HENKEL LOCTITE CORPORATION 10/28/02
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 01 of 05
Depend(R) ODC-Free 330 Adhesive
ADHESIVE 20253
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Product Name: Depend(R) ODC-Free 330 Adhesive
Item No.: ADHESIVE 20253 Part of Kit: 20253
Product Type: Structural Adhesive
2. COMPOSITION, INFORMATION ON INGREDIENTS
Ingredients CAS No. %
Heterocyclic methacrylate 2455-24-5 50-55
Polyethylene based rubber 68037-39-8 30-35
Alkyl methacrylate 688-84-6 5-10
METHACRYLIC ACID 79-41-4 5-10
CUMENE HYDROPEROXIDE* 80-15-9 0.1-1
2,6-DI-tert-BUTYL-p-CRESOL 128-37-0 0.1-1
Epoxy resin 25068-38-6 0.1-1
CARBON TETRACHLORIDE* 56-23-5 0.01-0.1
* This component is listed as a SARA Section 313 Toxic Chemical.
Under the Clean Air Act this product is exempted from labeling as an
ozone depleting chemical (40 CFR 82.106(b)(1)).
Ingredients which have exposure limits
Exposure Limits (TWA) ACGIH OSHA OTHER
Ingredients (TLV) (PEL)
Alkyl methacrylate None None 25ppm
METHACRYLIC ACID 20 ppm TWA 20 ppm TWA skin 4 ppm skin
70 mg/m3 70 mg/m3 skin 10 ppm skinSTEL
CUMENE HYDROPEROXIDE None None 1ppm(6mg/m3)
Skin(WEEL)
2,6-DI-tert-BUTYL-p-CRESOL 2 mg/m3 TWA None 10 mg/m3
CARBON TETRACHLORIDE 5 ppm TWA skin 2 ppm TWA None
31 mg/m3 skin 12.6 mg/m3
Exposure Limits (STEL) ACGIH OSHA
Ingredients (TLV) (PEL)
CARBON TETRACHLORIDE 10 ppm skin None
63 mg/m3 skin
HENKEL LOCTITE CORPORATION 10/28/02
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 02 of 05
Product Name: Depend(R) ODC-Free 330 Adhesive
Item No.: ADHESIVE 20253
3. HAZARDS IDENTIFICATION
Toxicity: Liquid is an eye irritant.
Vapors may irritate eye, nose and throat.
Oral LD50 more than 10000 mg/kg.
Dermal LD50 more than 4000 mg/kg.
Primary Routes of Entry: Eyes, skin, inhalation
Signs and Symptoms
of Exposure: Irritation of eyes, nose, throat.
Existing Conditions
Aggravated by Exposure: BHT: skin diseases, asthma
Carbon tetrachloride: cirrhosis of the liver
Literature Referenced Carcinogen
Ingredients Target Organ and Other Health Effects NTP IARC OSHA
Heterocyclic methacrylate ALG IRR NO NO NO
Polyethylene based rubber NTO NO NO NO
Alkyl methacrylate ALG IRR NO NO NO
METHACRYLIC ACID ALG COR IRR NO NO NO
CUMENE HYDROPEROXIDE ALG CNS COR IRR MUT NO NO NO
2,6-DI-tert-BUTYL-p-CRESOL IRR MUT NO N/A NO
Epoxy resin ALG IRR NO NO NO
CARBON TETRACHLORIDE AC2 CAR CNS IRR KID LIV SOM YES 2B NO
-------------------------------------------------------------------------------
Abbreviations
N/A Not Applicable 2B Possibly carcinogenic to humans
AC2 ACGIH suspected human carcinogen ALG Allergen
CAR Cardiac CNS Central nervous system
COR Corrosive IRR Irritant
KID Kidney LIV Liver
MUT Mutagen NTO No Target Organs
SOM Some evidence of carcinogenicity
4. FIRST AID MEASURES
Ingestion: Do not induce vomiting. Keep individual calm.
Obtain medical attention.
Inhalation: Remove to fresh air. If symptoms persist, obtain
medical attention.
Skin Contact: Wash with soap and water.
Eye Contact: Flush at least 15 minutes with water. Obtain
medical attention.
HENKEL LOCTITE CORPORATION 10/28/02
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 03 of 05
Product Name: Depend(R) ODC-Free 330 Adhesive
Item No.: ADHESIVE 20253
5. FIRE FIGHTING MEASURES
Flash Point: Approximately 188癋 Method: Tag Closed Cup
Recommended
Extinguishing Agents: Carbon dioxide, foam, dry chemical
Special Firefighting
Procedures: Not available
Hazardous Products formed
by Fire or Thermal Decomp Toxic chlorides
Unusual Fire or
Explosion Hazards: None
Explosive Limits:
(% by volume in air)Lower Not available
(% by volume in air)Upper Not available
6. ACCIDENTAL RELEASE MEASURES
Steps to be taken in case
of spill or leak: Soak up in an inert absorbent. Store in partly
filled, closed container until disposal.
7. HANDLING AND STORAGE
Safe Storage: Store below 100癋
(Contact Loctite Customer Service 1-800-243-4874 for shelf life information)
Handling: Keep away from eyes. Avoid breathing of vapors.
Avoid prolonged skin contact.
8. EXPOSURE CONTROLS, PERSONAL PROTECTION
Eyes: Safety glasses or goggles.
Skin: Rubber or plastic gloves.
Ventilation: Provide sufficient local ventilation to maintain
vapor concentration below TLV
Respiratory Not available
See Section 2 for Exposure Limits.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance: Amber liquid
Odor: Sharp, irritating
Boiling Point: More than 300癋
pH: Does not apply
Solubility in Water: Slight
Specific Gravity Approximately 1.1 at 80癋
Volatile Organic Compound
(EPA Method 24) 68.5%; 754 grams per liter
Vapor Pressure: Less than 10mm at 80癋
HENKEL LOCTITE CORPORATION 10/28/02
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 04 of 05
Product Name: Depend(R) ODC-Free 330 Adhesive
Item No.: ADHESIVE 20253
9. PHYSICAL AND CHEMICAL PROPERTIES (continued)
Vapor Density: Not available
Evaporation Rate
(Ether = 1) Not available
10. STABILITY AND REACTIVITY
Stability: Stable
Hazardous Polymerization: Will not occur
Incompatibility: None
Conditions to Avoid: Not available
Hazardous Decomposition
Products (non-thermal): None
11. TOXICOLOGICAL INFORMATION
See Section 3.
12. ECOLOGICAL INFORMATION
No data available
13. DISPOSAL CONSIDERATIONS
Recommended methods of
disposal: Incinerate following EPA and local regulations.
EPA Hazardous Waste
Number User should perform TCLP testing per 40 CFR 261.24
for D019.
14. TRANSPORTATION INFORMATION
DOT (49 CFR 172)
Domestic Ground Transport
Proper Shipping Name: Unrestricted (Not more than 450 liters);
Combustible liquids, n.o.s. (Tetrahydrofurfuryl
methacrylate solution)(More than 450 liters)
Hazard Class or
Division: Unrestricted (Not more than 450 liters)
Combustible liquid (More than 450 liters)
Identification Number: None (Not more than 450 liters);
NA 1993 (More than 450 liters)
Marine Pollutant: None
IATA
Proper Shipping Name: Unrestricted
Class or Division: Unrestricted
UN or ID Number: None
HENKEL LOCTITE CORPORATION 10/28/02
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 05 of 05
Product Name: Depend(R) ODC-Free 330 Adhesive
Item No.: ADHESIVE 20253
15. REGULATORY INFORMATION
CA Proposition 65: WARNING: This product contains a chemical known to
the State of California to cause cancer.
Epichlorohydrin, Carbon Tetrachloride,
Chloroform
16. OTHER INFORMATION
Estimated NFPA(R) Code:
Health Hazard: 2
Fire Hazard: 2
Reactivity Hazard: 0
Specific Hazard: Does not apply
Estimated HMIS(R) Code:
Health Hazard: 2
Flammability Hazard: 2
Reactivity Hazards: 0
Personal Protection: See Section 8.
NFPA is a registered trademark of the National Fire Protection Assn.
HMIS is a registered trademark of the National Paint and Coatings Assn.
Prepared By: Stephen Repetto
Title: Research Chemist, Environmental Health & Safety
Company: Henkel Loctite Corporation, Rocky Hill CT 06067
(24hr.) Phone: (860) 571-5100
Revision Date: August 14, 2000 Revision: 0031
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