MATERIAL SAFETY DATA SHEET
Company Name: Superior Stone Products, Inc.
Product Name: Superior E-5000 - Part B
Issue Date: 01/01/04
Revision Date: 02/04/08
MSDS Number: SUP-90491
Section I ?Chemical Product and Company Identification
Product Identifier: Superior E-5000 - Part B
Product Description: Epoxy Adhesive and Filler - Part B
Chemical Family: Amine
24 Hour Emergency Telephone Number:
MANUFACTURER:
CHEMTREC 800-424-9300
Superior Stone Products, Inc.
8580 Byron Commerce Drive
Byron Center, MI 49315
616-583-0171
Section II ?Composition/Information on Ingredients
If present, IARC, NTP and OSHA carcinogens and chemicals subject to the reporting requirements of SARA title III
Section 313 are identified in this Section.
Ingredient CAS# % (By Weight) OSHA PEL ACGIH TLV
Diethylenetriamine 111-40-0 <10% 10 ppm 1 ppm
Bisphenol, A 80-05-7 <10% Not Established Not Established
Benzyl Alcohol 100-51-6 <20% Not Established Not Established
Nonylphenol 25154-52-3 <25% Not Established Not Established
Isophorone Diamine 2855-13-2 <30% Not Established Not Established
DETA-Reaction products w/ 28063-82-3 <10% Not Established Not Established
ethylene oxide
Section III ?Hazards Identification/Possible Routes of Entry
Caution - Corrosive
Caution - Combustible Liquid
Ingestion: Toxic or harmful if swallowed. May cause severe burns of the mouth and throat as well as a danger of
perforation of the esophagus and the stomach. May cause gastrointestinal disturbances, pain and discomfort. May
cause central nervous system effects such as headaches, nausea, dizziness, confusion and breathing difficulties.
Skin: Product is severely irritating to the skin. May case skin sensitization and chemical burns. If absorbed through
the skin, may cause central nervous system effects such as headaches, nausea, dizziness, confusion and breathing
difficulties.
Eye: May cause severe eye irritation and burns. May cause lachrymation (tears). Severe damage to the eyes may
occur causing blindness.
Inhalation: May cause nose, throat and lung irritation or burns. May cause central nervous system effects such as
headaches, nausea, dizziness, confusion and breathing difficulties if vapors/aerosols are inhaled in high concentrations.
HMIS Codes:
Fire: 1
Health: 3
Reactivity: 0
Personal Protective Index: X
Page 1 of 4
MATERIAL SAFETY DATA SHEET
Company Name: Superior Stone Products, Inc.
Product Name: Superior E-5000 - Part B
Issue Date: 01/01/04
Revision Date: 02/04/08
MSDS Number: SUP-90491
Section IV ?First Aid Measures
If Swallowed: Do not induce vomiting unless directed by a medical professional. Never give anything by mouth to an
unconscious person. Prevent aspiration of vomit. Turn victims head to the side. Seek immediate medical attention.
Skin Contact Remove contaminated clothing. Immediately flush area with cool water. Continue irrigating skin until
Contact:
medical assistance is obtained. If clothing is stuck to the burn area do not pull off, but cut around it. Cover burn area
with a sterile dressing. Seek immediate medical attention.
If Inhaled: Remove to fresh air. If breathing is labored or has stopped artificial respiration may be provided by a
certified individual at the direction of a medical professional. Seek immediate medical attention.
Eyes: Hold eyelids apart and immediately flush with water for at least 15 minutes. Seek immediate medical attention.
If medical attention is not immediately available continue irrigation until patient receives medical care.
Section V - Fire Fighting Measures
Flash Point: 95oC (203oF) (Estimated)
Class IIIB Combustible Liquid
Hazardous Products of Combustion: Carbon monoxide may be generated if incomplete combustion occurs. May
generate ammonia and toxic nitrogen oxide gasses. Do not allow runoff from fire fighting to enter drains or water
courses. Use of water may result in the formation of very toxic aqueous solutions. Downwind personnel should be
evacuated.
Extinguishing Agents: Use water fog, foam, dry chemical, dry sand, limestone powder or carbon dioxide. Water
spray may be used to cool down tanks in proximity to the fire.
Special Fire Fighting Procedures: Utilize full protective clothing and self-contained breathing apparatus
Fire Fighting Pr
Unusual Fire And Explosion Hazards: Intense heat may cause nearby containers to erupt.
Fire
Section VI - Accidental Release Measures
Procedure For Cleanup: Ventilate area. Use self contained breathing apparatus and chemically protective clothing.
For
Wear suitable protective clothing, cloves and eye/face protection. Absorb spill with an absorbent material such as
sawdust, vermiculite or sand and place in a closed chemical container. If large spill, dike the area to prevent this material
from entering water systems or sewers. Prevent contamination of soil and water. Dispose of material in accordance
with federal, state/provincial and local regulations.
Section VII - Handling and Storage
General Procedures: Read and observe all precautions on product label and material safety data sheet before
handling. Refer to product label or manufactures technical bulletins for the proper use and handling of this material.
Avoid contact with skin, eyes and clothing. Do not use or store near flame, sparks or hot surfaces. Use only in well
ventilated area. Keep container closed. Do not weld, heat or drill container.
Storage Temperature: 50o - 100o F
Temperature:
Shelf Life: One (1) year when stored at room temperature.
Section VIII - Exposure Controls/Personal Protection
Respiratory Protection: Not normally required if adequate ventilation is provided. In a confined space, self-
contained breathing apparatus may be required. Use only a NIOSH/MSHA approved respiratory protection if exposed to
vapors above the PEL.
Ventilation: Normal ventilation is typically adequate in most situations. If the PEL is exceed, provide explosion proof
ventilation to reduce these levels.
Protective Gloves: Wear appropriate protective gloves to prevent skin contact.
Eye Protection: Wear safety glasses, face shield or chemical goggles.
Page 2 of 4
MATERIAL SAFETY DATA SHEET
Company Name: Superior Stone Products, Inc.
Product Name: Superior E-5000 - Part B
Issue Date: 01/01/04
Revision Date: 02/04/08
MSDS Number: SUP-90491
Section IX ?Physical and Chemical Properties
Form: Liquid
Appearance: Light Amber to Amber
Odor: Amine
Boiling Point: > 200oC (>392oF) (estimated)
Point:
Vapor Pressure: <1.00 mmHg @ 70oF (21oC)
Pressure:
Solubility in Water: Slightly Soluble
Water:
Section X - Stability and Reactivity
Stability: Stable under normal use conditions.
Incompatibility (materials to avoid): Oxidizing agents, Organic acids, sodium hypochlorite, mineral acids, reactive
metals, materials reactive with hydroxyl compounds, nitrous acid and other nitrosating agents and caustic sodas. This
product may slowly corrode copper, aluminum, zinc and galvanized surfaces. Reaction with peroxides may result in a
violent decomposition of peroxide possibly creating and explosion. CAUTION! N-Nitroamines, many of which are known
to be potent carcinogens, may be formed when the product comes in contact with nitrous acid, nitrites or atmospheres
with high nitrous oxide concentrations.
Hazardous Decomposition or Combustion Products: Nitric acid, ammonia, nitrogen oxides (NOx), nitrogen oxide
may react with water vapor to form corrosive nitric acid, carbon monoxide (CO), carbon dioxide (CO2), aldehydes,
flammable hydrocarbon fragments (e.g. acetylene) and nitrosamine.
Section XI - Toxicological Information
Acute Oral Toxicity: No data available for this product.
Toxicity
oxicity:
Acute Dermal Toxicity: No data available for this product.
Toxicity
oxicity:
Acute Inhalation Toxicity: No data available for this product.
Toxicity
oxicity:
Contact manufacturer for any applicable toxicological information.
Section XII - Ecological Information
No data available for this product. Contact manufacturer for any applicable ecological information.
Section XIII - Disposal Considerations
Dispose of container and unused contents in accordance with federal, provincial, state and local requirements. For further
information, contact your provincial, state or local solid waste agency or the United States Environmental Protection
Agency's RCRA hotline (800-424-9346).
Section XIV - Transportation Information
Transportation Data/DOT
Amines, Liquid, Corrosive, n.o.s.
Hazard Class: 8
NA/UN Number: 2735
Packing Group: III
Please refer to U.S. Department of Transportation regulations for more information
Page 3 of 4
MATERIAL SAFETY DATA SHEET
Company Name: Superior Stone Products, Inc.
Product Name: Superior E-5000 - Part B
Issue Date: 01/01/04
Revision Date: 02/04/08
MSDS Number: SUP-90491
Section XV - Regulatory Information
Regulations:
Federal Regulations:
Sara Title III - Section 311
Title
Immediate (Acute) Health Effects: Yes
Chronic (Delayed) Health Effects: Yes
Fire Hazard: No
Sudden Release of Pressure Hazard: No
Reactivity: No
Title
Sara Title III - Section 313
None
Canadian Ingredient Disclosure List:
Benzyl Alcohol (100-51-6)
Isophorone Diamine (2855-13-2)
Bisphenol A (80-05-7)
WHMIS Classification:
Class B - Division 3
Class D - Division 1 - Subdivision A
Class E
Section XVI - Other Information
MANUFACTURER DISCL AIMER This information is provided in good faith and is correct to the best of Superior
MANUFACTURER DISCLAIMER AIMER:
Stone Products' knowledge as of the date hereof; however, Superior Stone Products makes no representation as to its
completeness or accuracy. Customers are encouraged to make their own determination as to the suitability of this
product for their purpose prior to use. Superior Stone Products disclaims responsibility to damages of any kind resulting
from the use of this information. THERE ARE NO WARRANTIES OR REPRESENTATIONS, EXPRESS OR IMPLIED, INCLUDING
THOSE OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE WITH RESPECT TO THIS INFORMATION OR TO
THE PRODUCT IT DESCRIBES.
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