7/20/04
Associated Technologies. Date of Preparation:
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MATERIAL SAFETY DATA SHEET
SECTION 1 - PRODUCT AND COMPANY IDENTIFICATION
AT- 4020 (Component A)
Product Name:
Product Use/Class: Methyl Methacrylate Adhesive Resin
MANUFACTURER:
Associated Technologies
610 N. Bicycle Path ?Suite 7
Port Jefferson Station, NY 11776
EMERGENCY TELEPHONE NUMBERS: 800 255 3924 CHEM TEL
SECTION 2. - COMPOSITION/INFORMATION ON INGREDIENTS
ITEM CHEMICAL NAME CAS NUMBER WT
1 Methyl Methacrylate (MMA) 80-62-6 40-75
2 Cumene Hydroperoxide 80-15-9 1-5
3 Methacrylic acid 79-41-4 5-10
4 p-toluenesulfonyl chloride 98-59-9 1-5
5 Maleic acid 110-16-7 1-5
OSHA HAZARDOUS COMPONENTS (29 CFR 1910.1200)
EXPOSURE LIMITS 8 hrs. TWA (ppm)
ITEM ACGIH TLV OSHA PEL OTHER
1 100ppm
100ppm 100ppm (Canada)
2
None None Skin
3
20ppm (Skin) 20ppm (skin) none
4 &5
N.A. N.A. N.A.
SECTION 3. - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW:
PHYSICAL STATE: Liquid. COLOR: Milky white, gray. ODOR: Pungent. Acrylic.
WARNING! FLAMMABLE LIQUID AND VAPOR. MAY CAUSE ALLERGIC SKIN REACTION
MAY CAUSE EYE, SKIN, AND RESPIRATORY TRACT IRRITATION
POTENTIAL HEALTH EFFECTS:
EYE:
Moderate eye irritation. Redness. Excess tearing.
SKIN:
Allergic skin reaction. itching. Moderate skin irritation. Redness.
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INGESTION:
Toxicity by ingestion is not likely to occur
INHALATION:
Moderate respiratory tract irritation. Shortness of breath. Coughing.
CHRONIC:
Detailed information provided in section 11.
CONDITIONS AGGRAVATED BY EXPOSURE:
Respiratory disorders. Skin disorders. Eye disorders
SECTION 4. - FIRST AID MEASURES
EYE:
Immediately flush eyes with water for at least 20 minutes. Get immediate medical attention.
SKIN:
Wash thoroughly with soap and water. Discard contaminated clothing. Do not use organic solvents. If irritation occurs, get medical
attention.
INHALATION:
Remove person to fresh air or apply artificial respiration if not breathing. Get medical attention if short of breathe or if respiratory
symptoms develop.
INGESTION:
Give 1-2 glasses of milk or water to conscious person. Get immediate medical attention. DO NOT INDUCE VOMITING.
SECTION 5. - FIRE FIGHTING MEASURES
2.1 MMA, Upper 12.5 for MMA
51F (TCC)
Flashpoint and Method: Flammable Limits:
NA
Autoignition Temperature:
EXTINGUISHING MEDIA:
Flammable liquid, insoluble in water.
Use DRY chemical powder
SPECIAL FIRE FIGHTING INSTRUCTIONS:
Fire fighters should wear positive pressure self-contained breathing apparatus (SCBA) and full turnout gear.
HAZARDOUS COMBUSTION PRODUCTS:
Oxides of carbon and nitrogen. Hydrogen cyanide. Methylene bisphenyl isocyanate. Hydrocarbons. Smoke. Cyclopentanone.
Butanediol. Tetrahydrofuran
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SECTION 6. - ACCIDENTAL RELEASE MEASURES
Remove sources of ignition. Use with ventilation. Dike area to prevent spreading. Absorb on vermiculite, sand or other inert
absorbing material. Dispose of as chemical waste in accordance with current local, state, and federal regulations. Do not discharge into
water. Incineration recommended. Wash spill area with strong detergent. After proper mixing of resin and activator sides, the material
will polymerize into a cured solid state which can be treated as a nonhazardous solid . Applicable CERCLA/RCRA waste code:0001
(ignitability) U162 (MMA)
SECTION 7. - HANDLING AND STORAGE
HANDLING:
Avoid prolonged or repeated breathing of vapor. Avoid contact with skin and eyes. Wash hands before smoking or eating.
STORAGE:
Avoid storage over 100F, contamination with incompatible materials. Store in cool place. Do not store in direct sunlight.
Recommended storage in flammable material containment area
SECTION 8. - EXPOSURE CONTROLS/PERSONAL PROTECTION
ENGINEERING CONTROLS:
Use local exhaust ventilation if the potential for airborne exposure exists
PERSONAL PROTECTION:
RESPIRATORY PROTECTION:
Use NIOSH approved respirator if there is potential to exceed any exposure limit(s).
Use chemical resistant, impermeable clothing including gloves and either an apron or body suit to prevent
SKIN PROTECTION: skin contact .
Chemical splash goggles or safety glasses with side shields.
EYE PROTECTION:
NA
OTHER PROTECTIVE EQUIPMENT:
SECTION 9. - PHYSICAL AND CHEMICAL PROPERTIES
29mm at 20C >1 Heavier than air, 3.5 for MMA
Vapor Pressure: Vapor Density:
Slight 0.94-1.0
Solubility in H20: Specific Gravity:
214F for MMA NA
Boiling Point: Freezing Point:
Liquid NA
Physical State: pH:
Pungent. Acrylic Light gel, milky white in color
Odor: Appearance:
1.98%; 1.92 g/l (adhesive & activator mixed)
VOC:
SECTION 10. - STABILITY AND REACTIVITY
STABILITY: Stable
INCOMPATIBLE MATERIALS AND CONDITIONS TO AVOID:
No known conditions to avoid. Oxidizing agents, Alkalis, Moisture. Strong acids. Strong bases. Reducing agent. Ultraviolet
radiation. Amines
HAZARDOUS POLYMERIZATION:
May occur. Excessive aging. Excessive heat. Polymerization catalysts. Oxygen-free atmosphere. Inhibitor depletion. Direct
sunlight.
None known
HAZARDOUS DECOMPOSITION PRODUCTS:
AT- 4020 (Component A) 7/20/04
Date of Preparation:
Product Name
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SECTION 11. - TOXICOLOGICAL INFORMATION
PRODUCT TOXICOLOGY DATA: Not available Carcinogen
Ingredients NTP IARC OSHA
Methyl methacrylate No N/A No
Organic peroxide No No
No
Methacrylic acid No No No
p-toluenesulfonyl chloride No No No
Maleic acid No NO No
Ingredients Target Organ and other health effects
Methyl methacrylate Allergen. Irritant. Nervous System. Respiratory. Kidney. Liver
Organic peroxide Allergen. Central nervous system. Corrosive. Irritant. Mutagen
Methacrylic acid Allergen. Corrosive. Irritant.
p-toluenesulfonyl chloride Allergen, Irritant, Corrosive
Maleic acid Allergen, Corrosive, Irritant, Respiratory passages
SECTION 12. - ECOLOGICAL INFORMATION
Not available
SECTION 13. - DISPOSAL CONSIDERATIONS
Dispose according to EPA and local governmental regulations. EPA Hazardous waste # 0001;U162;D003
DISPOSAL METHOD:
SECTION 14. - TRANSPORT INFORMATION
DOT (49 CFR 172)
Adhesives
HAZARD CLASS: 3
PROPER SHIPPING NAME:
II
IDENTIFICATION NUMBER: UN1133 PACKING GROUP:
Consumer Commodity
EXCEPTIONS: Single unit less than or equal to 1 liter PROPER SHIPPING NAME:
CLASS / DIVISION: ORM-D
INTERNATIONAL AIR TRANSPORTATION (IATA)
Adhesives
CLASS / DIVISION: 3
PROPER SHIPPING NAME:
II
IDENTIFICATION NUMBER: UN1133 PACKING GROUP:
Consumer Commodity, Class 9, ID 8000, less than 500 ml.
EXCEPTIONS:
7/20/04
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SECTION 15. - REGULATORY INFORMATION
TSCA (Toxic Substance Control Act):
All components are listed on or exempt from listing on the Toxic Substances Control Act Inventory.
CERCLA (Comprehensive Emergency Response, Compensation, and Liability Act):
NA
SARA TITLE III (Superfund Amendments and Reauthorization Act):
313 Reportable Ingredients:
Methyl Methacrylate, Cumene hydroperoxide, maleic acid
CANADIAN INVENTORY STATUS:
All components are listed on or are exempt from listing on the Canadian Domestic Substances List
CALIFORNIA PROPOSITION 65:
This product contains chemicals known to the state of California to cause cancer, birth defects, or other reproductive harm
SECTION 16. - OTHER INFORMATION
NFPA
2 3 2 None
Health Fire Reactivity Special
Hazardous Materials Information System (HMIS) Ratings:
2 3 2 See section 8
Flammability
Health Reactivity Protective Equipment:
REVISION SUMMARY:
Change to 16 section format. Revision 1 7/20/04
This information is furnished without warranty, representation, or license of any kind, except that this information is
accurate to the best of the Supplier's knowledge, or is obtained from sources believed by the Supplier to be accurate. No
warranty is expressed or implied regarding the accuracy of this information or the results to be obtained from its use
thereof. The Supplier assumes no responsibility for injuries proximately caused by use of the Material if reasonable
safety procedures are not followed as stipulated in this Data Sheet. Additionally, the Supplier assumes no responsibility
for injuries proximately caused by abnormal use of the Material even if reasonable safety procedures are followed. Buyer
assumes the risk in its use of the Material.
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