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MSDS Material Safety Data Sheet
CAS

872-50-4 7732-18-5 121-44-8

File Name: 872-50-4_7732-18-5_121-44-8.asp

                           HUMISEAL?DIV. OF CHASE CORP.
MATERIAL SAFETY DATA SHEET
Product: HUMISEAL 1H2O UR5S
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

HUMISEAL DIVISION OF CHASE CORP.
MANUFACTURED BY:
128 FIRST STREET
PITTSBURGH, PA 15238

866-932-0800
GENERAL INFORMATION:

800-424-9300, Only in the event of chemical emergencies involving a spill, leak,
EMERGENCY, CHEMTREC:
fire, exposure or any accident involving chemicals.

04/27/09
REVISION DATE:
JEFF SARGEANT
PREPARED BY:

2. COMPOSITION/INFORMATION ON INGREDIENTS
APP. % BY
CAS NUMBER IDENTIFICATION
WGT.
872-50-4 N-Methyl-2-pyrrolidone 6%
Proprietary Polyurethane Resin 32%
7732-18-5 Water 58%
121-44-8 Triethylamine 2%
Proprietary Optical Brightener 0.25%
Proprietary Surfactants 1.5%

3. HAZARDOUS IDENTIFICATION
HAZARDOUS POLYMERIZATION: Will Not Occur

ROUTES OF EXPOSURE: Inhalation, Skin, Eyes and Ingestion.

IMMEDIATE EFFECTS:

INHALATION: Causes irritation to respiratory tract. Causes stupor (central nervous system depression).

SKIN CONTACT: Repeated or prolonged contact can cause drying and irritation of the skin.

EYE CONTACT: Liquid and vapors are irritating to eyes. Contact with vapors can cause severe irritation.

INGESTION: Ingestion is not an anticipated route of exposure for this material in industrial use. Can cause
tissue damage.

MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE:

Significant exposure to these chemicals may adversely affect people with chronic disease of the respiratory system,
skin and/or eyes.

4. FIRST AID MEASURES
GENERAL ADVICE: Consult Physician immediately.

INHALATION: Remove victim to fresh air and provide oxygen if breathing is difficult.


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HUMISEAL?DIV. OF CHASE CORP.
MATERIAL SAFETY DATA SHEET
SKIN CONTACT: Flush with water while removing contaminated clothing. Wash skin with soap and water.
Seek medical attention if irritation develops or persists. Wash contaminated clothing before
reuse.

EYE CONTACT: Flush eyes with large quantities of clean running water for at least 15 minutes. Seek
immediate medical attention.

INGESTION: Give victim 1 or 2 glasses of water or milk. (Never give anything by mouth to an unconscious
person.) Do not induce vomiting. If vomiting occurs spontaneously, keep head below hips to
prevent aspiration into lungs. Contact Physician immediately.

5. FIRE FIGHTING MEASURES
SUITABLE EXTINGUISHING MEDIA: Foam, Carbon Dioxide, water spray or dry chemical. Use self-contained
breathing apparatus and full fire fighting clothing.
FIRE AND EXPLOSION HAZARDS: Closed containers may rupture when exposed to extreme heat. Air
oxidation of this product may cause it to spontaneously combust.

HAZARDOUS COMBUSTION Carbon monoxide, carbon dioxide and irritating or toxic vapors.
PRODUCTS:

6. ACCIDENTAL RELEASE MEASURES
PRECAUTIONS FOR PERSONNEL: Wear protective clothing. Ensure adequate ventilation. Use self-contained
breathing apparatus if required.

ENVIRONMENTAL PRECAUTIONS: Avoid discharge to drains, sewers and natural water supply.

PROCESS FOR CLEANING: For small spills, absorb with inert material then place in a chemical waste
container. Remove sources of ignition. Scoop material with non-sparking
tools.

7. HANDLING AND STORAGE
HANDLING: Ventilate work area sufficiently. Keep containers closed. Avoid contact with eyes, skin and clothing.
Wash hands thoroughly after handling and before eating or drinking.

STORAGE: Store containers tightly closed when not in use in a cool, dry and well ventilated area. Keep from
freezing. Allow product to reach room temperature before using.

8. EXPOSURE RESTRICTIONS AND PERSONAL PROTECTION
MATERIALS WITH LIMITS THAT REQUIRE SUPERVISION:

CAS APP. % OSHA
IDENTIFICATION VALUE UNIT
NUMBER BY WGT. PEL
872-50-4 N-Methyl-2-pyrrolidone 6% TWA 25/103 ppm/(m
121-44-8 Triethylamine 2% TWA 25 g/m3)
ppm

ADDITIONAL ADVICE: Use personal protective equipment, i.e., suitable work clothing, eye goggles and
protective gloves (butyl rubber). Use adequate ventilation to maintain airborne
concentrations to levels that are below recommended exposure limits. A NIOSH/MSHA
approved air purifying respirator, equipped with organic vapor cartridge, may be used if
airborne concentrations are expected to exceed exposure limits.

9. PHYSICAL PROPERTIES
ODOR: MILD AMINE-LIKE

CHANGE OF STATE UNIT
VALUE/AREA METHOD
0
FREEZING POINT: <0 C
0
BOILING POINT: >100 C
0
C (0F)
FLASH POINT: >100 TCC
IGNITION TEMPERATURE:

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HUMISEAL?DIV. OF CHASE CORP.
MATERIAL SAFETY DATA SHEET
SPECIFIC GRAVITY: 1.05 H2O = 1
% VOLATILE BY VOLUME: 65 %
SOLUBILITY IN WATER: Completely Miscible
PH VALUE: Weakly alkaline
VISCOSITY: 50 CPS
FLAMMABLE LIMITS: LEL N/A UEL N/A
EVAPORATION RATE: <1 BUAC = 1
APPEARANCE MILKY WHITE LIQUID

10. STABILITY AND REACTIVITY
STABILITY: This material is stable during storage and during its intended use.
CONDITIONS TO AVOID: Keep from freezing
MATERIALS TO AVOID: Contact with strong oxidizing, acidic or alkaline agents.
DECOMPOSITION PRODUCTS: Thermal decomposition may form: Carbon Monoxide, Carbon Dioxide and
oxides of Nitrogen.
HAZARDOUS Hazardous polymerization will not occur.
POLYMERIZATION:

11. TOXICOLOGICAL INFORMATION
ACUTE ORAL LD: Ingestion in high concentrations may cause injuries to gastrointestinal tract.
ACUTE DERMAL: May cause eye or skin irritation with susceptible persons. Prolonged skin contact may
cause irritation.
ACUTE INHALATION: Inhalation in high concentrations may cause injuries to respiratory tract.
OTHER: Liquid and vapor are irritating to the eyes.

12. ECOLOGICAL INFORMATION
VOLATILE ORGANIC COMPOUNDS: 65 Grams Per Liter (g/l). Pounds Per Gallon (lb/g).


13. DISPOSAL CONSIDERATIONS
DISPOSAL METHOD: Disposal should be made in accordance with Federal, State and Local regulations. For
further information, contact your state or local waste agency or use EPA RCRA Hotline (1-
800-424-9346)

14. TRANSPORT INFORMATION
SHIPPING CLASS: DOT: Not Regulated

15. REGULATORY INFORMATION
SARA SECTION 302:
SARA (311,312) HAZARD CLASS: This material is classified as an IMMEDIATE HEALTH HAZARD and
DELAYED HEATH HAZARD under the US Superfund Amendment and
Reauthorization Act.
SARA (313) CHEMICALS: N-Methyl-2-prrrolidone (CAS# 872-50-4) 6.0%, triethylamine (CAS# 121-44-8)
CERCLA: Triethylamine (121-44-8): Reportable Quantity = 5,000 lbs
CPSC CLASSIFICATION:
HMIS: FLAMMABILITY: 1 REACTIVITY: 0 HEALTH: 2
NFPA: FLAMMABILITY: 1 REACTIVITY: 0 HEALTH: 2

CALIFORNIA PROPOSITION 65:
A. This product contains a chemical known to the State of CA to cause birth defects or other reproductive harm.
B. This product contains a chemical known to the State of CA to cause cancer.
C. This product contains a chemical known to the State of CA to cause cancer and birth defects or other
reproductive harm. (N-methylpyrolidone CAS# 872-50-4)

ECCN: EAR99




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HUMISEAL?DIV. OF CHASE CORP.
MATERIAL SAFETY DATA SHEET

16. OTHER INFORMATION
THIS DATA IS OFFERED IN GOOD FAITH AS TYPICAL VALUES AND ARE NOT A PRODUCT SPECIFICATION.
NO WARRANTY, EITHER EXPRESSED OR IMPLIED IS MADE. THE STATED RECOMMENDED HANDLING
PROCEDURES ARE BELIEVED TO BE GENERALLY APPLICABLE. HOWEVER, EACH USER SHOULD REVIEW
THESE RECOMMENDATIONS IN THE SPECIFIC CONTEXT OF THE INTENDED USE.

C = Ceiling Limit, NEGL = Negligible, N/A = Not Applicable, N/E = Not Established, PROP. = Proprietary.




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