MSDS FOR RECHARGEABLE LITHIUM-ION BATTERIES
Material/Product Safety Data Sheet
(MSDS-PSDS)
Rechargeable lithium-ion Simplified Advice Code
MP/VL products
single cells and multi-cell battery packs
Revision 3 G
Date 06/2005
1. Identification of the Substance or Preparation and Company
Product Rechargeable lithium-ion
cylindrical and medium prismatic
single cells and multi-cell battery packs
Saft America Inc. Saft
Production sites
313 Crescent Street Rue Georges Leclanch?br>
Valdese BP 1039
North Carolina 28690 86060 Poitiers cedex 9
USA FRANCE
Tel. No. +1 (828) 874 4111 +33 (0)5 49 55 48 48
Fax No. +1 (828) 874 2431 +33 (0)5 49 55 48 50
Emergency contacts +1 (703) 527 3887 (CHEMTREC US Service Center)
Within the USA +1 (800) 424 9300
2. Composition & Information on Ingredients
Each cell consists of an hermetically sealed metallic container containing a number of chemicals and
materials of construction of which the following could potentially be hazardous upon release.
Ingredient Content CAS No. CHIP Classification
Lithium 0
metal (in spite of their name, these
batteries do not contain
any lithium metal)
LiCoO2 30% 12190-79-3 R22, R43
(Lithium S2, S22, S24, S26, S36,
cobaltite) S37, S45
13% 141-78-6
Organic R21, R22, R41, R42, R43
EA (Ethyl Acetate) 96-49-1
solvents S2, S24, S26, S36,
EC (Ethyl Carbonate) 616-38-6 S37, S45
DMC (DiMethyl Carbonate)
(Boiling Points: EA: -84癈;
EC: +38癈 DMC: +4癈)
R14, R21, R22, R4, R43
LiPF6 1% S2, S8, S22, S24, S26,
S36, S37, S45
(Lithium
hexafluoro
phosphate)
Carbon
16% 1333-86-4 NONE KNOWN
(Cn)
Amount varies depending on cell size
MSDS Li-ion
Rev. 3 June 2005
3. Hazards Identification
Do not short circuit, puncture, incinerate, crush, immerse, force discharge or expose to temperatures above
the declared operating temperature range of the product. Risk of fire or explosion. The rechargeable
lithium-ion batteries described in this Product Safety Data Sheet are sealed units which are not hazardous
when used according to the recommendations of the manufacturer.
Under normal conditions of use, the electrode materials and liquid electrolyte they contain are not exposed
to the outside, provided the battery integrity is maintained and seals remain intact. Risk of exposure only in
case of abuse (mechanical, thermal, electrical) which leads to the activation of safety valves and/or the
rupture of the battery container. Electrolyte leakage, electrode materials reaction with moisture/water or
battery vent/explosion/fire may follow, depending upon the circumstances.
4. First Aid Measures
Remove from exposure, rest and keep warm. In severe cases obtain medical
Inhalation
attention.
Wash off skin thoroughly with water. Remove contaminated clothing and
Skin contact
wash before reuse. In severe cases obtain medical attention.
Irrigate thoroughly with water for at least 15 minutes. Obtain medical
Eye contact
attention.
Wash out mouth thoroughly with water and give plenty of water to drink.
Ingestion
Obtain medical attention.
All cases of eye contamination, persistent skin irritation and casualties who
Further treatment have swallowed this substance or been affected by breathing its vapours
should be seen by a Doctor.
5. Fire Fighting Measures
CO2 extinguishers, halon or copious quantities of water or water-based foam can be used to cool down
burning Li- ion cells and batteries.
Do not use for this purpose sand, dry powder or soda ash, graphite powder or fire blankets.
Extinguishing media Use water or CO2 on burning Li-ion cells or batteries
6. Accidental Release Measures
Remove personnel from area until fumes dissipate. If the skin has come into contact with the electrolyte, it
should be washed thoroughly with water.
Sand or earth should be used to absorb any exuded material. Seal leaking battery and contaminated
absorbent material in plastic bag and dispose of as Special Waste in accordance with local regulations.
MSDS Li-ion
Rev. 3 June 2005
7. Handling and Storage
Do not crush, pierce, short (+) and (-) battery terminals with conductive
(i.e. metal) goods. Do not directly heat or solder. Do not throw into fire.
Handling
Do not mix batteries of different types and brands. Do not mix new and used batteries.
Keep batteries in non conductive (i.e. plastic) trays.
Store in a cool (preferably below 30癈) and ventilated area, away from moisture,
sources of heat, open flames, food and drink. Keep adequate clearance between walls
and batteries. Temperature above 70癈 may result in battery leakage and rupture.
Storage
Since short circuit can cause burn, leakage and rupture hazard, keep batteries in
original packaging until use and do not jumble them.
Follow Manufacturers recommendations regarding maximum recommended currents
and operating temperature range.
Other
Applying pressure on deforming the battery may lead to disassembly followed by eye,
skin and throat irritation.
8. Exposure Controls & Personal Protection
Compound:
0.1 mg/m3 max. (OSHA)
LiCoO2
Occupational
EC, EA, DMC N/A
exposure standard
LiPF6 N/A
Respiratory
In all fire situations, use self-contained breathing apparatus.
protection
Hand
In the event of leakage wear gloves.
protection
Eye
Safety glasses are recommended during handling.
protection
In the event of leakage, wear chemical apron.
Other
MSDS Li-ion
Rev. 3 June 2005
9. Physical and Chemical Properties
Cylindrical or prismatic shape
Appearance
Odour
Not Applicable
pH
Not applicable unless individual components exposed
Flash point
Not applicable unless individual components exposed
Flammability
Not applicable unless individual components exposed
Relative density
Not applicable unless individual components exposed
Solubility (water)
Not applicable unless individual components exposed
Solubility (other)
10. Stability and Reactivity
Product is stable under conditions described in Section 7.
Heat above 70癈 or incinerate. Deform. Mutilate. Crush. Pierce.
Conditions to avoid.
Disassemble Short circuit. Expose over a long period to humid conditions.
Materials to avoid
Hazardous
CO, CO2
decomposition
Products
11. Toxicological Information
None, unless battery ruptures. In the event of exposure to internal contents,
corrosive fumes will be very irritating to skin, eyes and mucous membranes.
Signs & symptoms
Overexposure can cause symptoms of non-fibrotic lung injury and membrane
irritation.
Lung irritant.
Inhalation
Skin irritant
Skin contact
Eye irritant.
Eye contact
Tissue damage to throat and gastro-respiratory tract if swallowed.
Ingestion
Medical conditions
In the event of exposure to internal contents, eczema, skin allergies, lung
generally aggravated
injuries, asthma and other respiratory disorders may occur.
by exposure
12. Ecological Information
None known if used/disposed of correctly.
Mammalian effects
None known if used/disposed of correctly.
Eco-toxicity
Bioaccumulation
None known if used/disposed of correctly.
potential
None known if used/disposed of correctly.
Environmental fate
13. Disposal Considerations
Do not incinerate, or subject cells to temperatures in excess of 70oC. Such abuse can result in loss of seal,
leakage, and/or cell explosion. Dispose of in accordance with appropriate local regulations.
MSDS Li-ion
Rev. 3 June 2005
14. Transport Information
For the single cell batteries and multicell battery packs that are non-restricted to transport,
use lithium-ion batteries inside label.
For the single cell batteries and multicell battery packs which are restricted to transport
Label for conveyance (assigned to the Miscellaneous Class 9), use Class 9 Miscellaneous Dangerous Goods and
UN Identification Number labels.
In all cases, refer to the product transport certificate issued by the Manufacturer.
UN 3090
UN number
Lithium Batteries
Shipping name
Depending on their equivalent lithium metal content, some single cells and small
Hazard classification multicell battery packs may be non- assigned to Class 9 (Refer to Transport
Certificate)
II
Packing group
9033
IMDG Code
CAS
4.1-06
EmS No.
No
Marine pollutant
Class 9
ADR Class
15. Regulatory Information
R22 Harmful if swallowed.
LiCoO2
R43 May cause sensitization by skin contact.
R21 Risk of damage to the skin
EA/EC/DMC R22 Harmful if swallowed.
Risk phrases
Organic R41 Risk of serious damage to eye.
solvents R42 May cause sensitization by inhalation.
mix R43 May cause sensitization by skin contact.
R14 Reacts with water
R21 Harmful in contact with skin
LiPF6 R22 Harmful if swallowed.
R41 Risk of serious damage to eye
R43 May cause sensitization by skin contact.
S2 Keep out of reach of children
S22 Do not breathe dust
S24 Avoid contact with skin.
S26 In case of contact with eyes, rinse immediately with
LiCoO2
plenty of water.
S36 Wear suitable protective clothing.
S37 Wear suitable gloves.
S45 In case of incident, seek medical attention.
S2 Keep out of reach of children.
S24 Avoid contact with skin.
EA/EC/DMC
S26 In case of contact with eyes, rinse immediately with
Organic
plenty of water.
Safety phrases
solvents
S36 Wear suitable protective clothing.
mix
S37 Wear suitable gloves.
S45 In case of incident, seek medical attention.
S2 Keep out of reach of children.
S8 Keep away from moisture
S22 Do not breathe dust
S24 Avoid contact with skin
LiPF6 S26 In case of contact with eyes, rinse immediately with
plenty of water.
S36 Wear suitable protective clothing.
S37 Wear suitable gloves.
S45 In case of incident, seek medical attention.
Classified under CHIP
UK regulatory references
MSDS Li-ion
Rev. 3 June 2005
16. Other information
This information has been compiled from sources considered to be dependable and is, to the best of our
knowledge and belief, accurate and reliable as of the date compiled. However, no representation, warranty
(either expressed or implied ) or guarantee is made to the accuracy, reliability or completeness of the
information contained herein.
This information relates to the specific materials designated and may not be valid for such material used in
combination with any other materials or in any process. It is the user's responsibility to satisfy himself as to the
suitability and completeness of this information for his particular use.
Saft does not accept liability for any loss or damage that may occur, whether direct, indirect, incidental or
consequential, from the use of this information. Saft does not offer warranty against patent infringement.
MSDS Li-ion
Rev. 3 June 2005
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