SPECIALTY BATTERY GROUP
Lithium Battery Division
MATERIAL SAFETY DATA SHEET
(form according to EEC Directive 93/112/EC)
NAME : LITHIUM-ION RECHARGEABLE BATTERIES
1 - IDENTIFICATION (of the product and the supplier)
1.1 Product : Rechargeable battery
Yes X
No
Trade name and model : LITHIUM-ION RECHARGEABLE BATTERIES
IEC designation :
Models : MP series MP 144350 ?MP 174865 ?MP 176065
VL series VL 34570 ?VL 34480
Electrochemical system :
Electrodes Negative electrode Positive electrode
Carbon Lithium cobaltite (LiCoO2)*
Solution of lithium hexafluorophosphate (LiPF6)
Electrolyte
**
in a mixture of organic solvents
3.6 Volts
Nominal voltage
*
Equivalent name : lithiated cobalt oxide.
**
Ethylene Carbonate (EC) + DiMethyl Carbonate (DMC) + DiEthyl Carbonate (DEC) + Ethyl Acetate (EA).
1.2 Supplier :
Name : SAFT
Address : For MP series For VL series
Rue Georges Leclanch?- BP 1039 313 Crescent Street
86060 Poitiers Cedex 09 - France Valdese, NC-28690 - USA
Phone : +33 (0)5.49.55.48.48 +1 (0)828.874.4111
Fax : +33 (0)5.49.55.48.50 +1 (0)828.874.2431
1.3 Emergency contact :
For MP series : Plant Manager Phone : +33 (0)5.49.55.48.48
For VL series : CHEMTREC Phone : +1.800.424.9300
For information : +1.828.874.4111 or +1.828.438.3287
Revision 2 Date 11/2003 1
SPECIALTY BATTERY GROUP
Lithium Battery Division
2 - COMPOSITION (typical weight percentages of basic material)
Metals % Plastics % Others %
31 - Polypropylene 10 29
- Steel, Copper, Lithium cobaltite
-
16
Aluminum Carbon
-
13
Organic solvents
-
1
Salts
-
0
Lithium metal
-
3 - HAZARDS IDENTIFICATION
3.1 Physical :
The Lithium-Ion rechargeable batteries described in this Material Safety Data Sheet are sealed
units which are not hazardous when used according to the recommendations of the
manufacturer.
Under normal conditions of use, the solid electrode materials and liquid electrolyte they contain
are non-reactive provided the battery integrity is maintained and seals remain intact. Risk of
exposure only in case of abuse (mechanical, thermal, electrical) which leads to the activation of
the safety valve and/or the rupture of the battery container. Electrolyte leakage, electrode
materials reaction with moisture/water or battery vent/explosion/fire may follow, depending upon
the circumstances.
SAFT MP and VL batteries are fitted with a safety vent for protection in case of excessive
internal pressure and/or temperature.
3.2 Chemical :
Classification of dangerous substances contained into the product
as per directive 67/548/EEC
Substance Melting Boiling point Classification
point
CAS N? Chemical Exposure Indication Special Safety
symbol limit of danger risk (1) advices (2)
S2 S22
12190-79-3 LiCoO2 > 1000癈 N/A 0.1 mg/m3 R22 S24 S26 S36
OSHA R43 S37 S43 S45
EC : 96-49-1 Organic EC : 38癈 EC : 243癈 None Flammable R21 R22 S2 S24
DMC : 616-38-6 solvents DMC : 4癈 DMC : 90癈 established R41 S26 S36
DEC : 105-58-8 (DC-DMC DEC : - 43癈 DEC : 127癈 OSHA R42/43 S37 S45
EA : 141-78-6 DEC-EA) EA : - 84癈 EA : 77癈
N/A None Irritant R14 S2 S8 S22
21324-40-3 LiPF6 (decomposes N/A established Corrosive R21 R22 S24 S26 S36
at 160癈) OSHA R41 R43 S37 S45
Revision 2 Date 11/2003 2
SPECIALTY BATTERY GROUP
Lithium Battery Division
1 ?Nature of special risks :
R 14 Reacts with water.
R 21 Harmful in contact with skin.
R 22 Harmful if swallowed.
R 41 Risk of serious damage to the eye.
R 42/43 May cause sensitization by inhalation and skin contact.
R 43 May cause sensitization by skin contact.
2 ?Safety advices :
S2 Keep out of reach from children.
S8 Keep away from moisture.
S 22 Do not breathe dust.
S 24 Avoid contact with skin.
S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical
attention.
S 36 Wear suitable protective clothing.
S 37 Wear suitable gloves.
S 45 In case of incident, seek medical attention.
4 - FIRST AID MEASURES
In case of battery rupture or explosion, evacuate personnel from contaminated area and
provide maximum ventilation to clear out fumes/gases.
In all case, seek medical attention.
Eye contact : Flush with plenty of water (eyelids held open) for at least 15 minutes.
Skin contact : Remove all contaminated clothing and flush affected areas with plenty of
water and soap for at least 15 minutes.
Do not apply greases or ointments.
Ingestion : Dilute by giving plenty of water and get immediate medical attention.
Assure that the victim does not aspirate vomited material by use of positional
drainage.
Assure that mucus does not obstruct the airway.
Do not give anything by mouth to an unconscious person.
Inhalation : Remove to fresh air and ventilate the contaminated area.
Give oxygen or artificial respiration if needed.
Revision 2 Date 11/2003 3
SPECIALTY BATTERY GROUP
Lithium Battery Division
5 - FIRE-FIGHTING MEASURES
Fire and explosion hazard : The batteries can leak and/or spout vaporized or
decomposed and combustible electrolyte fumes in case of
exposure above 70癈 resulting from inappropriate use or
from the environment.
Possible formation of hydrogen fluoride (HF) and
phosphorous oxides during fire.
LiPF6 salt contained in the electrolyte releases hydrogen
fluoride (HF) in contact with water.
Extinguishing media : Suitable : CO2,
Dry chemical or Foam extinguishers
Not to be used : Type D extinguishers
Special exposure hazards : Following cell overheating due to external source or due to
unproper use, electrolyte leakage or battery container
rupture may occur and release inner component/material in
the environment.
Eye contact : The electrolyte solution contained in the battery is
irritant to ocular tissues.
Skin contact : The electrolyte solution contained in the battery
causes skin irritation.
Ingestion : The ingestion of electrolyte solution causes tissue
damage to throat and gastro/respiratory tract.
Inhalation : Contents of a leaking or ruptured battery can cause
respiratory tract, mucus, membrane irritation and edema.
Special protective equipment : Use self-contained breathing apparatus to avoid breathing
irritant fumes.
Wear protective clothing and equipment to prevent body contact with
electrolyte solution.
6 - ACCIDENTAL RELEASE MEASURES
The material contained within the batteries would only be expelled under abusive conditions.
Using shovel or broom, cover battery or spilled substances with dry sand or vermiculite,
place in approved container (after cooling if necessary) and dispose in accordance with local
regulations.
Revision 2 Date 11/2003 4
SPECIALTY BATTERY GROUP
Lithium Battery Division
7 - HANDLING AND STORAGE
The batteries should not be opened, destroyed nor incinerate since they may leak or rupture
and release in the environment the ingredients they contain.
Handling : Do not crush, pierce, short (+) and (-) battery terminals with conductive (i.e.
metal) goods. Do not directly heat or solder. Do not throw into fire. Do
not mix batteries of different types and brands. Do not mix new and used
batteries. Keep batteries in non-conductive (i.e. plastic) trays.
Storage : Store in a cool (preferably below 30癈) and ventilated area away from moisture,
sources of heat, open flames, food and drink. Keep adequate clearance
between walls and batteries. Temperature above 70癈 may result in
battery leakage and rupture. Since short circuit can cause burn, leakage
and rupture hazard, keep batteries in original packaging until use and do
not jumble them.
Other : Follow manufacturer recommendations regarding maximum recommended
currents and operating temperature range.
Applying pressure on deforming the battery may lead to disassembly
followed by eye, skin and throat irritation.
8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
Respiratory protection : Not necessary under normal use. In case of battery rupture, use
self-contained full-face respiratory equipment.
Hand protection : Not necessary under normal use. Use Viton rubber gloves if handling a
leaking or rupured battery.
Eye protection : Not necessary under normal use. Wear safety goggles or glasses with
side shields if handling a leaking or ruptured battery.
Skin protection : Not necessary under normal use. Use rubber apron and protective
working in case of handling of a ruptured battery.
9 - PHYSICAL AND CHEMICAL PROPERTIES
9.1 Appearance : (Physical shape and color as supplied)
Small prismatic metal cylinders, hermetically sealed and fitted
with an external plastic sleeving.
Revision 2 Date 11/2003 5
SPECIALTY BATTERY GROUP
Lithium Battery Division
9.2 Temperature range :
Continuous Occasional
in storage + 30癈 max - 40/+ 70癈
during discharge - 30/+ 70癈 - 40/+ 70癈
during charge 0/+ 50癈 0/+ 50癈
130 Wh/kg
9.3 Specific energy :
(Note : Wh = Nominal voltage x Rated Ah as defined in IEC
standard N?285. kg = Average battery weight)
300 Wh/kg
9.4 Specific pulse power :
9.5 Mechanical resistance : As defined in relevant IEC standard
9.6 Other :
10 - STABILITY AND REACTIVITY
Conditions to avoid : Heat above 70癈 or incinerate.
Deform, mutilate, crush, pierce, disassemble.
Short circuit.
Prolonged exposure to humid conditions.
Materials to avoid : N/A.
Hazardous decomposition products : Corrosive/Irritant Hydrogen fluoride (HF) is produced
in case of reaction of lithium hexafluorophosphate
(LiPF6) with water.
Combustible vapors and formation of Hydrogen fluoride (HF)
and phosphorous oxides during fire.
11 - TOXOLOGICAL INFORMATION
SAFT MP and VL Lithium-Ion rechargeable batteries do not contain toxic materials.
12 - ECOLOGICAL INFORMATION
When properly used or disposed, SAFT MP and VL Lithium-Ion rechargeable batteries do not
present environmental hazard.
Revision 2 Date 11/2003 6
SPECIALTY BATTERY GROUP
Lithium Battery Division
13 - DISPOSAL CONSIDERATIONS
Dispose in accordance with applicable regulations which vary from country to country.
(In more countries, the thrashing of used batteries is forbidden and the end-users are invited
to dispose them properly, eventually through not-for-profit organizations, mandated by local
governments or organized on a voluntary basis by professionals).
Lithium-Ion batteries should have their terminals insulated and be preferably wrapped in
plastic bags prior to disposal.
13.1 Incineration : Incineration should never be performed by battery users but eventually
by trained professionals in authorized facilities with proper gas
and fumes treatment.
13.2 Landfilling : Leachability regulations (mg/l)
Component Leachability EC limit EPA Other*
Iron 100 5
Nickel 500 2 0.5
* applicable to France
13.3 Recycling : Send to authorized recycling facilities, eventually through
licensed waste carrier.
14 - TRANSPORT INFORMATION
14.1 United Nations : UN? 3090
Classification 9
Packaging ICAO 903 for Air Transport
IMDG 903 for Sea Transport
14.2 International conventions : Air IATA Yes
Sea IMDG Yes
Land ADR (road) Yes
RID (rail) Yes
14.3 Other : In the USA : Code of Federal Regulations
(49 CFR Ch. 1 ?173-185)
Revision 2 Date 11/2003 7
SPECIALTY BATTERY GROUP
Lithium Battery Division
15 - REGULATION INFORMATION
The transport of rechargeable lithium-ion batteries is regulated by various bodies (IATA, IMO,
ADR, US-DOT) that follow the United Nations "Recommendations on the Transport of
Dangerous Goods, Model Regulations, 13th Revised edition - 2003 - Ref. ST/SG/AC.10/1 Rev.
13".
Depending on their lithium metal equivalent weight content, design, and ability to pass safety
tests defined by the UN in the "Recommendations on the Transport of Dangerous Good -
Manual of Tests and Criteria - 3rd Revised edition - 2002 - Ref. ST/SG/AC.10/11 Rev.3
Amendment 1 獿ithium Batteries?, the lithium-ion cells and the battery packs may or may not
be assigned to the UN N?3090 Class-9, that is restricted for transport.
Individual lithium-ion cells and battery packs with respectively less than 1.5 and 8 grams of
equivalent lithium metal content that pass the UN-defined safety tests, are not restricted for
transport (1.0 Ah of declared nominal capacity = 0.3 gram of Li equivalent weight content).
16 - OTHER INFORMATION / DISCLAIMER
This information has been compiled from sources considered to be dependable and is, to the
best of our knowledge and belief, accurate and reliable as of the date compiled. However, no
representation, warranty (either expressed or implied) or guarantee is made to the accuracy,
reliability or completeness of the information contained herein.
This information relates to the specific materials designated and may not be valid for such
material used in combination with any other materials or in any process. It is the user's
responsibility to satisfy himself as to the suitability and completeness of this information for his
particular use.
SAFT does not accept liability for any loss or damage that may occur, whether direct, indirect,
incidental or consequential, from the use of this information. SAFT does not offer warranty
against patent infringement. Additional information is available by calling the telephone
number above designated purpose.
Revision 2 Date 11/2003
(Previous issue First Edition 07/2000)
Signed _________________
Alain Kerouanton
Ltithium Product Manager
Revision 2 Date 11/2003 8
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