Huntsman Advanced Materials Americas Inc.
4917 Dawn Avenue
East Lansing, MI 48823-5691
8am to 5pm Phone: (517) 351-5900
24-Hour Emergency Phone: 1-888-354-3323
MSDS No: 33713
Effective Date: 1/18/05 Material Safety Data Sheet
Health: 2*
1. PRODUCT IDENTIFICATION 3
Flammability: 3
2 1
Reactivity: 1
Trade Name: Araldite 2021 Resin
Personal Protection:
Chemical Family: Acrylate
HMIS RATING
NFPA RATING
Intended Use or Product Type: Adhesive resin component
2. COMPOSITION / INFORMATION ON INGREDIENTS
O CAS No. CHEMICAL IDENTITY EXPOSURE LIMITS CARCINOGEN
S STATUS
H ACGIH OSHA MFR. IARC NTP OSHA
A TWA STEL PEL STEL
* 80-62-6 2- Propenoic Acid, 2-Methyl-, 100 NE 100 NE NE NR NR NR
Methyl Ester ppm ppm
Common Methyl methacrylate
Name:
* 79-41-4 2- Propenoic Acid, 2-Methyl- 20 ppm NE NE NE NE NR NR NR
Common Methacrylic acid
Name:
* = OSHA Hazardous Ingredient
3. HAZARDS IDENTIFICATION
Emergency Overview: Flammable. Causes irritation if inhaled and can cause skin irritation, eye irritation, and allergic skin
reaction. May be harmful if absorbed through skin or if swallowed.
Primary Route(s) of Entry: Dermal; heated product may produce inhalable vapors.
Chronic: Overexposure may have effects on heart, lungs, kidney, and liver.
4. FIRST AID MEASURES
Ingestion: If conscious, give 2 - 4 glasses of water to drink. Do not induce vomiting. Call a physician.
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Araldite 2021 Resin Huntsman Advanced Materials
Americas Inc.
Effective Date: 1/18/05
Skin: Immediately wash with soap and water. Remove contaminated clothing and launder before reuse. Destroy contaminated
shoes.
Inhalation: Remove to fresh air. Call a physician.
Eyes: Immediately flush eyes with water for at least 15 minutes. Call a physician.
Overexposure Effects: Causes irritation if inhaled and can cause skin irritation, eye irritation, and allergic skin reaction. May be
harmful if absorbed through skin or if swallowed.
Medical Conditions Aggravated by Exposure: Skin, eye and pulmonary conditions.
Additional Information: Referral to a physician is recommended if there is any question about the seriousness of any injury.
5. FIRE FIGHTING MEASURES
Flash Point: 50癋 ( 10 癈)
Flash Point Method Used: TCC
Flammable Limits in Air (Lower - % by volume): 2.1
Flammable Limits in Air (Upper - % by volume): 12.5
Fire Fighting Extinguishing Media: Carbon dioxide, dry chemical, foam, water.
Fire Fighting Equipment: Use self-contained breathing apparatus.
Fire and Explosion Hazards: Decomposition and combustion products may be toxic.
6. ACCIDENTAL RELEASE MEASURES
Accidental Release Measures: Remove spillage by absorbing in absorbent material.
7. HANDLING AND STORAGE
Signal Word: Warning!
Precautions: Flammable liquid. Keep away from heat, sparks, and flame. Keep container closed when not in use. Use with
adequate ventilation. Causes irritation if inhaled and can cause skin irritation, eye irritation, and allergic skin reaction. May be
harmful if absorbed through skin or if swallowed. Avoid breathing vapor or mist. Avoid contact with eyes, skin, and clothing.
Avoid tasting or swallowing. Keep container closed when not in use. Use with adequate ventilation. Wash thoroughly after
handling. Notice! Overexposure may have effects on heart, lungs, kidney, and liver.
Other Handling Information: Nuisance dust may be generated when sanding or sawing cured material.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Skin Protection: Wear impermeable gloves.
Respiratory Protection: Use NIOSH approved organic vapor cartridge respirator when vapor/mist exposure is likely.
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Effective Date: 1/18/05
Eye Protection: Wear splash-proof chemical goggles.
Engineering Controls: General mechanical and local exhaust in accordance with ACGIH recommendations.
9. PHYSICAL AND CHEMICAL PROPERTIES
Color: Off White
Odor: Varied fragant odor
Physical State: Paste
Solubility in Water: Not Determined
Viscosity: Not Evaluated
Vapor Pressure: 28 mm Hg at 68癋 (20 癈)
Specific Gravity: 1.03 (water = 1)
Boiling Point: 213癋 (101 癈)
Evaporation Rate: 3 (Butyl Acetate = 1)
Vapor Density: > 1 (Air = 1)
pH: psi
Percent Volatile: Negligible.
10. STABILITY AND REACTIVITY
Conditions to Avoid: Excessive heat for prolonged periods of time.
Stability: Stable.
Incompatibility: Strong oxidizers, acids and bases.
Hazardous Decomposition Products: Combustion may form toxic materials, such as carbon dioxide, carbon monoxide.
Hazardous Polymerization: Will not occur.
11. TOXICOLOGICAL INFORMATION
Acute Oral Effects (LD50): Component(s) are slightly toxic, 500 - 5000 mg/kg (rat).
Acute Dermal Toxicity (LD50): Component(s) are slightly toxic, 1000 - 2000 mg/kg (rabbit).
Acute Inhalation Exposure Effects: Respiratory irritant.
Sensitization: Possible in susceptible individuals.
Skin Irritation: Irritant.
Eye Irritation: Irritant.
12. ECOLOGICAL INFORMATION
13. DISPOSAL CONSIDERATIONS
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Araldite 2021 Resin Huntsman Advanced Materials
Americas Inc.
Effective Date: 1/18/05
Waste Disposal Method: Consult qualified local or corporate personnel for method that will comply with local, state and federal
health and environmental regulations.
14. TRANSPORT INFORMATION
DOT: Non-Bulk
Proper Shipping Name: Consumer commodity, orm-d
15. REGULATORY INFORMATION
US Federal Regulations:
Occupational Safety and Health Act (OSHA): This Material Safety Data Sheet (MSDS) has been prepared in compliance with
the federal OSHA Hazard Communication Standard 29 CFR 1910.1200. This product is considered to be a hazardous chemical
under that standard.
Resource Conservation and Recovery Act (RCRA): Not a hazardous waste under RCRA (40 CFR 261).
SARA Title III: Section 313 Toxic Chemical List (TCL): This product contains a toxic chemical(s) for routine annual toxic
chemical release reporting under section 313 (40 CFR 372). This information must be included in all MSDS's copied or distributed
for this material.
Chemical Name: 2- Propenoic Acid, 2-Methyl-, Methyl Ester
Common Name: Methyl methacrylate
Percent in Composition: 55 % by wt
Comment:
TSCA Section 8(b) - Inventory Status: Chemical components listed on TSCA Inventory.
TSCA Section 12(b) - Export Notification: This product does not contain any chemical(s) that are subject to a Section 12(b)
export notification.
State Regulations:
California Proposition 65: This product does not contain any chemicals currently on the California list of Known Carcinogens and
Reproductive Toxins.
Pennsylvania Right-to-Know: The following is required composition information:
Chemical Name: 2- Propenoic Acid, 2-Methyl-, Methyl Ester
Common Name: Methyl methacrylate
CAS Number: 80-62-6
Comment: Environmental Hazardous Substance
Chemical Name: Adhesive Resin
CAS Number: Held confidential by our supplier
Comment: Not on Pennsylvania Hazardous Substance List
Chemical Name: 2- Propenoic Acid, 2-Methyl-
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Araldite 2021 Resin Huntsman Advanced Materials
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Effective Date: 1/18/05
Common Name: Methacrylic acid
CAS Number: 79-41-4
Comment: Hazardous Substance
16. OTHER INFORMATION
MSDS No: 33713
Approved By: Dianne Blessing
Title: EH&S Specialist
Disclaimer: The information and recommendations contained herein are based upon tests in controlled laboratory conditions, are
believed to be correct, and are provided for the sole purpose of hazard communication as part of Huntsman's product safety
program. This product has not been tested for, and therefore is not recommended or suitable for, uses for which prolonged contact
with mucous membranes, abraded skin, or blood is intended or likely, or for uses for which implantation within the human body is
intended, and Huntsman assumes no liability for any such uses.
The information and recommendations contained herein are not intended to constitute performance information concerning the
product, which is available in separate technical data sheets available from Huntsman upon request. Users are urged, and are urged
to urge others who may come in contact with the product, to obtain and consult data sheets prior to purchase, use, transportation or
storage of the product.
HUNTSMAN MAKES NO REPRESENTATION OR WARRANTY, EXPRESS OR IMPLIED, INCLUDING WARRANTIES OF
MERCHANTABILITY, QUALITY, OR FITNESS FOR A PARTICULAR PURPOSE. HUNTSMAN'S LIABILITY IS
STRICTLY LIMITED TO REIMBURSEMENT OF BUYER'S PURCHASE PRICE, OR IN HUNTSMAN'S DISCRETION
REPLACEMENT, OF THE PRODUCT IN RESPECT OF WHICH SUCH CLAIM IS MADE. HUNTSMAN'S LIABILITY IS
STRICTLY LIMITED BY LEGAL NOTICES IN TECHNICAL DATA SHEETS, PRODUCT LITERATURE AND/OR SALE
DOCUMENTS. The foregoing DISCLAIMERS and LIMITATION OF LIABILITY supercede inconsistent or contradictory
provisions in Buyer's documents.
USER SHOULD CONSULT A LEGAL ADVISOR OR THE APPROPRIATE GOVERNMENTAL AGENCY TO DETERMINE
THE APPLICABILITY OR EFFECT OF ANY LAW OR REGULATION WITH RESPECT TO THE PRODUCT. HUNTSMAN
DOES NOT UNDERTAKE TO FURNISH ADVICE ON SUCH MATTERS.
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