MATERIAL SAFETY DATA SHEET
IPS Date Revised: FEB 2008
WELD-ON Supersedes: OCT 2007
Information on this form is furnished solely for the purpose of compliance with the Occupational Safety and Health Act and shall not be used for any other purpose.
IPS Corporation urges the customers receiving this Material Safety Data Sheet to study it carefully to become aware of the hazards, if any, of the product involved.
In the interest of safety, you should notify your employees, agents and contractors of the information on this sheet.
SECTION I - IDENTIFICATION
MANUFACTURER'S NAME Transportation Emergencies:
IPS Corporation, Structural Adhesives CHEMTREC: (800) 424-9300
ADDRESS Medical Emergencies:
600 Ellis Road, Durham, NC 27703 3 E COMPANY (24 Hour No.) (800) 451-8346
Business: (310) 898-3300
CHEMICAL NAME and FAMILY TRADE NAME: WELD-ON SS 1100 Series
Reactive Cement, Weld-On SS 1105, Weld-On 1115 - Component A
Mixture of Synthetic Resins and Methyl Methacrylate Monomer FORMULA: Proprietary
SECTION II - HAZARDOUS INGREDIENTS
None of the ingredients below are listed as
carcinogens by IARC, NTP or OSHA CAS# WEIGHT % ACGIH-TLV ACGIH-STEL OSHA-PEL OSHA-STEL
Acrylic Synthetic Resin Blend NON/HAZ N/A N/A
Methyl Methacrylate Monomer 80-62-6 < 60.0* 100 PPM 100 PPM
Maleic Acid 110-16-7 < 5.0 N/E N/E
Methacrylic Acid 79-41-4 < 9.0* 20 PPM-TWA 20 PPM (Skin)
Organic Peroxide 80-15-9 <1.0* 50 PPM 50 PPM
Under some circumstances, mutagenic changes have been observed with Methyl Methacrylate in animal studies. Precautions should be taken to avoid unnecessary
exposure to this cement.
*Title III Section 313 Supplier Notification: This product contains toxic chemicals subject to the reporting requirements of Section 313 of the Emergency Planning
and Community Right-To-Know Act of 1986 and of 40CFR372. This information must be included in all MSDS's that are copied and distributed for this material.
BULK SHIPPING INFORMATION / CONTAINERS LARGER THAN ONE LITER SPECIAL HAZARD DESIGNATIONS
HMIS NFPA HAZARD RATING
DOT Shipping Name: Adhesive
DOT Hazard Class: 3 HEALTH: 2 2 0 - MINIMAL
Identification Number: UN 1133 FLAMMABILITY: 3 3 1 - SLIGHT
Packaging Group: II REACTIVITY: 1 1 2 - MODERATE
Label Required: Flammable Liquid PROTECTIVE 3 - SERIOUS
EQUIPMENT: H 4 - SEVERE
SHIPPING INFORMATION FOR CONTAINERS LESS THAN ONE LITER
DOT Shipping Name: Consumer Commodity H = Eye, Hand/Skin, Respiratory Protection and Impervious Apron
DOT Hazard Class: ORM-D
SECTION III - PHYSICAL DATA
APPEARANCE ODOR BOILING POINT (?C)
F/?br>
Off-White, paste Distinct fragrant odor 214?(101?Based on Methyl Methacrylate
F C)
Monomer
SPECIFIC GRAVITY @ 73??3.6?(20??2?br>
F C ) VAPOR PRESSURE (mm Hg.) PERCENT VOLATILE BY VOLUME (%)
Typical 0.96 ?0.040 29 mm Hg. @ 68?(20?based on Methyl
F C) < 70 %
Methacrylate Monomer
VAPOR DENSITY (Air = 1) EVAPORATION RATE (BUAC = 1) SOLUBILITY IN WATER
3.46 based on Monomer Approx. 3 Based on Monomer 1.6
VOC STATEMENT: Maximum VOC 75 grams/liter (when mixed with Component "B"). Reactive Adhesive. Meets SCAQMD Rule 1168 requirements for Plastic Cement Welding.
SECTION IV - FIRE AND EXPLOSION HAZARD DATA
FLASH POINT FLAMMABLE LIMITS LEL UEL
51?(11?T.C.C.
F C) (PERCENT BY VOLUME) 2.1 12.5
FIRE EXTINGUISHING MEDIA
Ansul "Purple K" potassium bicarbonate dry chemical, any appropriately sized ABC dry chemical, carbon dioxide or foam extinguisher can be used for small fires. Use
of a water fog by trained personnel can extinguish small/large fires.
SPECIAL FIRE FIGHTING PROCEDURES
Evacuate enclosed areas. Stay upwind. Full protective equipment, including self-contained breathing apparatus, is recommended. Fight fires from a safe distance or
protected area. Use of a water fog by trained personnel can extinguish small/large fires and avoid water flow or water streams/spray distributing burning material or
contaminated water over a large area or into sewers or storm drains. Use water spray to cool containers, to flush spills from source of ignition and to disperse vapors.
UNUSUAL FIRE AND EXPLOSION HAZARDS
Sealed containers exposed to elevated temperatures may rupture explosively due to polymerization. Vapors are heavier than air and may travel to source(s) of ignition
at or near ground or lower level(s) and flash back. Susceptible to spontaneous heating. Considered a fire hazard because of low flash point.
200-c
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SECTION V - HEALTH HAZARD DATA
PRIMARY ROUTES
OF ENTRY: X Inhalation X Skin Contact Eye Contact Ingestion
EFFECT OF OVEREXPOSURE
ACUTE:
Inhalation: Exposure may result in nausea, drowsiness, dizziness, headache and other CNS effects. Can cause irritation of eyes and nasal passages.
Skin Contact: Skin irritant. Potential skin sensitizer. Repeated or prolonged contact may result in skin irritation, contact dermatitis, rash, itching, swelling.
Eye Contact: Direct exposure may result in irritation with corneal or conjuctival inflammation.
Ingestion: Moderately toxic. Do not induce vomiting and obtain prompt medical attention.
CHRONIC:
Inhalation Toxicity described in animals exposed by inhalation include inflammation of the nasal cavity and changes in nasal sensory cells and
slight decrease in body weight.
Ingestion Toxicity described in animals exposed by ingestion include decreased body weight and increased relative kidney weight at high dose levels.
REPRODUCTIVE EFFECTS TERATOGENICITY MUTAGENICITY EMBRYOTOXICITY SENSITIZATION TO PRODUCT SYNERGISTIC PRODUCTS
N. AP. N. AP. POSS N. AP. N. AP. N. AV.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: This material may aggravate an existing dermatitis. Individuals with pre-existing diseases of the lungs,
liver or kidney may have increased susceptibility to the toxicity of excessive exposures.
EMERGENCY AND FIRST AID PROCEDURES
Inhalation: Remove patient to fresh air and if breathing stopped, give artificial respiration. If breathing is difficult, give oxygen. Contact physician
immediately.
Eye Contact: Immediately flush eyes with water for 15 minutes and contact a physician.
Skin Contact: Wash skin with soap and water for at least 15 minutes. If irritation develops, get medical attention.
Ingestion: Give 1 or 2 glasses of water or milk. Do not induce vomiting. Call physician or poison control center immediately.
SECTION VI - REACTIVITY
STABILITY UNSTABLE CONDITIONS TO AVOID: Exposure to fire, heat, sparks, open flame and other sources of ignition,
STABLE X direct sunlight or contact with oxidizing materials.
INCOMPATIBILITY ACTIVE OXYGEN CONTENT (Component "A") < 1% Not con-
(MATERIALS TO AVOID) Reducing and oxidizing agents. sidered an EPA hazardous Waste, Number D003, Reactive Waste
HAZARDOUS DECOMPOSITION PRODUCTS
This product gives out carbon monoxide (CO), carbon dioxide (CO? and smoke upon combustion. Generates heat when mixed with oxidizing materials.
HAZARDOUS MAY OCCUR X CONDITIONS TO AVOID
POLYMERIZATION WILL NOT OCCUR Keep away from heat Above 130?(55?sparks, open flame and other sources of ignition.
F C),
Do not store above 100?(38?br>
F C)
SECTION VII - SPILL OR LEAK PROCEDURES
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED
Eliminate all ignition sources. Avoid exposure of personnel to toxic concentration of vapor and guard against accidental fire and explosion. Contain liquid with sand, earth or
nonflammable absorbent material sweep and scoop up using non-sparking tools and transfer into steel drums for recovery or disposal. Prevent liquid from entering drains.
WASTE DISPOSAL METHOD
Follow local, State and Federal regulations. Material should not be allowed to drain into domestic sewer or storm drains. Consult authorities or disposal expert.
SECTION VIII - SPECIAL PROTECTION INFORMATION
RESPIRATORY PROTECTION (Specify type)
Atmospheric levels should be maintained below established exposure limits contained in Section II. For emergency conditions, use an approved positive pressure self-
contained breathing apparatus.
VENTILATION
Use only with adequate ventilation. Avoid use in close quarters or confined spaces. Open doors and/or windows to ensure airflow in volume and pattern to keep airborne
contaminants below applicable exposure limits found in Section II. Use local exhaust ventilation to remove airborne contaminants from employee breathing zone. Use only
explosion-proof ventilation equipment.
PROTECTIVE GLOVES EYE PROTECTION
PVA or rubber coated gloves Splashproof chemical goggles
OTHER PROTECTIVE EQUIPMENT AND HYGIENIC PRACTICES
Good industrial hygiene practices and impervious apron and a source of running water to flush or wash the eyes and skin in case of contact.
SECTION IX - SPECIAL PRECAUTIONS
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING
Store in a cool dark place below 70?(21?br>
F C). Keep away from all sources of heat, sparks, open flame and other sources of ignition. Close container after each use.
Ground containers when pouring. Use with adequate ventilation. Avoid contact with eyes, skin and clothing. Wash thoroughly after handling. Train employees on all special
handling procedures before they work with this product.
OTHER PRECAUTIONS
Follow all precautionary information given on container label, product bulletins and our solvent cementing literature. All material handling equipment should be
electrically grounded.
The information contained herein is based on data considered accurate. However, no warranty is expressed or implied regarding the accuracy of this data or the results to be obtained from the use
thereof.
200 + p
Sheet 2 of 2
MATERIAL SAFETY DATA SHEET
IPS Date Revised: FEB 2008
WELD-ON Supersedes: OCT 2007
Information on this form is furnished solely for the purpose of compliance with the Occupational Safety and Health Act and shall not be used for any other purpose.
IPS Corporation urges the customers receiving this Material Safety Data Sheet to study it carefully to become aware of the hazards, if any, of the product involved.
In the interest of safety, you should notify your employees, agents and contractors of the information on this sheet.
SECTION I
MANUFACTURER'S NAME Transportation Emergencies:
IPS Corporation CHEMTREC: (800) 424-9300
ADDRESS Medical Emergencies:
17109 S. Main St., P.O. Box 379, Gardena, CA. 90248 3 E COMPANY (24 Hour No.) (800) 451-8346
Business: (310) 898-3300
CHEMICAL NAME and FAMILY TRADE NAME: WELD-ON SS 1100 Series
Acrylic Reactive Adhesive Activator WELD-ON SS 1105 & SS 1115 Component B (Activator)
FORMULA: Proprietary
SECTION II - HAZARDOUS INGREDIENTS
None of the ingredients below are listed as
carcinogens by IARC, NTP or OSHA CAS# WEIGHT % ACGIH-TLV ACGIH-STEL OSHA-PEL OSHA-STEL
Acrylic Synthetic Resins
Methyl Methacrylate Monomer 80-62-6 < 64.0* 100 PPM 100 PPM
Catalyst/Initiators NON-HAZ
*Title III Section 313 Supplier Notification: This product contains toxic chemicals subject to the reporting requirements of Section 313 of the Emergency Planning
and Community Right-To-Know Act of 1986 and of 40CFR372. This information must be included in all MSDS's that are copied and distributed for this material.
BULK SHIPPING INFORMATION / CONTAINERS LARGER THAN ONE LITER SPECIAL HAZARD DESIGNATIONS
HMIS NFPA HAZARD RATING
DOT Shipping Name: Adhesive
DOT Hazard Class: 3 HEALTH: 2 2 0 - MINIMAL
Identification Number: UN 1133 FLAMMABILITY: 3 3 1 - SLIGHT
Packaging Group: III REACTIVITY: 1 1 2 - MODERATE
Label Required: Flammable Liquid PROTECTIVE 3 - SERIOUS
EQUIPMENT: H 4 - SEVERE
SHIPPING INFORMATION FOR CONTAINERS LESS THAN ONE LITER
DOT Shipping Name: Consumer Commodity H = Eye, Hand/Skin, Respiratory Protection and Impervious Apron
DOT Hazard Class: ORM-D
SECTION III - PHYSICAL DATA
APPEARANCE ODOR BOILING POINT (?C)
F/?br>
Black or off-white, viscous liquid Distinct fragrant odor 214?(101?Based on Methyl Methacrylate
F C)
Monomer
SPECIFIC GRAVITY @ 73??3.6?(23??2?br>
F C ) VAPOR PRESSURE (mm Hg.) PERCENT VOLATILE BY VOLUME (%)
Typical 0.96 ?0.040 29 mm Hg. @ 68?(20?based on Methyl
F C) <64 %
Methacrylate Monomer
VAPOR DENSITY (Air = 1) EVAPORATION RATE (BUAC = 1) SOLUBILITY IN WATER
3.46 Approx. 3 Based on Monomer 1.6
VOC STATEMENT: Maximum VOC 75 grams/liter (when components mixed). Reactive Adhesive. Meets SCAQMD Rule 1168.
SECTION IV - FIRE AND EXPLOSION HAZARD DATA
FLASH POINT FLAMMABLE LIMITS LEL UEL
51?(11?C.O.C
F C) (Percent by Volume) 0.47 -
FIRE EXTINGUISHING MEDIA
Ansul "Purple K" potassium bicarbonate dry chemical, any appropriately sized ABC dry chemical, carbon dioxide, or foam extinguisher can be used for small fires. Use of
of a water fog by trained personnel can extinguish small/large fires and avoid water flow or water streams distributing burning material or contaminated water over a large
area or into sewers or storm drains.
SPECIAL FIRE FIGHTING PROCEDURES
Full protective equipment, including self-contained breathing apparatus, is recommended. Cool containers of material exposed to heat with cold water spray.
Use of a water fog by trained personnel can avoid large amounts of water or water streams distributing the burning material over a large area, into sewers or storm drains.
Fight fires from a safe distance or protected area.
UNUSUAL FIRE AND EXPLOSION HAZARDS
Sealed containers exposed to elevated temperatures may rupture explosively due to polymerization. Vapors are heavier than air and may travel to source(s) of ignition
at or near ground or lower level(s). Susceptible to spontaneous heating. Considered a mild fire hazard because of low flash point. Peroxides and decomposition
products are flammable and can ignite with explosive force if confined.
200b
Sheet 1 of 2
SECTION V - HEALTH HAZARD DATA
PRIMARY ROUTES
OF ENTRY: X Inhalation X Skin Contact Eye Contact Ingestion
EFFECT OF OVEREXPOSURE
ACUTE:
Inhalation: Exposure may result in nausea, drowsiness, dizziness, headache and other CNS effects. Can cause irritation of eyes and nasal passages.
Skin Contact: Skin irritant. Potential skin sensitizer. Repeated or prolonged contact may result in skin irritation, contact dermatitis, rash, itching, swelling.
Eye Contact: Direct exposure may result in irritation with corneal or conjuctival inflammation.
Ingestion: Moderately toxic. Do not induce vomiting and obtain prompt medical attention.
CHRONIC:
Inhalation Toxicity described in animals exposed by inhalation include inflammation of the nasal cavity and changes in nasal sensory cells and
slight decrease in body weight.
Ingestion Toxicity described in animals exposed by ingestion include decreased body weight and increased relative kidney weight at high dose levels.
REPRODUCTIVE EFFECTS TERATOGENICITY MUTAGENICITY EMBRYOTOXICITY SENSITIZATION TO PRODUCT SYNERGISTIC PRODUCTS
N. AP. N. AP. POSS N. AP. N. AP. N. AV.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: This material may aggravate an existing dermatitis. Individuals with pre-existing diseases of the lungs,
liver or kidney may have increased susceptibility to the toxicity of excessive exposures.
EMERGENCY AND FIRST AID PROCEDURES
Inhalation: Remove patient to fresh air and if breathing stopped, give artificial respiration. If breathing is difficult, give oxygen. Contact physician
immediately.
Eye Contact: Immediately flush eyes with water for 15 minutes and contact a physician.
Skin Contact: Wash skin with soap and water for at least 15 minutes. If irritation develops, get medical attention.
Ingestion: Give 1 or 2 glasses of water or milk. Do not induce vomiting. Call physician or poison control center immediately.
SECTION VI - REACTIVITY
STABILITY UNSTABLE CONDITIONS TO AVOID: Exposure to fire, heat, sparks, open flame and other sources of ignition,
STABLE X direct sunlight or contact with oxidizing materials.
INCOMPATIBILITY ACTIVE OXYGEN CONTENT (Component "A") < 1% Not con-
(MATERIALS TO AVOID) Reducing and oxidizing agents. sidered an EPA hazardous Waste, Number D003, Reactive Waste
HAZARDOUS DECOMPOSITION PRODUCTS
This product gives out carbon monoxide (CO), carbon dioxide (CO? and smoke upon combustion. Generates heat when mixed with oxidizing materials.
HAZARDOUS MAY OCCUR X CONDITIONS TO AVOID
POLYMERIZATION WILL NOT OCCUR Keep away from heat Above 130?(55?sparks, open flame and other sources of ignition.
F C),
Do not store above 100?(38?br>
F C)
SECTION VII - SPILL OR LEAK PROCEDURES
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED
Eliminate all ignition sources. Avoid exposure of personnel to toxic concentration of vapor and guard against accidental fire and explosion. Contain liquid with sand, earth or
nonflammable absorbent material sweep and scoop up using non-sparking tools and transfer into steel drums for recovery or disposal. Prevent liquid from entering drains.
WASTE DISPOSAL METHOD
Follow local, State and Federal regulations. Material should not be allowed to drain into domestic sewer or storm drains. Consult authorities or disposal expert.
SECTION VIII - SPECIAL PROTECTION INFORMATION
RESPIRATORY PROTECTION (Specify type)
Atmospheric levels should be maintained below established exposure limits contained in Section II. For emergency conditions, use an approved positive pressure self-
contained breathing apparatus.
VENTILATION
Use only with adequate ventilation. Avoid use in close quarters or confined spaces. Open doors and/or windows to ensure airflow in volume and pattern to keep airborne
contaminants below applicable exposure limits found in Section II. Use local exhaust ventilation to remove airborne contaminants from employee breathing zone. Use only
explosion-proof ventilation equipment.
PROTECTIVE GLOVES EYE PROTECTION
PVA or rubber coated gloves Splashproof chemical goggles
OTHER PROTECTIVE EQUIPMENT AND HYGIENIC PRACTICES
Good industrial hygiene practices and impervious apron and a source of running water to flush or wash the eyes and skin in case of contact.
SECTION IX - SPECIAL PRECAUTIONS
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING
Store in a cool dark place below 70?(21?br>
F C). Keep away from all sources of heat, sparks, open flame and other sources of ignition. Close container after each use.
Ground containers when pouring. Use with adequate ventilation. Avoid contact with eyes, skin and clothing. Wash thoroughly after handling. Train employees on all special
handling procedures before they work with this product.
OTHER PRECAUTIONS
Follow all precautionary information given on container label, product bulletins and our solvent cementing literature. All material handling equipment should be
electrically grounded.
The information contained herein is based on data considered accurate. However, no warranty is expressed or implied regarding the accuracy of this data or the results to be obtained from the use
thereof.
200 + p
Sheet 2 of 2
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