Material Safety Data Sheet
Revision Date: 06/10/2005 Issue date: 06/10/2005
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Product name: Speedbonder H3000 Item No. : 83001_PART A
Product type: Acrylics Region: United States
Company address: Contact Information:
Henkel Corporation Telephone: 860.571.5100
1001 Trout Brook Crossing Emergency telephone: 860.571.5100
Rocky Hill, Connecticut 06067 Internet: www.loctite.com
2. COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous components % ACGIH TLV OSHA PEL OTHER
Methyl methacrylate 30-60 100 ppm STEL 100 ppm TWA 50 ppm
80-62-6 50 ppm TWA 410 mg/m?TWA
Polyethylene based rubber 10-30 None None None
Proprietary
Nepheline syenite 5-10 None None None
37244-96-5
Methacrylic acid 1-5 20 ppm TWA None None
79-41-4
2,6-Di-t-butyl-p-cresol 1-5 2 mg/m?TWA inhalable None None
128-37-0 fraction and vapor
Talc 0.1-1 2 mg/m?TWA respirable = 20 mppcf TWA 50 ppm
14807-96-6 fraction, particulate matter
containing no asbestos
and < 1% crystalline silica
3. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
HMIS:
Physical state: Liquid HEALTH: 2*
Color: White Opaque FLAMMABILITY: 3
Odor: Sharp PHYSICAL HAZARD: 1
Personal Protection: See Section 8
WARNING: FLAMMABLE LIQUID AND VAPOR.
CAUSES EYE, SKIN AND RESPIRATORY TRACT IRRITATION
HARMFUL IF SWALLOWED.
MAY CAUSE ALLERGIC SKIN REACTION.
Relevant routes of exposure: Skin, Inhalation, Eyes, Ingestion
Potential Health Effects
Inhalation: Vapors may cause headaches, nausea, dizziness and respiratory tract irritation.
Skin contact: Irritating to skin. May cause allergic skin reaction.
Eye contact: Vapors may irritate eyes. Contact with eyes will cause irritation.
Ingestion: May be harmful if swallowed. Ingestion causes irritation and effects similar to inhalation.
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Existing conditions aggravated by Eye, skin, and respiratory disorders.
exposure:
See Section 11 for additional toxicological information.
4. FIRST AID MEASURES
Inhalation: Remove to fresh air. If symptoms develop and persist, get medical attention.
Skin contact: Wash with soap and water. Remove contaminated clothing and shoes. Wash clothing before reuse.
Get medical attention if symptoms occur.
Eye contact: Flush with copious amounts of water, preferably, lukewarm water for at least 15 minutes, holding
eyelids open all the time. Get medical attention.
Ingestion: Do not induce vomiting. Keep individual calm. Obtain medical attention.
5. FIRE-FIGHTING MEASURES
Flash point: 14癈 (58癋) Setaflash Closed cup
Autoignition temperature: Not available
Flammable/Explosive limits-lower %: Not available
Flammable/Explosive limits-upper %: Not available
Extinguishing media: Foam, dry chemical or carbon dioxide.
Special fire fighting procedures: Wear self-contained breathing apparatus and full protective clothing, such as turn-out gear.
Unusual fire or explosion hazards: Vapors may accumulate in low or confined areas, travel considerable distance to source of ignition,
and flash back.
Hazardous combustion products: Oxides of carbon. Oxides of nitrogen. Hydrogen cyanide. Aldehydes. Toxic fumes. Acrid smoke and
fumes. Irritating organic vapors.
6. ACCIDENTAL RELEASE MEASURES
Environmental precautions: Prevent product from entering drains or open waters.
Clean-up methods: Remove all ignition sources. Ensure adequate ventilation. Soak up with inert absorbent. Store in a
closed container until ready for disposal.
7. HANDLING AND STORAGE
Handling: Avoid contact with eyes, skin and clothing. Avoid breathing vapor and mist. Wash thoroughly after
handling. During use and until all vapors are gone: Keep area ventilated - do not smoke; extinguish all
flames, pilot lights, and heaters; turn off stoves, electrical tools and appliances, and any other sources
of ignition. Make sure containers are properly grounded before use or transfer of material.
Storage: Keep in a cool, well ventilated area away from heat, sparks and open flame. Keep container tightly
closed until ready for use. For safe storage, store at or below 32癈 (90癋).
Incompatible products: Refer to Section 10.
For information on product shelf life contact Henkel Customer Service at (800) 243-4874.
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8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Engineering controls: Use local exhaust ventilation to maintain airborne concentrations below established exposure limits.
Respiratory protection: Use NIOSH approved respirator if there is potential to exceed exposure limit(s).
Skin protection: Chemical resistant, impermeable gloves. Nitrile gloves.
Eye/face protection: Safety goggles or safety glasses with side shields.
See Section 2 for exposure limits.
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical state: Liquid
Color: White Opaque
Odor: Sharp
Vapor pressure: 28 mmHg @20癈 (68?F)
pH: Not applicable
Boiling point/range: Greater than 100癈 (212癋)
Melting point/range: Not available
Specific gravity: 1.06
Vapor density: Greater than 1
Evaporation rate: Faster than ether
Solubility in water: Slight
Partition coefficient (n-octanol/water): Not available
VOC content: 9.01%; 95.5 grams/liter (Adhesive and Activator mixed)
10. STABILITY AND REACTIVITY
Stability: Stable.
Hazardous polymerization: May occur.
Hazardous decomposition products: Oxides of carbon. Oxides of nitrogen. Hydrogen cyanide. Aldehydes. Alcohols. Carbon tetrachloride.
Styrene. Acrolein. Acetophenone. Ethylbenzene. Cumene. 4-Vinyl cyclohexene. Phenols. Irritating
organic vapors. Toxic fumes. Smoke.
Incompatability: Oxidizing agents. Reducing agents. Acids. Bases.
Conditions to avoid: See "Handling and Storage" (Section 7) and "Incompatabilty" (Section 10). Do not mix in batches
greater than 100 grams (0.220 pounds) unless you plan to use immediately.
11. TOXICOLOGICAL INFORMATION
Carcinogen Status
Hazardous components NTP Carcinogen IARC Carcinogen OSHA Carcinogen
Methyl methacrylate No No No
80-62-6
Polyethylene based rubber No No No
Proprietary
Nepheline syenite No No No
37244-96-5
Methacrylic acid No No No
79-41-4
2,6-Di-t-butyl-p-cresol No No No
128-37-0
Talc No No No
14807-96-6
Literature Referenced Target Organ & Other Health Effects
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Hazardous components Health Effects/Target Organs
Methyl methacrylate Allergen, Irritant, Kidney, Liver, Nervous System, Respiratory, Mutagen
80-62-6
Polyethylene based rubber No Target Organs
Proprietary
Nepheline syenite No Target Organs
37244-96-5
Methacrylic acid Allergen, Corrosive, Irritant
79-41-4
2,6-Di-t-butyl-p-cresol Mutagen, Irritant
128-37-0
Talc Some evidence of carcinogenicity, Lung, Irritant
14807-96-6
12. ECOLOGICAL INFORMATION
Ecological information: Not available
13. DISPOSAL CONSIDERATIONS
Information provided is for unused product only.
Recommended method of disposal: Dispose of according to Federal, State and local governmental regulations.
EPA hazardous waste number: D001: Ignitable.
14. TRANSPORT INFORMATION
U.S. Department of Transportation Ground (49 CFR):
Proper shipping name: Adhesives
Hazard class or division: 3
Identification number: UN 1133
Packing group: II
Exceptions: Consumer Commodity ORM-D (Not more than 5 L)
Marine pollutant: None
International Air Transportation (ICAO/IATA):
Proper shipping name: Adhesives
Hazard class or division: 3
Identification number: UN 1133
Packing group: II
Exceptions: May Qualify as Consumer Commodity ID8000 (Not more than 500 ml)
WaterTransportation (IMO/IMDG):
Proper shipping name: Adhesives
Hazard class or division: 3
Identification number: UN1133
Packing group: II
Marine pollutant: None
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15. REGULATORY INFORMATION
United States Regulatory Information
TSCA 8 (b) Inventory Status: All components are listed or are exempt from listing on the Toxic Substances Control Act Inventory.
TSCA 12 (b) Export Notification: 4-Methoxyphenol (150-76-5).
CERCLA/SARA Section 302 EHS: None above reporting de minimus.
CERCLA/SARA Section 311/312: Immediate Health Hazard, Delayed Health Hazard, Fire
CERCLA/SARA 313: This product contains the following toxic chemicals subject to the reporting requirements of section 313
of the Emergency Planning and Community Right-To-Know Act of 1986 (40 CFR 372). Methyl
Methacrylate (CAS# 80-62-6) .
California Proposition 65: This product contains a chemical known to the State of California to cause cancer.
Canada Regulatory Information
CEPA DSL/NDSL Status: All components are listed on or are exempt from listing on the Domestic Substances List.
WHMIS hazard class: B.2, D.2.A, D.2.B
16. OTHER INFORMATION
This material safety data sheet contains changes from the previous version in sections: 14
Prepared by: Kyra Kozak Woods, Product Safety and Regulatory Affairs Specialist
DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel Corporation
does not assume responsibility for any results obtained by persons over whose methods Henkel Corporation has no control. It is the
user's responsibility to determine the suitability of Henkel's products or any production methods mentioned herein for a particular
purpose, and to adopt such precautions as may be advisable for the protection of property and persons against any hazards that may be
involved in the handling and use of any of Henkel Corporation's products. In light of the foregoing, Henkel Corporation specifically
disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular purpose, arising from sale
or use of Henkel Corporation's products. Henkel Corporation further disclaims any liability for consequential or incidental damages of
any kind, including lost profits.
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