutant Marine pollutant
Description of the goods ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S.
(FLUOXASTROBIN, PROTHIOCONAZOLE SOLUTION)
IATA
UN-Number 3082
Labels 9
Packaging group III
Description of the goods ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S.
(FLUOXASTROBIN, PROTHIOCONAZOLE SOLUTION )
15. REGULATORY INFORMATION
Classification and labelling in accordance with the EC Directive on dangerous
preparations 1999/45/EC as amended.
Classification:
Labelling according to EC Directives
Hazardous components which must be listed on the label:
?Trifloxystrobin
?Fluoxastrobin
?Prothioconazole
Symbol(s)
N Dangerous for the environment
R-phrase(s)
R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
S-phrase(s)
S35 This material and its container must be disposed of in a safe way.
S57 Use appropriate container to avoid environmental contamination.
The classification/labelling information below is that which has been approved under 'The
European Communities (Authorization, placing on the market, use and control of Plant
Protection products) Regulations 2003' and any subsequent amendments and may differ
from that indicated by any toxicological and/or other testing otherwise indicated in this
'Safety Data Sheet'.
Symbol(s)
Xi Irritant
N Dangerous for the environment
Bayer CropScience
SAFETY DATA SHEET according to Regulation (EU) No. 1907/2006
COYOTE EC300 4X3L BOT IE 7/7
Version 1 / IRL Revision Date: 20.08.2007
102000011056 Print Date: 07.03.2008
R-phrase(s)
R37 Irritating to respiratory system.
R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
S-phrase(s)
S2 Keep out of the reach of children.
S23 Do not breathe spray.
S25 Avoid contact with eyes.
S35 This material and its container must be disposed of in a safe way.
S57 Use appropriate container to avoid environmental contamination.
Exceptional labelling
To avoid risks to man and the environment, comply with the instructions for use.
Contains trifloxystrobin. May produce an allergic reaction.
Further information
WHO-classification: III (Slightly hazardous)
16. OTHER INFORMATION
Further information
Text of R phrases mentioned in Section 3:
R20 Harmful by inhalation.
R22 Harmful if swallowed.
R36 Irritating to eyes.
R43 May cause sensitization by skin contact.
R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
The information given in this Data Sheet has been included in accordance with the guidelines
established by Regulation (EC) 1907/2006. This data sheet complements the user's instructions,
but does not replace them. The information it contains is based on the knowledge available about
the product concerned at the time it was compiled. Users are further reminded of the possible
risks of using a product for purposes other than those for which it was intended. The required
information complies with current EEC legislation. Addressees are requested to observe any
additional national requirements.
Changes since the last version are highlighted in the margin. This version replaces all previous
versions.
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